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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Название: Chemistry of the Elements
Авторы: Greenwood N.N., Earnshaw A.
Аннотация: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Рубрика: Химия /
Статус предметного указателя: Готов указатель с номерами страниц
ed2k: ed2k stats
Издание: second edition
Год издания: 1997
Количество страниц: 1340
Добавлена в каталог: 18.02.2007
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Предметный указатель
polymer, partially halogenated derivatives 728
polymer, structure 727 728
polymer, superconducting properties of 408 646 722 727 728
polymer, synthesis 726 728
structure 671
667
as ligand 758 759
728—729
728—729
725 726
, polymerization to qv 726—727
, preparation 727
, structure and bonding 726
727 728
408 646 722—725
, preparation 722
, reactions 725 730 734 736
, structure and bonding 856 857
729
894—894
, bonding 897 898
, bonding compared with H bond 64
894—896
894 895 896 898 900 901
-Process in stars 11
-alumina see “Sodium -alumina”
-elimination reactions 926
-monoclinic sulfur 655
Absolute configuration, determination of 1125 1126
Abundance of elements, Tables of 1294
Acetylides see “Carbides”
Acid strength of binary hydrides 49 51
Acid strength of binary hydrides of HF 815
Acid strength of binary hydrides of oxoacids (Pauling's rales) 50
Acidity function (Hammett) 51 52
Actinide contraction 1264
Actinide elements, abundance 1253
Actinide elements, alkyls and aryls 1278
Actinide elements, atomic and physical properties 1263
Actinide elements, carbonyls 1278
Actinide elements, chalcogenides 1471
Actinide elements, complexes, +1 oxidation state 1278
Actinide elements, complexes, +2 oxidation state 1278
Actinide elements, complexes, +3 oxidation state 1277
Actinide elements, complexes, +4 oxidation state 1275
Actinide elements, complexes, +5 oxidation state 1274
Actinide elements, complexes, +6 oxidation state 1273
Actinide elements, complexes, +7 oxidation state 1273
Actinide elements, coordination numbers and stereochemistries 1267
Actinide elements, cyclopentadienyls 1278
Actinide elements, discovery 1252
Actinide elements, group trends 1264—1267
Actinide elements, halides 1269—1272
Actinide elements, hydrides 64 1267
Actinide elements, lanthanide-like behaviour 1251 1264 1266
Actinide elements, magnetic properties 1272 1273
Actinide elements, mixed metal oxides 1269
Actinide elements, organometallic compounds 1278—1280
Actinide elements, oxidation states 1268
Actinide elements, oxides 1268—1269
Actinide elements, preparation of artificial elements 1252—1262
Actinide elements, problems of isolation and characterization 1251 1260 1262 1264
Actinide elements, redox behaviour 1265—1266
Actinide elements, separation from used nuclear fuels 1260—1262
Actinide elements, sepectroscopic properties 1272—1273
Actinium see “Actinide elements” “Group
Actinium, abundance 945
Actinium, discovery 944
Actinium, radioactive decay series 1254
Actinoid see “Actinide elements”
Actinon see “Actinide elements”
Actinylions 1273 1274
Activated carbon 274 see
Adenine 61 62
Adenosine triphosphate (ATP) in life processes 528 1101
Adenosine triphosphate (ATP) in nitrogen fixation 1035 1036
Adenosine triphosphate (ATP) in phosphorus cycle 476
Adenosine triphosphate (ATP) in photosynthesis 125
Adenosine triphosphate (ATP), discovery in muscle fibre 474
Agate 342
Air 411 604 889 890
Alane 227
Albite 357
Alkali metals (Li, Na, K. Rb, Cs, Fr) see individual metals: Li Na K Rb Cs Fr
Alkali metals (Li, Na, K. Rb, Cs, Fr), abundance 69
Alkali metals (Li, Na, K. Rb, Cs, Fr), alkoxides 87
Alkali metals (Li, Na, K. Rb, Cs, Fr), atomic properties 75
Alkali metals (Li, Na, K. Rb, Cs, Fr), biological systems containing 70 71 73 97
Alkali metals (Li, Na, K. Rb, Cs, Fr), carbonates 59—90
Alkali metals (Li, Na, K. Rb, Cs, Fr), chelated complexes of 112
Alkali metals (Li, Na, K. Rb, Cs, Fr), chemical reactivity of 76
Alkali metals (Li, Na, K. Rb, Cs, Fr), complexes of 90
Alkali metals (Li, Na, K. Rb, Cs, Fr), crown-ether complexes of 90
Alkali metals (Li, Na, K. Rb, Cs, Fr), cryptates of 90
Alkali metals (Li, Na, K. Rb, Cs, Fr), cyanates 324
Alkali metals (Li, Na, K. Rb, Cs, Fr), cyanides 321
Alkali metals (Li, Na, K. Rb, Cs, Fr), discovery of 68 69
Alkali metals (Li, Na, K. Rb, Cs, Fr), flame colours of 75
Alkali metals (Li, Na, K. Rb, Cs, Fr), halides imides, amides 99—102
Alkali metals (Li, Na, K. Rb, Cs, Fr), hydrides, reactions of 84
Alkali metals (Li, Na, K. Rb, Cs, Fr), hydrogen carbonates (bicarbonates) 88
Alkali metals (Li, Na, K. Rb, Cs, Fr), hydroxides 86 87
Alkali metals (Li, Na, K. Rb, Cs, Fr), imides, amides, bonding in 80
Alkali metals (Li, Na, K. Rb, Cs, Fr), imides, amides, properties of 82—83
Alkali metals (Li, Na, K. Rb, Cs, Fr), intercalation compounds with graphite 293 294
Alkali metals (Li, Na, K. Rb, Cs, Fr), intermetallic compounds with As, Sb, Bi 554 555
Alkali metals (Li, Na, K. Rb, Cs, Fr), isolation of 68 69
Alkali metals (Li, Na, K. Rb, Cs, Fr), nitrates 89
Alkali metals (Li, Na, K. Rb, Cs, Fr), nitrites 90
Alkali metals (Li, Na, K. Rb, Cs, Fr), organometallic compounds 106
Alkali metals (Li, Na, K. Rb, Cs, Fr), oxides 84
Alkali metals (Li, Na, K. Rb, Cs, Fr), oxoacid salts 87—90
Alkali metals (Li, Na, K. Rb, Cs, Fr), ozonides 85
Alkali metals (Li, Na, K. Rb, Cs, Fr), peroxides 84 85
Alkali metals (Li, Na, K. Rb, Cs, Fr), physical properties 74 75
Alkali metals (Li, Na, K. Rb, Cs, Fr), polysulfides 677—679 679 681
Alkali metals (Li, Na, K. Rb, Cs, Fr), reactions in liquid ammonia 78—79
Alkali metals (Li, Na, K. Rb, Cs, Fr), sesquioxides 85
Alkali metals (Li, Na, K. Rb, Cs, Fr), solubilites in liquid ammonia 78
Alkali metals (Li, Na, K. Rb, Cs, Fr), solutions in amines 79
Alkali metals (Li, Na, K. Rb, Cs, Fr), solutions in liquid ammonia 77—79
Alkali metals (Li, Na, K. Rb, Cs, Fr), solutions in polyetbers 79
Alkali metals (Li, Na, K. Rb, Cs, Fr), suboxides 84 85 86
Alkali metals (Li, Na, K. Rb, Cs, Fr), sulfides 679 681 682
Alkali metals (Li, Na, K. Rb, Cs, Fr), superoxides 84 85
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), abundance 108—110
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), atomic properties 111
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), chemical reactivity of 112
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), complexes of 122—127
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), halides, crystal structures of 117—118
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), halides, uses 118
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), hydride halides, MHX 119
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), hydrides 64 115
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), hydroxides 119—122
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), intermetallic compounds with As, Sb, Bi 554 555
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), organometallic compounds 127—138
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), oxides 119 121
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), oxoacid salts 122
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), ozonides 119
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), peroxides 119
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), physical properties 112
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), stereochemistry of 114
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), sulfides 679
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), superoxides 121
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), thermal stability of oxoacid salts 113
Alkaline earth metals (Be, Mg, Ca, Sr, Ba, Ra), univalent compounds of 113 see Mg Ca Sr Ba Ra”
Alkene insertion reactions (Ziegler) 259 260
Alkene metathesis 1038
Alkene metathesis, polymerization (Ziegler — Natta) 240 241 972
Allotelluric acid 782
Allotropy see individual elements: B C P S
Alnico steel 1114 1146
Aluminium see “Group 13 elements”
Aluminium hydroxide, bayerile and gibbsite 243 245
Aluminium ion, hydration number of 604
Aluminium oxide hydroxide, diaspore and boehmite 243
Aluminium oxides see ”Portland cement” “High-alumina
Aluminium oxides, "Saffil" fibres 244
Aluminium oxides, catalytic activity 244
Aluminium oxides, corundum 242 243
Aluminium oxides, structural classification 242 243
Aluminium trimethyl, 291 258 259
Aluminium trimethyl, , reactions with 131
Aluminium, abundance 217
Aluminium, alloys 220
Aluminium, borohydride 169 228
Aluminium, chalcogenides 252
Aluminium, halide complexes 233—237
Aluminium, heterocyclic organo-AIN oligomers 265 266
Aluminium, history of 216
Aluminium, hydrides 227
Aluminium, hydrido complexes 228—231
Aluminium, III-V compounds 255 258
Aluminium, lower haiides AIX, AIX2 233
Aluminium, organometallic compounds 257—266
Aluminium, orthophosphale AIPO4 526
Aluminium, production 216. 218—226
Aluminium, ternary oxide phases 247—252
Aluminium, trialkyls and triaryls 257 258—260
Aluminium, trialkyls and triaryls in Ziegler — Natta catalysis 259—263 972
Aluminium, trialkyls and triaryls, dimeric structure of 253
Aluminium, trialkyls and triaryls, preparation 259
Aluminium, trichloride 233
Aluminium, trichloride adducts, structure of 234 235 672
Aluminium, trichloride, Friedel — Crafts activity of 234 236
Aluminium, trichloride, structure 234
Aluminium, trihalide complexes 233—237
Aluminium, uses 220
Alumino-silicates see “Silicate minerals”
Alumino-thermic process 1003
Alums 216
Alums, chrome 1027
Alums, chromeiron 1088
Alums, chromerhodium 1129
Alums, chrometitanium 970
Alums, chromevanadium 993
Amalgamation process 1175 1201 1203
Americium 1252 1262 see
Amethyst 342
Amidopolyphosphates 506
Aminoboranes 209
Ammonia, adduct with NI3 441
Ammonia, chemical reactions 423 424 486
Ammonia, fertilizer applications 422
Ammonia, hydrazine, production from (Raschig synthesis) 427 428
Ammonia, industrial production 408 419
Ammonia, inversion frequency 423
Ammonia, inversion of, discovery 403
Ammonia, liquid, acid-base reactions in 425
Ammonia, liquid, alkali metal solutions in 77—79 392
Ammonia, liquid, ammonolysis of 535
Ammonia, liquid, amphoteric behaviour in 425
Ammonia, liquid, discovery of coloured metal solutions 408
Ammonia, liquid, H bonding in 52—55 422
Ammonia, liquid, metathesis reactions in 425
Ammonia, liquid, redox reactions in 425
Ammonia, liquid, solubility of compounds in 424 425
Ammonia, liquid, solvate formation in 425
Ammonia, liquid, solvent properties of 77—79 422 424—426
Ammonia, liquid, syntheses in 426 and passim
Ammonia, liquid, synthesis of metal cluster ions in 392 393
Ammonia, nitric acid production from 466 467
Ammonia, odour 420
Ammonia, physical properties 422 423
Ammonia, production statistics 420
Ammonia, synthesis of (Haber — Bosch) 408 420
Ammonia, uses of 422
Ammonium nitrate, explosive decomposition of 466 469
Ammonium nitrate, thermolysis of 443 469
Ammonium nitrite, decomposition to 409
Ammonium phosphates 524
Ammonium salts 422
Amosites 351
Amphiboles 351
Amphoteric behaviour of 697
Amphoteric behaviour of (Lewis acid-base) 811
Amphoteric behaviour of 981
Amphoteric behaviour of Al and Ga 225
Amphoteric behaviour of ZnO 1209
Amphoteric behaviour, definition 225
Amphoteric cations 52
Anderson structure 1011
Andrieux's phosphide synthesis 489
Andrussow process for HCN 321
Angeli's salt 459 460
Angular functions 1285 1288 1289
Anorthite 357 358
Anti-knock additives 371 799
Anti-tumour activity of complexes 1163
Antiferroelectrics 58
Antimonides 554
Antimonides, monious acid, 575 578
Antimonite esters 561
Antimony, abundance and distribution 548—549
Antimony, allotropes 551—552
Antimony, alloys 549 554
Antimony, aniino derivatives 561
Antimony, atomic properties 550
Antimony, catenation 583
Antimony, chalcogenides 581 582
Antimony, chemical reactivity 552 553 577
Antimony, cluster anions 553 588
Antimony, coordination geometries 554
Antimony, encapsulated 554
Antimony, halide complexes 564—570
Antimony, halides 558—566 see trihalides” “Antimony pentahalides” “Antimony oxide-halides” “Antimony mixed “Antimony halide
Antimony, halogeno-organic compounds” 596 598
Antimony, history 547
Antimony, hydride 551—558
Antimony, intennetallic compounds see “Antimonides”
Antimony, metal-metal bonded clusters 583 588 589
Antimony, mixed halides 563 562
Antimony, organometaHic halides 596 597
Antimony, organometallic compounds 592 596—598
Antimony, oxidation state diagram 578
Antimony, oxide 572—574
Antimony, oxide halides 570—572
Antimony, oxides and oxocompounds 572—578
Antimony, oxoacid salts of 591
Antimony, pentahalides 561—562 568—570 785
Antimony, pentaphenyl 545
Antimony, physical properties 551. 552
Antimony, selenium complex anions 581
Antimony, sulfide, 547 549 580—581 648
Antimony, trichloride solvent system 560
Antimony, trifluoride as fluorinating agent 560
Antimony, trihalides 558—561 564—566 569
Antimony, uses 549
Antimony, volt-equivalent diagram 578
Antintonates 577
Apatites 109 475 480 525
Apatites, reduction to phosphides 489
Aquaregia 790 792 1179
Aragonite 109
Arenes as ligands 940
Argentite (silver glance) 1174
Argon see “Noble gases”
Argon, atomic and physical properties 891
Argon, clathrates 893
Argon, discovery 889
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