Главная    Ex Libris    Книги    Журналы    Статьи    Серии    Каталог    Wanted    Загрузка    ХудЛит    Справка    Поиск по индексам    Поиск    Форум   
blank
Авторизация

       
blank
Поиск по указателям

blank
blank
blank
Красота
blank
Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



Обсудите книгу на научном форуме



Нашли опечатку?
Выделите ее мышкой и нажмите Ctrl+Enter


Название: Chemistry of the Elements

Авторы: Greenwood N.N., Earnshaw A.

Аннотация:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: second edition

Год издания: 1997

Количество страниц: 1340

Добавлена в каталог: 18.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
blank
Предметный указатель
Cluster compounds, boron carbide      149
Cluster compounds, boron hydrides      151—180
Cluster compounds, carbido metal carhonyls      1107—1108
Cluster compounds, carboranes      181—189
Cluster compounds, cobalt, rhodium and indium carbonyls      928ff 1140—1143
Cluster compounds, cobalt-sulfur complexes      1119
Cluster compounds, gold phosphines      1197
Cluster compounds, iron, ruthenium and osmium carhonyls      928 1104—1108
Cluster compounds, lanthanide halides      1242
Cluster compounds, lithium alkyls      103—105
Cluster compounds, lithium imides      100
Cluster compounds, mercury-containing      1120
Cluster compounds, metal borides      148 149—151
Cluster compounds, metallocarboranes      189—195
Cluster compounds, metallohoranes      171—173 178
Cluster compounds, molyhdenum and tungsten dihalides      1022
Cluster compounds, nickel, palladium and platinum carbonyls      1168—1171
Cluster compounds, niobium and tantalum halides      991
Cluster compounds, of phosphorus, arsenic, antimony and bismuth      563 588
Cluster compounds, of tellurium      761 764
Cluster compounds, rhenium alkyls      1068 1069
Cluster compounds, rhenium carbidocarbonyls      1065
Cluster compounds, scandium halides      950
Cluster compounds, stabilization by encapsulated heteroatoms      950 966 992 1065 1107 1141. 1242
Cluster compounds, technethun and rhenium chalcogenides      1049
Cluster compounds, tungsten and molyhdenum halides      1021—1022
Cluster compounds, zirconium halides      965
Cobalt, abundance      JII3
Cobalt, allyl complexes      933
Cobalt, arsenide      555 556
Cobalt, atomic and physical properties      1115—1116
Cobalt, biochemistry of      1138 1139 1322
Cobalt, carbidocarbonyls      1141—1142
Cobalt, carbonyls      928 929 1140—1143
Cobalt, complexes, +1 oxidation state      1133
Cobalt, complexes, +2 oxidation state      1129—1133
Cobalt, complexes, +3 oxidation state      1122—1129
Cobalt, complexes, +4 oxidation state      1121
Cobalt, complexes, +5 oxidation state      1121
Cobalt, complexes, lower oxidation states      1137
Cobalt, complexes, with $\mathrm{SO_2}$      701
Cobalt, complexes, with S      666—669
Cobalt, coordination numbers and stereochemistries      1117
Cobalt, cyclobutadiene complex      936
Cobalt, cyclooctatetraene complexes      942
Cobalt, cyclopenladienyls      1143
Cobalt, dithiolene complexes, redox series      676
Cobalt, halides      1119—1121
Cobalt, importance of $\mathrm{CO^{III}}$ in early coordination chemistry      914 1122 1123 1302
Cobalt, nitrate (anhydrous)      469
Cobalt, nitrato complexes      469 470 543
Cobalt, optical resolution of $mathrm{[Co{(\mu-OH)_2Co(NH_3)_4}_3}      670 915
Cobalt, organomelallic compounds      1139—1143
Cobalt, oxidation states      1117
Cobalt, oxides      1117—1119
Cobalt, oxoanions      1120 1121
Cobalt, production and uses      1114 1115
Cobalt, reactivity of element      1116
Cobalt, relationship with other transition elements      1116—1117
Cobalt, standard reduction potentials      1122
Cobalt, sulfides      1118
Cobaltile (cobalt glance)      1114
Cobaltocene      939 1143
Coesite      342 343
Coinage metals (Cu, Ag, Au)      1173 see
Coke      274 see
Coke, historical importance is steel making      1070 1072
Cold fusion (nuclear)      1280 1283—1284
Columbite      977
Columhium      976 see
Combustion      600—602 612
Complexometric titration of $\mathrm{Bi^{III}}$ with EDTA      577
Contact process      see “Sulfuric acid manufacture”
Cooper pairs      1183
Cooperativity      11000 1199
Coordinate bond      198 921 see
Coordination number      912
Coordination number, above nine      917
Coordination number, eight      916
Coordination number, five      914
Coordination number, four      913
Coordination number, nine      917
Coordination number, seven      916
Coordination number, six      916
Coordination number, three      913
Coordination number, two      945
Copper oxide $\mathrm{Cu_{2-x}O}$, nonstoichiometry in      642
Copper, abundance      1174
Copper, acetylide      1180
Copper, alkenes and alkynes      1199
Copper, alkyls and aryls      1200
Copper, biochemistry of      1197
Copper, carhoxylates      1192—1193
Copper, chalcogenides      1181—1182
Copper, complexes, +1 oxidation state      1194—1197
Copper, complexes, +2 oxidation stale      1189-1194
Copper, complexes, +3 oxidation stale      1187
Copper, Cu-S-O system      677
Copper, halides      1183—1187
Copper, history      1173
Copper, nitrate, structure of      471 1190
Copper, nitrato complexes      469 470 471 544
Copper, organometallic compounds      925 1199 1200
Copper, oxides      1181
Copper, production and uses      1174 1175 see
Corundum      see “Aluminium oxides”
Cosmic black-body radiation      2
Cossee “mechanism      261
Cotton effect      1125
Creutz — Taube anion      1097
Cristobalite      343 344
Critical mass      1256 1257 1261
Crocidolite      351
Crocoite      1003
Crown ethers      96 97
Crown ethers, complexes with alkali metals      95 97
Crown ethers, complexes with alkaline earth metals      124
Crown ethers, “hole sizes” of      96
Crown ethers, “triple-decker” complex Cryolite      219
Crypt, complexes with alkali metals      97 393 394
Crypt, complexes with alkaline earth metals      125
Crypt, molecular structure of      98
Crystal field splittings      922—923
Crystal field stabilization energy      1131
Crystal field theory      922
Crystal field, octahedral      922
Crystal field, strong      923
Crystal field, weak      922
Cuhic, eight coordination      916 1275 1480
Cupellation      1173
Cuprite      1174
Curium      1252 1262 see
Cyanamide      319
Cyanamide, industrial production      324
Cyanates      320 324
Cyanates, as ligands      325
Cyanide ion as ligand      322 926
Cyanide process      1175 1196
Cyanogen      319—321
Cyanogen, halides      320 323 340
Cyanuric acid      305
Cyanuric compounds      320 323
Cyclo polyphosphoric acids      529 see
Cyclo-$\mathrm{S_6}$ ($\varepsilon$-sulfur)      656
Cyclo-$\mathrm{S_7}$      656—657
Cyclo-$\mathrm{S_8}$ ($\alpha$), crystal and molecular structure      654
Cyclo-$\mathrm{S_8}$ ($\alpha$), physical properties      654—656
Cyclo-$\mathrm{S_8}$ ($\alpha$), polymerization at $\lambda$ point      660
Cyclo-$\mathrm{S_8}$ ($\alpha$), solubility      654
Cyclo-$\mathrm{S_8}$ ($\alpha$), transition $\alpha-S_8 \rightleftharpoons \beta-\mathrm{S_8}$      654
Cyclo-$\mathrm{S_8}$ ($\alpha$), vapour pressure      660
Cyclo-polyphosphates      529—531
Cyclo-silicates      347 349
Cyclobutadiene as $\eta^4$ ligand      935—938
Cycloheptatrienyl as $\eta^7$ ligand      941
Cyclometaphosphoric acids $\mathrm{(HРo_3)_n}      512 see “Cydo-poly-phospates”
Cycloocta-l,5-diene (cod) as ligand      932
Cyclooctatetraene as $\eta^8$ ligand      942
Cyclooctatetraene as $\eta^8$ ligand, as $\eta^2$, $\eta^4$, $\eta^6$ etc., ligand      943
Cyclopentadienyl, as $\eta^1$ ligand      940 see individual
Cyclopentadienyl, as $\eta^5$ ligand      937—940
Cyclophosphazanes      533 534
Cycto-$\mathrm{S_9}$      657
Cycto-$\mathrm{S_{10}}$      656—657
Cycto-$\mathrm{S_{11}}$      657
Cycto-$\mathrm{S_{12}}$      656—658
Cycto-$\mathrm{S_{13}}$      656 658 778
Cycto-$\mathrm{S_{14}}$      656 659
Cydo-polyarsanes      584-586
Cydometaphosphimic acids      541 542
Cytochrames      1095 1101 1198 1279
Cytosine      61. 62
Cаtеnа-polyarsanes      584—587
d orbitals      922—923 1285—1289
d orbitals, splitting by crystal fields      922—923
d-block contraction      27 222 251 561. 1234
Dalton's atomic theory      509
Dalton's law of multiple proportions      509
Dawson structure      1015
Decaborane, $\mathrm{B_{10}H_{14}}$      159 163
Decaborane, $\mathrm{B_{10}H_{14}}$, adduct formation      176
Decaborane, $\mathrm{B_{10}H_{14}}$, Bronsted acidity      175
Decaborane, $\mathrm{B_{10}H_{14}}$, chemical reactions      175—177
Decaborane, $\mathrm{B_{10}H_{14}}$, preparations      187
Decaborane, $\mathrm{B_{10}H_{14}}$, structure      175
Degussa process for HCN      321
Density of the elements, periodic trends in      24
Denticity      906
Deoxyribonucleic acids      476
Detergents, polyphosphates in      474 477
Detergents, sodium tripolyphosphate in      528
Deuterium, atomic properties      34
Deuterium, diwovery      32
Deuterium, ortho- and para-      36
Deuterium, physical properties      35
Deuterium, preparation      39
Dewar — Chatt — Duncanson theory      931
Diagonal relationship      27
Diagonal relationship, B and Si      202 347
Diagonal relationship, Be and Al      107
Diagonal relationship, Li and Mg      76 102 1113
Diagonal relationship, N and S      722
Diamond, chemical properties      278
Diamond, occurrence and distribution      271 272
Diamond, physical properties      278
Diamond, production and uses      272
Diarsane, $\mathrm{As_2H_4}$      583 see
Diaspore      243
Diatomaceous earth      342
Diatomic molecules (homonuclear), bond dissociation, energies of      584
Diazotization of aromatic amines      463
Dibenzenechromium      940 1039 see
Diborane, $\mathrm{B_2H_6}$      154 159
Diborane, $\mathrm{B_2H_6}$, chemical reactions      163—170
Diborane, $\mathrm{B_2H_6}$, cleavage reactions      165
Diborane, $\mathrm{B_2H_6}$, hydroboration reactions      166 183
Diborane, $\mathrm{B_2H_6}$, preparation      164
Diborane, $\mathrm{B_2H_6}$, pyrolysis      164
Dibromonium cation $\mathrm{Br_2^+}$, compound with $\mathrm{Sb_3F_{16}^-}$      569
Dicacodyl, $\mathrm{As_2Me_4}$      583—585
Dichlonne hexoxide, $\mathrm{C_{12}O_6}$      844 845 849 850
Dichlorine monoxide, $\mathrm{Cl_2O}$      844—847
Dichromate ion, $\mathrm{Cr_2O_7^{2-}}$      1009
Dicyandiamide      320 324
Dielectric constant, influence of H bonding      55
Dihydrogen      34
Dihydrogen, coordination chemistry of      44—47
Dimethyl suit oxide as ionizing solvent      694
Dimethylaminophosphorus dihalides      533
Dinicrogen monoxide      see “Nitrous oxide”
Dinitrogen pentoxide $\mathrm{N_2O_5}$      444 458
Dinitrogen tetroxide      444 454—458
Dinitrogen tetroxide, chemical reactions      456—458
Dinitrogen tetroxide, nonaqueous solvent properties      456—458
Dinitrogen tetroxide, physical properties      456 457
Dinitrogen tetroxide, preparation      456
Dinitrogen tetroxide, structure      455 see
Dinitrogen trioxide, $\mathrm{N_2O_4}$      444
Dinitrogen, as ligand      408 413—416
Dinitrogen, complexes, synthesis of      413 414
Dinitrogen, coordination modes      415
Dinitrogen, discovery of donor properties      414 1097
Dinitrogen, isoelectronic with CO, $\mathrm{c_2H_4}$      416
Diopside      349
Dioxygen      see “Oxygen” “Oxygen “Singlet”
Dioxygen, bonding in metal complexes      619—620
Dioxygen, chemical properties      612 613
Dioxygen, coordination chemistry of      615
Dioxygen, difluoride      639
Dioxygen, molecular-orbital diagram      606
Dioxygen, paramagnetic behaviour      601
Dioxygen, reaction with haemoglohin      614 1099—1101
Dioxygen, reactions of coordinated $\mathrm{O_2}$      619—620
Dioxygen, singlet state      607 614 716
Dioxygen, singlet-triplet transitions      606
Dioxygen, superoxo and peroxo complexes      615 616
Dioxygen, Vaska's discovery of reversible coordination      615 1135
Diphosphazenes      535
Diphosphonic acid      see “Diphosphorous acid”
Diphosphoric acid, $\mathrm{H_4P_2O_7}$      510 516 518
Diphosphorous acid, $\mathrm{H_4P_2O_5}$      512
Diphosphorus tetrahalides      497
Disilenes      362
Disulfates, $\mathrm{S_2O_7^{2-}}$      705 712
Disulfates, $\mathrm{S_2O_7^{2-}}$, imido derivatives      743
Disulfates, $\mathrm{S_2O_7^{2-}}$, preparation in liquid $\mathrm{SO_2}$      700
Disulfites, $\mathrm{S_2O_5^-}$      705 720
Disulfuric acid, $\mathrm{H_2S_2O_7}$      705 711
Disulfurous acid, $\mathrm{H_2S_2O_5}$      853 705 720
Dithiocarbamates      317
Dithiocarbamates, as ligands      665 673 674 796
Dithiolenes as ligands      665 674—676
Dithionates, $\mathrm{S_2O_6^{2-}}      705 715
Dithionic acid, $\mathrm{H_2S_2O_6}$      705 715
Dithionites, $\mathrm{S_2O_4^{2-}}$      705 720
Dithionous acid, $\mathrm{H_2S_2O_4}$      705 720
DNA      see “Deoxyribonucleic acids”
Dobereiner's triads      21
Dodecahedral complexes      916
Dolomite      109 272
Donor-acceptor complexes      see “Class-a and class-b metal ions” “Coordinate “Ligands” individual
Donor-acceptor complexes Of $\mathrm{AlX_3}$      235—237
Donor-acceptor complexes of $\mathrm{AsX_3}$      552 564
Donor-acceptor complexes of $\mathrm{CN^-}$      321 322
Donor-acceptor complexes of $\mathrm{GaH_3}$      232
Donor-acceptor complexes of $\mathrm{H_2S}$      673 673 714
Donor-acceptor complexes of $\mathrm{N_2}$      414—416 1097
Donor-acceptor complexes Of $\mathrm{O_2}$      615—620
Donor-acceptor complexes of $\mathrm{PH_3}$ and tertiary phosphines      493—495
Donor-acceptor complexes of $\mathrm{PX_3}$      495 497
Donor-acceptor complexes Of $\mathrm{SbF_5}$      561 569 570 702
Donor-acceptor complexes of $\mathrm{SCN^-}$      324—327 345
Donor-acceptor complexes of $\mathrm{SF_4}$      686
Donor-acceptor complexes of $\mathrm{SO_3}$      703 704
Donor-acceptor complexes of $\mathrm{S_4N_4}$      723
Donor-acceptor complexes of $\mathrm{S_n}$      665—672
Donor-acceptor complexes of CO      see “Carbonyls”
Donor-acceptor complexes of cyclo-polyarsanes      584—586
Donor-acceptor complexes of cyclo-polyphosphazenes      540
Donor-acceptor complexes of dithiocarbamates and xanthates      673 674 1080
1 2 3 4 5 6 7 8 9 10 11 12 13 14
blank
Реклама
blank
blank
HR
@Mail.ru
       © Электронная библиотека попечительского совета мехмата МГУ, 2004-2024
Электронная библиотека мехмата МГУ | Valid HTML 4.01! | Valid CSS! О проекте