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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Íàçâàíèå: Chemistry of the Elements

Àâòîðû: Greenwood N.N., Earnshaw A.

Àííîòàöèÿ:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: second edition

Ãîä èçäàíèÿ: 1997

Êîëè÷åñòâî ñòðàíèö: 1340

Äîáàâëåíà â êàòàëîã: 18.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Iridium, halides      1119—1121
Iridium, organometallic compounds      1139—1143
Iridium, oxidation states      1117
Iridium, oxides      1117 1118
Iridium, production and uses      1114
Iridium, reactivity of element      1116
Iridium, relationship with other transition elements      1116—1117
Iridium, sulfides      1117
Iron age      1070
Iron pyrites, reserves of      651
Iron pyrites, source of S      759—649
Iron pyrites, structure      555 557 680
Iron, abundance      1071
Iron, allyls      933
Iron, alums      1088
Iron, atomic and physical properties      1074
Iron, biochemistry of      1098
Iron, bis (cyclopentadienyl)      see “Ferrocene”
Iron, carbidocarbonyls      1107—1108
Iron, carbonyl halides      1108
Iron, carbonyl hydrides and carbonylate      1107
Iron, carbonyls      928 1071 1104
Iron, chalcogenides      1080 1081
Iron, complexes, +2 oxidation state      1091—1095
Iron, complexes, +3 oxidation state      1088—1091
Iron, complexes, lower oxidation states      1098
Iron, complexes, with $SO_{2}$      702
Iron, complexes, with S      666 671
Iron, complexes, with SO      696
Iron, cyclooctatetraene complexes      945
Iron, cyclopentadienyls      1109—1112 (see also “Ferrocene”)
Iron, dithiocarbamate complexes      673 1090
Iron, electronic spin states      1079
Iron, halides      1083—1085
Iron, history      1070 1072
Iron, mixed metal oxides (ferrites)      1081
Iron, organometallic compounds      937 1104—1112
Iron, oxidation states      1077 1078
Iron, oxides      1079 1080
Iron, oxoanions      1081 1121
Iron, production and uses      1071—1072
Iron, proteins      1098—1104
Iron, reactivity of element      1075
Iron, relationship with other transition elements      1077
Iron, standard reduction potentials      1077 1093 1101
Iron-sulfur proteins      1102—1104
Irving — Williams order      909
Isocyanates      319 322
Isocyanates as polyurethane intermediates      305
Isohypophosphoric acid [diphosphoric (III, $H_{4}P_{2}O_{6}$)]      512 515 516
Isomerism      918
Isomerism, cis-trans      919 1128
Isomerism, conformational      918
Isomerism, coordination      920
Isomerism, fac-mer      919
Isomerism, geometrical      919
Isomerism, ionization      920
Isomerism, ligand      921
Isomerism, linkage      920
Isomerism, optical      919
Isomerism, polymerization      921
Isomerism, polytopal      918
Isomerism, syn-anti      935
Isomerism, “classical-nonclassical” in organoboron structures      186
Isopolymolybdates      1175—1183
Isopolyniobates      987
Isopolytantalates      987
Isopolytungstates      1175—1183
Isopolyvanadates      1146—1150
Isotopes, definition of      22
Jahn — Teller effect      1021
Jahn — Teller effect in $Cu^{II}$      1190
Jahn — Teller effect in $Ti^{III}$      970
Jahn — Teller effect in high-spin $Cr^{II}$      1021 1032
Jahn — Teller effect in high-spin $Mn^{II}$      1049 1057
Jahn — Teller effect in low-spin $Co^{II}$      1133
Jasper      342
Joliotium      see “Dubnium”
Kaolinite      349 352—354 357
Karl Fischer reagent      627
Keatite      342 343
Keggin structure      1014 1015
Keiselguhr      342
Kinetic inertness of chromium(lll) complexes      1027
Kinetic inertness of cobalt(III) complexes      1123
Kirsanov reactions      535
Kraft cheese process      524
Kraft paper process      89
Kroll process      955 956
Krypton      see also “Noble gases”
Krypton, atomic and physical properties      801 890
Krypton, clathrates      893
Krypton, compounds of      903
Krypton, discovery      889
Kupfernickel      1144 1145
Kurchatovium      see “Rutherfordium”
Kurrol's salt      528—531
Landolt's chemical clock      864
Lanthanide contraction      27 1232 1234
Lanthanide elements      see also “Group 3 elements”
Lanthanide elements as products of nuclear fission      1228 1251 1260
Lanthanide elements, +2 oxidation state      1240 1248
Lanthanide elements, +4 oxidation state      1240 1244
Lanthanide elements, abundance      1229
Lanthanide elements, alkyls and aryls      249
Lanthanide elements, aquo ions      1245
Lanthanide elements, arsenides      555
Lanthanide elements, atomic and physical properties      1232—1235
Lanthanide elements, carbonyls      1238
Lanthanide elements, chalcogenides      679 1238 1239
Lanthanide elements, complexes      1244—1248
Lanthanide elements, coordination numbers and stereochemistries      1236 1237
Lanthanide elements, cyclopentadienides      1238
Lanthanide elements, group trends      1232—1237
Lanthanide elements, halides      1240—1242
Lanthanide elements, history      1228
Lanthanide elements, magnetic properties      1242—1244
Lanthanide elements, organometallic compounds      1248 1249
Lanthanide elements, oxides      1238 1239
Lanthanide elements, production and uses      1230—1232
Lanthanide elements, separation of individual elements      1424 1426—1428
Lanthanide elements, spectroscopic properties      1242—1244
Lanthanoid      see “Lanthanide elements”
Lanthanon      see “Lanthanide elements”
Lanthanum      see also “Group 3 elements” “Lanthanide
Lanthanum, abundance      945
Lanthanum, complexes      950—953
Lanthanum, discovery      944 1228
Lanthanum, halides      949—950
Lanthanum, organometallic compounds      953
Lanthanum, oxide      949
Lanthanum, production and uses      945—946
Lanthanum, salts with oxoanions      949
Lapiz lazuli      359
Laser, ruby      1029
Lattice defects, nonstoichiometry      643 (see also “Spinels (inverse)”)
Lattice energy      see also “Actinide elements”
Lattice energy of hypothetical compounds      83
Lattice energy, calculation of      82
Lattice energy, Lawrencium      1252 1262
Lead chamber process for $H_{2}SO_{4}$      646
Lead in antiquity      367
Lead, abundance      368
Lead, alloys      371
Lead, atomic properties      371
Lead, atomic weight variability      368
Lead, benzene complex with $Pb^{II}$      405
Lead, bis(cyclopentadienyl)      395 404
Lead, chalcogenides      389
Lead, chemical reactivity and group trends      435 373
Lead, cluster anions      374 393
Lead, cluster complexes      387 395
Lead, dihalides      375 381 382
Lead, dinitrate      388
Lead, halogeno complexes      382
Lead, hydride      375
Lead, hydroxo cluster cation      395
Lead, isolation and purification      369—371
Lead, metal-metal bonded compounds      392
Lead, mixed dihalides      382
Lead, monomeric $Pb(OAr)_{2}$      390
Lead, monoxide      383 384 386 395
Lead, nitrate, thermolysis of      456 469
Lead, nonstoichiometric oxides      385—387
Lead, organohydrides      375
Lead, organometallic compounds      402—405
Lead, oxides, nonstoichiometric      384—387
Lead, oxides, uses of      386
Lead, oxoacid salts      388
Lead, Pb-S-O system      677
Lead, physical properties      371 372
Lead, pigments      386 388
Lead, production statistics      369 370 371
Lead, pseudohalogen derivatives      389
Lead, radiogenic origin      368
Lead, retrafluoride      388
Lead, sulfate      388
Lead, tetraacetate      388
Lead, tetrahalides      375 381
Lead, toxicity      367 368
Lead, uses      371 386
Leblanc process for NaOH      71 790
Lewis acid (acceptor)      905 (see also “Donor-acceptor complexes” “Class-a
Lewis base (donor)      198 905 “Ligands”)
Lifschitz salts      1156 1160
Ligand field theory      922
Ligand polyhedral model      1105 1140
Ligands      see also “Class-a and class-b metals” “Hapticity” “Linkage “Synergic
Ligands, ambidentate      907 920
Ligands, chelating      906
Ligands, classification as “hard” and “soft”      326 909
Ligands, classification by number of donor atoms      906—907
Ligands, macrocyclic      907
Ligands, non-innocent      1055
Ligands, tripod      907
Ligands, “octopus”      99
Lime, production and uses of      119—121
Limestone, occurrence and uses      109 120—121 274
Limonite      1071 1146
Linde synthetic zeolites      358 359
Linkage isomerism of $SO_{2}$      702
Linkage isomerism of nitrite ion      463 464 920
Linkage isomerism of thiocyanate ion      326 920
Litharge      see “Lead monoxide”
Lithium      see also “Alkali metals”
Lithium compounds, industrial uses of      70
Lithium compounds, organometallics, synthesis of      102 103
Lithium compounds, organometallics, synthetic uses of      105—106
Lithium tetrahydroaluminate, synthetic reactions of      229
Lithium, abundance      69
Lithium, acetylide, synthetic use of      103
Lithium, alkyls and aryls      102—106
Lithium, aluminium hydride      228—229
Lithium, compounds with oxygen      84 85
Lithium, coordination chemistry of      90—94
Lithium, diagonal relationship with Mg      76 102
Lithium, discovery of      68
Lithium, methyl, bonding in      103
Lithium, methyl, structure of tetrameric cluster      103 104 113
Lithium, organometallic compounds      102—106
Lithium, production of metal      71 73
Lithium, reduction potential of      75 76
Lithium, stereochemistry of      91
Lithium, terrestrial distribution of      69
Lithium, variable atomic weight of      18
Lithium, “anomalous” properties of      75—76
Lithophile elements      648
Lodestone      1080
lodic acid, $HIO_{3}$      863 864 866
Loellingite structure      557
Lone pair, stereochemical influence      377 772 775—777
Lonsdaleite      274 276
Low-spin complexes of octahedral, $d^{4}$ ions      1087
Lutetium      1228 (see also “Lanthanide elements”)
Macrocyclic effect      911
Macrocyclic polyethers      see “Crown ethers”
Maddrell's salt      528—531
Madelung constant      83
Magma, crystallization of silicates from      329
Magneli-type phases of titanium oxides      959
Magneli-type phases of vanadium oxides      952
Magnesium      see also “Alkaline earth metals”
Magnesium in biochemical processes      125
Magnesium, alkyl alkoxides      133 136
Magnesium, complexes of      123—126
Magnesium, cyclopentadienyl      136
Magnesium, diagonal relationship with Li      76 102
Magnesium, dialkyls and diaryls      131—133
Magnesium, history of      108
Magnesium, organometallic compounds      131 (see also “Grignard reagents”)
Magnesium, porphyrin complexes of      see “Chlorophyl”
Magnesium, production and uses of      110 111
magnetic moment      see also “Spin equilibria”
Magnetic moment of low-spin, octahedral, $d^{4}$ ions      1087
Magnetic moment, orbital contribution to      1132 1158
Magnetic quantum number m      22
Magnetite, $Fe_{3}O_{4}$      1071
Magnetite, $Fe_{3}O_{4}$, inverse spinel structure      249 1080
Magnus's salt      1163
Malachite      1174
Malathion      509
Manganates      1050 1051 1222
Manganese      see also “Group 7 elements”
Manganese, abundance      1040
Manganese, allyl complexes      934
Manganese, biochemistry of      1061—1062
Manganese, carbonyls      928 1062—1064
Manganese, chalocogenides      1049
Manganese, complexes, +2 oxidation state      1058—1061
Manganese, complexes, +3 oxidation state      1057—1058
Manganese, complexes, +4 oxidation state      1056
Manganese, complexes, lower oxidation states      1061
Manganese, complexes, with $SO_{2}$      702
Manganese, complexes, with S      667—669
Manganese, cyclooctatetraene complex      943
Manganese, cyclopentadienyls      1065—1067
Manganese, dioxides      1045—1048
Manganese, dioxides, uses of      1048
Manganese, halides and oxohalides      1051
Manganese, nodules      1041
Manganese, organometallic compounds      935 943 1062—1069
Manganese, oxides      1045
Manganese, production and uses      1041—1043
Manganin      1042
Marcasite structure      555—557 680
Marcasite structure, mineral $FeS_{2}$      648
Marine acid      793
Marsh's test for As      558
Martensite      1075
Mass number of atom      22
Masurium      1040 (see also “Technetium”)
Matches      474 509
Meitnerium      1281 1283
Melamine      323
Mellitic acid      289
Melting points, influence of H bonding      54
Mendeleev's periodic table      20
Mendeleev, prediction of new elements      29 217
Mendelevium      1252 1262
Mercaptans, origin of name      1220
1 2 3 4 5 6 7 8 9 10 11 12 13 14
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