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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Название: Chemistry of the Elements

Авторы: Greenwood N.N., Earnshaw A.

Аннотация:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: second edition

Год издания: 1997

Количество страниц: 1340

Добавлена в каталог: 18.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Terbium      1229 (see also “Lanthanide elements”)
Terbium, +4 oxidation state      1237 1239
Tetracyanoethylene complexes, bonding in      931
Tetrafluoroethylene complexes, bonding in      932
Tetrafluoronitronium cation $NF_{4}^{+}$      439
Tetrahalogenophosphonium cations $PX_{4}^{+}$      499—500
Tetrahedral complexes      914
Tetrahydroaluminate ion, as ligand      231
Tetrahydroborates of Al      260 228 229
Tetrahydroborates of Ga      231
Tetrahydroborates of Zr and Hf      969
Tetrahydroborates, use in synthesis      166—168
Tetrametaphosphimate conformers      542
Tetrathionates, $S_4O_{6}^{2—}$, preparation and structure      717 718
Thallium      see also “Group 13 elements”
Thallium, abundance      217
Thallium, chalcogenides      252—254
Thallium, discovery      217
Thallium, halide complexes      240
Thallium, III—V compounds      255—258
Thallium, lower halides      241
Thallium, monohalides      241 242
Thallium, organometallic compounds      261 265
Thallium, oxides      246
Thallium, production      221
Thallium, similarity of $Tl^I$ to alkali metals      226
Thallium, trihalides      239
Thallium, triiodide $Tl^{I}[I_3]^{—}$      239 240
Thiazyl halides NSX      736—738
Thio-urea      317
Thioarsenites      580
Thiocarbonyl (CS) complexes      319
Thiocyanates      320 324
Thiocyanates as ambidentate ligands      326—327 907 920
Thioethers as ligands      673
Thionitrosyl (NS) complexes      453 454
Thionyl bromide      694
Thionyl chloride      693 694
Thionyl chloride, relation to $SO_2$ and $Me_2SO$ as ionizing solvent      694
Thionyl fluoride      688 693 694
Thionyl fluoride, mixed fluoride chloride      694
Thiophosphoryl, halides, $PSX_3$      500 502
Thiophosphoryl, pseudohalides      501
Thioselenates      783
Thiosulfates, $S_2O_{3}^{2—}$      705 714 715
Thiosulfates, $S_2O_{3}^{2—}$, as ligands      714 715
Thiosulfates, $S_2O_{3}^{2—}$, redox reactions in analysis      714 715
Thiosulfates, $S_2O_{3}^{2—}$, structure      714 715
Thiosulfates, $S_2O_{3}^{2—}$, use in photography      714 1186 1187
Thiosulfuric acid, $H_2S_2O_3$      705 714
Thiosulfuric acid, $H_2S_2O_3$, isomeric $H_2S.SO_3$      714
Thiosulfuric acid, $H_2S_2O_3$, redox interconversions in water      714
Thixotropy      356 968
Thorium      see also “Actinide elements”
Thorium, abundance      1253
Thorium, bis(cyclooctatetraene)      942
Thorium, production and uses      1255
Thorium, radioactive decay series      1254
Thorium, redox behaviour      1265—1267
Thorium, use as a nuclear fuel      1258 1259
Thortveitite      348
Three-centre bonds in Al trialkyls and triaryls      258
Three-centre bonds in beryllium alkyls      127
Three-centre bonds in magnesium alkyls      127
Three-centre bonds, $H_{3}^{+}$ ion      37
Three-centre bonds, BBB bond      158
Three-centre bonds, BHB bond      64 151ff
Three-centre bonds, BHM bond      177
Thulium      1228 (see also “Lanthanide elements”)
Thymine      61 62
Thyroxine      794 795
Tin in antiquity      367 368
Tin, abundance      368
Tin, allotropes      373
Tin, alloys      370
Tin, atomic properties      371—372
Tin, bis(cyclopentadienyl)      402
Tin, chalcogenides      389
Tin, chemical reactivity and group trends      373
Tin, cluster anions      374 393
Tin, cluster complexes      383 395
Tin, compounds, use of      385 400
Tin, dibromide      380
Tin, dichloride      379 380
Tin, difluoride      379
Tin, dihalides      375 377—381
Tin, diiodide      380
Tin, dioxide      384 386 387 388 400
Tin, halogeno complexes      377—381 399
Tin, hydrides      375
Tin, hydroxo species      383 395
Tin, isolation and purification      369
Tin, metal-metal bonded compounds      391 396 399—404
Tin, monomeric $Sn(OAr)_2$      391
Tin, monoxide      377 383 387 388
Tin, nitrates      387
Tin, organometallic compounds      396—403
Tin, organometallic compounds, oligomerization      396
Tin, organometallic compounds, production statistics      400
Tin, organometallic compounds, toxic action      400
Tin, organometallic compounds, uses of      400
Tin, oxoacid salts      387 388
Tin, physical properties      371 373
Tin, production statistics      368 379
Tin, pseudohalogen derivatives      389
Tin, sulfide      389
Tin, tetrahalides      375 381 385
Tin, uses      370 385
Titanates      963—964
Titanates, ferroelectric properties      963
Titanium      see also “Group 4 elements”
Titanium, abundance      955
Titanium, alkoxides      967
Titanium, alkyls and aryls      973
Titanium, alum      970
Titanium, bronzes      964
Titanium, carbonyls      973
Titanium, complexes, +3 oxidation state      969—971
Titanium, complexes, +4 oxidation state      967—969
Titanium, complexes, lower oxidation states      971—975
Titanium, complexes, with S      670 672
Titanium, compounds with oxoanions      966
Titanium, cyclooctatetraene complex      943
Titanium, cyclopentadienyls      973—975
Titanium, dioxide      959
Titanium, discovery      954
Titanium, estimation using $H_2O_2$      968
Titanium, halides      964—966
Titanium, mixed metal oxides (titanates)      963—964
Titanium, nonstoichiometric oxide phases      642 961
Titanium, organometallic compounds      972—975
Titanium, production and uses      955—956
Titanium, sulfides      962
Titanium, “sponge”      956
Tobermorite gel      252
Tolman's cone angle      494
Tooth enamel      477
Toothpastes, calcium compounds in      528
Trans-effect      1164
Trans-effect in $Pt^{II}$ complexes      1163 1164
Trans-effect in $Rh^{III}$ complexes      1127
Trans-effect in $[OsNCl_5]^{2—}$      1085
Trans-influence      1164 1165
Trans-influence in $Pt^{II}$ complexes      1165
Trans-influence in $[OsNCl_5]^{2—}$      1085
Transactinide elements      1280—1284
Transferrin      1103
Transistor action      331 332
Transistor action, chemistry of manufacture      332
Transistor action, discovery      331
Transition element ions, coordination chemistry      905—943
Transition elements      see also “Transition element ions”
Transition elements, characteristic properties      905
Transition elements, definition of      905
Transuranium elements      see also “Actinide elements”
Transuranium elements, discovery of      21 29 1252
Transuranium elements, extraction from reactor wastes      1262
Tri-capped trigonal prismatic complexes      917
Tricalcium aluminate, $Ca_3Al_2O_6$, structure      251 (see also “Portland cement”)
Tricalcium phosphate $[Ca_5(PO_4)_3OH]      524
Tridymite      343
Trigonal bipyramidal complexes      914
Trigonal prismatic complexes      915
Triperiodic acid      see “Periodic acids”
Triphosphoric acid $H_5P_3O_{10}$      512
Tris(dimethylamino)phosphine      533
Trithiocarbonates      317
Trithionates, $S_3O_{6}^{2—}$, preparation and structure      717 718
Tritium, atomic properties      34
Tritium, discovery      33
Tritium, physical properties      35
Tritium, preparation of tritiated compounds      42
Tritium, radioactivity of      42
Tritium, synthesis      41
Tritium, uses as a tracer      42
Tropylium (cycloheptatrienyl)      942
Tungstates      1009—1016
Tungsten      see also “Group 6 elements”
Tungsten, abundance      1003
Tungsten, benzene tricarbonyl      941
Tungsten, blues      1008
Tungsten, bronzes      1016
Tungsten, carbonyls      928 1037—1038
Tungsten, carbyne complexes      929
Tungsten, chalcogenides      1017—1018
Tungsten, complexes, +2 oxidation state      1031—1034
Tungsten, complexes, +3 oxidation state      1027—1031
Tungsten, complexes, +4 oxidation state      1025—1027
Tungsten, complexes, +5 oxidation state      1024 1025
Tungsten, complexes, +6 oxidation state      1023—1024
Tungsten, complexes, with S      670
Tungsten, cyclopentadienyl derivatives      1039
Tungsten, discovery      1002
Tungsten, halides and oxohalides      1019—1023
Tungsten, heteropolyacids and salts      1014—1016
Tungsten, hexacarbonyl      928 1038
Tungsten, isopolyacids and salts      1009—1014
Tungsten, nonstoichiometric oxides      1008
Tungsten, organometallic compounds      829 940 941 1037—1039
Tungsten, oxides      1007—1009
Tungsten, production and uses      1003
Tungstic acid      1010
Tungstocene      1038
Turnbull's blue      1094
Tutton salts of copper      1190
Tutton salts of vanadium      993
Type metal      547 549
Tyrian purple      790 791 793
u (ungerade), definition of      938
Ultramarines      354 359
Units, conversion factors      1293
Units, non-SI      1293
Universe, expansion of      2 5
Universe, origin of      1 2
Uranium      see also “Actinide elements”
Uranium hexafluoride      1259 1269—1271
Uranium oxides, nonstoichiometry in      643
Uranium, abundance      1253
Uranium, bis(cyclooctatetraene)      942
Uranium, isotopic enrichment      1259
Uranium, production      1255
Uranium, radioactive decay series      1254
Uranium, redox behaviour      1265—1267
Uranium, variable atomic weight      17
Uranyl ion      1266 1269 1273—1274
Urea      305 311 323 422
Urea, hydrazine production from      429
Urea, phosphate      524
Urea, Wohler's synthesis      408
Valence bond theory of transition metal complexes      921-924
Valence, periodic trends in      27
Valinomycin      96
Van Arkel-de Boer process      956
Vanadates      981 983—987
Vanadium      see also “Group 5 elements”
Vanadium, abundance      977
Vanadium, accumulation in blood of invertebrates      999
Vanadium, alkyls and aryls      999
Vanadium, biochemistry of      999
Vanadium, bronzes      987
Vanadium, carbonyl      928 1000
Vanadium, chalcogenides      988
Vanadium, complexes, +2 oxidation state      998
Vanadium, complexes, +3 oxidation state      996—998
Vanadium, complexes, +4 oxidation state      994—996
Vanadium, complexes, +5 oxidation state      994
Vanadium, compounds with oxoanions      993
Vanadium, cyclopentadienyls      939 1000
Vanadium, discovery      976
Vanadium, dithiolene complexes      674 675
Vanadium, halides and oxohalides      988—993
Vanadium, hexacarbonyl      828 928
Vanadium, isopolyacids and salts      983—987
Vanadium, nonstoichiometric oxides      982
Vanadium, organometallic compounds      927 939 941 942 997—1001
Vanadium, oxides      981—983
Vanadium, production and uses      977
Vanadocene      1000
Vanadyl compounds      982 995 996
Vaska's compound      615 616 1135—1137
Venus, atmosphere of      645 646
Vermiculite      349 357
Viscose rayon      317
Vitamin $B_{12}$      1138 1139 1226
Volt equivalent, definition      434
Volt equivalent, diagrams      436—438
Vortmann's sulfate      1127
Vulcanization of rubber      646
Wackenroder's solution      717 719
Wacker process      1172
Wade's rules      161 162 181 553 590 591
Water supplies, treatment of      120
Water, acid-base behaviour      48 628
Water, aquo complexes      625
Water, autoprotolysis constant      48
Water, chemical properties      627
Water, clathrate hydrates      626 627
Water, distribution and availability      621—623
Water, H bonding in      52—55
Water, heavy (D2O)      623
Water, history      620
Water, hydrates      625—627
Water, hydrolysis reactions      627
Water, ice, polymorphism      624
Water, ionic product of      48
Water, Karl Fischer reagent for      627
Water, lattice water      625
Water, physical properties      623—625 754
Water, pollution of      622
Water, polywater      632 633
Water, purification and recycling      622 623
Water, self ionic dissociation of      48
Water, tritiated $(T_2O)$      623
Water, zeolitic water      625
Water-gas shift reaction      38 311 421 1106
Water-gas shift reaction in Haber — Bosch $NH_3$ synthesis      421
White arsenic      see “Arsenic oxide”
Wilkinson's catalyst      43 1134—1135
Wilson's disease      1198
Wittig reaction      474 475 545
1 2 3 4 5 6 7 8 9 10 11 12 13 14
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