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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Название: Chemistry of the Elements
Авторы: Greenwood N.N., Earnshaw A.
Аннотация: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Рубрика: Химия /
Статус предметного указателя: Готов указатель с номерами страниц
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Издание: second edition
Год издания: 1997
Количество страниц: 1340
Добавлена в каталог: 18.02.2007
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Предметный указатель
Rhodium, cyclopentadienyls 1143
Rhodium, discovery 1113
Rhodium, halides 1119—1121
Rhodium, optical resolution of 670
Rhodium, organometallic compounds 1139—1143
Rhodium, oxidation states 1117
Rhodium, oxides 1117 1118
Rhodium, production and uses 1114
Rhodium, reactivity of element 1116
Rhodium, relationship with other transition elements 1119 1295
Rhodium, sulfides 1118
Rhodocene 1143
Ribonucleic acids 476
Ring-laddering 99
Ring-stacking 99
RNA 476
Rochelle salt, discovery of ferroelectricity in 57 963
Roussin's salts 447 1094
Rubidium see also “Alkali metals”
Rubidium, abundance 70
Rubidium, compounds with oxygen 70—71
Rubidium, discovery 69
Rubridoxins 1098 1101 1102
Ruby 242 1003
Ruby, laser 1029
Russell — Saunders coupling 1242
Rusting of iron 1076
Ruthenates 1082
Ruthenium red 1091
Ruthenium, abundance 1071
Ruthenium, atomic and physical properties 1074—1076
Ruthenium, bipyridyl complexes and solar energy conversion 1096
Ruthenium, blue 1097
Ruthenium, carbidocarbonyls 1107—1108
Ruthenium, carbonyl 928 1104—1105
Ruthenium, carbonyl halides 1108
Ruthenium, carbonyl hydrides and carbonylate anions 1105—1108
Ruthenium, chalcogenides 1081
Ruthenium, complexes, +2 oxidation state 1091—1097
Ruthenium, complexes, +3 oxidation state 1088 1091
Ruthenium, complexes, +4 oxidation state 1086—1088
Ruthenium, complexes, +5 oxidation state 1086
Ruthenium, complexes, +6 oxidation state 1085
Ruthenium, complexes, +7 oxidation state 1085
Ruthenium, complexes, +8 oxidation state 1085
Ruthenium, complexes, with 702
Ruthenium, complexes, with S 668—670
Ruthenium, coordination numbers and stereochemistries 1078
Ruthenium, discovery 1070
Ruthenium, halides 1082—1084
Ruthenium, mixed valence compounds of 1097
Ruthenium, nitrosyl complexes 1097
Ruthenium, organometallic compounds 1104—1287
Ruthenium, oxidation states 1077 1078
Ruthenium, oxides 1079 1080 1255
Ruthenium, oxoanions 1081
Ruthenium, production and uses 1073
Ruthenium, reactivity of element 1075
Ruthenium, relationship to other transition elements 1075—1079
Ruthenium, standard reduction potentials 1077
Ruthenocene 937 1111
Rutherfordium 1281—1282
Rutile 955 961 1119
Rutile, structure type 962
S-N heterocycles incorporating a third element 736 737
s-process in stars 12
Salt (NaCl), history 790 792
Salt (NaCl), location of deposits 793 795
Salt (NaCl), uses in chemical industry 71 72
Saltpetre 407 (see also “Potassium nitrate”)
Samarium 1228 (see also “Lanthanide elements”)
Samarium, +2 oxidation state 1239 1240 1241 1248
Samarium, magnetic properties 1243
Scandium see also “Group 3 elements”
Scandium as eka-boron 944
Scandium, abundance 945
Scandium, complexes 950—953
Scandium, discovery 944 1228
Scandium, halides 949 950
Scandium, organometallic compounds 953
Scandium, oxide 949
Scandium, production 945
Scandium, salts with oxoanions 949
Scheelite 1003 1004 1169
Schoenites 1190
Scope 273
Scotch hearth process for roasting PbS 677
Seaborgium 1281—1283
Secondary valency 912
Selenates 781
Selenic acid, 782
Selenides 765 766
Selenites and diselenites 781
Selenium, abundance 748
Selenium, allotropy 761—753
Selenium, atomic and physical properties 753 754
Selenium, chemical reactivity 754—759
Selenium, coordination geometries 756—757
Selenium, dioxide 779 780
Selenium, discovery 747
Selenium, halide complexes 776
Selenium, halides 767 768 772
Selenium, hydride, 759 766—767
Selenium, nitride, 783
Selenium, organocompounds 759 786 787
Selenium, oxides 779—780
Selenium, oxoacids 781—783
Selenium, oxohalides 777 910
Selenium, polyatomic anions 762—765
Selenium, polyatomic cations, , 759—761
Selenium, production and uses 748 749
Selenium, pseudohalides 778 779 911
Selenium, redox properties 755
Selenium, sulfate 786
Selenium, sulfides 783
Selenium, toxicity 759
Selenium, trioxide 780
Selenocyanate ion 329 324—325
Selenocyanate ion, ambidentate properties 757 778
Selenopolythionates 783
Selenosulfates 783
Selenous acid, 781
Semiconductors, As, Sb and Bi chalcogenides 581 679
Semiconductors, III—V 221 255 258 549
Semiconductors, II—VI 255
Semiconductors, nonstoichiometric oxides 644
SHIP technique 1283
SI units inside back cover, conversion to non SI units 1293
Siderite 1071
Siderophile elements 648
Silaethenes 362
Silaneimines 361
Silanes, chemical reaction 338—339
Silanes, homocyclic polysilanes 363
Silanes, physical properties 337
Silanes, silyl haiides 339 340
Silanes, silyl potassium 339 340
Silanes, synthesis 337
Silanethiones 360
Silenes 362
Silica see also “Quartz” “Tridymite” “Cristobalite” “Coesite” “Stishovite”
Silica in transistor technology 383
Silica, fumed 345
Silica, gel 345
Silica, historical importance 328
Silica, hydrated 346
Silica, phase diagram 344
Silica, polymorphism 342—346
Silica, uses 345 346
Silica, vitreous 344
Silicate minerals 347—359
Silicate minerals, comparison with silicones 364
Silicates 328—330 347—359
Silicates with chain structures (metasilicates) 349 350
Silicates with discrete units 347—348
Silicates with framework structures 354—359
Silicates with layer structures 349—357
Silicates, disilicates 348
Silicates, metasilicates 348 350
Silicates, orthosilicates 347 348
Silicates, soluble (Na, K) 344 346
Silicides 336—337
Silicides, preparation 336
Silicides, structural units in 337
Silicomanganese 1041
Silicon, abundance and distribution 329
Silicon, atomic properties 330 371
Silicon, carbide 334
Silicon, chemical properties of 328 331 372
Silicon, coordination numbers 335
Silicon, dioxide see “Silica”
Silicon, double bonds to 362
Silicon, halides 340—342
Silicon, history 328
Silicon, hydrides see “Silanes”
Silicon, isolation 329 330
Silicon, nitride 360
Silicon, organic compounds 361—366
Silicon, physical properties 330 371 372
Silicon, purification 330
Silicon, sulfide 359
Silicones 364—366
Silicones, comparison with mineral silicates 364
Silicones, elastomers 365
Silicones, oils 365
Silicones, organotin, curing agents for 400
Silicones, resins 365
Silicones, synthesis 364 365
Silicones, uses 365
Siloxanes 364 366
Silver halides in photographic emulsions 1186
Silver, abundance 1174
Silver, acetylide 1180
Silver, alkenes and alkynes 1199
Silver, chalcogenides 1181—1182
Silver, complexes, +1 oxidation state 1195 1196
Silver, complexes, +2 oxidation state 1189
Silver, complexes, +3 oxidation state 1187 1188
Silver, halides 1183—1185
Silver, history 1173
Silver, nitrate, thermolysis of 469
Silver, organometallic compounds 1199—1200
Silver, oxides 1181
Silver, production and uses 1174
Silylamides 360 361
Singlet oxygen 607
Singlet oxygen, generation of 614
Singlet oxygen, reactions of 615
Skutterudite see “Cobalt arsenide”
Smalt 1113
Smaltite 1114 1145
Soapstone see “Talc”
Sodalite see “Ultramarines”
Sodanitre see “Chile saltpetre”
Sodide anion, 99
Sodium see also “Alkali metals”
Sodium chloride structure 80 242 983
Sodium hypochlorite, industrial uses 860
Sodium hypochlorite, Raschig synthesis of hydrazine using 427 428
Sodium, -alumina, structure and properties 249 250
Sodium, -alumina, use in Na/S batteries 678
Sodium, abundance 69
Sodium, arsenide 554
Sodium, azide 409 453 440
Sodium, bismuthate 554
Sodium, carbonate, hydrates of 88 89 104
Sodium, carbonate, production and uses of 89
Sodium, chlorate 862
Sodium, compounds with oxygen 84—86
Sodium, diphosphates 526 527
Sodium, discovery 68
Sodium, distribution 69 70
Sodium, dithionite 721 722
Sodium, hydroxide, production and uses of 72 89
Sodium, hypophosphite 513
Sodium, nitrate, thermolysis of 468 469
Sodium, nitroprusside 447
Sodium, nitroxylate 459
Sodium, orthonirate 471
Sodium, phosphates 512 521 523 524—525
Sodium, polysulfides 677—679 681 688
Sodium, polythionates, preparation and structure 717—718
Sodium, production of metal 71
Sodium, silicates, soluble 343 346
Sodium, solutions in liquid ammonia 77—79 393
Sodium, sulfate, production and uses of 89
Sodium, sulfide batteries 678 679
Sodium, thiosulfate, in photography 714 1186 1187
Sodium, tripolyphosphate 527 528
Solar energy conversion 1096
Solvay process 71
Solvay process, byproduct Ca from 112
Solvo-acids and bases in anhydrous 711
Solvo-acids and bases in liquid , 560
Solvo-acids and bases in liquid 831
Solvo-acids and bases in liquid 425
Solvo-acids and bases in liquid 457
Solvo-acids and bases in water 628
Soro-silicates 347—349
Spallation 14
Spectral sensitization of photographic emulsions 1186
Spectroscopic terms 1242
Sphalerite (Zinc blende) 649 1202
Sphalerite (Zinc blende), structure of 679 1209
Spiegeleisen 1041
Spin crossover see “Spin equilibria”
Spin equilibria in and compounds 1034
Spin equilibria in compounds 1096
Spin equilibria in compounds 1095
Spin equilibria in compounds 1066—1067
Spin equilibria in niobium halides 992
Spin quantum number 22
Spin-forbidden bands in compounds of 1089
Spin-forbidden bands in compounds of 1060
Spin-forbidden bands in compounds of 1158
Spin-orbit coupling in ions 1087
Spin-orbit coupling in actinide ions 1271
Spin-orbit coupling in lanthanide ions 1242
Spin-orbit coupling in octahedral 1158
Spin-orbit coupling in tetrahedral 1132
Spinel 109
Spinel structure in 1118
Spinel structure in (inverse) 1079
Spinel structure in 1048
Spinel structure in ferrites and garnets 1081
Spinel structure in ternary sulfides 681
Spinel structure, defect structure of - 243
Spinel structure, normal and inverse 247—249 1080
Spinel structure, valence disordered types 249
Spodumene 69 349
Square antiprismatic complexes 916
Square planar complexes 913
Square pyramidal complexes 914
Stability constants of coordination compound, factors affecting 908—911
Stability constants of coordination compound, overall 908
Stability constants of coordination compound, stepwise 908
Staging see “Graphite intercalation compound”
Standard reduction potentials 434
Standard reduction potentials, IUPAC sign convention 436
Stannates 354
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