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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
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Íàçâàíèå: Chemistry of the Elements
Àâòîðû: Greenwood N.N., Earnshaw A.
Àííîòàöèÿ: When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.
Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.
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Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Èçäàíèå: second edition
Ãîä èçäàíèÿ: 1997
Êîëè÷åñòâî ñòðàíèö: 1340
Äîáàâëåíà â êàòàëîã: 18.02.2007
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Donor-acceptor complexes of dithiolenes 674
Donor-acceptor complexes of Group 13 halides 237—239
Donor-acceptor complexes of NO see “Nitrosyls
Donor-acceptor complexes of SO, , 700—703
Donor-acceptor complexes, first 408
Donor-acceptor complexes, stability of 198
Double-helix structure of nucleic acids 474
Downs cell 72 73
Dry batteries 1204
Dubnium 1281—1282
Dysprosium 1229 see
Dysprosium, +4 oxidation state 1244
e-Process in stars 8
Effective atomic number (BAN) rule 921 see
Effective ionic radii, Table of 1295
Eighteen electron rule 1037 1104 1109 1112 1134
Einsteinium 1252 1262 see
Eka-silicon, Mendeleev's predictions 29
Electric arc process of steelmaking 1072
Electrical properties, influence of H bonding 53
Electrofluorination 821
Electron affinity 75 82 800
Electron transfer reactions, mechanisms of 1124
Electron-counting rules for boranes 161
Electron-counting rules for carbonyl clusters 1107 1142 1169
Electron-counting rules for carhoranes 181
Electron-counting rules for gold-phosphine clusters 1197
Electron-counting rules for metal-halide clusters 966 1018 1022
Electron-counting rules for metallocarboranes 194
Electronegativity, definition of 26
Electronegativity, periodic trends in 26
Electronic structure and chemical periodicity 21—23
Electronic structure of atoms 21—23
Elements, abundance in crustal rocks 1294
Elements, bond dissociation energies of gaseous diatomic 584
Elements, cosmic abundance 3 l2
Elements, isolopic composition of 47
Elements, origin of 1 5 9 I2
Elements, periodic table of see “Inside front cover”
Elements, periodicity in properties 20—31
Elements, table of atomic weights see “Inside back cover”
Elements, Z=104-112 see “Transactinide”
Ellingham diagram 308 307 369
Emerald 107 1003
Enstatite 349
Entropy and the chelate effect 910
Equilibrium process in stars (e-process) 8
Erbium 1229 see
Ethene (ethylene) as a ligand 930 931
Europium 1229 see
Europium, +2 oxidation stale 1239 1240 1241 1248
Europium, magnetic properties of 1243
Eutrophication 478 528
Exclusion principle (Pauli) 22
Extended X-ray absorption fine structure (EXAFS) 1036
f-block contraction 562 1234
Faraday's phosphide synthesis 489
Faujasite 358
Fehling's test 1181
Feldspars 354 358 414
Femanium ion 1109
Fenton's reagent 636
Fermi level, definition of 332
Fermium 1252 1262 see
Ferredoxins 1035 1036 1098 1101—1103
Ferrites 1081 1209
Ferritin 1098 1104
Ferrocene, bonding 938—939
Ferrocene, historical importance of 924 1070 1109
Ferrocene, physical properties 937
Ferrocene, reactions 1109—1112
Ferrocene, structure 937
Ferrocene, synthesis 938 1109
Ferrochrome 1003
Ferroelectricity 57—58 386 571
Ferromanganese 1041
Ferromolybdenum 1003
Ferrophosphonis 480 492 525
Ferrosilicon alloys 330
Ferrovanadium 977
First short period, “anomalous” properties of 27
Fischer (Karl) reagent 628
Fischer — Tropsch process 309 1106
Fish population, relation to phosphate-rich waters 479
Flint 328 342
Fluorapatite see “Apatites”
Fluoridation and dental caries 447 525 791 792
Fluorides 820—821
Fluorides, solubility in HF 817
Fluorides, synthesis 820—821
Fluorinated peimo compounds 639 640
Fluorinating agents 820—821
Fluorinating agents, 560
Fluorinating agents, 562 563
Fluorine see “Halogens”
Fluorine, abundance and distribution 795
Fluorine, atomic and physical properties 800—804
Fluorine, chemical synthesis of 821
Fluorine, history 789—792
Fluorine, isolation 789 791
Fluorine, oxides see “Oxygen fluorides”
Fluorine, oxoacid, HOF 789 853 856
Fluorine, preparation of fluorides using 820
Fluorine, production and uses 796—798
Fluorine, radioactive isotopes 801 802 936
Fluorine, reactivity 804—806
Fluorine, stereochemistry 806
Fluorine, toxicity 792 810
Fluorite, 109
Fluorite, , crystal stucture of 117
Fluorosulfuric acid 689
Fluorspar 789 790 see
Fluorspar, fluorescence 789 790
Fluxional hehaviour see “Stereochemical non-rigidity”
Francium see “Alkali metals”
Francium, abundance 68
Francium, discovery 68
Frasch process for sulfur 646
Freons (eg ) 304 791
Friedel — Crafts catalysis, complexes 171 176 186 235 236 338
Friedel — Crafts catalysis, complexes 199
Friedel — Crafts catalysis, 385
Fuller's earth see “Montmorillonite”
Fullerenes, chemical properties 282—287
Fullerenes, discovery 279
Fullerenes, incorporation of heteroatoms 287—9
Fullerenes, structure 280
Fullerides 285
Fullerols 284
Fulminate ion 319 433
g (gerade), definition 938
Gabbro rock 358
Gadolinium 1229 (see also “Lanthanide elements”)
Gadolinium, diiodide 1242
Galena (Pb glance) 649 (see also “Lead sulfide”)
Galena, roasting reactions 677
Gallane 231
Gallium see also “Group 13 elements”
Gallium, abundance 218
Gallium, arsenide, semiconductor 221
Gallium, as eka-aluminium 216
Gallium, chalcogenides 252 253
Gallium, discovery 216
Gallium, hydride 231
Gallium, hydride halides 232
Gallium, III—V compounds 256
Gallium, ion, hydration number of 605
Gallium, lower halides 240
Gallium, organometallic compounds 262—266
Gallium, oxides 246
Gallium, production and uses 219
Gallium, sulfides 285 286
Gallium, trihalides 237
Garnets 348
Garnets, magnetic properties of 946 1081
Garnierite 1145
German silver 1146
Germanes see “Germanium hydrides”
Germanium, abundance 368
Germanium, atomic properties 371 372
Germanium, chalcogenides 389 390
Germanium, chemical reactivity and group trends 373 375
Germanium, cluster anions 393
Germanium, dihalides 376
Germanium, dihydroxide 382
Germanium, dioxide 383
Germanium, discovery 367
Germanium, halogeno complexes 376
Germanium, hydrides 374 373
Germanium, hydrohalides 375
Germanium, isolation from flue dust 369
Germanium, monomeric 390
Germanium, monoxide 376 382
Germanium, organo compounds 376 396 404
Germanium, physical properties 371 372
Germanium, silicate analogues 383
Germanium, sulfate 387
Germanium, tetraacetate 387
Germanium, tetrahalides 375 377
Germanium, uses 369
Germanocene 398
Germenes 397
Germylenes 397
Gibbs' phase rule 676
Gibbsite 243 245 352
Girbotol process 311
Glassmaker's soap 1048
Gold see also “Group 11 elements”
Gold, abundance 1174
Gold, alkyls 1180 1200
Gold, chalcogenides 1181—1182
Gold, cluster compounds 1197 1198
Gold, complexes, +1 oxidation state 1196
Gold, complexes, +2 oxidation state 1189
Gold, complexes, +3 oxidation state 1188—1189
Gold, complexes, lower oxidation states 1197
Gold, complexes, with S 666
Gold, halides 1183—1184
Gold, history 1173
Gold, nitrato complexes 469 471
Gold, organometallic compounds 925 1199—1200
Gold, oxide 1181
Gold, production and uses 1367 1174
Graham's salt 528—531
Graphite, alkali metal intercalates 293
Graphite, chemical properties 289—292
Graphite, halide intercalates 295 295
Graphite, intercalation compounds 293—294
Graphite, monofluoride 289
Graphite, occurrence and distribution 270
Graphite, oxide 289 290
Graphite, oxide intercalates 296
Graphite, physical properties 278
Graphite, production and uses 271
Graphite, structure 275
Graphite, subfluoride 289—290
Greek alphabet see “Back end paper”
Greenhouse effect 273 687
Grignard reagents 131—136
Grignard reagents, allyl 933
Grignard reagents, constitution of 131 132
Grignard reagents, crystalline adducts of 133
Grignard reagents, preparation of 132
Grignard reagents, Schlenk equilibrium 131 132
Grignard reagents, synthetic uses of 134 135 151
Group 0 elements see “Noble gases”
Group 1 elements see “Alkali metals”
Group 10 elements see “Nickel” “Palladium” “Platinum”
Group 11 elements (Cu, Ag, Au) see also “Copper” “Silver” “Goid”
Group 11 elements (Cu, Ag, Au), atomic and physical properties 1176 1177
Group 11 elements (Cu, Ag, Au), coordination numbers and stereochemistries 1179 1180
Group 11 elements (Cu, Ag, Au), group trends 1177—1180
Group 11 elements (Cu, Ag, Au), oxidation states 1179
Group 12 elements (Zn, Cd, Hg) see also “Zinc” “Cadmium” “Mercury” “Element
Group 12 elements (Zn, Cd, Hg), atomic and physical properties 1203 1205
Group 12 elements (Zn, Cd, Hg), coordination numbers and stereochemistries 1207
Group 12 elements (Zn, Cd, Hg), group trends 1205—1208
Group 13 elements (B, Al, Ga, In, Tl), + 1 oxidation state 224 227
Group 13 elements (B, Al, Ga, In, Tl), amphoteric behaviour of Al, Ga 225
Group 13 elements (B, Al, Ga, In, Tl), atomic properties 222
Group 13 elements (B, Al, Ga, In, Tl), chemical reactivity 224—227
Group 13 elements (B, Al, Ga, In, Tl), group trends 223—227 237
Group 13 elements (B, Al, Ga, In, Tl), physical properties 222 224
Group 13 elements (B, Al, Ga, In, Tl), trihalide complexes, stability of 237—239
Group 13 elements (B, Al, Ga, In, Tl), unusual sterochemistries 256
Group 14 elements see “Carbon” “Silicon” “Germanium” “Tin” “Lead”
Group 15 elements see “Nitrogen” “Phosphorus” “Arsenic” “Antimony” “Bismuth”
Group 16 elements see “Oxygen” “Sulfur” “Selenium” “Tellurium” “Polonium”
Group 17 elements see “Halogens”
Group 2 elements see “Alkaline earth metals”
Group 3 elements (Sc, Y, La; Ac) see also “Lanthanide elements”
Group 3 elements (Sc, Y, La; Ac), atomic and physical properties 946 947
Group 3 elements (Sc, Y, La; Ac), chemical reactivity 948—949
Group 3 elements (Sc, Y, La; Ac), group trends 948—949
Group 3 elements (Sc, Y, La; Ac), high coordination, numbers 952
Group 3 elements (Sc, Y, La; Ac), oxidation states lower than +3 949 950
Group 4 elements (Ti, Zr, Hf) see also “Titanium” “Zirconium” “Hafnium” “Rutherfordium”
Group 4 elements (Ti, Zr, Hf), atomic and physical properties 957—958
Group 4 elements (Ti, Zr, Hf), coordination numbers and stereochemistries 960
Group 4 elements (Ti, Zr, Hf), group trends 957—960
Group 4 elements (Ti, Zr, HO, oxidation states 960
Group 5 elements (V, Nb, Ta) see also “Vanadium” “Niobium” “Tantalum” “Dubnium”
Group 5 elements (V, Nb, Ta), atomic and physical properties 978
Group 5 elements (V, Nb, Ta), coordination numbers and stereochemistries 980
Group 5 elements (V, Nb, Ta), group trends 979 980
Group 5 elements (V, Nb, Ta), oxidation states 980
Group 6 elements (Cr, Mo, W) see also “Chromium” “Molybdenum” “Tungsten”
Group 6 elements (Cr, Mo, W), atomic and physical properties 1004 1008
Group 6 elements (Cr, Mo, W), coordination numbers and stereochemistries 1006
Group 6 elements (Cr, Mo, W), group trends 1005
Group 6 elements (Cr, Mo, W), oxidation states 1006
Group 7 elements (Mn, Tc, Re) see also “Manganese” “Technetium” “Rhenium”
Group 7 elements (Mn, Tc, Re), atomic and physical properties 1043
Group 7 elements (Mn, Tc, Re), coordination numbers and stereochemistries 1046
Group 7 elements (Mn, Tc, Re), group trends 1044 1045
Group 7 elements (Mn, Tc, Re), oxidation states 1046
Group 7 elements (Mn, Tc, Re), oxoanions 1049 1050
Group 7 elements (Mn, Tc, Re), redox properties 1044 1045
Group 8 elements see “Iron” “Ruthenium” “Osmium”
Group 9 elements see “Cobalt” “Rhodium” “Indium”
Guanidine 305
Guanine 61 62
Guano 408
Gunpowder 645 646
Gypsum 109 122
Gypsum, diluent in superphosphate fertilizer 525
Gypsum, occurrence in evaporites 647
Gypsum, process for manufacture 521 522
Gypsum, S recovery from 651 652
H bridge-bond in boranes and carboranes 154
Haber — Bosch ammonia synthesis 408 409
Haber — Bosch ammonia synthesis, historical development 421
Haber — Bosch ammonia synthesis, production statistics 421
Haber — Bosch ammonia synthesis, technical details 421
Haem 126 1099
Haematin 1099
Haematite 1071
Haemocyanin 1199
Haemoglobin 1098—1101
Hafnates 964
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