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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Название: Chemistry of the Elements
Авторы: Greenwood N.N., Earnshaw A.
Аннотация: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Рубрика: Химия /
Статус предметного указателя: Готов указатель с номерами страниц
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Издание: second edition
Год издания: 1997
Количество страниц: 1340
Добавлена в каталог: 18.02.2007
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Предметный указатель
Cluster compounds, boron carbide 149
Cluster compounds, boron hydrides 151—180
Cluster compounds, carbido metal carhonyls 1107—1108
Cluster compounds, carboranes 181—189
Cluster compounds, cobalt, rhodium and indium carbonyls 928ff 1140—1143
Cluster compounds, cobalt-sulfur complexes 1119
Cluster compounds, gold phosphines 1197
Cluster compounds, iron, ruthenium and osmium carhonyls 928 1104—1108
Cluster compounds, lanthanide halides 1242
Cluster compounds, lithium alkyls 103—105
Cluster compounds, lithium imides 100
Cluster compounds, mercury-containing 1120
Cluster compounds, metal borides 148 149—151
Cluster compounds, metallocarboranes 189—195
Cluster compounds, metallohoranes 171—173 178
Cluster compounds, molyhdenum and tungsten dihalides 1022
Cluster compounds, nickel, palladium and platinum carbonyls 1168—1171
Cluster compounds, niobium and tantalum halides 991
Cluster compounds, of phosphorus, arsenic, antimony and bismuth 563 588
Cluster compounds, of tellurium 761 764
Cluster compounds, rhenium alkyls 1068 1069
Cluster compounds, rhenium carbidocarbonyls 1065
Cluster compounds, scandium halides 950
Cluster compounds, stabilization by encapsulated heteroatoms 950 966 992 1065 1107 1141. 1242
Cluster compounds, technethun and rhenium chalcogenides 1049
Cluster compounds, tungsten and molyhdenum halides 1021—1022
Cluster compounds, zirconium halides 965
Cobalt, abundance JII3
Cobalt, allyl complexes 933
Cobalt, arsenide 555 556
Cobalt, atomic and physical properties 1115—1116
Cobalt, biochemistry of 1138 1139 1322
Cobalt, carbidocarbonyls 1141—1142
Cobalt, carbonyls 928 929 1140—1143
Cobalt, complexes, +1 oxidation state 1133
Cobalt, complexes, +2 oxidation state 1129—1133
Cobalt, complexes, +3 oxidation state 1122—1129
Cobalt, complexes, +4 oxidation state 1121
Cobalt, complexes, +5 oxidation state 1121
Cobalt, complexes, lower oxidation states 1137
Cobalt, complexes, with 701
Cobalt, complexes, with S 666—669
Cobalt, coordination numbers and stereochemistries 1117
Cobalt, cyclobutadiene complex 936
Cobalt, cyclooctatetraene complexes 942
Cobalt, cyclopenladienyls 1143
Cobalt, dithiolene complexes, redox series 676
Cobalt, halides 1119—1121
Cobalt, importance of in early coordination chemistry 914 1122 1123 1302
Cobalt, nitrate (anhydrous) 469
Cobalt, nitrato complexes 469 470 543
Cobalt, optical resolution of $mathrm{[Co{(\mu-OH)_2Co(NH_3)_4}_3} 670 915
Cobalt, organomelallic compounds 1139—1143
Cobalt, oxidation states 1117
Cobalt, oxides 1117—1119
Cobalt, oxoanions 1120 1121
Cobalt, production and uses 1114 1115
Cobalt, reactivity of element 1116
Cobalt, relationship with other transition elements 1116—1117
Cobalt, standard reduction potentials 1122
Cobalt, sulfides 1118
Cobaltile (cobalt glance) 1114
Cobaltocene 939 1143
Coesite 342 343
Coinage metals (Cu, Ag, Au) 1173 see
Coke 274 see
Coke, historical importance is steel making 1070 1072
Cold fusion (nuclear) 1280 1283—1284
Columbite 977
Columhium 976 see
Combustion 600—602 612
Complexometric titration of with EDTA 577
Contact process see “Sulfuric acid manufacture”
Cooper pairs 1183
Cooperativity 11000 1199
Coordinate bond 198 921 see
Coordination number 912
Coordination number, above nine 917
Coordination number, eight 916
Coordination number, five 914
Coordination number, four 913
Coordination number, nine 917
Coordination number, seven 916
Coordination number, six 916
Coordination number, three 913
Coordination number, two 945
Copper oxide , nonstoichiometry in 642
Copper, abundance 1174
Copper, acetylide 1180
Copper, alkenes and alkynes 1199
Copper, alkyls and aryls 1200
Copper, biochemistry of 1197
Copper, carhoxylates 1192—1193
Copper, chalcogenides 1181—1182
Copper, complexes, +1 oxidation state 1194—1197
Copper, complexes, +2 oxidation stale 1189-1194
Copper, complexes, +3 oxidation stale 1187
Copper, Cu-S-O system 677
Copper, halides 1183—1187
Copper, history 1173
Copper, nitrate, structure of 471 1190
Copper, nitrato complexes 469 470 471 544
Copper, organometallic compounds 925 1199 1200
Copper, oxides 1181
Copper, production and uses 1174 1175 see
Corundum see “Aluminium oxides”
Cosmic black-body radiation 2
Cossee “mechanism 261
Cotton effect 1125
Creutz — Taube anion 1097
Cristobalite 343 344
Critical mass 1256 1257 1261
Crocidolite 351
Crocoite 1003
Crown ethers 96 97
Crown ethers, complexes with alkali metals 95 97
Crown ethers, complexes with alkaline earth metals 124
Crown ethers, “hole sizes” of 96
Crown ethers, “triple-decker” complex Cryolite 219
Crypt, complexes with alkali metals 97 393 394
Crypt, complexes with alkaline earth metals 125
Crypt, molecular structure of 98
Crystal field splittings 922—923
Crystal field stabilization energy 1131
Crystal field theory 922
Crystal field, octahedral 922
Crystal field, strong 923
Crystal field, weak 922
Cuhic, eight coordination 916 1275 1480
Cupellation 1173
Cuprite 1174
Curium 1252 1262 see
Cyanamide 319
Cyanamide, industrial production 324
Cyanates 320 324
Cyanates, as ligands 325
Cyanide ion as ligand 322 926
Cyanide process 1175 1196
Cyanogen 319—321
Cyanogen, halides 320 323 340
Cyanuric acid 305
Cyanuric compounds 320 323
Cyclo polyphosphoric acids 529 see
Cyclo- ( -sulfur) 656
Cyclo- 656—657
Cyclo- ( ), crystal and molecular structure 654
Cyclo- ( ), physical properties 654—656
Cyclo- ( ), polymerization at point 660
Cyclo- ( ), solubility 654
Cyclo- ( ), transition 654
Cyclo- ( ), vapour pressure 660
Cyclo-polyphosphates 529—531
Cyclo-silicates 347 349
Cyclobutadiene as ligand 935—938
Cycloheptatrienyl as ligand 941
Cyclometaphosphoric acids $\mathrm{(HРo_3)_n} 512 see “Cydo-poly-phospates”
Cycloocta-l,5-diene (cod) as ligand 932
Cyclooctatetraene as ligand 942
Cyclooctatetraene as ligand, as , , etc., ligand 943
Cyclopentadienyl, as ligand 940 see individual
Cyclopentadienyl, as ligand 937—940
Cyclophosphazanes 533 534
Cycto- 657
Cycto- 656—657
Cycto- 657
Cycto- 656—658
Cycto- 656 658 778
Cycto- 656 659
Cydo-polyarsanes 584-586
Cydometaphosphimic acids 541 542
Cytochrames 1095 1101 1198 1279
Cytosine 61. 62
Cаtеnа-polyarsanes 584—587
d orbitals 922—923 1285—1289
d orbitals, splitting by crystal fields 922—923
d-block contraction 27 222 251 561. 1234
Dalton's atomic theory 509
Dalton's law of multiple proportions 509
Dawson structure 1015
Decaborane, 159 163
Decaborane, , adduct formation 176
Decaborane, , Bronsted acidity 175
Decaborane, , chemical reactions 175—177
Decaborane, , preparations 187
Decaborane, , structure 175
Degussa process for HCN 321
Density of the elements, periodic trends in 24
Denticity 906
Deoxyribonucleic acids 476
Detergents, polyphosphates in 474 477
Detergents, sodium tripolyphosphate in 528
Deuterium, atomic properties 34
Deuterium, diwovery 32
Deuterium, ortho- and para- 36
Deuterium, physical properties 35
Deuterium, preparation 39
Dewar — Chatt — Duncanson theory 931
Diagonal relationship 27
Diagonal relationship, B and Si 202 347
Diagonal relationship, Be and Al 107
Diagonal relationship, Li and Mg 76 102 1113
Diagonal relationship, N and S 722
Diamond, chemical properties 278
Diamond, occurrence and distribution 271 272
Diamond, physical properties 278
Diamond, production and uses 272
Diarsane, 583 see
Diaspore 243
Diatomaceous earth 342
Diatomic molecules (homonuclear), bond dissociation, energies of 584
Diazotization of aromatic amines 463
Dibenzenechromium 940 1039 see
Diborane, 154 159
Diborane, , chemical reactions 163—170
Diborane, , cleavage reactions 165
Diborane, , hydroboration reactions 166 183
Diborane, , preparation 164
Diborane, , pyrolysis 164
Dibromonium cation , compound with 569
Dicacodyl, 583—585
Dichlonne hexoxide, 844 845 849 850
Dichlorine monoxide, 844—847
Dichromate ion, 1009
Dicyandiamide 320 324
Dielectric constant, influence of H bonding 55
Dihydrogen 34
Dihydrogen, coordination chemistry of 44—47
Dimethyl suit oxide as ionizing solvent 694
Dimethylaminophosphorus dihalides 533
Dinicrogen monoxide see “Nitrous oxide”
Dinitrogen pentoxide 444 458
Dinitrogen tetroxide 444 454—458
Dinitrogen tetroxide, chemical reactions 456—458
Dinitrogen tetroxide, nonaqueous solvent properties 456—458
Dinitrogen tetroxide, physical properties 456 457
Dinitrogen tetroxide, preparation 456
Dinitrogen tetroxide, structure 455 see
Dinitrogen trioxide, 444
Dinitrogen, as ligand 408 413—416
Dinitrogen, complexes, synthesis of 413 414
Dinitrogen, coordination modes 415
Dinitrogen, discovery of donor properties 414 1097
Dinitrogen, isoelectronic with CO, 416
Diopside 349
Dioxygen see “Oxygen” “Oxygen “Singlet”
Dioxygen, bonding in metal complexes 619—620
Dioxygen, chemical properties 612 613
Dioxygen, coordination chemistry of 615
Dioxygen, difluoride 639
Dioxygen, molecular-orbital diagram 606
Dioxygen, paramagnetic behaviour 601
Dioxygen, reaction with haemoglohin 614 1099—1101
Dioxygen, reactions of coordinated 619—620
Dioxygen, singlet state 607 614 716
Dioxygen, singlet-triplet transitions 606
Dioxygen, superoxo and peroxo complexes 615 616
Dioxygen, Vaska's discovery of reversible coordination 615 1135
Diphosphazenes 535
Diphosphonic acid see “Diphosphorous acid”
Diphosphoric acid, 510 516 518
Diphosphorous acid, 512
Diphosphorus tetrahalides 497
Disilenes 362
Disulfates, 705 712
Disulfates, , imido derivatives 743
Disulfates, , preparation in liquid 700
Disulfites, 705 720
Disulfuric acid, 705 711
Disulfurous acid, 853 705 720
Dithiocarbamates 317
Dithiocarbamates, as ligands 665 673 674 796
Dithiolenes as ligands 665 674—676
Dithionates, $\mathrm{S_2O_6^{2-}} 705 715
Dithionic acid, 705 715
Dithionites, 705 720
Dithionous acid, 705 720
DNA see “Deoxyribonucleic acids”
Dobereiner's triads 21
Dodecahedral complexes 916
Dolomite 109 272
Donor-acceptor complexes see “Class-a and class-b metal ions” “Coordinate “Ligands” individual
Donor-acceptor complexes Of 235—237
Donor-acceptor complexes of 552 564
Donor-acceptor complexes of 321 322
Donor-acceptor complexes of 232
Donor-acceptor complexes of 673 673 714
Donor-acceptor complexes of 414—416 1097
Donor-acceptor complexes Of 615—620
Donor-acceptor complexes of and tertiary phosphines 493—495
Donor-acceptor complexes of 495 497
Donor-acceptor complexes Of 561 569 570 702
Donor-acceptor complexes of 324—327 345
Donor-acceptor complexes of 686
Donor-acceptor complexes of 703 704
Donor-acceptor complexes of 723
Donor-acceptor complexes of 665—672
Donor-acceptor complexes of CO see “Carbonyls”
Donor-acceptor complexes of cyclo-polyarsanes 584—586
Donor-acceptor complexes of cyclo-polyphosphazenes 540
Donor-acceptor complexes of dithiocarbamates and xanthates 673 674 1080
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