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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Iridium, halides 1119—1121
Iridium, organometallic compounds 1139—1143
Iridium, oxidation states 1117
Iridium, oxides 1117 1118
Iridium, production and uses 1114
Iridium, reactivity of element 1116
Iridium, relationship with other transition elements 1116—1117
Iridium, sulfides 1117
Iron age 1070
Iron pyrites, reserves of 651
Iron pyrites, source of S 759—649
Iron pyrites, structure 555 557 680
Iron, abundance 1071
Iron, allyls 933
Iron, alums 1088
Iron, atomic and physical properties 1074
Iron, biochemistry of 1098
Iron, bis (cyclopentadienyl) see “Ferrocene”
Iron, carbidocarbonyls 1107—1108
Iron, carbonyl halides 1108
Iron, carbonyl hydrides and carbonylate 1107
Iron, carbonyls 928 1071 1104
Iron, chalcogenides 1080 1081
Iron, complexes, +2 oxidation state 1091—1095
Iron, complexes, +3 oxidation state 1088—1091
Iron, complexes, lower oxidation states 1098
Iron, complexes, with 702
Iron, complexes, with S 666 671
Iron, complexes, with SO 696
Iron, cyclooctatetraene complexes 945
Iron, cyclopentadienyls 1109—1112 (see also “Ferrocene”)
Iron, dithiocarbamate complexes 673 1090
Iron, electronic spin states 1079
Iron, halides 1083—1085
Iron, history 1070 1072
Iron, mixed metal oxides (ferrites) 1081
Iron, organometallic compounds 937 1104—1112
Iron, oxidation states 1077 1078
Iron, oxides 1079 1080
Iron, oxoanions 1081 1121
Iron, production and uses 1071—1072
Iron, proteins 1098—1104
Iron, reactivity of element 1075
Iron, relationship with other transition elements 1077
Iron, standard reduction potentials 1077 1093 1101
Iron-sulfur proteins 1102—1104
Irving — Williams order 909
Isocyanates 319 322
Isocyanates as polyurethane intermediates 305
Isohypophosphoric acid [diphosphoric (III, )] 512 515 516
Isomerism 918
Isomerism, cis-trans 919 1128
Isomerism, conformational 918
Isomerism, coordination 920
Isomerism, fac-mer 919
Isomerism, geometrical 919
Isomerism, ionization 920
Isomerism, ligand 921
Isomerism, linkage 920
Isomerism, optical 919
Isomerism, polymerization 921
Isomerism, polytopal 918
Isomerism, syn-anti 935
Isomerism, “classical-nonclassical” in organoboron structures 186
Isopolymolybdates 1175—1183
Isopolyniobates 987
Isopolytantalates 987
Isopolytungstates 1175—1183
Isopolyvanadates 1146—1150
Isotopes, definition of 22
Jahn — Teller effect 1021
Jahn — Teller effect in 1190
Jahn — Teller effect in 970
Jahn — Teller effect in high-spin 1021 1032
Jahn — Teller effect in high-spin 1049 1057
Jahn — Teller effect in low-spin 1133
Jasper 342
Joliotium see “Dubnium”
Kaolinite 349 352—354 357
Karl Fischer reagent 627
Keatite 342 343
Keggin structure 1014 1015
Keiselguhr 342
Kinetic inertness of chromium(lll) complexes 1027
Kinetic inertness of cobalt(III) complexes 1123
Kirsanov reactions 535
Kraft cheese process 524
Kraft paper process 89
Kroll process 955 956
Krypton see also “Noble gases”
Krypton, atomic and physical properties 801 890
Krypton, clathrates 893
Krypton, compounds of 903
Krypton, discovery 889
Kupfernickel 1144 1145
Kurchatovium see “Rutherfordium”
Kurrol's salt 528—531
Landolt's chemical clock 864
Lanthanide contraction 27 1232 1234
Lanthanide elements see also “Group 3 elements”
Lanthanide elements as products of nuclear fission 1228 1251 1260
Lanthanide elements, +2 oxidation state 1240 1248
Lanthanide elements, +4 oxidation state 1240 1244
Lanthanide elements, abundance 1229
Lanthanide elements, alkyls and aryls 249
Lanthanide elements, aquo ions 1245
Lanthanide elements, arsenides 555
Lanthanide elements, atomic and physical properties 1232—1235
Lanthanide elements, carbonyls 1238
Lanthanide elements, chalcogenides 679 1238 1239
Lanthanide elements, complexes 1244—1248
Lanthanide elements, coordination numbers and stereochemistries 1236 1237
Lanthanide elements, cyclopentadienides 1238
Lanthanide elements, group trends 1232—1237
Lanthanide elements, halides 1240—1242
Lanthanide elements, history 1228
Lanthanide elements, magnetic properties 1242—1244
Lanthanide elements, organometallic compounds 1248 1249
Lanthanide elements, oxides 1238 1239
Lanthanide elements, production and uses 1230—1232
Lanthanide elements, separation of individual elements 1424 1426—1428
Lanthanide elements, spectroscopic properties 1242—1244
Lanthanoid see “Lanthanide elements”
Lanthanon see “Lanthanide elements”
Lanthanum see also “Group 3 elements” “Lanthanide
Lanthanum, abundance 945
Lanthanum, complexes 950—953
Lanthanum, discovery 944 1228
Lanthanum, halides 949—950
Lanthanum, organometallic compounds 953
Lanthanum, oxide 949
Lanthanum, production and uses 945—946
Lanthanum, salts with oxoanions 949
Lapiz lazuli 359
Laser, ruby 1029
Lattice defects, nonstoichiometry 643 (see also “Spinels (inverse)”)
Lattice energy see also “Actinide elements”
Lattice energy of hypothetical compounds 83
Lattice energy, calculation of 82
Lattice energy, Lawrencium 1252 1262
Lead chamber process for 646
Lead in antiquity 367
Lead, abundance 368
Lead, alloys 371
Lead, atomic properties 371
Lead, atomic weight variability 368
Lead, benzene complex with 405
Lead, bis(cyclopentadienyl) 395 404
Lead, chalcogenides 389
Lead, chemical reactivity and group trends 435 373
Lead, cluster anions 374 393
Lead, cluster complexes 387 395
Lead, dihalides 375 381 382
Lead, dinitrate 388
Lead, halogeno complexes 382
Lead, hydride 375
Lead, hydroxo cluster cation 395
Lead, isolation and purification 369—371
Lead, metal-metal bonded compounds 392
Lead, mixed dihalides 382
Lead, monomeric 390
Lead, monoxide 383 384 386 395
Lead, nitrate, thermolysis of 456 469
Lead, nonstoichiometric oxides 385—387
Lead, organohydrides 375
Lead, organometallic compounds 402—405
Lead, oxides, nonstoichiometric 384—387
Lead, oxides, uses of 386
Lead, oxoacid salts 388
Lead, Pb-S-O system 677
Lead, physical properties 371 372
Lead, pigments 386 388
Lead, production statistics 369 370 371
Lead, pseudohalogen derivatives 389
Lead, radiogenic origin 368
Lead, retrafluoride 388
Lead, sulfate 388
Lead, tetraacetate 388
Lead, tetrahalides 375 381
Lead, toxicity 367 368
Lead, uses 371 386
Leblanc process for NaOH 71 790
Lewis acid (acceptor) 905 (see also “Donor-acceptor complexes” “Class-a
Lewis base (donor) 198 905 “Ligands”)
Lifschitz salts 1156 1160
Ligand field theory 922
Ligand polyhedral model 1105 1140
Ligands see also “Class-a and class-b metals” “Hapticity” “Linkage “Synergic
Ligands, ambidentate 907 920
Ligands, chelating 906
Ligands, classification as “hard” and “soft” 326 909
Ligands, classification by number of donor atoms 906—907
Ligands, macrocyclic 907
Ligands, non-innocent 1055
Ligands, tripod 907
Ligands, “octopus” 99
Lime, production and uses of 119—121
Limestone, occurrence and uses 109 120—121 274
Limonite 1071 1146
Linde synthetic zeolites 358 359
Linkage isomerism of 702
Linkage isomerism of nitrite ion 463 464 920
Linkage isomerism of thiocyanate ion 326 920
Litharge see “Lead monoxide”
Lithium see also “Alkali metals”
Lithium compounds, industrial uses of 70
Lithium compounds, organometallics, synthesis of 102 103
Lithium compounds, organometallics, synthetic uses of 105—106
Lithium tetrahydroaluminate, synthetic reactions of 229
Lithium, abundance 69
Lithium, acetylide, synthetic use of 103
Lithium, alkyls and aryls 102—106
Lithium, aluminium hydride 228—229
Lithium, compounds with oxygen 84 85
Lithium, coordination chemistry of 90—94
Lithium, diagonal relationship with Mg 76 102
Lithium, discovery of 68
Lithium, methyl, bonding in 103
Lithium, methyl, structure of tetrameric cluster 103 104 113
Lithium, organometallic compounds 102—106
Lithium, production of metal 71 73
Lithium, reduction potential of 75 76
Lithium, stereochemistry of 91
Lithium, terrestrial distribution of 69
Lithium, variable atomic weight of 18
Lithium, “anomalous” properties of 75—76
Lithophile elements 648
Lodestone 1080
lodic acid, 863 864 866
Loellingite structure 557
Lone pair, stereochemical influence 377 772 775—777
Lonsdaleite 274 276
Low-spin complexes of octahedral, ions 1087
Lutetium 1228 (see also “Lanthanide elements”)
Macrocyclic effect 911
Macrocyclic polyethers see “Crown ethers”
Maddrell's salt 528—531
Madelung constant 83
Magma, crystallization of silicates from 329
Magneli-type phases of titanium oxides 959
Magneli-type phases of vanadium oxides 952
Magnesium see also “Alkaline earth metals”
Magnesium in biochemical processes 125
Magnesium, alkyl alkoxides 133 136
Magnesium, complexes of 123—126
Magnesium, cyclopentadienyl 136
Magnesium, diagonal relationship with Li 76 102
Magnesium, dialkyls and diaryls 131—133
Magnesium, history of 108
Magnesium, organometallic compounds 131 (see also “Grignard reagents”)
Magnesium, porphyrin complexes of see “Chlorophyl”
Magnesium, production and uses of 110 111
magnetic moment see also “Spin equilibria”
Magnetic moment of low-spin, octahedral, ions 1087
Magnetic moment, orbital contribution to 1132 1158
Magnetic quantum number m 22
Magnetite, 1071
Magnetite, , inverse spinel structure 249 1080
Magnus's salt 1163
Malachite 1174
Malathion 509
Manganates 1050 1051 1222
Manganese see also “Group 7 elements”
Manganese, abundance 1040
Manganese, allyl complexes 934
Manganese, biochemistry of 1061—1062
Manganese, carbonyls 928 1062—1064
Manganese, chalocogenides 1049
Manganese, complexes, +2 oxidation state 1058—1061
Manganese, complexes, +3 oxidation state 1057—1058
Manganese, complexes, +4 oxidation state 1056
Manganese, complexes, lower oxidation states 1061
Manganese, complexes, with 702
Manganese, complexes, with S 667—669
Manganese, cyclooctatetraene complex 943
Manganese, cyclopentadienyls 1065—1067
Manganese, dioxides 1045—1048
Manganese, dioxides, uses of 1048
Manganese, halides and oxohalides 1051
Manganese, nodules 1041
Manganese, organometallic compounds 935 943 1062—1069
Manganese, oxides 1045
Manganese, production and uses 1041—1043
Manganin 1042
Marcasite structure 555—557 680
Marcasite structure, mineral 648
Marine acid 793
Marsh's test for As 558
Martensite 1075
Mass number of atom 22
Masurium 1040 (see also “Technetium”)
Matches 474 509
Meitnerium 1281 1283
Melamine 323
Mellitic acid 289
Melting points, influence of H bonding 54
Mendeleev's periodic table 20
Mendeleev, prediction of new elements 29 217
Mendelevium 1252 1262
Mercaptans, origin of name 1220
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