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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ðóáðèêà: Õèìèÿ /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Mercuration 1222
Mercury, +1 oxidation state 1213—1215
Mercury, +2 oxidation state 1413—1416
Mercury, abundance 1202
Mercury, alkyls and aryls 1222
Mercury, chalcogenides 1208 1211
Mercury, cyclopentadienyls 1223
Mercury, halides 1211—1213
Mercury, history 1173
Mercury, organometallic compounds 926 1222—1224
Mercury, oxide 1208—1209
Mercury, polycations 1214 1215
Mercury, production and uses 1203
Mercury, sulfide, solubility of 638 679
Mercury, toxicity 1225
Mesoperiodic acid see “Periodic acids”
Metal cations, amphoteric 52
Metal cations, hydrolysis of 51
Metalloboranes 172—174 178
Metallocarbohedrenes (met-cars) 300
Metallocarboranes 189—195
Metallocarboranes, bonding 188 190 194
Metallocarboranes, chemical reactions 195
Metallocarboranes, structures 188
Metallocarboranes, synthesis 189—191
Metallocenes see “Ferrocene”
Metalloregulatory proteins 1226
Metaperiodic acid see “Periodic acids”
Metaphosphates see “Chain polyphosphates” “Cyclo-polyphosphates”
Metaphosphimic acid tautomers 541 (see also “Tetrametaphosphimates”)
Metatelluric acid 781
methane 300
Methane as greenhouse gas 274 302
Methane in Habcr-Bosch synthesis 420
Methanides see “Carbides”
Methyl bridges in 258 259
Methyl bridges in 127
Methyl bridges in and 131
Methyl methacrylate 321
Methylene complexes see “Carbene ligands”
Methylparathion 509
Meyer reaction 596
Meyer's periodic table 21 23
MICA 109 349 356—413
Millon's base 1218 1220
Mischmetall 946 1228
Mohorovicic discontinuity 358
Mohr's salt 1092
Molecular orbital theory of coordination compounds 922—924
Molecular sieves see “Zeolites”
Molybdates 1008—1016
Molybdenite, 649 1003
Molybdenum see also “Group 6 elements”
Molybdenum, abundance 1002
Molybdenum, benzene tricarbonyl 941
Molybdenum, biological activity 1035—1037
Molybdenum, blues 1008
Molybdenum, bronzes 1016
Molybdenum, carbonyls 928 1037 1038
Molybdenum, carbyne complexes 929
Molybdenum, chalcogenides 1017—1018
Molybdenum, complexes, +2 oxidation state 1031—1035
Molybdenum, complexes, +3 oxidation state 1027—1031
Molybdenum, complexes, +4 oxidation state 1025—1027
Molybdenum, complexes, +5 oxidation state 1024—1025
Molybdenum, complexes, +6 odixation state 1023—1024
Molybdenum, complexes, with 702
Molybdenum, complexes, with S 666—669 672
Molybdenum, compounds with quadruple metal-metal bonds 1032—1034
Molybdenum, cyclopentadienyl compounds 933 1038
Molybdenum, discovery 1002
Molybdenum, halides and oxohalides 1019
Molybdenum, heteropolyacids and salts 1014—1016
Molybdenum, isopolyacids and salts 1009—1014
Molybdenum, nitrogen fixation, role in 1035—1037
Molybdenum, nonstoichiometric oxides 1008
Molybdenum, organometallic compounds 1037—1039
Molybdenum, oxides 1007—1009
Molybdenum, production and uses 1003 1004
Molybdic acid 1010
Molybdocene 1038
Molybdoferredoxin 1035 1098
Monactin 96
Monazite 945 1230 1232 1254
Mond process 1146
Monel 1146
Montmorillonite 349 353 356
Mossbauer spectroscopy of nonstoichiometric oxides 642
Mossbauer spectroscopy with 371
Mossbauer spectroscopy with 753
Mossbauer spectroscopy with , 802 838 841
Mossbauer spectroscopy with 898
Mossbauer spectroscopy with 1094 1095 1096 1101
Mossbauer spectroscopy with 1062
Mother-of-pearl 122
Muriatic acid 792
Muscovite see “Mica”
Myoglobin 1098—1101
n-p-n junction see “Transistor”
N-type semiconductor see “Semiconductor” “Transistor”
Nacreous sulfur 655
NADP 125
Names of elements having Z >100 30 1252 1280—1283
Neodymium 1228 (see also “Lanthanide elements”)
Neodymium, +2 oxidation state 1237 1239 1241
Neodymium, +4 oxidation state 1244
Neon see also “Noble gases”
Neon, atomic and physical properties 891 892
Neon, discovery 889
Neptunium 1252 1262
Neptunium, bis(cyclooctatetraene) 942
Neptunium, radioactive decay series 1254
Nernst equation (for electrode potentials) 435
Neso-silicates 347 348
Nessler's reagent 1218
Neutrons, fast 1256
Neutrons, slow, thermal 1256
Newnham process for roasting PbS 677
Niccolite (Kupfernickel) 1145
Nichrome 1146
Nickel arsenide 555 556 649
Nickel arsenide, relation to 556 697
Nickel arsenide, structure type 555 556
Nickel silver 1146
Nickel, -allylic complexes 933 1172
Nickel, abundance 1145
Nickel, alkene and aklyne complexes 1170—1172
Nickel, aryls 1168
Nickel, atomic and physical properties 1148—1150
Nickel, biochemistry of 1167
Nickel, carbonyls 928 929 1168—1170
Nickel, chalocogenides 1152
Nickel, complexes with 702
Nickel, complexes, +1 oxidation state 1166
Nickel, complexes, +2 oxidation state 1156—1162
Nickel, complexes, +3 oxidation stale 1155
Nickel, complexes, +4 oxidation state 1154
Nickel, complexes, zero oxidation state 1166 1167
Nickel, coordination numbers and stereochemistries 1150
Nickel, cyclobutadiene complexes 936
Nickel, cyclopentadienyls 1170
Nickel, dithiolene complexes, redox series 675
Nickel, halides 1152 1153
Nickel, organometallic compounds 1167—1172
Nickel, oxidation states 1150
Nickel, oxides 1151 1152
Nickel, phosphides 489
Nickel, production and uses 1145—1148
Nickel, reactivity of elements 1149
Nickel, tetracarbonyl 928 929 1168
Nickel, “anomalous” behaviour of 1160 1159
Nickelocene 939 1170
Nielsbohrium see “Bohrium”
Niobates 987 (see also “Group 5 elements”)
Niobium, abundance 977
Niobium, alkyls and aryls 999
Niobium, bronzes 987
Niobium, carbonylate anions 980 1000
Niobium, chalcogenides 988
Niobium, complexes, +4 oxidation state 994—995
Niobium, complexes, +5 oxidation state 994
Niobium, compounds with oxoanions 993
Niobium, cyclopentadienyls 940 1000—1001
Niobium, discovery 976
Niobium, halides and oxohalides 988
Niobium, nonstoichiometric oxides 982
Niobium, organometallic compounds 999—1001
Niobium, oxides 982 983
Niobium, production and uses 977
Nitramide, 459
Nitrates 465 467—472 539—545
Nitrates, coordination modes 469—471
Nitrates, thermal stability 469
Nitric acid 422 456 457 459 465—468
Nitric acid, anhydrous 465 467
Nitric acid, hydrates 469 468
Nitric acid, industrial production 466 467
Nitric acid, industrial uses 467
Nitric acid, ionization in 711
Nitric oxide, bonding in paramagnetic molecule 446
Nitric oxide, catalytic production from 466
Nitric oxide, chemical reactions 446
Nitric oxide, colourless, not blue 446
Nitric oxide, complexes with transition metals see “Nitrosyl complexes”
Nitric oxide, crystal structure 446
Nitric oxide, dimeric 446
Nitric oxide, NO 422 442
Nitric oxide, physical properties 446
Nitric oxide, preparation 445
Nitric oxide, reaction with atomic N 413
Nitride ion, 417
Nitride ion, , as ligand 418—419
Nitrides 417—419
Nitrido complexes see “Nitride ion as ligand”
Nitriles see “Cyanides”
Nitrite ion, , coordination modes 463
Nitrite ion, , nitro-nitrito isomerism 463 464 920
Nitrites 422 461—465
Nitro-nitrito isomerism 463 464 920
Nitrogen see also “Dinitrogen”
Nitrogen, abundance in atmosphere 406 407—409
Nitrogen, abundance in crustal rocks 407
Nitrogen, atomic properties 411 412 550
Nitrogen, atomic, production and reactivity of 412 413
Nitrogen, atypical group properties 416 550
Nitrogen, chemical reactivity 412—416
Nitrogen, comparison with C and O 416
Nitrogen, comparison with heavier Group 15 elements 416 551 577
Nitrogen, cycle in nature 406 408 410
Nitrogen, dinitrogen tetrafluoride 439 440
Nitrogen, dioxide 444 455 612
Nitrogen, discovery 406
Nitrogen, fixation, industrial 466 (see also “Haber — Bosch ammonia synthesis”)
Nitrogen, fixation, natural 999 1035—1037 1098 1102
Nitrogen, halides 438—441
Nitrogen, history 407 408
Nitrogen, hydrides of 426—433 (see also “Ammonia” “Hydrazine” “Hydroxylamine”)
Nitrogen, industrial uses 409
Nitrogen, industrial uses, isotopes, discovery of 408
Nitrogen, isotopes, separation of 142
Nitrogen, ligand 408
Nitrogen, monoxide see “Nitric oxide”
Nitrogen, multiple bond formation 416 417
Nitrogen, oxidation states 434 437
Nitrogen, oxides 443—458
Nitrogen, oxoacids 459—466
Nitrogen, oxoanion salts see “Nitrosyl halides” “Nitryl
Nitrogen, physical properties 412
Nitrogen, production 411
Nitrogen, standard reduction potential for N species 434
Nitrogen, stereochemistry 413
Nitrogen, synthesis of pure 409
Nitrogen, tribromide 441
Nitrogen, trichloride 441
Nitrogen, trifluoride 438—439
Nitrogen, triiodide, ammonia adduct 441
Nitrogen, trioxide 444 458
Nitrogenase 1035 1098
Nitronium ion 458 712
Nitroprusside ion 1094 1095
Nitrosyl azide 433 443
Nitrosyl complexes 447—453
Nitrosyl complexes, coordination modes 450 450—452
Nitrosyl complexes, electronic structure of 450 451
Nitrosyl complexes, preparation 448 449
Nitrosyl halides 441 442
Nitrosyl trifluoride, 438 439
Nitrous acid 459 461—462
Nitrous acid, reaction with hydrazine 432
Nitrous oxide, 443—445
Nitrous oxide, , chemical reactions 443 445
Nitrous oxide, , isotopically labelled 443
Nitrous oxide, , physical properties 442 445
Nitrous oxide, , preparation 443
Nitrous oxide, , use in “whipped” ice cream 445
Nitroxyl 459 461
Nitroxylic acid 459
Nitryl halides, 441
Nmr spectroscopy with: 144
Nmr spectroscopy with: 371
Nmr spectroscopy with: 762
Nmr spectroscopy with: 802 803
Nmr spectroscopy with: 276 326 914 995 1104 1105
Nmr spectroscopy with: 326 408 411 1025
Nmr spectroscopy with: 408 411
Nmr spectroscopy with: 601 604 605 630 984 1012
Nmr spectroscopy with: 1012
Nmr spectroscopy with: 1165
Nmr spectroscopy with: 197 499 562 563 684 739 791 802—803 817 841 904 1022
Nmr spectroscopy with: 34 56 230 532 933 935 940 973 1111 1129 1135 1165 1223
Nmr spectroscopy with: 34
Nmr spectroscopy with: 330
Nmr spectroscopy with: 474 482 516 1165
Nmr spectroscopy with: 662
Nmr spectroscopy with: 791 802 803
Nmr spectroscopy with: 985
Nmr spectroscopy with: 762 769
Nmr spectroscopy with: 802 803
Nmr spectroscopy with: 1025
Nmr spectroscopy with: 144 197
NO see “Nitric oxide”
Nobel prize for Chemistry, list of laureates 1296—1299
Nobel prize for Physics, list of laureates 1300—1304
Nobelium 1252 1463
Noble gases (He, Ne, Ar, Kr, Xe, Rn) 888—904
Noble gases (He, Ne, Ar, Kr, Xe, Rn), atomic and physical properties 890—891
Noble gases (He, Ne, Ar, Kr, Xe, Rn), bonding in compounds of 897
Noble gases (He, Ne, Ar, Kr, Xe, Rn), chemical properties 892—904
Noble gases (He, Ne, Ar, Kr, Xe, Rn), clathrates 893
Noble gases (He, Ne, Ar, Kr, Xe, Rn), discovery 888 889
Noble gases (He, Ne, Ar, Kr, Xe, Rn), production and uses 889 890 1044
Nomenclature of elements having Z > 100 30 1252 1280—1283
Non-haem iron proteins (NHIP) 1102 1103
Nonactin 96
Nonaqueous solvent systems, 561
Nonaqueous solvent systems, 830 831
Nonaqueous solvent systems, 829
Nonaqueous solvent systems, 710—712 759
Nonaqueous solvent systems, 834
Nonaqueous solvent systems, 77—79 424—426
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