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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Название: Chemistry of the Elements
Авторы: Greenwood N.N., Earnshaw A.
Аннотация: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Рубрика: Химия /
Статус предметного указателя: Готов указатель с номерами страниц
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Издание: second edition
Год издания: 1997
Количество страниц: 1340
Добавлена в каталог: 18.02.2007
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Предметный указатель
Terbium 1229 (see also “Lanthanide elements”)
Terbium, +4 oxidation state 1237 1239
Tetracyanoethylene complexes, bonding in 931
Tetrafluoroethylene complexes, bonding in 932
Tetrafluoronitronium cation 439
Tetrahalogenophosphonium cations 499—500
Tetrahedral complexes 914
Tetrahydroaluminate ion, as ligand 231
Tetrahydroborates of Al 260 228 229
Tetrahydroborates of Ga 231
Tetrahydroborates of Zr and Hf 969
Tetrahydroborates, use in synthesis 166—168
Tetrametaphosphimate conformers 542
Tetrathionates, , preparation and structure 717 718
Thallium see also “Group 13 elements”
Thallium, abundance 217
Thallium, chalcogenides 252—254
Thallium, discovery 217
Thallium, halide complexes 240
Thallium, III—V compounds 255—258
Thallium, lower halides 241
Thallium, monohalides 241 242
Thallium, organometallic compounds 261 265
Thallium, oxides 246
Thallium, production 221
Thallium, similarity of to alkali metals 226
Thallium, trihalides 239
Thallium, triiodide 239 240
Thiazyl halides NSX 736—738
Thio-urea 317
Thioarsenites 580
Thiocarbonyl (CS) complexes 319
Thiocyanates 320 324
Thiocyanates as ambidentate ligands 326—327 907 920
Thioethers as ligands 673
Thionitrosyl (NS) complexes 453 454
Thionyl bromide 694
Thionyl chloride 693 694
Thionyl chloride, relation to and as ionizing solvent 694
Thionyl fluoride 688 693 694
Thionyl fluoride, mixed fluoride chloride 694
Thiophosphoryl, halides, 500 502
Thiophosphoryl, pseudohalides 501
Thioselenates 783
Thiosulfates, 705 714 715
Thiosulfates, , as ligands 714 715
Thiosulfates, , redox reactions in analysis 714 715
Thiosulfates, , structure 714 715
Thiosulfates, , use in photography 714 1186 1187
Thiosulfuric acid, 705 714
Thiosulfuric acid, , isomeric 714
Thiosulfuric acid, , redox interconversions in water 714
Thixotropy 356 968
Thorium see also “Actinide elements”
Thorium, abundance 1253
Thorium, bis(cyclooctatetraene) 942
Thorium, production and uses 1255
Thorium, radioactive decay series 1254
Thorium, redox behaviour 1265—1267
Thorium, use as a nuclear fuel 1258 1259
Thortveitite 348
Three-centre bonds in Al trialkyls and triaryls 258
Three-centre bonds in beryllium alkyls 127
Three-centre bonds in magnesium alkyls 127
Three-centre bonds, ion 37
Three-centre bonds, BBB bond 158
Three-centre bonds, BHB bond 64 151ff
Three-centre bonds, BHM bond 177
Thulium 1228 (see also “Lanthanide elements”)
Thymine 61 62
Thyroxine 794 795
Tin in antiquity 367 368
Tin, abundance 368
Tin, allotropes 373
Tin, alloys 370
Tin, atomic properties 371—372
Tin, bis(cyclopentadienyl) 402
Tin, chalcogenides 389
Tin, chemical reactivity and group trends 373
Tin, cluster anions 374 393
Tin, cluster complexes 383 395
Tin, compounds, use of 385 400
Tin, dibromide 380
Tin, dichloride 379 380
Tin, difluoride 379
Tin, dihalides 375 377—381
Tin, diiodide 380
Tin, dioxide 384 386 387 388 400
Tin, halogeno complexes 377—381 399
Tin, hydrides 375
Tin, hydroxo species 383 395
Tin, isolation and purification 369
Tin, metal-metal bonded compounds 391 396 399—404
Tin, monomeric 391
Tin, monoxide 377 383 387 388
Tin, nitrates 387
Tin, organometallic compounds 396—403
Tin, organometallic compounds, oligomerization 396
Tin, organometallic compounds, production statistics 400
Tin, organometallic compounds, toxic action 400
Tin, organometallic compounds, uses of 400
Tin, oxoacid salts 387 388
Tin, physical properties 371 373
Tin, production statistics 368 379
Tin, pseudohalogen derivatives 389
Tin, sulfide 389
Tin, tetrahalides 375 381 385
Tin, uses 370 385
Titanates 963—964
Titanates, ferroelectric properties 963
Titanium see also “Group 4 elements”
Titanium, abundance 955
Titanium, alkoxides 967
Titanium, alkyls and aryls 973
Titanium, alum 970
Titanium, bronzes 964
Titanium, carbonyls 973
Titanium, complexes, +3 oxidation state 969—971
Titanium, complexes, +4 oxidation state 967—969
Titanium, complexes, lower oxidation states 971—975
Titanium, complexes, with S 670 672
Titanium, compounds with oxoanions 966
Titanium, cyclooctatetraene complex 943
Titanium, cyclopentadienyls 973—975
Titanium, dioxide 959
Titanium, discovery 954
Titanium, estimation using 968
Titanium, halides 964—966
Titanium, mixed metal oxides (titanates) 963—964
Titanium, nonstoichiometric oxide phases 642 961
Titanium, organometallic compounds 972—975
Titanium, production and uses 955—956
Titanium, sulfides 962
Titanium, “sponge” 956
Tobermorite gel 252
Tolman's cone angle 494
Tooth enamel 477
Toothpastes, calcium compounds in 528
Trans-effect 1164
Trans-effect in complexes 1163 1164
Trans-effect in complexes 1127
Trans-effect in 1085
Trans-influence 1164 1165
Trans-influence in complexes 1165
Trans-influence in 1085
Transactinide elements 1280—1284
Transferrin 1103
Transistor action 331 332
Transistor action, chemistry of manufacture 332
Transistor action, discovery 331
Transition element ions, coordination chemistry 905—943
Transition elements see also “Transition element ions”
Transition elements, characteristic properties 905
Transition elements, definition of 905
Transuranium elements see also “Actinide elements”
Transuranium elements, discovery of 21 29 1252
Transuranium elements, extraction from reactor wastes 1262
Tri-capped trigonal prismatic complexes 917
Tricalcium aluminate, , structure 251 (see also “Portland cement”)
Tricalcium phosphate $[Ca_5(PO_4)_3OH] 524
Tridymite 343
Trigonal bipyramidal complexes 914
Trigonal prismatic complexes 915
Triperiodic acid see “Periodic acids”
Triphosphoric acid 512
Tris(dimethylamino)phosphine 533
Trithiocarbonates 317
Trithionates, , preparation and structure 717 718
Tritium, atomic properties 34
Tritium, discovery 33
Tritium, physical properties 35
Tritium, preparation of tritiated compounds 42
Tritium, radioactivity of 42
Tritium, synthesis 41
Tritium, uses as a tracer 42
Tropylium (cycloheptatrienyl) 942
Tungstates 1009—1016
Tungsten see also “Group 6 elements”
Tungsten, abundance 1003
Tungsten, benzene tricarbonyl 941
Tungsten, blues 1008
Tungsten, bronzes 1016
Tungsten, carbonyls 928 1037—1038
Tungsten, carbyne complexes 929
Tungsten, chalcogenides 1017—1018
Tungsten, complexes, +2 oxidation state 1031—1034
Tungsten, complexes, +3 oxidation state 1027—1031
Tungsten, complexes, +4 oxidation state 1025—1027
Tungsten, complexes, +5 oxidation state 1024 1025
Tungsten, complexes, +6 oxidation state 1023—1024
Tungsten, complexes, with S 670
Tungsten, cyclopentadienyl derivatives 1039
Tungsten, discovery 1002
Tungsten, halides and oxohalides 1019—1023
Tungsten, heteropolyacids and salts 1014—1016
Tungsten, hexacarbonyl 928 1038
Tungsten, isopolyacids and salts 1009—1014
Tungsten, nonstoichiometric oxides 1008
Tungsten, organometallic compounds 829 940 941 1037—1039
Tungsten, oxides 1007—1009
Tungsten, production and uses 1003
Tungstic acid 1010
Tungstocene 1038
Turnbull's blue 1094
Tutton salts of copper 1190
Tutton salts of vanadium 993
Type metal 547 549
Tyrian purple 790 791 793
u (ungerade), definition of 938
Ultramarines 354 359
Units, conversion factors 1293
Units, non-SI 1293
Universe, expansion of 2 5
Universe, origin of 1 2
Uranium see also “Actinide elements”
Uranium hexafluoride 1259 1269—1271
Uranium oxides, nonstoichiometry in 643
Uranium, abundance 1253
Uranium, bis(cyclooctatetraene) 942
Uranium, isotopic enrichment 1259
Uranium, production 1255
Uranium, radioactive decay series 1254
Uranium, redox behaviour 1265—1267
Uranium, variable atomic weight 17
Uranyl ion 1266 1269 1273—1274
Urea 305 311 323 422
Urea, hydrazine production from 429
Urea, phosphate 524
Urea, Wohler's synthesis 408
Valence bond theory of transition metal complexes 921-924
Valence, periodic trends in 27
Valinomycin 96
Van Arkel-de Boer process 956
Vanadates 981 983—987
Vanadium see also “Group 5 elements”
Vanadium, abundance 977
Vanadium, accumulation in blood of invertebrates 999
Vanadium, alkyls and aryls 999
Vanadium, biochemistry of 999
Vanadium, bronzes 987
Vanadium, carbonyl 928 1000
Vanadium, chalcogenides 988
Vanadium, complexes, +2 oxidation state 998
Vanadium, complexes, +3 oxidation state 996—998
Vanadium, complexes, +4 oxidation state 994—996
Vanadium, complexes, +5 oxidation state 994
Vanadium, compounds with oxoanions 993
Vanadium, cyclopentadienyls 939 1000
Vanadium, discovery 976
Vanadium, dithiolene complexes 674 675
Vanadium, halides and oxohalides 988—993
Vanadium, hexacarbonyl 828 928
Vanadium, isopolyacids and salts 983—987
Vanadium, nonstoichiometric oxides 982
Vanadium, organometallic compounds 927 939 941 942 997—1001
Vanadium, oxides 981—983
Vanadium, production and uses 977
Vanadocene 1000
Vanadyl compounds 982 995 996
Vaska's compound 615 616 1135—1137
Venus, atmosphere of 645 646
Vermiculite 349 357
Viscose rayon 317
Vitamin 1138 1139 1226
Volt equivalent, definition 434
Volt equivalent, diagrams 436—438
Vortmann's sulfate 1127
Vulcanization of rubber 646
Wackenroder's solution 717 719
Wacker process 1172
Wade's rules 161 162 181 553 590 591
Water supplies, treatment of 120
Water, acid-base behaviour 48 628
Water, aquo complexes 625
Water, autoprotolysis constant 48
Water, chemical properties 627
Water, clathrate hydrates 626 627
Water, distribution and availability 621—623
Water, H bonding in 52—55
Water, heavy (D2O) 623
Water, history 620
Water, hydrates 625—627
Water, hydrolysis reactions 627
Water, ice, polymorphism 624
Water, ionic product of 48
Water, Karl Fischer reagent for 627
Water, lattice water 625
Water, physical properties 623—625 754
Water, pollution of 622
Water, polywater 632 633
Water, purification and recycling 622 623
Water, self ionic dissociation of 48
Water, tritiated 623
Water, zeolitic water 625
Water-gas shift reaction 38 311 421 1106
Water-gas shift reaction in Haber — Bosch synthesis 421
White arsenic see “Arsenic oxide” “
Wilkinson's catalyst 43 1134—1135
Wilson's disease 1198
Wittig reaction 474 475 545
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