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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Название: Chemistry of the Elements

Авторы: Greenwood N.N., Earnshaw A.

Аннотация:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: second edition

Год издания: 1997

Количество страниц: 1340

Добавлена в каталог: 18.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
$(SN)_{X}$ polymer, partially halogenated derivatives      728
$(SN)_{X}$ polymer, structure      727 728
$(SN)_{X}$ polymer, superconducting properties of      408 646 722 727 728
$(SN)_{X}$ polymer, synthesis      726 728
$NbS_{2}Cl_{2}$ structure      671
$NbS_{2}X_{2}$      667
$Se_{2}$ as ligand      758 759
$S_{11}N_{2}$      728—729
$S_{14+X}N_{2}$      728—729
$S_{2}N_{2}$      725 726
$S_{2}N_{2}$, polymerization to $(SN)_{X}$ qv      726—727
$S_{2}N_{2}$, preparation      727
$S_{2}N_{2}$, structure and bonding      726
$S_{4}N_{2}$      727 728
$S_{4}N_{4}$      408 646 722—725
$S_{4}N_{4}$, preparation      722
$S_{4}N_{4}$, reactions      725 730 734 736
$S_{4}N_{4}$, structure and bonding      856 857
$S_{5}N_{6}$      729
$XeF_2$      894—894
$XeF_2$, bonding      897 898
$XeF_2$, bonding compared with H bond      64
$XeF_4$      894—896
$XeF_6$      894 895 896 898 900 901
$\alpha$-Process in stars      11
$\beta$-alumina      see “Sodium $\beta$-alumina”
$\beta$-elimination reactions      926
$\gamma$-monoclinic sulfur      655
Absolute configuration, determination of      1125 1126
Abundance of elements, Tables of      1294
Acetylides      see “Carbides”
Acid strength of binary hydrides      49 51
Acid strength of binary hydrides of HF      815
Acid strength of binary hydrides of oxoacids (Pauling's rales)      50
Acidity function $H_0$ (Hammett)      51 52
Actinide contraction      1264
Actinide elements, abundance      1253
Actinide elements, alkyls and aryls      1278
Actinide elements, atomic and physical properties      1263
Actinide elements, carbonyls      1278
Actinide elements, chalcogenides      1471
Actinide elements, complexes, +1 oxidation state      1278
Actinide elements, complexes, +2 oxidation state      1278
Actinide elements, complexes, +3 oxidation state      1277
Actinide elements, complexes, +4 oxidation state      1275
Actinide elements, complexes, +5 oxidation state      1274
Actinide elements, complexes, +6 oxidation state      1273
Actinide elements, complexes, +7 oxidation state      1273
Actinide elements, coordination numbers and stereochemistries      1267
Actinide elements, cyclopentadienyls      1278
Actinide elements, discovery      1252
Actinide elements, group trends      1264—1267
Actinide elements, halides      1269—1272
Actinide elements, hydrides      64 1267
Actinide elements, lanthanide-like behaviour      1251 1264 1266
Actinide elements, magnetic properties      1272 1273
Actinide elements, mixed metal oxides      1269
Actinide elements, organometallic compounds      1278—1280
Actinide elements, oxidation states      1268
Actinide elements, oxides      1268—1269
Actinide elements, preparation of artificial elements      1252—1262
Actinide elements, problems of isolation and characterization      1251 1260 1262 1264
Actinide elements, redox behaviour      1265—1266
Actinide elements, separation from used nuclear fuels      1260—1262
Actinide elements, sepectroscopic properties      1272—1273
Actinium      see “Actinide elements” “Group
Actinium, abundance      945
Actinium, discovery      944
Actinium, radioactive decay series      1254
Actinoid      see “Actinide elements”
Actinon      see “Actinide elements”
Actinylions      1273 1274
Activated carbon      274 see
Adenine      61 62
Adenosine triphosphate (ATP) in life processes      528 1101
Adenosine triphosphate (ATP) in nitrogen fixation      1035 1036
Adenosine triphosphate (ATP) in phosphorus cycle      476
Adenosine triphosphate (ATP) in photosynthesis      125
Adenosine triphosphate (ATP), discovery in muscle fibre      474
Agate      342
Air      411 604 889 890
Alane      227
Albite      357
Alkali metals (Li, Na, K. Rb, Cs, Fr)      see individual metals: Li Na K Rb Cs Fr
Alkali metals (Li, Na, K. Rb, Cs, Fr), abundance      69
Alkali metals (Li, Na, K. Rb, Cs, Fr), alkoxides      87
Alkali metals (Li, Na, K. Rb, Cs, Fr), atomic properties      75
Alkali metals (Li, Na, K. Rb, Cs, Fr), biological systems containing      70 71 73 97
Alkali metals (Li, Na, K. Rb, Cs, Fr), carbonates      59—90
Alkali metals (Li, Na, K. Rb, Cs, Fr), chelated complexes of      112
Alkali metals (Li, Na, K. Rb, Cs, Fr), chemical reactivity of      76
Alkali metals (Li, Na, K. Rb, Cs, Fr), complexes of      90
Alkali metals (Li, Na, K. Rb, Cs, Fr), crown-ether complexes of      90
Alkali metals (Li, Na, K. Rb, Cs, Fr), cryptates of      90
Alkali metals (Li, Na, K. Rb, Cs, Fr), cyanates      324
Alkali metals (Li, Na, K. Rb, Cs, Fr), cyanides      321
Alkali metals (Li, Na, K. Rb, Cs, Fr), discovery of      68 69
Alkali metals (Li, Na, K. Rb, Cs, Fr), flame colours of      75
Alkali metals (Li, Na, K. Rb, Cs, Fr), halides imides, amides      99—102
Alkali metals (Li, Na, K. Rb, Cs, Fr), hydrides, reactions of      84
Alkali metals (Li, Na, K. Rb, Cs, Fr), hydrogen carbonates (bicarbonates)      88
Alkali metals (Li, Na, K. Rb, Cs, Fr), hydroxides      86 87
Alkali metals (Li, Na, K. Rb, Cs, Fr), imides, amides, bonding in      80
Alkali metals (Li, Na, K. Rb, Cs, Fr), imides, amides, properties of      82—83
Alkali metals (Li, Na, K. Rb, Cs, Fr), intercalation compounds with graphite      293 294
Alkali metals (Li, Na, K. Rb, Cs, Fr), intermetallic compounds with As, Sb, Bi      554 555
Alkali metals (Li, Na, K. Rb, Cs, Fr), isolation of      68 69
Alkali metals (Li, Na, K. Rb, Cs, Fr), nitrates      89
Alkali metals (Li, Na, K. Rb, Cs, Fr), nitrites      90
Alkali metals (Li, Na, K. Rb, Cs, Fr), organometallic compounds      106
Alkali metals (Li, Na, K. Rb, Cs, Fr), oxides      84
Alkali metals (Li, Na, K. Rb, Cs, Fr), oxoacid salts      87—90
Alkali metals (Li, Na, K. Rb, Cs, Fr), ozonides      85
Alkali metals (Li, Na, K. Rb, Cs, Fr), peroxides      84 85
Alkali metals (Li, Na, K. Rb, Cs, Fr), physical properties      74 75
Alkali metals (Li, Na, K. Rb, Cs, Fr), polysulfides      677—679 679 681
Alkali metals (Li, Na, K. Rb, Cs, Fr), reactions in liquid ammonia      78—79
Alkali metals (Li, Na, K. Rb, Cs, Fr), sesquioxides      85
Alkali metals (Li, Na, K. Rb, Cs, Fr), solubilites in liquid ammonia      78
Alkali metals (Li, Na, K. Rb, Cs, Fr), solutions in amines      79
Alkali metals (Li, Na, K. Rb, Cs, Fr), solutions in liquid ammonia      77—79
Alkali metals (Li, Na, K. Rb, Cs, Fr), solutions in polyetbers      79
Alkali metals (Li, Na, K. Rb, Cs, Fr), suboxides      84 85 86
Alkali metals (Li, Na, K. Rb, Cs, Fr), sulfides      679 681 682
Alkali metals (Li, Na, K. Rb, Cs, Fr), superoxides      84 85
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), abundance      108—110
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), atomic properties      111
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), chemical reactivity of      112
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), complexes of      122—127
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), halides, crystal structures of      117—118
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), halides, uses      118
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), hydride halides, MHX      119
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), hydrides      64 115
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), hydroxides      119—122
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), intermetallic compounds with As, Sb, Bi      554 555
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), organometallic compounds      127—138
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), oxides      119 121
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), oxoacid salts      122
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), ozonides      119
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), peroxides      119
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), physical properties      112
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), stereochemistry of      114
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), sulfides      679
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), superoxides      121
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), thermal stability of oxoacid salts      113
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), univalent compounds of      113 see Mg Ca Sr Ba Ra”
Alkene insertion reactions (Ziegler)      259 260
Alkene metathesis      1038
Alkene metathesis, polymerization (Ziegler — Natta)      240 241 972
Allotelluric acid      782
Allotropy      see individual elements: B C P S
Alnico steel      1114 1146
Aluminium      see “Group 13 elements”
Aluminium hydroxide, bayerile and gibbsite      243 245
Aluminium ion, hydration number of      604
Aluminium oxide hydroxide, diaspore and boehmite      243
Aluminium oxides      see ”Portland cement” “High-alumina
Aluminium oxides, "Saffil" fibres      244
Aluminium oxides, catalytic activity      244
Aluminium oxides, corundum      242 243
Aluminium oxides, structural classification      242 243
Aluminium trimethyl, $\mathrm{Al_2Me_6}$      291 258 259
Aluminium trimethyl, $\mathrm{Al_2Me_6}$, reactions with $\mathrm{MgMe_2}$      131
Aluminium, abundance      217
Aluminium, alloys      220
Aluminium, borohydride      169 228
Aluminium, chalcogenides      252
Aluminium, halide complexes      233—237
Aluminium, heterocyclic organo-AIN oligomers      265 266
Aluminium, history of      216
Aluminium, hydrides      227
Aluminium, hydrido complexes      228—231
Aluminium, III-V compounds      255 258
Aluminium, lower haiides AIX, AIX2      233
Aluminium, organometallic compounds      257—266
Aluminium, orthophosphale AIPO4      526
Aluminium, production      216. 218—226
Aluminium, ternary oxide phases      247—252
Aluminium, trialkyls and triaryls      257 258—260
Aluminium, trialkyls and triaryls in Ziegler — Natta catalysis      259—263 972
Aluminium, trialkyls and triaryls, dimeric structure of      253
Aluminium, trialkyls and triaryls, preparation      259
Aluminium, trichloride      233
Aluminium, trichloride adducts, structure of      234 235 672
Aluminium, trichloride, Friedel — Crafts activity of      234 236
Aluminium, trichloride, structure      234
Aluminium, trihalide complexes      233—237
Aluminium, uses      220
Alumino-silicates      see “Silicate minerals”
Alumino-thermic process      1003
Alums      216
Alums, chrome      1027
Alums, chromeiron      1088
Alums, chromerhodium      1129
Alums, chrometitanium      970
Alums, chromevanadium      993
Amalgamation process      1175 1201 1203
Americium      1252 1262 see
Amethyst      342
Amidopolyphosphates      506
Aminoboranes      209
Ammonia, adduct with NI3      441
Ammonia, chemical reactions      423 424 486
Ammonia, fertilizer applications      422
Ammonia, hydrazine, production from (Raschig synthesis)      427 428
Ammonia, industrial production      408 419
Ammonia, inversion frequency      423
Ammonia, inversion of, discovery      403
Ammonia, liquid, acid-base reactions in      425
Ammonia, liquid, alkali metal solutions in      77—79 392
Ammonia, liquid, ammonolysis of $\mathrm{PCl_5}$      535
Ammonia, liquid, amphoteric behaviour in      425
Ammonia, liquid, discovery of coloured metal solutions      408
Ammonia, liquid, H bonding in      52—55 422
Ammonia, liquid, metathesis reactions in      425
Ammonia, liquid, redox reactions in      425
Ammonia, liquid, solubility of compounds in      424 425
Ammonia, liquid, solvate formation in      425
Ammonia, liquid, solvent properties of      77—79 422 424—426
Ammonia, liquid, syntheses in      426 and passim
Ammonia, liquid, synthesis of metal cluster ions in      392 393
Ammonia, nitric acid production from      466 467
Ammonia, odour      420
Ammonia, physical properties      422 423
Ammonia, production statistics      420
Ammonia, synthesis of (Haber — Bosch)      408 420
Ammonia, uses of      422
Ammonium nitrate, explosive decomposition of      466 469
Ammonium nitrate, thermolysis of      443 469
Ammonium nitrite, decomposition to $\mathrm{N_2}$      409
Ammonium phosphates      524
Ammonium salts      422
Amosites      351
Amphiboles      351
Amphoteric behaviour of $\mathrm{SbCl_5}$      697
Amphoteric behaviour of $\mathrm{SF_4}$ (Lewis acid-base)      811
Amphoteric behaviour of $\mathrm{V_2O5}$      981
Amphoteric behaviour of Al and Ga      225
Amphoteric behaviour of ZnO      1209
Amphoteric behaviour, definition      225
Amphoteric cations      52
Anderson structure      1011
Andrieux's phosphide synthesis      489
Andrussow process for HCN      321
Angeli's salt      459 460
Angular functions      1285 1288 1289
Anorthite      357 358
Anti-knock additives      371 799
Anti-tumour activity of $\mathrm{Pt^{II}}$ complexes      1163
Antiferroelectrics      58
Antimonides      554
Antimonides, monious acid, $\mathrm{H_3Sb0_3}$      575 578
Antimonite esters      561
Antimony, abundance and distribution      548—549
Antimony, allotropes      551—552
Antimony, alloys      549 554
Antimony, aniino derivatives      561
Antimony, atomic properties      550
Antimony, catenation      583
Antimony, chalcogenides      581 582
Antimony, chemical reactivity      552 553 577
Antimony, cluster anions      553 588
Antimony, coordination geometries      554
Antimony, encapsulated      554
Antimony, halide complexes      564—570
Antimony, halides      558—566 see trihalides” “Antimony pentahalides” “Antimony oxide-halides” “Antimony mixed “Antimony halide
Antimony, halogeno-organic compounds”      596 598
Antimony, history      547
Antimony, hydride      551—558
Antimony, intennetallic compounds      see “Antimonides”
Antimony, metal-metal bonded clusters      583 588 589
Antimony, mixed halides      563 562
Antimony, organometaHic halides      596 597
Antimony, organometallic compounds      592 596—598
Antimony, oxidation state diagram      578
Antimony, oxide $\mathrm{Sb_2O_3}$      572—574
Antimony, oxide halides      570—572
Antimony, oxides and oxocompounds      572—578
Antimony, oxoacid salts of      591
Antimony, pentahalides      561—562 568—570 785
Antimony, pentaphenyl      545
Antimony, physical properties      551. 552
Antimony, selenium complex anions      581
Antimony, sulfide, $\mathrm{Sb_2S_3}$      547 549 580—581 648
Antimony, trichloride solvent system      560
Antimony, trifluoride as fluorinating agent      560
Antimony, trihalides      558—561 564—566 569
Antimony, uses      549
Antimony, volt-equivalent diagram      578
Antintonates      577
Apatites      109 475 480 525
Apatites, reduction to phosphides      489
Aquaregia      790 792 1179
Aragonite      109
Arenes as $\eta^6$ ligands      940
Argentite (silver glance)      1174
Argon      see “Noble gases”
Argon, atomic and physical properties      891
Argon, clathrates      893
Argon, discovery      889
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