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Prigogine I., Rice S.A. — Advances in chemical physics. Volume 117
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Íàçâàíèå: Advances in chemical physics. Volume 117Àâòîðû: Prigogine I., Rice S.A. Àííîòàöèÿ: Providing the chemical physics field with a forum for critical, authoritative evaluations in every area of the discipline, the latest volume of Advances in Chemical Physics continues to provide significant, up-to-date chapters written by internationally recognized researchers.
This volume is essentially devoted to helping the reader obtain general information about a wide variety of topics in chemical physics. Advances in Chemical Physics, Volume 117 includes chapters addressing laser photoelectron spectroscopy, nonadiabatic transitions due to curve crossings, multidimensional raman spectroscopy, birefringence and dielectric relaxation in strong electric fields, and crossover formulae for Kramers Theory of thermally activated escape rates.
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Fluctuation-dissipation theorem, Kramers reaction rate theory, crossover between IHD/VLD regimes, variance of energy 664 Flusberg, A. 260(93) 273 Flux calculations, Kramers reaction rate theory, crossover between IHD/VLD regimes, double well potential bridging formula 652—655 Flux calculations, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, Langer's treatment of 587—588 Fokker — Planck equation see also "Smoluchowski equation" Fokker — Planck equation, Brownian motion, research background 277—279 Fokker — Planck equation, Brownian motion, theoretical summary 490—493 Fokker — Planck equation, continued fraction technique, differential-recurrence equations, moment systems 304—307 Fokker — Planck equation, dynamic Kerr effect, linear response theory, weak ac electric field steady-state response superimposed on dc bias field 348—349 Fokker — Planck equation, inertial effects, dielectric and birefringence relaxation 416—417 Fokker — Planck equation, inertial effects, dielectric and birefringence relaxation, spectra and relaxation times 436—439 Fokker — Planck equation, Kramers reaction rate theory 493—497 Fokker — Planck equation, Kramers reaction rate theory, axial/nonaxial symmetric potentials, escape rates 677—681 Fokker — Planck equation, Kramers reaction rate theory, axial/nonaxial symmetric potentials, nonaxial formula divergence for small axial symmetry departures 684—690 Fokker — Planck equation, Kramers reaction rate theory, crossover between IHD/VLD regimes 632 Fokker — Planck equation, Kramers reaction rate theory, crossover between IHD/VLD regimes, double well potential bridging formula 650—655 Fokker — Planck equation, Kramers reaction rate theory, crossover between IHD/VLD regimes, energy-action variables 634—637 Fokker — Planck equation, Kramers reaction rate theory, crossover between IHD/VLD regimes, energy-action variables, right-hand side operators 635 657—658 Fokker — Planck equation, Kramers reaction rate theory, escape rate validity 499—501 Fokker — Planck equation, Kramers reaction rate theory, intermediate-to-high damping (IHD) regime, Langer's treatment of 583—588 Fokker — Planck equation, Kramers reaction rate theory, intermediate-to-high damping (IHD) regime, left eigenvector 585 598—600 Fokker — Planck equation, Kramers reaction rate theory, Klein — Kramers equation, drift/diffusion coefficients 512 Fokker — Planck equation, Kramers reaction rate theory, Klein — Kramers equation, mean and mean square momentum changes 515—516 Fokker — Planck equation, Kramers reaction rate theory, Klein — Kramers equation, probability density, state space evolution 517—520 Fokker — Planck equation, Kramers reaction rate theory, Klein — Kramers equation, range of validity, damping regimes 551—555 Fokker — Planck equation, Kramers reaction rate theory, low-damping (LD) regime, FPT escape, adjoint operator 613—617 Fokker — Planck equation, Kramers reaction rate theory, low-damping (LD) regime, FPT escape, rate calculations 611—613 Fokker — Planck equation, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, integral expression of escape time 743—745 Fokker — Planck equation, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, principles 741—743 Fokker — Planck equation, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, series expression for summit time 752—753 Fokker — Planck equation, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, uniaxial anisotropy explicit expression 753—758 Fokker — Planck equation, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, zero-frequency limit, delta function orientation distribution 745—749 Fokker — Planck equation, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, zero-frequency limit, recurrence relations 749—752 Fokker — Planck equation, Kramers reaction rate theory, rotational Brownian motion 503—504 Fokker — Planck equation, Kramers reaction rate theory, rotational Brownian motion, mean first passage times (MFPT) escape rate calculation 575—578 Fokker — Planck equation, Kramers reaction rate theory, rotational Brownian motion, single domain ferromagnetic particles 565—566 Fokker — Planck equation, nonlinear Brownian relaxation, strong electric fields, nonstationary ac response 399—401 Fokker — Planck equation, nonlinear Brownian relaxation, strong electric fields, one-dimensional relaxation models 308—317 Fokker — Planck equation, nonlinear dielectric and birefringence relaxation 279—283 Fokker — Planck equation, relaxation time, linear response 465—468 Fokker — Planck equation, superparamagnetic particle relaxation, background 447 Fokker — Planck equation, superparamagnetic particle relaxation, transient nonlinear response 454—456 Fokker — Planck equation, superparamagnetic particle relaxation, uniaxial potential 457—460 Fokker — Planck equation, weak electric field, superimposition on strong dc bias field, perturbation solutions 358—373 Fokker — Planck equation, weak electric field, superimposition on strong dc bias field, perturbation solutions, dispersion plots 368—373 Fokker — Planck equation, weak electric field, superimposition on strong dc bias field, perturbation solutions, equilibrium and first-order solutions, matrix continued functions 362—364 Fokker — Planck equation, weak electric field, superimposition on strong dc bias field, perturbation solutions, second-order solutions 364—368 Forck, P. 10(62 65) 119 Forster, D. 417—419(104) 480 Fortune, P.J. 93(244) 124 Foster, S.C. 35(113) 120 Fotakis, C. 84(222) 86(235) 123—124 Four-transition-point asymptotic expansion, noncurve crossing, nonadiabatic transitions, exponential potential model 170—172 Four-transition-point asymptotic expansion, noncurve crossing, nonadiabatic transitions, future research 181—182 Four-transition-point asymptotic expansion, two-state curve crossing, nonadiabatic transitions, Stokes phenomenon, comparison of 141—142 Fourier transform, coherent anti-Stokes Raman scattering (CARS), intermolecular vibrations 246 Fourier transform, coherent anti-Stokes Raman scattering (CARS), intramolecular vibrations 241—243 Fourier transform, inertial effects, dielectric and birefringence relaxation, dielectric response 425—428 Fourier transform, inertial effects, dielectric and birefringence relaxation, linear Kerr effect response 428—429 Fourier transform, Kramers reaction rate theory, axial/nonaxial symmetric potentials, escape rates, uniaxial perturbation 704—706 725—740 Fourier transform, Kramers reaction rate theory, crossover between IHD/VLD regimes, double well potential model, bridging formula 651—655 Fourier transform, Kramers reaction rate theory, crossover between IHD/VLD regimes, double well potential model, Wiener — Hopf method 669—674 Fourier transform, Kramers reaction rate theory, crossover between IHD/VLD regimes, Green's function, energy diffusion equation, proof 660—663 Fourier transform, Kramers reaction rate theory, crossover between IHD/VLD regimes, Wiener — Hopf integral equation, energy distribution function 639—646 Fourier transform, Kramers reaction rate theory, crossover between IHD/VLD regimes, Wiener — Hopf integral equation, proofs 664—665 Fourier transform, Kramers reaction rate theory, Fourier transform, Kramers reaction rate theory, linear effect Kerr response 428—429 469—472 Fourier transform, Kramers reaction rate theory, nonlinear Brownian relaxation, strong electric fields, rigid polar molecules, superimposed ac/dc electric fields 374—382 Fourier transform, Kramers reaction rate theory, nonlinear dielectric and birefringence relaxation, strong dc electric fields 326—330 Fourier transform, Kramers reaction rate theory, nonlinear dielectric and Kerr effect relaxation, strong dc electric fields 343—347 Fourier transform, Kramers reaction rate theory, rotational diffusion, mean field potential, matrix continued fractions, complex susceptibility 442—446 Fourier transform, Kramers reaction rate theory, traverse susceptibility calculations 427 468—472 Fourkas, J.T. 245(20) 246—247(22) 254(45) 257(22 53—54 82 85 88) 258(82 85) 260(20 85 94—95) 269(85) 271—273 Fragmentation, ammonia molecules 100—105 Fragmentation, OCS molecule 93—97 Franck — Condon factor, (1 + 1') resonance-enhanced multiphoton ionization (REMPI) spectroscopy, hydrogen molecules 34 Franck — Condon factor, (3 + 1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy, deuterium molecular photoionization 28 Franck — Condon factor, (3 + 1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy, hydrogen molecule photodissociation 20—23 Franck — Condon factor, ammonia molecules 97—105 Franck — Condon factor, CIO radicals 78—81 Franck — Condon factor, SH radical, two-state interaction model 45—47 Franken, P.A. 402(90) 480 Fredholm integral equation, Kramers reaction rate theory, Klein — Kramers equation, range of validity, damping regimes 551 Fredin, S. 42(134) 121 Free rotational memory function, inertial effects, dielectric and birefringence relaxation, dielectric response 425—428 Free rotational memory function, inertial effects, dielectric and birefringence relaxation, equation of motion for 419—425 Free rotational memory function, inertial effects, dielectric and birefringence relaxation, extended rotational diffusion model 418—425 Free-induction decay (FID), overtone dephasing spectroscopy 266—269 Free-induction decay (FID), Raman-echo spectroscopy, liquid molecules 252—256 Freeman, C.G. 71(168) 122 Freitas, J.E. 254(46) 272 Frenkel, J. 489(7) 581(7) 762 Frequency-resolved optical Kerr effect spectroscopy, principles of 269—270 Friedman, J.R. 211(98) 219(98) 233 Fritz, G.W. 346—347(69) 479 Frye, J.M. 93(239) 124 Fujii, A. 36(120—121) 38(120—121) 120 Fujimura, Y. 3(5) 117 215—216(99) 233 Fukuda, Y. 282(21) 289(21) 462(21) 478 Fulton, R.L. 282(16) 478 Furukawa, T. 462(138) 481 Gallagher, T.F. 5(23) 117 Gamma relaxation function, Kramers reaction rate theory, axial/nonaxial symmetric potentials, escape rates, uniaxial perturbation 705—706 735—740 Gamma relaxation function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution, uniaxial anisotropy 753—758 Gamma relaxation function, nonlinear dielectric and birefringent high fields, build-up processes 286—288 Gammaitoni, L. 374(81) 396(81) 399(81) 401(81) 479 761—762(97) 765 Garanin, D.A. 358(74) 479 489(70) 503(70) 578(93 107) 579(93) 613(70) 624—626(70) 656(70) 675—676(70) 678(70) 684(70) 690(70) 694—695(70) 702(70) 759(107) 760(96) 764—765 Gardiner, B.G. 71(162) 122 Gardiner, C.W. 492—493(24) 763 Gas-phase molecules, laser photoelectron spectroscopy 7—8 Gas-phase molecules, Raman-echo spectroscopy 251 Gaspard, P. 762(99) 765 Gauyacq, D. 42(134) 121 Gayathri, N. 267(121) 274 Gaydon, A.G. 71(163) 122 Gefen, Y. 133(60 63—64 66) 182(60 63—64 66) 232 Geller, M. 71—72(183) 122 Geoghegan, L.J. 277(6) 446(6) 451(6) 454(6) 477 489(59) 504(65) 566(52) 574(59) 579(65) 584(65) 593(65) 597—598(65) 674(52) 682—684(65) 686(65) 704(65) 707(52) 709(65) 763—764 George, S.M. 254(43—44) 271 Gerade symmetry, (1 + 1') resonance-enhanced multiphoton ionization, hydrogen molecules 32—34 Gerade symmetry, molecular excited states, laser photoelectron spectroscopy 3—8 Gerade symmetry, three-atomic molecules, carbondisulfide complexes 84—85 Gericke, K.H. 40(131) 59(154) 72(191 197) 79(197 202) 121—123 Gerling, R.W. 440(120) 480 Geschwind, S. 251(31) 271 Gestblom, B. 568(83) 626(83) 741(83) 764 Gilbert equation, Kramers reaction rate theory, axial/nonaxial symmetric potentials, escape rates 676—681 Gilbert equation, Kramers reaction rate theory, axial/nonaxial symmetric potentials, nonaxial formula divergence for small axial symmetry departures 682—690 Gilbert equation, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit 579—581 Gilbert equation, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, magnetic spins 593—598 Gilbert equation, Kramers reaction rate theory, low-damping (LD) regime, escape rate calculations, adjoint Fokker — Planck operator, differential equation 614—617 Gilbert equation, Kramers reaction rate theory, low-damping (LD) regime, escape rate calculations, boundary layer approximation 629—630 Gilbert equation, Kramers reaction rate theory, low-damping (LD) regime, escape rate calculations, stretching transformation, mean first passage times (MFPT) 620—623 Gilbert equation, Kramers reaction rate theory, rotational Brownian motion 502—504 Gilbert equation, rotational Brownian motion, Kramers reaction rate theory, single domain ferromagnetic particles 562—566 Gilbert equation, superparamagnetic particle relaxation 447 Gilbert equation, superparamagnetic particle relaxation, strong dc magnetic field 448—450 Gilbert, T.L. 447(127) 481 Glab, W.L. 10(79) 119 Glass-Maujean, M. 34(108) 120 Glownia, J.H. 99—100(268—269) 124—125 Goldstein, H. 280(13) 477 494—495(32) 498(32) 532(32) 541(32) 613(32) 763 Goodman, F.O. 132(52) 193(52) 196(52) 232 Goodman, G.L. 109(295) 125 Goodwhite, H. 125 Gordon, M.A. 42(136) 121 Gordon, R.G. 417—418(103) 480 Gordon, R.J. 133(59) 232 Gorian, M. 674(85) 741(85) 764 Gosh, P.K. 6(34) 117 Gradshteyn, I.S. 469(140) 481 Graham, W.R.M. 59(152) 121 Grant, E.R. 5(21) 84(222) 86(228 235) 117 123—124 Green's function, inertial effects, dielectric and birefringence relaxation 416—417 Green's function, Kramers reaction rate theory, crossover between IHD/VLD regimes, double well potential bridging formula 650—655 Green's function, Kramers reaction rate theory, crossover between IHD/VLD regimes, energy diffusion equation 638—639 Green's function, Kramers reaction rate theory, crossover between IHD/VLD regimes, energy diffusion equation, proof 659—663 Green's function, Kramers reaction rate theory, crossover between IHD/VLD regimes, Fokker — Planck equation 637 Green's function, Kramers reaction rate theory, crossover between IHD/VLD regimes, Wiener — Hopf integral equation, energy distribution function 642—646 Green's function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential evolution, Fokker — Planck equation, zero-frequency limit, delta function orientation distribution 745—749 Green's function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential evolution, integral expression of escape time 743—745 Green's function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential evolution, principles 741—743 Green's function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential evolution, series expression for summit time 752—753 Green's function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential evolution, uniaxial anisotropy explicit expression 753—758 Green's function, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential evolution, zero-frequency limit recurrence relations 749—752 Green's function, Kramers reaction rate theory, rotational Brownian motion, integral relaxation time 578—579 Green's function, Kramers reaction rate theory, rotational Brownian motion, mean first passage times (MFPT) escape rate calculation 576—578 Green's function, nonlinear dielectric and birefringence relaxation 282—283 Greening, F.R. 84(217) 89(217) 123 Grieser, M. 10(62 65) 119 Grillon, G. 403(94) 480 Gross, E.P. 417(98 100) 440(100) 480 Grote — Hynes frequency, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, magnetic spins 597—598 Grote, R.F. 494(33) 597(33) 763 Guan, H.W. 403(93) 480 Guberman, S.L. 20(91) 34(91) 120 Guissani, Y. 417(105—106) 422(106) 480 Gunther, L. 604(64) 580—581(64 72) 593—594(64 72) 595(64) 596(64 72) 613—614(64 72) 615(64) 617—618(64 72) 622(64) 626(64 72) 629(64) 694(64 72) 764 Guyon, P.M. 34(108) 120 Haas, T. 59(154) 121 Habenicht, W. 99(270—271) 125 Habs, D. 10(62 65) 119 Haddock, J. 71(175) 122 Haenggi, P. 374(81) 396(81) 399(81) 401(81) 479 486—491(1) 501(1) 504(1) 527(1) 541(1) 576(1) 578—579(1) 581—583(1) 585(1) 588(1) 597(1) 601(1) 608(1) 611(1) 617(1) 620(1) 623(1) 632(1) 635(1) 656(1) 743(1) 761(97) 762(1 97) 762 765 Hahn, E.L. 246(25) 262(97) 270(97) 271 273 Hahn, S. 257(91) 264(91) 273 Half-collision/dissociation processes, laser photoelectron spectroscopy, hydrogen and deuterium molecules 9—11 Hamiltonian equations, Kramers reaction rate theory, axial/nonaxial symmetric potentials, escape rates, axial symmetric calculations 676—677 715—716 Hamiltonian equations, Kramers reaction rate theory, axial/nonaxial symmetric potentials, escape rates, nonaxial formula divergence for small axial symmetry departures 681—690 Hamiltonian equations, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, Langer's treatment of 581—588 Hamiltonian equations, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, magnetic spins 593—598 Hamiltonian equations, Kramers reaction rate theory, low-damping (LD) regime, escape rate calculations 626 Hancock, H. 424(111) 440(111) 470(111) 480 Harrel, S. 269(124) 274 Harris, A.L. 254(44) 271 Harris, C.B. 254(43—44) 271 Harris, R.A. 108(291) 125 Hartmann, S.R. 246(26) 248(29) 251(29 32—33) 260(93) 271 273 Hartree — Fock calculations, laser photoelectron spectroscopy, OH radicals 40—41 Hasselbach, K. 626(77—78) 764 Hatano, Y. 30(100) 32(105—106) 120 Hayes, E.F. 282(15) 462(15) 478 Heading, J. 137(74) 141(74) 171(74) 232 Heat bath systems, Klein — Kramers equation, intuitive derivation 510—511 Heat bath systems, Klein — Kramers equation, Kramers' derivation 512—522 Heat bath systems, Klein — Kramers equation, Liouville equation 508—509 Heat bath systems, Kramers reaction rate theory, intermediate-to-high damping (IHD) regime, Langer's treatment of 582—588 Heavy-light-heavy (HLH) reactions, nonadiabatic curve crossings, multidimensional problems 162—168 Hechtfischer, U. 10(60) 19(60) 21(60) 119 Heiles, C.E. 42(137) 121 Hellemans, L. 289(42—44) 373(42—44) 462(42—44 136—137) 478 481 Heller, E.J. 131(29) 168(29) 230(29) 231 Helm, H. 10(69 81—82) 119 Hepburn, J.W. 97(261) 124 Herek, J.L. 71(177) 122 Hermitian conjugation, nonlinear dielectric and birefringence relaxation, strong dc electric fields 322—330 Herzberg, G. 3(1—3) 10(87) 24(3 87) 27(1 3) 43(3) 59(3) 66(3) 84(2) 92(2) 94(2) 116 119 Hess, W. 99(274) 125 Hessian matrix, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, Kramers' formula as Langer's formula 590—593 Hessian matrix, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, Langer's treatment of 586—588 Hessian matrix, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, left eigenvector 585 598—600 Hessian matrix, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, magnetic spins 596—598 Hessler, J.P. 10(79) 119 Hiberty, P.C. 132(48) 232 Hickman, A.P. 10(80 82) 119 Hinkley, E.D. 71(180) 122 Hinnen, P.C. 29(99) 120 Hioe, F.T. 131(43) 205(43) 231 Hipes, P.G. 162(86) 233 Hiraya, A. 106—108(284) 109(294) 111(294) 113—114(301) 125 Hirota, E. 71(189) 93(238) 122 124 Ho, T.S. 215(100) 233 Hodgson, A. 40(130) 121 Hogervorst, W. 29(98) 120 Hollas, J.M. 97(262) 99(262) 124 Holt, R.B. 36(122) 120 Homer, B.K. 156(82) 233 Homogeneous nucleation, Kramers reaction-rate theory, intermediate-to-high damping (IHD) limit 580—581 Hopman, H.J. 10(68) 12(68) 33(68) 119 Horani, M. 42(134) 84(222) 121 123 Houston, P.L. 97(261) 124 Howe, J.D. 6(45) 7(47) 59(153) 106—108(47) 109(45) 111(45) 114(47) 118 121 Hsu, C.W. 43(143) 121 Hsu, K.J. 79(201) 123 Hu, P. 251(31) 271 Huber, J.R. 71(172) 84(213) 122—123 Huber, K.P. 3(3) 24(3) 27(3) 43(3) 59(3) 66(3) 116 Hubin-Franskin, M.-J. 84(221) 94(254) 123—124 Hudgens, J.W. 59(155 158) 66(155) 72(193 195) 73—74(195) 101(283) 121—122 125 Hueber, R.H. 86(234) 124 Hulin, D. 403(94) 480 Hund's case (b) coupling, (3 + 1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy, deuterium molecular photoionization 27—28 Hunter, G. 24(95—96) 120 Hydrodynamical derivative, Liouville equation, Klein — Kramers derivation 506—508 Hydrogen molecules, resonance-enhanced multiphoton ionization (REMPI) spectroscopy 9—34 Hydrogen molecules, resonance-enhanced multiphoton ionization (REMPI) spectroscopy, (1 + 1' REMPI) 29—34 Hydrogen molecules, resonance-enhanced multiphoton ionization (REMPI) spectroscopy, (3 + 1 REMPI) 12—23 Hydrogen molecules, resonance-enhanced multiphoton ionization (REMPI) spectroscopy, (3 + 1 REMPI), photodissociation 19—23 Hydrogen molecules, resonance-enhanced multiphoton ionization (REMPI) spectroscopy, (3 + 1 REMPI), photoionization 12—19 Hydrogen molecules, resonance-enhanced multiphoton ionization (REMPI) spectroscopy, dissociative recombination (DR) 9—11 Hynes, G.T. 494(33) 597(33) 763 Hyperpolarizability tensors, Kerr effect relaxation, linear ac response and aftereffect solution 412—416 Hyperpolarizability tensors, Kerr effect relaxation, nonlinear dielectric and birefringence relaxation, Smoluchowski equation 280—283 Hyperpolarizability tensors, Kerr effect relaxation, nonlinear step-on responses 401—412 Hyperspherical coordinate technique, nonadiabatic curve crossings, multidimensional problems 162—168 I-matrix propagation, molecular control, time-dependent external fields 206—214 I-matrix propagation, nonadiabatic transitions, curve crossings, multichannel processes 152—153 156—159 I-matrix propagation, nonadiabatic transitions, curve crossings, multidimensional problems 164—168 I-matrix propagation, noncurve crossing, nonadiabatic transitions, attractive potential model 180—181 I-matrix propagation, noncurve crossing, nonadiabatic transitions, Rosen — Zenker — Demkov model 174—175 I-matrix propagation, time-dependent level crossings, nonadiabatic transitions 197—201 Imigoden radical see "NH radical" Imry, Y. 133(61) 182(61) 232 Inaba, R. 252(38—40) 271 Ince, E.L. 742(89) 764 Induced dipole moment, nonlinear dielectric and birefringence relaxation, second-order perturbation solutions 367—368 Induced dipole moment, nonlinear dielectric and Kerr effect relaxation, strong dc electric fields, step-on response 336—340 Induced dipole moment, weak ac electric field steady-state response superimposed on dc bias field, linear response theory 349 Induced dipole moment, weak ac electric field steady-state response superimposed on dc bias field, transient and relaxation times 350—351 Inertial effects, dielectric and birefringence relaxation, dielectric response 425—428 Inertial effects, dielectric and birefringence relaxation, free rotation equation of motion 419—425 Inertial effects, dielectric and birefringence relaxation, free rotation equation of motion, general equations 417—419 Inertial effects, dielectric and birefringence relaxation, Kerr effect response 428—429 Inertial effects, dielectric and birefringence relaxation, linear response 416—439 Inertial effects, dielectric and birefringence relaxation, spectra and relaxation times 429—439 Inertial effects, Kramers reaction rate theory, Klein — Kramers equation, probability density, state space evolution 519—520 Inertial effects, Kramers reaction rate theory, Klein — Kramers equation, reaction rate calculations 527—531 Inertial effects, Kramers reaction rate theory, Klein — Kramers equation, velocity distribution 522 Inertial effects, Kramers reaction rate theory, rotational Brownian motion, dielectric relaxation 568—569 Inhomogeneity, fifth-order Raman spectroscopy, intermolecular vibrations 261—264 Inhomogeneity, Raman-echo spectroscopy, liquid molecules 253—256 Inhomogeneous nucleation, Kramers reaction-rate theory, intermediate-to-high damping (IHD) limit 580—581 Initial value representation, nonadiabatic transitions, multichannel and multidimensional problems 131 Initial value representation, two-state curve crossing, nonadiabatic transitions, multidimensional problems 168 Inn, E.C.Y. 86(231) 123 Inoue, N. 10(61) 119 Integral relaxation time, Kramers reaction rate theory, intermediate-to-high damping (IHD) limit, particle current density 600 607—608 Integral relaxation time, Kramers reaction rate theory, rigid Brownian rotator escape times, bistable potential, Green function time evolution 743—745 759—760 Integral relaxation time, Kramers reaction rate theory, rotational Brownian motion 578—579 Integral representation, Brownian motion principles 492—493 Integral representation, dynamic Kerr effect correlation time, weak ac electric field steady-state response superimposed on dc bias field 354—356
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