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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Название: Chemistry of the Elements

Авторы: Greenwood N.N., Earnshaw A.

Аннотация:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: second edition

Год издания: 1997

Количество страниц: 1340

Добавлена в каталог: 18.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Rhodium, cyclopentadienyls      1143
Rhodium, discovery      1113
Rhodium, halides      1119—1121
Rhodium, optical resolution of $cis-[Rh{\{}{\eta}^{2}-(NH)_{2}SO_{2}{\}}_{2}(OH)_{2})_{2}]^{—}$      670
Rhodium, organometallic compounds      1139—1143
Rhodium, oxidation states      1117
Rhodium, oxides      1117 1118
Rhodium, production and uses      1114
Rhodium, reactivity of element      1116
Rhodium, relationship with other transition elements      1119 1295
Rhodium, sulfides      1118
Rhodocene      1143
Ribonucleic acids      476
Ring-laddering      99
Ring-stacking      99
RNA      476
Rochelle salt, discovery of ferroelectricity in      57 963
Roussin's salts      447 1094
Rubidium      see also “Alkali metals”
Rubidium, abundance      70
Rubidium, compounds with oxygen      70—71
Rubidium, discovery      69
Rubridoxins      1098 1101 1102
Ruby      242 1003
Ruby, laser      1029
Russell — Saunders coupling      1242
Rusting of iron      1076
Ruthenates      1082
Ruthenium red      1091
Ruthenium, abundance      1071
Ruthenium, atomic and physical properties      1074—1076
Ruthenium, bipyridyl complexes and solar energy conversion      1096
Ruthenium, blue      1097
Ruthenium, carbidocarbonyls      1107—1108
Ruthenium, carbonyl      928 1104—1105
Ruthenium, carbonyl halides      1108
Ruthenium, carbonyl hydrides and carbonylate anions      1105—1108
Ruthenium, chalcogenides      1081
Ruthenium, complexes, +2 oxidation state      1091—1097
Ruthenium, complexes, +3 oxidation state      1088 1091
Ruthenium, complexes, +4 oxidation state      1086—1088
Ruthenium, complexes, +5 oxidation state      1086
Ruthenium, complexes, +6 oxidation state      1085
Ruthenium, complexes, +7 oxidation state      1085
Ruthenium, complexes, +8 oxidation state      1085
Ruthenium, complexes, with $SO_{2}$      702
Ruthenium, complexes, with S      668—670
Ruthenium, coordination numbers and stereochemistries      1078
Ruthenium, discovery      1070
Ruthenium, halides      1082—1084
Ruthenium, mixed valence compounds of      1097
Ruthenium, nitrosyl complexes      1097
Ruthenium, organometallic compounds      1104—1287
Ruthenium, oxidation states      1077 1078
Ruthenium, oxides      1079 1080 1255
Ruthenium, oxoanions      1081
Ruthenium, production and uses      1073
Ruthenium, reactivity of element      1075
Ruthenium, relationship to other transition elements      1075—1079
Ruthenium, standard reduction potentials      1077
Ruthenocene      937 1111
Rutherfordium      1281—1282
Rutile      955 961 1119
Rutile, structure type      962
S-N heterocycles incorporating a third element      736 737
s-process in stars      12
Salt (NaCl), history      790 792
Salt (NaCl), location of deposits      793 795
Salt (NaCl), uses in chemical industry      71 72
Saltpetre      407 (see also “Potassium nitrate”)
Samarium      1228 (see also “Lanthanide elements”)
Samarium, +2 oxidation state      1239 1240 1241 1248
Samarium, magnetic properties      1243
Scandium      see also “Group 3 elements”
Scandium as eka-boron      944
Scandium, abundance      945
Scandium, complexes      950—953
Scandium, discovery      944 1228
Scandium, halides      949 950
Scandium, organometallic compounds      953
Scandium, oxide      949
Scandium, production      945
Scandium, salts with oxoanions      949
Scheelite      1003 1004 1169
Schoenites      1190
Scope      273
Scotch hearth process for roasting PbS      677
Seaborgium      1281—1283
Secondary valency      912
Selenates      781
Selenic acid, $H_{2}SeO_{4}$      782
Selenides      765 766
Selenites and diselenites      781
Selenium, abundance      748
Selenium, allotropy      761—753
Selenium, atomic and physical properties      753 754
Selenium, chemical reactivity      754—759
Selenium, coordination geometries      756—757
Selenium, dioxide      779 780
Selenium, discovery      747
Selenium, halide complexes      776
Selenium, halides      767 768 772
Selenium, hydride, $H_{2}Se$      759 766—767
Selenium, nitride, $Se_{4}N_{4}$      783
Selenium, organocompounds      759 786 787
Selenium, oxides      779—780
Selenium, oxoacids      781—783
Selenium, oxohalides      777 910
Selenium, polyatomic anions      762—765
Selenium, polyatomic cations, $Se_{n}^{2+}$, $[Te_{n}Se_{4—n}]^{2+}$      759—761
Selenium, production and uses      748 749
Selenium, pseudohalides      778 779 911
Selenium, redox properties      755
Selenium, sulfate      786
Selenium, sulfides      783
Selenium, toxicity      759
Selenium, trioxide      780
Selenocyanate ion      329 324—325
Selenocyanate ion, ambidentate properties      757 778
Selenopolythionates      783
Selenosulfates      783
Selenous acid, $H_{2}SeO_{3}$      781
Semiconductors, As, Sb and Bi chalcogenides      581 679
Semiconductors, III—V      221 255 258 549
Semiconductors, II—VI      255
Semiconductors, nonstoichiometric oxides      644
SHIP technique      1283
SI units inside back cover, conversion to non SI units      1293
Siderite      1071
Siderophile elements      648
Silaethenes      362
Silaneimines      361
Silanes, chemical reaction      338—339
Silanes, homocyclic polysilanes      363
Silanes, physical properties      337
Silanes, silyl haiides      339 340
Silanes, silyl potassium      339 340
Silanes, synthesis      337
Silanethiones      360
Silenes      362
Silica      see also “Quartz” “Tridymite” “Cristobalite” “Coesite” “Stishovite”
Silica in transistor technology      383
Silica, fumed      345
Silica, gel      345
Silica, historical importance      328
Silica, hydrated      346
Silica, phase diagram      344
Silica, polymorphism      342—346
Silica, uses      345 346
Silica, vitreous      344
Silicate minerals      347—359
Silicate minerals, comparison with silicones      364
Silicates      328—330 347—359
Silicates with chain structures (metasilicates)      349 350
Silicates with discrete units      347—348
Silicates with framework structures      354—359
Silicates with layer structures      349—357
Silicates, disilicates      348
Silicates, metasilicates      348 350
Silicates, orthosilicates      347 348
Silicates, soluble (Na, K)      344 346
Silicides      336—337
Silicides, preparation      336
Silicides, structural units in      337
Silicomanganese      1041
Silicon, abundance and distribution      329
Silicon, atomic properties      330 371
Silicon, carbide      334
Silicon, chemical properties of      328 331 372
Silicon, coordination numbers      335
Silicon, dioxide      see “Silica”
Silicon, double bonds to      362
Silicon, halides      340—342
Silicon, history      328
Silicon, hydrides      see “Silanes”
Silicon, isolation      329 330
Silicon, nitride      360
Silicon, organic compounds      361—366
Silicon, physical properties      330 371 372
Silicon, purification      330
Silicon, sulfide      359
Silicones      364—366
Silicones, comparison with mineral silicates      364
Silicones, elastomers      365
Silicones, oils      365
Silicones, organotin, curing agents for      400
Silicones, resins      365
Silicones, synthesis      364 365
Silicones, uses      365
Siloxanes      364 366
Silver halides in photographic emulsions      1186
Silver, abundance      1174
Silver, acetylide      1180
Silver, alkenes and alkynes      1199
Silver, chalcogenides      1181—1182
Silver, complexes, +1 oxidation state      1195 1196
Silver, complexes, +2 oxidation state      1189
Silver, complexes, +3 oxidation state      1187 1188
Silver, halides      1183—1185
Silver, history      1173
Silver, nitrate, thermolysis of      469
Silver, organometallic compounds      1199—1200
Silver, oxides      1181
Silver, production and uses      1174
Silylamides      360 361
Singlet oxygen      607
Singlet oxygen, generation of      614
Singlet oxygen, reactions of      615
Skutterudite      see “Cobalt arsenide”
Smalt      1113
Smaltite      1114 1145
Soapstone      see “Talc”
Sodalite      see “Ultramarines”
Sodanitre      see “Chile saltpetre”
Sodide anion, $Na^{—}$      99
Sodium      see also “Alkali metals”
Sodium chloride structure      80 242 983
Sodium hypochlorite, industrial uses      860
Sodium hypochlorite, Raschig synthesis of hydrazine using      427 428
Sodium, $\beta$-alumina, structure and properties      249 250
Sodium, $\beta$-alumina, use in Na/S batteries      678
Sodium, abundance      69
Sodium, arsenide      554
Sodium, azide      409 453 440
Sodium, bismuthate      554
Sodium, carbonate, hydrates of      88 89 104
Sodium, carbonate, production and uses of      89
Sodium, chlorate      862
Sodium, compounds with oxygen      84—86
Sodium, diphosphates      526 527
Sodium, discovery      68
Sodium, distribution      69 70
Sodium, dithionite      721 722
Sodium, hydroxide, production and uses of      72 89
Sodium, hypophosphite      513
Sodium, nitrate, thermolysis of      468 469
Sodium, nitroprusside      447
Sodium, nitroxylate      459
Sodium, orthonirate      471
Sodium, phosphates      512 521 523 524—525
Sodium, polysulfides      677—679 681 688
Sodium, polythionates, preparation and structure      717—718
Sodium, production of metal      71
Sodium, silicates, soluble      343 346
Sodium, solutions in liquid ammonia      77—79 393
Sodium, sulfate, production and uses of      89
Sodium, sulfide batteries      678 679
Sodium, thiosulfate, in photography      714 1186 1187
Sodium, tripolyphosphate      527 528
Solar energy conversion      1096
Solvay process      71
Solvay process, byproduct Ca from      112
Solvo-acids and bases in anhydrous $H_{2}SO_{4}$      711
Solvo-acids and bases in liquid $AsCl_{3}$, $SbCl_{3}$      560
Solvo-acids and bases in liquid $BrF_{3}$      831
Solvo-acids and bases in liquid $NH_{3}$      425
Solvo-acids and bases in liquid $N_{2}O_{4}$      457
Solvo-acids and bases in water      628
Soro-silicates      347—349
Spallation      14
Spectral sensitization of photographic emulsions      1186
Spectroscopic terms      1242
Sphalerite (Zinc blende)      649 1202
Sphalerite (Zinc blende), structure of      679 1209
Spiegeleisen      1041
Spin crossover      see “Spin equilibria”
Spin equilibria in $Cr^{II}$ and $Mo^{II}$ compounds      1034
Spin equilibria in $Fe^{III}$ compounds      1096
Spin equilibria in $Fe^{II}$ compounds      1095
Spin equilibria in $Mn^{II}$ compounds      1066—1067
Spin equilibria in niobium halides      992
Spin quantum number $m_{s}$      22
Spin-forbidden bands in compounds of $Fe^{III}$      1089
Spin-forbidden bands in compounds of $Mn^{III}$      1060
Spin-forbidden bands in compounds of $Ni^{II}$      1158
Spin-orbit coupling in $d^{4}$ ions      1087
Spin-orbit coupling in actinide ions      1271
Spin-orbit coupling in lanthanide ions      1242
Spin-orbit coupling in octahedral $Ni^{II}$      1158
Spin-orbit coupling in tetrahedral $Co^{II}$      1132
Spinel      109
Spinel structure in $Co_{3}O_{4}$      1118
Spinel structure in $Fe_{3}O_{4}$ (inverse)      1079
Spinel structure in $Mn_{3}O_{4}$      1048
Spinel structure in ferrites and garnets      1081
Spinel structure in ternary sulfides      681
Spinel structure, defect structure of $\gamma$-$Al_{2}O_{3}$      243
Spinel structure, normal and inverse      247—249 1080
Spinel structure, valence disordered types      249
Spodumene      69 349
Square antiprismatic complexes      916
Square planar complexes      913
Square pyramidal complexes      914
Stability constants of coordination compound, factors affecting      908—911
Stability constants of coordination compound, overall      908
Stability constants of coordination compound, stepwise      908
Staging      see “Graphite intercalation compound”
Standard reduction potentials      434
Standard reduction potentials, IUPAC sign convention      436
Stannates      354
1 2 3 4 5 6 7 8 9 10 11 12 13 14
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