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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Argon, production and uses 889
Arsenates 577
Arsenic, abundance and distribution 548 549
Arsenic, allotropes 551
Arsenic, alloys 549 554
Arsenic, amino derivatives 561
Arsenic, atomic properties 550
Arsenic, catenation 583—590
Arsenic, chalcogenide cluster cations 579
Arsenic, chalcogenides 578—583
Arsenic, chemical reactivity 552—554 577
Arsenic, cluster anions 553 588—591
Arsenic, coordination geometries 553
Arsenic, diiodide 564
Arsenic, encapsulated 554
Arsenic, extraction and production 548 549
Arsenic, halide complexes 564—569
Arsenic, halides 558—566 see trihalides” “Arsenic pentahalides” “Arsenic diiodide” “Arsenic oxide “Arsenic mixed “Arsenic halide
Arsenic, halogenoorganoarsenic compounds 593—596
Arsenic, history 547
Arsenic, hydrides 557 558 583 679
Arsenic, intermetaUic compounds see “Arsenides
Arsenic, metal-metal bonded species 583—590
Arsenic, mixed halides 563
Arsenic, organic compounds 553
Arsenic, organoarsenic(I) compounds 597
Arsenic, organoarsenic(III) compounds 583—587 592—594 596
Arsenic, organoarsenic(III) compounds, arsabenzene 593
Arsenic, organoarsenic(III) compounds, arsanaphthalene 593
Arsenic, organoarsenic(III) compounds, physiological activity 596
Arsenic, organoarsenic(III) compounds, preparation of 593 595
Arsenic, organoarsenic(III) compounds, reactions of 593 595
Arsenic, organoarsenic(V) compounds 594 596
Arsenic, oxidation state diagram 578
Arsenic, oxide 549 572—575
Arsenic, oxide , reactions 574
Arsenic, oxide , structure and polymorphism 573
Arsenic, oxide , uses 549 574
Arsenic, oxide halides 570—572
Arsenic, oxides and oxocompounds 570—578
Arsenic, oxoacid salts of 591
Arsenic, pentahatides 561. 664
Arsenic, physical properties 551 552
Arsenic, selenides 581
Arsenic, sulfide, 547 548 578 579 648
Arsenic, sulfide, , chemical reactions 580 581
Arsenic, sulfide, , structure 578 579
Arsenic, sulfide, 548 578—581 649
Arsenic, sulfides, 578—580
Arsenic, triangular species 583 586—589
Arsenic, trichloride solvent system 560
Arsenic, trihalides 558—561 564 566
Arsenic, uses 549
Arsenic, volt-equivalent diagram 578
Arsenicals, therapeutic uses 593 see
Arsenides 554—558
Arsenides, stoichiometries 554
Arsenides, structures 554—557
Arsenidine complexes 597
Arsenious acid 574
Arsenite 575 575 577
Arsenite esters 561
Arsenopyrite 649
Arsine 558
Arsinic acids 594
Arsinous acids 594
Arsonic acids RAsO(OH) 596
Arsonous acids 594
Asbestos 109 351
Asbestos minerals 349 351
Astatate ion, " 886
Astatide ion 886
Astatine see “Halogens”
Astatine, abundance 796
Astatine, atomic properties 800
Astatine, chemistry 885. 886
Astatine, nuclear synthesis 791 795
Astatine, radioactivity of isotopes 795 885
Astatine, redox systematks 885
Astatine, trihalide ions 886
Atactic polymer 972
Atmophile elements 648
Atmosphere, composition 409 603
Atmosphere, industrial production of gases from 409 604
Atmosphere, origin of in 602
Atom-at-a-time chemistry 1282
Atomic energy 1256
Atomic orbitals 1285—1289
Atomic piles 1256 see
Atomic properties, periodic trends in 23—27
Atomic volume curve, periodicity of 23 24
Atomic weight, definition 15
Atomic weights, history of 15 601
Atomic weights, precision of 15—19
Atomic weights, Table of see “Front end paper”
Atomic weights, variability of 17—19 368
ATP see “Adenosine triphosphate”
Autoprotolysis constants of anhydrous acids 710
Azides 433
Azoferredoxin 1036 1098
Azotobacter 999 1036
Azotobacter vinetandii 1036
Back ( ) bonding 923 926 927 931 1166
Baddeleyite 955
Baddeleyite, structure of 955
Baking powders 524 525
Barium see “Alkaline earth metals”
Barium, history of 108
Barium, organometallic compounds 136
Barium, polysulfides 681
Bart reaction 596
Basic oxygen steel process 120 1072
Bastnaesite 945 1229 1232
Batteries, dry 1204
Batteries, lead 371 549
Batteries, sodium-sulfur 678
Bauxite 243
Bauxite in Al production 219
Bauxite, production statistics 218
Bayer process 167
Bayerite 243 245
Belousov — Zhabotinskii oscillating reactions 865
Bentonite see “Montmorillonite”
Benzene as ligand 940—941
Berkelium 1252 1262 see
Berry pseudorotation 474 499 914 see
Beryl 107 108 349
Beryllia see “Beryllium oxide”
Beryllium see “Alkaline earth metals”
Beryllium compounds, toxicity of 107
Beryllium ion, hydration number of 605
Beryllium, alkoxides etc 122 129
Beryllium, alkyls 126—130
Beryllium, borohydridc 115 116
Beryllium, chloride 116 117
Beryllium, complexes of 122—125
Beryllium, cyclopentadienyl complexes 130
Beryllium, discovery 107 108
Beryllium, fluoride 116
Beryllium, hydride 115 115 128
Beryllium, oxide 107 119—120
Beryllium, salts, hydrolysis of 121
Beryllium, uses of metal and alloys 110
Beryllium, ‘anomalous’ properties of 114 122
Beryllium, ‘basic acetate’ 122 123
Beryllium, ‘basic nitrate’ 122
Bessemer process 1072
BHB bridge bond, comparison with H bond 64 70 see
Biotite see “Micas“
Bismuth, abundance and distribution 548 549 550
Bismuth, allotropes 551 551
Bismuth, alloys 549 554
Bismuth, atomic properties 550
Bismuth, Bi+cation 564 591
Bismuth, catenation 582
Bismuth, chalcogenides 581 582
Bismuth, chemical reactivity 552 553.
Bismuth, cluster cations 564 565 583 588—591
Bismuth, extraction and production 549 550
Bismuth, halide complexes 564—567
Bismuth, halides 558—564 see trihalides “Bismuth pentahalides” “Bismuth oxide “Bismuth lower “Bismuth mixed “Bismuth halide
Bismuth, history 547
Bismuth, hydride 557 558
Bismuth, hydroxide, 575
Bismuth, hydroxo cluster cation, 575 591 592
Bismuth, intermetallic compounds see “Bismuthides”
Bismuth, lower halides 564
Bismuth, metal-metal bonded clusters 583 583—591
Bismuth, mixed halides 564
Bismuth, nitrate and related complexes 591. 592
Bismuth, organometallic compounds 592 596 599
Bismuth, oxidation state diagram 578
Bismuth, oxide halides 572 572
Bismuth, oxide, 573 574
Bismuth, oxides and oxo compounds 573—575
Bismuth, oxoacid salts of 591
Bismuth, pentafluoride 561
Bismuth, physical properties 550 552
Bismuth, trihalides 558—561 564 566
Bismuth, uses 549
Bismuth, volt-equivalent diagram 578
Bismuthates 577
Bismuthides 554
Bismuthine 557
Biuret 305 1191
Blast furnace 1073
Bleaching powder 790 860
Blue vitriol 1190
Boehmite 243
Bohrium 1281 1283
Boiiing points, influence of H bonding 54
Bom — Haber cycle 94—96 79 82—83
Borane adducts, 165
Borane adducts, amine-boranes 208—209
Borane anions 151 166 178 181 590 see
Boranes, arachno-structures 152 154 159
Boranes, as ligands 177
Boranes, bonding 157—162 590
Boranes, classification 151
Boranes, closo-structures 152 153 161
Boranes, conjuncto-structures 152 155—157
Boranes, hypno-strucuires 152 153 172
Boranes, nido- structures 152 154 161
Boranes, nomenclature 157
Boranes, optical resolution of 670
Boranes, physical properties 162 163
Boranes, preparation 162
Boranes, topology 158—160 175 see “Petaborane” “Decaborane” “Metalloboranes” “Carboranes” etc.
Borate minerals, occurrence 140
Borate minerals, production and uses 140 see
Borates 205—207
Borates, B-O distances in 206
Borates, industrial uses 207
Borates, structural principles 205
Borax 139 see
Borazanes 209
Borazine 210 408
Bordeaux mixture (fungicide) 1190
Boric acids, 203
Boric acids, 204
Borides, bonding 151
Borides, catenation in 148
Borides, preparation 146
Borides, properties and uses 146
Borides, stoichiometry 145 147
Borides, structure 147—151
Borohydrides see “Borane anions” “Tetrahydro-borates”
Boron 167 see
Boron carbide 149
Boron carbide 149
Boron carbide 143
Boron halides 195—202
Boron halides, 200 202
Boron halides, 200
Boron halides, lower halides 199—202 see
Boron nitride, $\mathrm{B_{50}N_2} 143
Boron trifluoride see “Boron trihalides”
Boron trihalides, adducts 198—199
Boron trihalides, bonding 196
Boron trihalides, physical properties 196
Boron trihalides, preparation 196
Boron trihalides, scrambling reactions 197 198
Boron, abundance 139
Boron, allotropes 141—144
Boron, atomic properties 144 222
Boron, chemical properties 144 145
Boron, crystal structures of allotropes 141
Boron, hydrides see “Boranes”
Boron, isolation 139—140 144
Boron, neutron capture therapy using 179
Boron, nitride 208 208
Boron, nuclear properties 144
Boron, oxide 203
Boron, physical properties 144 222
Boron, sulfides 213—214
Boron, variables atomic weight of 17
Boron-nitrogen compounds 207—211
Boron-oxygen compounds 203—207
Boron-oxygen compounds, organic derivatives 207
brass 1175 1178 1178 1201 1203 1397
Brimstone 645 646
Bromates, 862—864
Bromates, , reaction scheme 866
Bromates, , redox systematics 853—856
Bromic acid, 863
Bromides, synthesis of 821 822 see
Bromine see “Halogens”
Bromine, abundance and distribution 795
Bromine, atomic and physical properties 800—804
Bromine, cations 842—844
Bromine, history 790 790 792. 925
Bromine, monochloride 824 825 833
Bromine, monofboride 825 833
Bromine, oxide fluorides 880—881
Bromine, oxides 850 851
Bromine, oxides, nomenclature 853
Bromine, oxides, redox properties 853—855 see oxides individual “Bromine oxides bromic “Bromine oxides bromates” “Bromine oxides perbromates” etc.
Bromine, pentafluoride 832—834
Bromine, production and uses 798 800
Bromine, radioactive isotopes 801 802
Bromine, reactivity 805
Bromine, standard reduction potentials 854
Bromine, stereochemistry 806
Bromine, trifluoride 827—831 832
Bromine, volt-equivalent diagram 855
Bronsted's acid-base theory 32 48
Bronsted's acid-base theory in aqueous solutions 628
Bronsted's acid-base theory in non-aqueous solutions 51
Bronze 1173 1175
Bronzes, molybdenum 1016
Bronzes, titanium 964
Bronzes, tungsten 1016
Bronzes, vanadium 987
Brucite 121 352 385
Buffer solutions 48 49 521 524
Bulky tertiary phosphine ligands, special properties of 494
Butadiene as a fj4 ligand 935—936
Cadmium chloride structure 1211
Cadmium iodide structure type 556 680 680 1211
Cadmium iodide structure type, nonstoinchiometry in 679
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