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Rappoport Z. (ed.) — The Chemistry of Dines and Polyenes (vol. 1)
Rappoport Z. (ed.) — The Chemistry of Dines and Polyenes (vol. 1)

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Название: The Chemistry of Dines and Polyenes (vol. 1)

Автор: Rappoport Z. (ed.)

Аннотация:

Dienes and polyenes are an extremely important group of chemicals in the investigation of different types of syntheses. Dienes and Polyenes are found in a large number of natural and man-made products including such natural products as terpenes, cholesterol, Vitamin A, and many essential oils, as well as many polymers and rubber products. In recent years the organometallic complexes of these compounds have been found to play an important role in synthesis. This volume is an invaluable reference source for researchers in academia and industry in organic and natural product chemistry and materials science. An extensive work covering all aspects of the synthetic analytical, biochemical, physical, and environmental aspects of these important molecules.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1997

Количество страниц: 1054

Добавлена в каталог: 20.04.2006

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Предметный указатель
$1,\omega$-Bis(diarylethenyl)alkanes, radiolysis of      338
$17\alpha$-(2-Iodoett)enyl)androsta-4,6-dien-$17\beta$-ol-3-one, $\sidset{^{125}}{}I$-labelled, synthesis of      845 846
$Ag^+-\pi$-complexation, in separation of dienes/polyenes      485
$C_{60}$      58 930 963
$[Cys-\sidset{^{14}}{}CO]LTC_4$, synthesis of      830 831
$\alpha$-Carbonyl radicals      644
$\alpha$-Farnesene, deuterium-labelled, synthesis of      791—793
$\alpha$-Lumieolehieine, synthesis of      268 269
$\alpha$-Phellandrene, photocyeloaddition of      274 275
$\alpha$-Terpinene, ring cleavage of      892
$\alpha,\omega$ Dialkylpolyenes, absorption spectra of      155
$\alpha,\omega$ Dialkylpolyenes, Raman spectra of      166—168
$\alpha,\omega$-Diphenylpolyenes, absorption spectra of      155 156
$\alpha,\omega$-Dithienylpolyenes, absorption spectra of      155 156
$\beta$-Angelica lactone, Diels — Alder reaction of      19
$\beta$-Carotene, deuterium-labelled, synthesis of      784 786
$\beta$-Carotene, structure of      150
$\beta$-Carotene, thermochemistry of      87
$\beta$-Vetivone, synthesis of      282 283
$\gamma$-Laetones, fonnation of      644 645
$\omega$-Iodoundecenyl cholesteryl ether, $\sidset{^{125}}{}I$-labelled, synthesis of      846
$\pi$-Allyl complexes      654 661 662 676
$\pi$-Olefln complexes      654
$\pi$-Orbitals, manifold of      214
$\pi$-Orbitals, noneonjugated, interaction between      215—228 250—254
$\pi$-Orbitals, two-centre      201 202
(Diene)palladium(II) complexes      654
1,1-Divinylcyclopropane, structure of      26—28
1,1-Divinylethylene, thermochemistry of      93
1,2-Dibromides, dehydrobromination of      364 365
1,2-Divinylcyclohexanes, oxidation of      658—660
1,3,5,7,9-Decapentaene, structure of      31
1,3-Butadiene, acidity of      735 736
1,3-Butadiene, conformation of      6 7 113 114 141 158—161
1,3-Butadiene, copolymerization with styrene      346
1,3-Butadiene, Diels — Alder reaction of      17—19
1,3-Butadiene, electronic transitions in      141 142
1,3-Butadiene, excited states of      11—13
1,3-Butadiene, force constants for      6
1,3-Butadiene, geometry of      4 5 114
1,3-Butadiene, harmonic vibrational frequencies for      5
1,3-Butadiene, MOs of      141 142
1,3-Butadiene, photodimerization of      296
1,3-Butadiene, polymerization of      343 345 346
1,3-Butadiene, radiolysis of      335
1,3-Butadiene, structure of      31 32 35
1,3-Butadiene, structure of, compared to radialenes      55 56
1,3-Butadiene, symmetry in      141—143
1,3-Butadiene, vibrational spectra of      158—161
1,3-Cyclohexadiene, Diels — Alder reaction of      566 568
1,3-Cyclohexadiene, polymerization of, radiation-induced      343 344
1,3-Cyclooctadienes, cyclization of      508
1,3-Cyclooctadienes, radiolysis of      335
1,3-Dienes      (see also “1 “1
1,3-Dienes, 1,4-chloroacetoxylation of      663 664
1,3-Dienes, 1,4-diacetoxylation of      662 663
1,3-Pentadiene, acidity of      740
1,3-Pentadiene, radiolysis of      335
1,4-Benzoquinones, as oxidizing agents      658 662 666 670 675 676
1,4-Benzoquinones, Diels — Alder reaction of      564 565
1,4-Chlorolactonization      668
1,4-Cyclohexadiene, reactions with hydrogen atoms      328
1,4-Dialkoxylation      666
1,4-Dienes      (see also “1
1,4-Dienes, palladium-catalysed oxidation of      660 661
1,4-Dienes, photorearrangement of      277—280
1,4-Oxyamination, palladium-catalysed      670
1,4-Oxychlorination      669 675
1,4-Oxylaetonization      668
1,4-Pentadiene, structure of      26 27
1,4-Pentadiene, thermochemistry of      71
1,5-Cyclooctadienes, palladium-catalysed oxidation of      657
1,6-Diphenylhexatriene, thermochemistry of      89
1-Phenylethyl radicals, addition to dienes      624
10,11-Dibromodibenzosuberone, tritium-labelled, synthesis of      821 822
13-cis-Retinoic acids      (see also “4-Oxo-13-cis-Retinoic acid”)
13-cis-Retinoic acids synthesis of, $\sidset{^{14}}{}C$-labelled      834 836
13-cis-Retinoic acids synthesis of, deuterium-labelled      783 784
15-Deoxy-16-hydroxy-16-methyl-5-thiaprosta-glandin $E_1$ methyl esters, deuterium-labelled, synthesis of      797—799
17-Amino-22-(4’-azido-3’-iodophenacyl)-17-demethoxygeldanamycin, $\sidset{^{125}}{}I$-labelled, synthesis of      847
2,3-Dichlorobutadiene, polymerization of, radiation-induced      343
2,3-Dimethylbutadiene, polymerization of, radiation-induced      343 344
2,4-Dimethylpentadiene, conformation of      7
2,5-Cyclohexadienones, photorearrangement of      280—285
2,6-Cycloheptadienones, photorearrangement of      286 287
2,7-Cyclooctadienones, photorearrangement of      285 286
2-Hydroxyalkyl-4-pyrones, photorearrangement of      290 291
3,4-Dimethylenecyclobutene, thermochemistry of      93 99 100
3-Hydroxy-4-pyrones, photorearrangement of      288 289
3-Hydroxyalkylpyrroles, synthesis of      305 306
4-Hydroxycyclohexene, radiolytic formation of      331
4-Hydroxypyrylium ions, photorearrangement of      289
4-Oxo-13-cis-retinoic acid, $\sidset{^{13}}{}C$-labelled, synthesis of      805
9-cis-Retinoic acids, tritium-labelled, synthesis of      808 809
Ab initio calculations      3
Ab initio calculations for Diels — Alder reaction      17—19
Ab initio calculations for evaluation of contributions to CD      124
Ab initio calculations for excited states      13 14
Abbott, P.A.      871(17) 886
Abdi-Oskoui, H.      557(42) 612
Abe, S.      827(146) 864
Abecassis, J.      398(121 122) 471
Abell, P.I.      627 634 636(35) 650
Abelman, M.M.      433(211) 476
Abeln, J.      605(183) 616
Abels, J.      590(129d) 615
Aben, R.W.      402 403(134c) 472
Aben, R.W.M.      586(115) 592(140) 615
Abiko, A.      420(166b) 474
Abram, T.S.      874(27) 886
Abrams, G.D.      531(94) 545
Absorption spectroscopy      151
Absorption spectroscopy of diene chromophore      112—114
Absorption spectroscopy of polyenes      155—158
Absorption spectroscopy of radiolytic intermediates      328—333
Acetylene, acidity of      735
Acetylene, deprotonation energy of      737 738
Achenbach, H.      494(22) 505
Achi, S.S.      639(78) 651
Achiba, Y.      179(15) 254
Achini, R.S.      532(95) 545
Acidity, gas-phase      733 734
Acidity, gas-phase of allyl hydrogens      739 740
Acidity, gas-phase of vinyl hydrogens      735—737
Acquardo, M.      298(78) 322
Acrolein, Diels — Alder reaction of      20
Acrylonitrile, radical addition to      625 626 648
Activation volume      548—552
Activation volume relationship with ring size      603 608 609
Acuna, A.U.      423(172a) 474
Adachi, N.      660(27) 680
Adam, M.      34(42) 62 440 443(245c) 477
Adam, W.      277(32c) 321 905(89) 911(128—131) 914(151) 924 925
Adamczak O.      36(50) 62 70(8 9) 104
Adams, J.      410(155a) 473 496(27) 505
Adger, BJ.      458(295) 479
Adjacency matrix      201 204
Adlington, R.M.      377(68c) 469 849(197) 866
Adlof, R.O.      778(6 9) 861
Aebischer, J.N.      248(304) 261
Afonso, C.A.M.      430(193a) 475
Afzal, J.      401(130) 472
Agarrabeita, A.R.      278(37) 321
Agarwal, D.D.      907(103) 924
Ager, D.J.      424(178e 178i) 475
Aglietto, M.      158(55) 171
Agmon, I.      947(48) 975
Agnel, G.      436(223a) 477
Ahamed, Z.      446 451(257f) 478
Ahem, D.      860(238) 867
Ahlrichs, R.      40(85) 63
Ahmad, S.      378(73) 469 898(50) 923
Ahmed, G.      315 317(120) 324
Ahuja, V.K.      781(13) 861
Aihara, J.      51(137b) 64
Aihara, M.      788(35) 862
Aistars, A.      315(112b) 324
Aizenshtat, Z.      492 493 503(15) 504 920(191) 926
Akagi, J.      913(141) 925
Akai, S.      408(154c) 473
Akasaka, T.      916(164) 925
AkasaM, Y.      313(109d 109f 109h) 324
Akermark, A.      423(175) 474
Akermark, B.      416(164b) 423(174) 434(209c) 473 474 476 653(lb) 661(30) 679 680
Akhunova, V.R.      921(205) 926
Al-Jobomy, M.I.      175(6) 254
Al-Laham, M.A.      32(25) 62
Alami, M.      438 439(233 234a) 455(283a) 477 479
Albert, B.      182(110) 257
Albert, I.D.L.      15(89) 22
Alberts, A.W.      827(144) 864
Alberts, I.L.      35 36(46a) 62 161(76) 171
ALBERTS, IA.      4(15) 21
Albrecht, A.C.      153(25) 170 243(298) 261
Albright, T.A.      174(1) 254
Alcock, H.R.      343(92) 344(94) 356
Alder, K.      518(44) 544
Aldol products      299
AlexaMs, A.      449(267a) 456(288) 478 479
Alfassi, Z.B.      332(18) 354
Algrim, DJ.      745 746(48) 751
Alkylidenecycloalkanes      (see also “Methylenecycloalkanes”)
Alkylidenecycloalkanes, structure of      50—52
Alkylidenecycloalkenes      (see also “Methylenecycloalkenes”)
Alkylidenecycloalkenes structure of      51—54
Alkynes      (see also “Acetylene” “Polyalkynes”)
Alkynes isomerization of      456 457
Alkynyl cations      869
all-trans-Menaquinone-4, $\sidset{^{14}}{}C$-labelled, synthesis of      837
Allan, M.      184(145) 236(268) 257 260
Allauddin, M.M.      399(124h 124i) 401(124i) 472
Allen, C.F.H.      401(132a) 472
Allen, F.H.      41(90) 63
Allen, W.S.      770(20) 774
Allenby, G.      808(83) 863
Allenes      (see also “Chlorotriarylallenes” “Cumulated
Allenes epoxidation of      905 906
Allenes formation of      265
Allenes oxidation of, palladium-catalysed      677—679
Allenes oxidation of, with ozone      921
Allenes oxidation of, with singlet oxygen      915 916
Allenes radiolysis of      338
Allenes reduction of, selective      466 467
Allenes thermochemistry of      72
Allenic polyenes      see “Cumulated polyenes”
Allenyl cations      869 870
Allenyl cations cycloadditions of      877—881
Allenyl cations ferrocenyl-substituted      874 875
Allenyl cations generation of      870—881
Allenyl cations identification of      881 882
Allenyl halides, photolysis of      870 871
Allinger, N.      749(67) 751
Allinger, N.L.      38(67) 39(77) 63 70 71 88(7) 104 563(64a) 613 686(4) 730
Allred, A.      (29) 731
Allyl anions      (see also “Diphenylallyl anions” “Triphenylallyl
Allyl anions in solution      744—750
Allyl anions stabilization of      740—743
Allyl anions structure of      741 742
Allyl anions theoretical studies of      740—744
Allyl carbanions      673
Allyl cations, trapping of      647 648
Allyl radical cyclization      627—630
Allyl radicals      329 335 339 350
Allyl radicals dimerization of      640—643
Allyl radicals, electron affinity of      739
Allyl radicals, oxidation of      646—649
Allyl radicals, stabilization energy for      627
Allyl radicals, trapping of, with closed-shell molecules      634—637
Allyl radicals, trapping of, with radicals      637—640
Allylic acetates, decarboxylative eliminations of      372—374
Allylic alcohols, formation of      891
Allylic axial chirality rule      120—126
Allylic axial chirality rule diene/olefin picture of      125—127 131 132
Allylic dihalides, dehalogenation of      366
Allylic halides, dehydrohalogenation of      364 366
Allylic hydrogens, abstraction of      328
Allylic hydrogens, gas-phase acidity of      739 740
Allylic nitroacetates, reductive elimination reactions of      377
Allylic substituents, contribution to CD intensity      123—126
Allylic sulphones, as precursors of conjugated dienes/polyenes      394 396
Allyllithiums      744 745 747
Allylpotassiums      746 747
Allylsilanes, cationic cyclization of      533—536
Allylsilanes, reactions of      673 674
Almenningen, A.      40(84) 42(92) 53 54(152) 63 65 158(45) 170
Alonso, D.      17 19 20(112 114) 23
Alonso, I.      393(104) 471
Alper, H.      456(286 287) 479
Alshuth, T.      150 151(12) 170
Alteramide A, intramolecular [4+4]photocycloaddition of      308
Alvarez, J.      430(192) 475
Alvarez, R.      446 451(257g) 478
Amann, CM.      290(64) 322
Amano, A.      18(132a) 23
Amat Gueriie, F.      423(172a) 474
Amberg, W.      897(44) 923
Ambident cations      871
Ambiphilic radicals      648
Amide ions, reactions of      735 736
Amiich, M.J.Jr.      549(22d) 612
Amim, E.von      347(116) 356
Amit, A.      49(124) 64
AMl method, in study of Diels — Alder reaction      18
Amould, D.      394(105e) 471
Amrein, W.      56(167) 65 940 945(26a) 975
Amrich, M.J.      601(170) 616
Amstrup, B.      31(14) 61
Anastasia, M.      893(15) 922
Anastassiou, A.G.      180 183(76) 256
Ancel, J.-E.      382 384(83h) 470
Andersen, B.      49(123) 64
Andersen, N.H.      526(76a-c) 545
Anderson, D.R.      402 403(134b) 472
Anderson, R.      424(178(1 475
Anderson, RJ.      532(95) 545
Anderson, W.S.      346(100) 356
Andersson, K.      243(296) 261
Andersson, P.G.      668(49a 49b 50) 669(51) 670(52 53) 672 673(54a 54b) 675(58a 58b 59) 676(58b) 677(60) 680 681
Andino, J.M.      922(219) 926
Ando, W.      916(164) 925
Andre, C      388 390(96d) 470
Andre, J.M.      2 15(2) 20
Andreini, B.P.      452(269c) 478
Andres, J.L.      32(25) 62
Andres, J.M.      15(84 87) 16(87 93) 22 371(44) 468
Andrewes, A.G.      501 504(49) 505
Andrews, A.G.      494(23) 505
Andrews, G.C.      812(94) 863
Andrews, L.      233(232) 236(250 253 255 263 264) 237(263 264 276 277 285) 248(250 264 285) 249(250 263 264 285) 250(306) 260 261
Andrews, R.C.      394(105b) 471
Andriamialisoa, Z.      368 369(31b) 380(79 80) 468 470
Andzelm, J.      17 18(98) 22
Anet, E.F.L.J.      791(41) 862
Anet, F.A.L.      81(35a) 107
Anet, R.      405(142) 472
Angell, R.      424(180) 475
Anghoh, A.G.      408(154c) 473
Angus, R.O.Jr.      947(57) 975
Anh, N.T.      17 19 20(116) 23
Annulenes, chemical shifts for      484
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