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Greenwood N.N., Earnshaw A. — Chemistry of the Elements
Greenwood N.N., Earnshaw A. — Chemistry of the Elements



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Íàçâàíèå: Chemistry of the Elements

Àâòîðû: Greenwood N.N., Earnshaw A.

Àííîòàöèÿ:

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century.

Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will notonly value during their formal education, but will keep and refer to throughout their careers as chemists.


ßçûê: en

Ðóáðèêà: Õèìèÿ/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: second edition

Ãîä èçäàíèÿ: 1997

Êîëè÷åñòâî ñòðàíèö: 1340

Äîáàâëåíà â êàòàëîã: 18.02.2007

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Donor-acceptor complexes of dithiolenes      674
Donor-acceptor complexes of Group 13 halides      237—239
Donor-acceptor complexes of NO      see “Nitrosyls
Donor-acceptor complexes of SO, $\mathrm{S_2O_2}$, $\mathrm{SO_2}$      700—703
Donor-acceptor complexes, first $(\mathrm{H_3NBF_3})$      408
Donor-acceptor complexes, stability of      198
Double-helix structure of nucleic acids      474
Downs cell      72 73
Dry batteries      1204
Dubnium      1281—1282
Dysprosium      1229 see
Dysprosium, +4 oxidation state      1244
e-Process in stars      8
Effective atomic number (BAN) rule      921 see
Effective ionic radii, Table of      1295
Eighteen electron rule      1037 1104 1109 1112 1134
Einsteinium      1252 1262 see
Eka-silicon, Mendeleev's predictions      29
Electric arc process of steelmaking      1072
Electrical properties, influence of H bonding      53
Electrofluorination      821
Electron affinity      75 82 800
Electron transfer reactions, mechanisms of      1124
Electron-counting rules for boranes      161
Electron-counting rules for carbonyl clusters      1107 1142 1169
Electron-counting rules for carhoranes      181
Electron-counting rules for gold-phosphine clusters      1197
Electron-counting rules for metal-halide clusters      966 1018 1022
Electron-counting rules for metallocarboranes      194
Electronegativity, definition of      26
Electronegativity, periodic trends in      26
Electronic structure and chemical periodicity      21—23
Electronic structure of atoms      21—23
Elements, abundance in crustal rocks      1294
Elements, bond dissociation energies of gaseous diatomic      584
Elements, cosmic abundance      3 l2
Elements, isolopic composition of      47
Elements, origin of      1 5 9 I2
Elements, periodic table of      see “Inside front cover”
Elements, periodicity in properties      20—31
Elements, table of atomic weights      see “Inside back cover”
Elements, Z=104-112      see “Transactinide”
Ellingham diagram      308 307 369
Emerald      107 1003
Enstatite      349
Entropy and the chelate effect      910
Equilibrium process in stars (e-process)      8
Erbium      1229 see
Ethene (ethylene) as a ligand      930 931
Europium      1229 see
Europium, +2 oxidation stale      1239 1240 1241 1248
Europium, magnetic properties of      1243
Eutrophication      478 528
Exclusion principle (Pauli)      22
Extended X-ray absorption fine structure (EXAFS)      1036
f-block contraction      562 1234
Faraday's phosphide synthesis      489
Faujasite      358
Fehling's test      1181
Feldspars      354 358 414
Femanium ion      1109
Fenton's reagent      636
Fermi level, definition of      332
Fermium      1252 1262 see
Ferredoxins      1035 1036 1098 1101—1103
Ferrites      1081 1209
Ferritin      1098 1104
Ferrocene, bonding      938—939
Ferrocene, historical importance of      924 1070 1109
Ferrocene, physical properties      937
Ferrocene, reactions      1109—1112
Ferrocene, structure      937
Ferrocene, synthesis      938 1109
Ferrochrome      1003
Ferroelectricity      57—58 386 571
Ferromanganese      1041
Ferromolybdenum      1003
Ferrophosphonis      480 492 525
Ferrosilicon alloys      330
Ferrovanadium      977
First short period, “anomalous” properties of      27
Fischer (Karl) reagent      628
Fischer — Tropsch process      309 1106
Fish population, relation to phosphate-rich waters      479
Flint      328 342
Fluorapatite      see “Apatites”
Fluoridation and dental caries      447 525 791 792
Fluorides      820—821
Fluorides, solubility in HF      817
Fluorides, synthesis      820—821
Fluorinated peimo compounds      639 640
Fluorinating agents      820—821
Fluorinating agents, $\mathrm{AsF_3}, \mathrm{SbF_3}$      560
Fluorinating agents, $\mathrm{AsF_5}, \mathrm{BiF_5}, \mathrm{SbF_5}$      562 563
Fluorine      see “Halogens”
Fluorine, abundance and distribution      795
Fluorine, atomic and physical properties      800—804
Fluorine, chemical synthesis of      821
Fluorine, history      789—792
Fluorine, isolation      789 791
Fluorine, oxides      see “Oxygen fluorides”
Fluorine, oxoacid, HOF      789 853 856
Fluorine, preparation of fluorides using      820
Fluorine, production and uses      796—798
Fluorine, radioactive isotopes      801 802 936
Fluorine, reactivity      804—806
Fluorine, stereochemistry      806
Fluorine, toxicity      792 810
Fluorite, $\mathrm{CaF_2}$      109
Fluorite, $\mathrm{CaF_2}$, crystal stucture of      117
Fluorosulfuric acid      689
Fluorspar      789 790 see
Fluorspar, fluorescence      789 790
Fluxional hehaviour      see “Stereochemical non-rigidity”
Francium      see “Alkali metals”
Francium, abundance      68
Francium, discovery      68
Frasch process for sulfur      646
Freons (eg $\mathrm{CCl_2F_2}$)      304 791
Friedel — Crafts catalysis, $\mathrm{AlX_3}$ complexes      171 176 186 235 236 338
Friedel — Crafts catalysis, $\mathrm{BF_3}$ complexes      199
Friedel — Crafts catalysis, $\mathrm{SnCl_4}$      385
Fuller's earth      see “Montmorillonite”
Fullerenes, chemical properties      282—287
Fullerenes, discovery      279
Fullerenes, incorporation of heteroatoms      287—9
Fullerenes, structure      280
Fullerides      285
Fullerols      284
Fulminate ion      319 433
g (gerade), definition      938
Gabbro rock      358
Gadolinium      1229 (see also “Lanthanide elements”)
Gadolinium, diiodide      1242
Galena (Pb glance)      649 (see also “Lead sulfide”)
Galena, roasting reactions      677
Gallane      231
Gallium      see also “Group 13 elements”
Gallium, abundance      218
Gallium, arsenide, semiconductor      221
Gallium, as eka-aluminium      216
Gallium, chalcogenides      252 253
Gallium, discovery      216
Gallium, hydride      231
Gallium, hydride halides      232
Gallium, III—V compounds      256
Gallium, ion, hydration number of      605
Gallium, lower halides      240
Gallium, organometallic compounds      262—266
Gallium, oxides      246
Gallium, production and uses      219
Gallium, sulfides      285 286
Gallium, trihalides      237
Garnets      348
Garnets, magnetic properties of      946 1081
Garnierite      1145
German silver      1146
Germanes      see “Germanium hydrides”
Germanium, abundance      368
Germanium, atomic properties      371 372
Germanium, chalcogenides      389 390
Germanium, chemical reactivity and group trends      373 375
Germanium, cluster anions      393
Germanium, dihalides      376
Germanium, dihydroxide      382
Germanium, dioxide      383
Germanium, discovery      367
Germanium, halogeno complexes      376
Germanium, hydrides      374 373
Germanium, hydrohalides      375
Germanium, isolation from flue dust      369
Germanium, monomeric $Ge(OAr)_{2}$      390
Germanium, monoxide      376 382
Germanium, organo compounds      376 396 404
Germanium, physical properties      371 372
Germanium, silicate analogues      383
Germanium, sulfate      387
Germanium, tetraacetate      387
Germanium, tetrahalides      375 377
Germanium, uses      369
Germanocene      398
Germenes      397
Germylenes      397
Gibbs' phase rule      676
Gibbsite      243 245 352
Girbotol process      311
Glassmaker's soap      1048
Gold      see also “Group 11 elements”
Gold, abundance      1174
Gold, alkyls      1180 1200
Gold, chalcogenides      1181—1182
Gold, cluster compounds      1197 1198
Gold, complexes, +1 oxidation state      1196
Gold, complexes, +2 oxidation state      1189
Gold, complexes, +3 oxidation state      1188—1189
Gold, complexes, lower oxidation states      1197
Gold, complexes, with S      666
Gold, halides      1183—1184
Gold, history      1173
Gold, nitrato complexes      469 471
Gold, organometallic compounds      925 1199—1200
Gold, oxide      1181
Gold, production and uses      1367 1174
Graham's salt      528—531
Graphite, alkali metal intercalates      293
Graphite, chemical properties      289—292
Graphite, halide intercalates      295 295
Graphite, intercalation compounds      293—294
Graphite, monofluoride      289
Graphite, occurrence and distribution      270
Graphite, oxide      289 290
Graphite, oxide intercalates      296
Graphite, physical properties      278
Graphite, production and uses      271
Graphite, structure      275
Graphite, subfluoride      289—290
Greek alphabet      see “Back end paper”
Greenhouse effect      273 687
Grignard reagents      131—136
Grignard reagents, allyl      933
Grignard reagents, constitution of      131 132
Grignard reagents, crystalline adducts of      133
Grignard reagents, preparation of      132
Grignard reagents, Schlenk equilibrium      131 132
Grignard reagents, synthetic uses of      134 135 151
Group 0 elements      see “Noble gases”
Group 1 elements      see “Alkali metals”
Group 10 elements      see “Nickel” “Palladium” “Platinum”
Group 11 elements (Cu, Ag, Au)      see also “Copper” “Silver” “Goid”
Group 11 elements (Cu, Ag, Au), atomic and physical properties      1176 1177
Group 11 elements (Cu, Ag, Au), coordination numbers and stereochemistries      1179 1180
Group 11 elements (Cu, Ag, Au), group trends      1177—1180
Group 11 elements (Cu, Ag, Au), oxidation states      1179
Group 12 elements (Zn, Cd, Hg)      see also “Zinc” “Cadmium” “Mercury” “Element
Group 12 elements (Zn, Cd, Hg), atomic and physical properties      1203 1205
Group 12 elements (Zn, Cd, Hg), coordination numbers and stereochemistries      1207
Group 12 elements (Zn, Cd, Hg), group trends      1205—1208
Group 13 elements (B, Al, Ga, In, Tl), + 1 oxidation state      224 227
Group 13 elements (B, Al, Ga, In, Tl), amphoteric behaviour of Al, Ga      225
Group 13 elements (B, Al, Ga, In, Tl), atomic properties      222
Group 13 elements (B, Al, Ga, In, Tl), chemical reactivity      224—227
Group 13 elements (B, Al, Ga, In, Tl), group trends      223—227 237
Group 13 elements (B, Al, Ga, In, Tl), physical properties      222 224
Group 13 elements (B, Al, Ga, In, Tl), trihalide complexes, stability of      237—239
Group 13 elements (B, Al, Ga, In, Tl), unusual sterochemistries      256
Group 14 elements      see “Carbon” “Silicon” “Germanium” “Tin” “Lead”
Group 15 elements      see “Nitrogen” “Phosphorus” “Arsenic” “Antimony” “Bismuth”
Group 16 elements      see “Oxygen” “Sulfur” “Selenium” “Tellurium” “Polonium”
Group 17 elements      see “Halogens”
Group 2 elements      see “Alkaline earth metals”
Group 3 elements (Sc, Y, La; Ac)      see also “Lanthanide elements”
Group 3 elements (Sc, Y, La; Ac), atomic and physical properties      946 947
Group 3 elements (Sc, Y, La; Ac), chemical reactivity      948—949
Group 3 elements (Sc, Y, La; Ac), group trends      948—949
Group 3 elements (Sc, Y, La; Ac), high coordination, numbers      952
Group 3 elements (Sc, Y, La; Ac), oxidation states lower than +3      949 950
Group 4 elements (Ti, Zr, Hf)      see also “Titanium” “Zirconium” “Hafnium” “Rutherfordium”
Group 4 elements (Ti, Zr, Hf), atomic and physical properties      957—958
Group 4 elements (Ti, Zr, Hf), coordination numbers and stereochemistries      960
Group 4 elements (Ti, Zr, Hf), group trends      957—960
Group 4 elements (Ti, Zr, HO, oxidation states      960
Group 5 elements (V, Nb, Ta)      see also “Vanadium” “Niobium” “Tantalum” “Dubnium”
Group 5 elements (V, Nb, Ta), atomic and physical properties      978
Group 5 elements (V, Nb, Ta), coordination numbers and stereochemistries      980
Group 5 elements (V, Nb, Ta), group trends      979 980
Group 5 elements (V, Nb, Ta), oxidation states      980
Group 6 elements (Cr, Mo, W)      see also “Chromium” “Molybdenum” “Tungsten”
Group 6 elements (Cr, Mo, W), atomic and physical properties      1004 1008
Group 6 elements (Cr, Mo, W), coordination numbers and stereochemistries      1006
Group 6 elements (Cr, Mo, W), group trends      1005
Group 6 elements (Cr, Mo, W), oxidation states      1006
Group 7 elements (Mn, Tc, Re)      see also “Manganese” “Technetium” “Rhenium”
Group 7 elements (Mn, Tc, Re), atomic and physical properties      1043
Group 7 elements (Mn, Tc, Re), coordination numbers and stereochemistries      1046
Group 7 elements (Mn, Tc, Re), group trends      1044 1045
Group 7 elements (Mn, Tc, Re), oxidation states      1046
Group 7 elements (Mn, Tc, Re), oxoanions      1049 1050
Group 7 elements (Mn, Tc, Re), redox properties      1044 1045
Group 8 elements      see “Iron” “Ruthenium” “Osmium”
Group 9 elements      see “Cobalt” “Rhodium” “Indium”
Guanidine      305
Guanine      61 62
Guano      408
Gunpowder      645 646
Gypsum      109 122
Gypsum, diluent in superphosphate fertilizer      525
Gypsum, occurrence in evaporites      647
Gypsum, process for $H_{3}PO_{4}$ manufacture      521 522
Gypsum, S recovery from      651 652
H bridge-bond in boranes and carboranes      154
Haber — Bosch ammonia synthesis      408 409
Haber — Bosch ammonia synthesis, historical development      421
Haber — Bosch ammonia synthesis, production statistics      421
Haber — Bosch ammonia synthesis, technical details      421
Haem      126 1099
Haematin      1099
Haematite      1071
Haemocyanin      1199
Haemoglobin      1098—1101
Hafnates      964
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