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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Íàçâàíèå: Chemistry of the Elements

Àâòîðû: Greenwood N.N., Earnshaw A.

Àííîòàöèÿ:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: second edition

Ãîä èçäàíèÿ: 1997

Êîëè÷åñòâî ñòðàíèö: 1340

Äîáàâëåíà â êàòàëîã: 18.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Argon, production and uses      889
Arsenates      577
Arsenic, abundance and distribution      548 549
Arsenic, allotropes      551
Arsenic, alloys      549 554
Arsenic, amino derivatives      561
Arsenic, atomic properties      550
Arsenic, catenation      583—590
Arsenic, chalcogenide cluster cations      579
Arsenic, chalcogenides      578—583
Arsenic, chemical reactivity      552—554 577
Arsenic, cluster anions      553 588—591
Arsenic, coordination geometries      553
Arsenic, diiodide      564
Arsenic, encapsulated      554
Arsenic, extraction and production      548 549
Arsenic, halide complexes      564—569
Arsenic, halides      558—566 see trihalides” “Arsenic pentahalides” “Arsenic diiodide” “Arsenic oxide “Arsenic mixed “Arsenic halide
Arsenic, halogenoorganoarsenic compounds      593—596
Arsenic, history      547
Arsenic, hydrides      557 558 583 679
Arsenic, intermetaUic compounds      see “Arsenides
Arsenic, metal-metal bonded species      583—590
Arsenic, mixed halides      563
Arsenic, organic compounds      553
Arsenic, organoarsenic(I) compounds      597
Arsenic, organoarsenic(III) compounds      583—587 592—594 596
Arsenic, organoarsenic(III) compounds, arsabenzene      593
Arsenic, organoarsenic(III) compounds, arsanaphthalene      593
Arsenic, organoarsenic(III) compounds, physiological activity      596
Arsenic, organoarsenic(III) compounds, preparation of      593 595
Arsenic, organoarsenic(III) compounds, reactions of      593 595
Arsenic, organoarsenic(V) compounds      594 596
Arsenic, oxidation state diagram      578
Arsenic, oxide $\mathrm{As_2O_3}$      549 572—575
Arsenic, oxide $\mathrm{As_2O_3}$, reactions      574
Arsenic, oxide $\mathrm{As_2O_3}$, structure and polymorphism      573
Arsenic, oxide $\mathrm{As_2O_3}$, uses      549 574
Arsenic, oxide halides      570—572
Arsenic, oxides and oxocompounds      570—578
Arsenic, oxoacid salts of      591
Arsenic, pentahatides      561. 664
Arsenic, physical properties      551 552
Arsenic, selenides      581
Arsenic, sulfide, $\mathrm{AS_2S_3}$      547 548 578 579 648
Arsenic, sulfide, $\mathrm{AS_2S_3}$, chemical reactions      580 581
Arsenic, sulfide, $\mathrm{AS_2S_3}$, structure      578 579
Arsenic, sulfide, $\mathrm{AS_4S_4}$      548 578—581 649
Arsenic, sulfides, $\mathrm{As_4S_n}$      578—580
Arsenic, triangular species      583 586—589
Arsenic, trichloride solvent system      560
Arsenic, trihalides      558—561 564 566
Arsenic, uses      549
Arsenic, volt-equivalent diagram      578
Arsenicals, therapeutic uses      593 see
Arsenides      554—558
Arsenides, stoichiometries      554
Arsenides, structures      554—557
Arsenidine complexes      597
Arsenious acid $\mathrm{As(OH)_3}$      574
Arsenite      575 575 577
Arsenite esters      561
Arsenopyrite      649
Arsine      558
Arsinic acids $\mathrm{R_2AsO(OH)}$      594
Arsinous acids $\mathrm{R_2AsOH}$      594
Arsonic acids RAsO(OH)      596
Arsonous acids $\mathrm{RAs(OH)_2}$      594
Asbestos      109 351
Asbestos minerals      349 351
Astatate ion, $\mathrm{ÀtO_3^{-}}$"      886
Astatide ion $\mathrm{At^{-}}$      886
Astatine      see “Halogens”
Astatine, abundance      796
Astatine, atomic properties      800
Astatine, chemistry      885. 886
Astatine, nuclear synthesis      791 795
Astatine, radioactivity of isotopes      795 885
Astatine, redox systematks      885
Astatine, trihalide ions      886
Atactic polymer      972
Atmophile elements      648
Atmosphere, composition      409 603
Atmosphere, industrial production of gases from      409 604
Atmosphere, origin of $\mathrm{O_2}$ in      602
Atom-at-a-time chemistry      1282
Atomic energy      1256
Atomic orbitals      1285—1289
Atomic piles      1256 see
Atomic properties, periodic trends in      23—27
Atomic volume curve, periodicity of      23 24
Atomic weight, definition      15
Atomic weights, history of      15 601
Atomic weights, precision of      15—19
Atomic weights, Table of      see “Front end paper”
Atomic weights, variability of      17—19 368
ATP      see “Adenosine triphosphate”
Autoprotolysis constants of anhydrous acids      710
Azides      433
Azoferredoxin      1036 1098
Azotobacter      999 1036
Azotobacter vinetandii      1036
Back ($\pi$) bonding      923 926 927 931 1166
Baddeleyite      955
Baddeleyite, structure of      955
Baking powders      524 525
Barium      see “Alkaline earth metals”
Barium, history of      108
Barium, organometallic compounds      136
Barium, polysulfides      681
Bart reaction      596
Basic oxygen steel process      120 1072
Bastnaesite      945 1229 1232
Batteries, dry      1204
Batteries, lead      371 549
Batteries, sodium-sulfur      678
Bauxite      243
Bauxite in Al production      219
Bauxite, production statistics      218
Bayer process      167
Bayerite      243 245
Belousov — Zhabotinskii oscillating reactions      865
Bentonite      see “Montmorillonite”
Benzene as ligand      940—941
Berkelium      1252 1262 see
Berry pseudorotation      474 499 914 see
Beryl      107 108 349
Beryllia      see “Beryllium oxide”
Beryllium      see “Alkaline earth metals”
Beryllium compounds, toxicity of      107
Beryllium ion, hydration number of      605
Beryllium, alkoxides etc      122 129
Beryllium, alkyls      126—130
Beryllium, borohydridc      115 116
Beryllium, chloride      116 117
Beryllium, complexes of      122—125
Beryllium, cyclopentadienyl complexes      130
Beryllium, discovery      107 108
Beryllium, fluoride      116
Beryllium, hydride      115 115 128
Beryllium, oxide      107 119—120
Beryllium, salts, hydrolysis of      121
Beryllium, uses of metal and alloys      110
Beryllium, ‘anomalous’ properties of      114 122
Beryllium, ‘basic acetate’      122 123
Beryllium, ‘basic nitrate’      122
Bessemer process      1072
BHB bridge bond, comparison with H bond      64 70 see
Biotite      see “Micas“
Bismuth, abundance and distribution      548 549 550
Bismuth, allotropes      551 551
Bismuth, alloys      549 554
Bismuth, atomic properties      550
Bismuth, Bi+cation      564 591
Bismuth, catenation      582
Bismuth, chalcogenides      581 582
Bismuth, chemical reactivity      552 553.
Bismuth, cluster cations      564 565 583 588—591
Bismuth, extraction and production      549 550
Bismuth, halide complexes      564—567
Bismuth, halides      558—564 see trihalides “Bismuth pentahalides” “Bismuth oxide “Bismuth lower “Bismuth mixed “Bismuth halide
Bismuth, history      547
Bismuth, hydride      557 558
Bismuth, hydroxide, $\mathrm{Bi(OH)_3}$      575
Bismuth, hydroxo cluster cation, $\mathrm{[Bi_6(OH)_12]^{6+}}$      575 591 592
Bismuth, intermetallic compounds      see “Bismuthides”
Bismuth, lower halides      564
Bismuth, metal-metal bonded clusters      583 583—591
Bismuth, mixed halides      564
Bismuth, nitrate and related complexes      591. 592
Bismuth, organometallic compounds      592 596 599
Bismuth, oxidation state diagram      578
Bismuth, oxide halides      572 572
Bismuth, oxide, $\mathrm{Bi_2O_3}}$      573 574
Bismuth, oxides and oxo compounds      573—575
Bismuth, oxoacid salts of      591
Bismuth, pentafluoride      561
Bismuth, physical properties      550 552
Bismuth, trihalides      558—561 564 566
Bismuth, uses      549
Bismuth, volt-equivalent diagram      578
Bismuthates      577
Bismuthides      554
Bismuthine      557
Biuret      305 1191
Blast furnace      1073
Bleaching powder      790 860
Blue vitriol      1190
Boehmite      243
Bohrium      1281 1283
Boiiing points, influence of H bonding      54
Bom — Haber cycle      94—96 79 82—83
Borane adducts, $\mathrm{LBH_3}$      165
Borane adducts, amine-boranes      208—209
Borane anions      151 166 178 181 590 see
Boranes, arachno-structures      152 154 159
Boranes, as ligands      177
Boranes, bonding      157—162 590
Boranes, classification      151
Boranes, closo-structures      152 153 161
Boranes, conjuncto-structures      152 155—157
Boranes, hypno-strucuires      152 153 172
Boranes, nido- structures      152 154 161
Boranes, nomenclature      157
Boranes, optical resolution of $\mathrm{i-B_{18}H_{22}}$      670
Boranes, physical properties      162 163
Boranes, preparation      162
Boranes, topology      158—160 175 see “Petaborane” “Decaborane” “Metalloboranes” “Carboranes” etc.
Borate minerals, occurrence      140
Borate minerals, production and uses      140 see
Borates      205—207
Borates, B-O distances in      206
Borates, industrial uses      207
Borates, structural principles      205
Borax      139 see
Borazanes      209
Borazine      210 408
Bordeaux mixture (fungicide)      1190
Boric acids, $\mathrm{B(OH)_3}$      203
Boric acids, $\mathrn{HBO_2}$      204
Borides, bonding      151
Borides, catenation in      148
Borides, preparation      146
Borides, properties and uses      146
Borides, stoichiometry      145 147
Borides, structure      147—151
Borohydrides      see “Borane anions” “Tetrahydro-borates”
Boron      167 see
Boron carbide $\mathrm{B_4C}$      149
Boron carbide $\mathrm{B_{13}C_2}$      149
Boron carbide $\mathrm{B_{50}C_2}$      143
Boron halides      195—202
Boron halides, $\mathrm{BnÕn}$      200 202
Boron halides, $\mathrm{B_2X_4}$      200
Boron halides, lower halides      199—202 see
Boron nitride, $\mathrm{B_{50}N_2}      143
Boron trifluoride      see “Boron trihalides”
Boron trihalides, adducts      198—199
Boron trihalides, bonding      196
Boron trihalides, physical properties      196
Boron trihalides, preparation      196
Boron trihalides, scrambling reactions      197 198
Boron, abundance      139
Boron, allotropes      141—144
Boron, atomic properties      144 222
Boron, chemical properties      144 145
Boron, crystal structures of allotropes      141
Boron, hydrides      see “Boranes”
Boron, isolation      139—140 144
Boron, neutron capture therapy using $\mathrm{^{10}B}$      179
Boron, nitride      208 208
Boron, nuclear properties      144
Boron, oxide      203
Boron, physical properties      144 222
Boron, sulfides      213—214
Boron, variables atomic weight of      17
Boron-nitrogen compounds      207—211
Boron-oxygen compounds      203—207
Boron-oxygen compounds, organic derivatives      207
brass      1175 1178 1178 1201 1203 1397
Brimstone      645 646
Bromates, $\mathrm{BrO_3^-}$      862—864
Bromates, $\mathrm{BrO_3^-}$, reaction scheme      866
Bromates, $\mathrm{BrO_3^-}$, redox systematics      853—856
Bromic acid, $\mathrm{HBrO_3}$      863
Bromides, synthesis of      821 822 see
Bromine      see “Halogens”
Bromine, abundance and distribution      795
Bromine, atomic and physical properties      800—804
Bromine, cations $\mathrm{Br_n^+}$      842—844
Bromine, history      790 790 792. 925
Bromine, monochloride      824 825 833
Bromine, monofboride      825 833
Bromine, oxide fluorides      880—881
Bromine, oxides      850 851
Bromine, oxides, nomenclature      853
Bromine, oxides, redox properties      853—855 see oxides individual “Bromine oxides bromic “Bromine oxides bromates” “Bromine oxides perbromates” etc.
Bromine, pentafluoride      832—834
Bromine, production and uses      798 800
Bromine, radioactive isotopes      801 802
Bromine, reactivity      805
Bromine, standard reduction potentials      854
Bromine, stereochemistry      806
Bromine, trifluoride      827—831 832
Bromine, volt-equivalent diagram      855
Bronsted's acid-base theory      32 48
Bronsted's acid-base theory in aqueous solutions      628
Bronsted's acid-base theory in non-aqueous solutions      51
Bronze      1173 1175
Bronzes, molybdenum      1016
Bronzes, titanium      964
Bronzes, tungsten      1016
Bronzes, vanadium      987
Brucite      121 352 385
Buffer solutions      48 49 521 524
Bulky tertiary phosphine ligands, special properties of      494
Butadiene as a fj4 ligand      935—936
Cadmium chloride structure      1211
Cadmium iodide structure type      556 680 680 1211
Cadmium iodide structure type, nonstoinchiometry in      679
1 2 3 4 5 6 7 8 9 10 11 12 13 14
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