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Miessler G., Tarr D.A. — Inorganic Chemistry
Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
$B_2$, molecular orbitals      127
$CN^-$ (cyanide), as ligand      475
$C_2$ axes, perpendicular      86 87 101
$C_2$, molecular orbitals      127
$C_A$, $E_A$, $C_B$, and $E_B$ values      190
$C_n$ axis      82
$FHF^-$, hydrogen bonding      174
$FHF^-$, molecular orbitals      140—143 175
$F_2$, molecular orbitals      127 128
$F_2$, symmetry      90
$H_c$, critical magnetic field for superconductivity      228
$IF_7$      53
$I_2$, spectra in different solvents      178
$m_l$, magnetic quantum number      26
$m_s$, spin quantum number      26 27
$Ni(cyclobutadiene)_2$, symmetry      90
$OCN^-$ (cyanate ion), VSEPR and structure      54
$ONOO^-$ (peroxynitrite), structure      278
$SCN^-$ (thiocyanate) VSEPR and structure      54
$sp^2$ hybrids in water      158
$S_n$, rotation-reflection operation      80
$S_N1$ CB mechanism      426 427
$S_N1$ lim mechanism      416
$S_N2$ lim mechanism      416
$S_{2n}$, axes      83 88
$[Co(tren)(sal)]^+$ isomers      313
$\beta$ decay      8
$\Delta H^0$ from temperature dependence of equilibrium constant      192 193
$\Delta S^0$ from temperature dependence of equilibrium constant      193
$\Delta_0$ in octahedral complexes      346
$\Delta_0$ in octahedral complexes, determining from spectra      393—395 401 402
$\mathrm{(AsBr_3)}$, bond angle      66
$\mathrm{(AsCl_3)}$, bond angle      66
$\mathrm{(AsF_3)}$, bond angle      66
$\mathrm{(AsH_3)}$, bond angle      66
$\mathrm{(AsH_3)}$, bond angle, VSEPR and structure      66
$\mathrm{(C_5H_5)_2Fe}$, ferrocene      457
$\mathrm{A1_2(CH_3)_6}$ structure      296
$\mathrm{Al_3N_3}$ ring      261
$\mathrm{Al_4(OH)_8Si_4O_{10}}$ (kaolinite)      234
$\mathrm{Au(PPh_3)}$ fragment      566
$\mathrm{B(OH)_3$, symmetry      89
$\mathrm{BeCl_2}$, bonding      56 57
$\mathrm{BeF_2}$, bonding      56 57
$\mathrm{Be_2}$, molecular orbitals      127
$\mathrm{BF_3\dot NH_3}$ adduct      170 171
$\mathrm{BF_3\dot O(C_2H_5)_2}$ adduct, boiling point      171
$\mathrm{BF_3}$, bonding      58 59
$\mathrm{BF_3}$, molecular orbitals      154—156
$\mathrm{BF_3}$, symmetry      89
$\mathrm{BrF_3}$      290
$\mathrm{BrF_3}$, solvent      168
$\mathrm{BrF_3}$, VSEPR and structure      60
$\mathrm{BrF_4^-}$      290
$\mathrm{BrF_5}$, symmetry      89
$\mathrm{B_2H_6}$, bonding      256—258
$\mathrm{B_3P_3}$ rings      261
$\mathrm{B_6H_6^{2-}}$, bonding      573 574
$\mathrm{B_{12}H_{12}^{2-}}$, symmetry      85 86
$\mathrm{CCl_4}$, dipole moment      68
$\mathrm{CH_4}$, dipole moment      68
$\mathrm{CH_4}$, symmetry      85 86
$\mathrm{CH_4}$, VSEPR and structure      59
$\mathrm{ClF_3}$      53 290
$\mathrm{ClF_3}$, VSEPR and structure      60
$\mathrm{ClF_5}$      290
$\mathrm{ClOF_3}$, structure      62
$\mathrm{CO_2}$ (carbon dioxide)      267
$\mathrm{CO_2}$ (carbon dioxide) and greenhouse effect      634
$\mathrm{CO_2}$ (carbon dioxide), electron-dot diagram      52
$\mathrm{CO_2}$ (carbon dioxide), geometry      52
$\mathrm{CO_2}$ (carbon dioxide), molecular orbitals      143—147
$\mathrm{CO_2}$ (carbon dioxide), symmetry      85 86
$\mathrm{CO_3^{2-}}$ (carbonate ion), electron-dot diagram      52
$\mathrm{CO_3^{2-}}$ (carbonate ion), molecular orbitals      156
$\mathrm{CO_3^{2-}}$ (carbonate ion), structure and dipole moment      68
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$      499 500
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$, $^1HNMR$      499
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$, cis and trans isomers      499 500
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$, synthesis      499
$\mathrm{Cr(CO)_6}$ and 18—electron rule      463—465
$\mathrm{Cr(CO)_6}$, molecular orbitals      464
$\mathrm{C_2H_2Cl_2Br_2}$, symmetry      85
$\mathrm{C_2H_2}$      90
$\mathrm{C_2H_2}$, electron-dot diagram and geometry      52
$\mathrm{C_5H_5}$ and CO complexes      491
$\mathrm{C_5H_5}$, cyclopentadienyl      485
$\mathrm{C_6D_6}$ synthesis      535
$\mathrm{C_{60}}$, buckminsterfullerene      4 265
$\mathrm{C_{60}}$, buckminsterfullerene as ligand      493—495
$\mathrm{C_{70}}$      265
$\mathrm{C_{80}}$      265
$\mathrm{Eu^{2+}}(aq)$ reactions      443
$\mathrm{fac-Mo(CO)_3(NCCH_3)_3}$, CO stretching modes      110
$\mathrm{Fe(C_5H_5)_2}$ (staggered), symmetry      90
$\mathrm{Fe(\eta^5C_5H_5)(\eta^5C_{70}(CH_3)_3)}$      495
$\mathrm{Fe}^{3+}}$ as acid      178 197 198
$\mathrm{Fe}^{3+}}$, halide charge-transfer complexes      179
$\mathrm{HBr}$      287
$\mathrm{HClBrC} — \mathrm{CHClBr}$, symmetry      84
$\mathrm{HCl}$      287
$\mathrm{HCl}$, symmetry      85 86
$\mathrm{HCN}, bonding      62
$\mathrm{HCN}, symmetry      89
$\mathrm{HCo(CO)_4}$      527
$\mathrm{HCP}$      62
$\mathrm{He_2}$, molecular orbitals      126
$\mathrm{HRh(CO)_2(PPh_3)_3}$, hydroformylation catalyst      537 538
$\mathrm{HS03F\dot Ta(S)_3F)_5}$      204
$\mathrm{HSO_3F\dot Nb(SO_3F)_5}$      204
$\mathrm{H_1SO_4}$, acid strength      197
$\mathrm{H_2C} = \mathrm{CClBr}$, symmetry      84
$\mathrm{H_2O_2}$, symmetry      87 88
$\mathrm{H_2O}$, bond angle      60 66
$\mathrm{H_2O}$, symmetry      82 89
$\mathrm{H_2O}$, VSEPR and structure      59 66
$\mathrm{H_2Se}$, VSEPR and structure      66
$\mathrm{H_2S}$ VSEPR and structure      66
$\mathrm{H_2Te}$, VSEPR and structure      66
$\mathrm{H_2}$, bonding      118
$\mathrm{H_2}$, complexes      478
$\mathrm{H_2}$, molecular orbitals      125
$\mathrm{H_2}$, source      275
$\mathrm{H_3CCH_3}$, symmetry      87 88
$\mathrm{H_3PO_4}$, acid strength      197
$\mathrm{H_3^+}$ ion, molecular orbitals      143
$\mathrm{ICl}_4^-$      290
$\mathrm{IOF_3}$, symmetry      90
$\mathrm{IOF_4}$      62
$\mathrm{KrF_2}$      295
$\mathrm{K[Pt(C_2H_4)Cl_3]\dot H_2O}$, Zeise’s salt      457 482 483
$\mathrm{LiAlH_4}$      248
$\mathrm{Li_2}$, molecular orbitals      127
$\mathrm{Ma_2b_2cd}$ isomers      314
$\mathrm{Mg(OH)_2\dot Si_2O_5}$ Minerals, structure      235
$\mathrm{Mg_3(OH)_4Si_2O_5}$      234
$\mathrm{NaCl}$, radius ratio      219
$\mathrm{NaCl}$, structure      215
$\mathrm{Na_2Fe(CO)_4}$ (Collman’s reagent)      527
$\mathrm{NC1_3}$, bond angle      66
$\mathrm{Ne_2}$, molecular orbitals      127 129
$\mathrm{NF_3}$, bond angle      66
$\mathrm{NH_3}$      87 88
$\mathrm{NH_3}$, character table      99
$\mathrm{NH_3}$, molecular orbitals      151—153
$\mathrm{NH_3}$, symmetry      87 88 99
$\mathrm{NH_3}$, synthesis      274
$\mathrm{NH_3}$, VSEPR and structure      60 61 66 68
$\mathrm{NH_4^+}$, molecular energy levels      172
$\mathrm{Ni(CO)_4}$      457
$\mathrm{Ni(CO)_4}$, molecular orbitals      360 361
$\mathrm{Ni(CO)_4}$, synthesis      473
$\mathrm{NiAs}$ crystal structure      217
$\mathrm{NO_2}$, nitrogen dioxide      276
$\mathrm{NO_3^-}$ (nitrate ion), molecular orbitals      156
$\mathrm{NO_{\chi}}$ and acid rain      276
$\mathrm{NO}$ (nitrosyl), as ligand      476
$\mathrm{NO}$ (nitrosyl), as ligand, complexes      476
$\mathrm{NO}$ (nitrosyl), as ligand, linear and bent bonding modes      476
$\mathrm{N}_2$ complexes      475
$\mathrm{N}_2$, molecular orbitals      128
$\mathrm{N}_2$, photoelectron spectrum and molecular orbitals      131
$\mathrm{N}_2$, symmetry      90
$\mathrm{N}_2H_4$, , symmetry      89
$\mathrm{N}_2O$, , product of catalytic converters      628
$\mathrm{N}_2^{2-}$,      structure
$\mathrm{N}_3^-$, , molecular orbital diagram      147
$\mathrm{N}_5^+$, synthesis and structure      272
$\mathrm{OCl_2}$, bond angle      66
$\mathrm{OF_2}$, bond angle      66
$\mathrm{Os(C_5H_5)_2}$ (eclipsed), symmetry      89
$\mathrm{O_2^+}$ (dioxygenyl ion)      128
$\mathrm{O_2^-}$ (superoxide ion)      128
$\mathrm{O_2^{2-}}$ (peroxide ion)      128
$\mathrm{O_2}$ (dioxygen)      128
$\mathrm{O_2}$ (dioxygen), molecular orbitals      127 128
$\mathrm{O_2}$ (dioxygen), paramagnetic      128 280
$\mathrm{O_2}$ (dioxygen), photoelectron spectrum and molecular orbitals      131
$\mathrm{P(C_6H_5)_3}$, symmetry      89
$\mathrm{PBr_3}$, bond angle      66
$\mathrm{PC1_3}$, bond angle      66
$\mathrm{PC1_3}$, symmetry      89
$\mathrm{PCl_6^-}$, structure      62
$\mathrm{PF_3}$, bond angle      66
$\mathrm{PF_5}$, symmetry      87
$\mathrm{PH_3}$, VSEPR and structure      66
$\mathrm{POF_3}$      55
$\mathrm{P_4O_{10}}$, and phosphoric acid synthesis      279
$\mathrm{P_4}$, electronic equivalents      557
$\mathrm{P_4}$, structure      273
$\mathrm{RhCl(PPh_3)_3}$, Wilkinson’s catalyst      542
$\mathrm{RnF_2}$      295
$\mathrm{Ru_3(CO)_9(\mu_3-\eta^2, \eta^2, \eta^2-C_{60})}$      495
$\mathrm{SbBr_3}$, bond angle      66
$\mathrm{SbCl_3}$, bond angle      66
$\mathrm{SbF_3}$, bond angle      66
$\mathrm{SbF_4^-}$      62
$\mathrm{SbF_5}$ as acid      168
$\mathrm{SbH_3}$, VSEPR and structure      66
$\mathrm{SC1_2}$, bond angle      66
$\mathrm{Sc_3N@C_{80}}$      496
$\mathrm{SeF_3^-}$      62
$\mathrm{SeOCl_2}$      62
$\mathrm{SF_2}$, bond angle      66
$\mathrm{SF_4}$, symmetry      90
$\mathrm{SF_4}$, VSEPR and structure      60 61
$\mathrm{SF_5^-}$      62
$\mathrm{SF_6}$ and natural orbital bonding      161
$\mathrm{SF_6}$, structure      53 58
$\mathrm{SF_6}$, symmetry      85 86
$\mathrm{SOCl_2}$, structure      62
$\mathrm{SOF_4}$      55
$\mathrm{SO_3F^-}$      55
$\mathrm{SO_3}$, dipole moment      68
$\mathrm{SO_3}$, electron-dot structure      52 56
$\mathrm{SO_3}$, hybrid orbitals, $sp^2$      158
$\mathrm{SO_3}$, molecular orbitals      156
$\mathrm{V(CO)_6}$      17-electron
$\mathrm{Xe-F}$ compounds      292
$\mathrm{XeF^+}$, structure      294
$\mathrm{XeF_2}$, structure      293
$\mathrm{XeF_2}$, synthesis      293
$\mathrm{XeF_2}$, VSEPR and structure      61
$\mathrm{XeF_4}$, structure      293
$\mathrm{XeF_4}$, symmetry      90
$\mathrm{XeF_4}$, synthesis      293
$\mathrm{XeF_6}$, structure      294
$\mathrm{XeOF_2}$, structure      62
$\mathrm{XeO_3}$ reactions      295
$\mathrm{XeO_4}$ reactions      295
$\mathrm{YBa_2Cu_3O_7}$, structure      230
$\mathrm{YBa_2Cu_3O_7}$, superconductor      230
$\mathrm{[(CH_3)A1N}(2, 6—diisopropylphenyl)]_3$      261
$\mathrm{[(\eta^5-C_5H_5)Mo(CO)_2]_2}$ and bridging carbonyls      471
$\mathrm{[Co(Co(NH_3)_4(OH)_2)_3]Br_6}$, totally inorganic optically active compound      301
$\mathrm{[Co(CO)_4]^-}$      527
$\mathrm{[Co(en)_2(H_2O)X]^{n+}}$, rates of substitution reactions      432
$\mathrm{[Co(en)_3]^{3+}}$, chirality of ring conformation      318
$\mathrm{[Co(en)_3]^{3+}}$, symmetry      87 88
$\mathrm{[Co(H_2NC_2H_4NH_2)_2Cl_2]^+}$, cis and trans isomers      301
$\mathrm{[Co(NH_3)_4Cl_2]^+}$, cis and trans isomers      301
$\mathrm{[Co(NH_3)_5(H_2O)]^{3+}}$, rates of substitution      424
$\mathrm{[CoX_2(trien)]^+}$, $\alpha$ and $\beta$ forms      319
$\mathrm{[Cu(H_2O)_6]^{2+}}$ absorption spectrum      399
$\mathrm{[Cu(H_2O)_6]^{2+}}$ absorption spectrum, color      380
$\mathrm{[Fe(CN)_5(NO)]^{2-}}$, vasodilator      477
$\mathrm{[Fe(CO)_2(CN)_4]^{2-}}$      475
$\mathrm{[Fe(CO)_3(CN)_3]^-}$      475
$\mathrm{[Fe(CO)_]^{2-}}$, in synthesis      527
$\mathrm{[Fe(trien)]^{3+}}$, peroxide decomposition, catalyst      600
$\mathrm{[M(H_2O)_6]^{n+}}$, absorption spectra      397
$\mathrm{[Mn(H_2O)_6]^{2+}}$, absorption spectrum      397 405
$\mathrm{[Mo_2Cl_8]^{4-}}$, spectrum and bonding      570
$\mathrm{[Ni(H_2O)_6]^{2+}}$, rates of substitution      424
$\mathrm{[Os_2Cl_8]^{2-}}$, bonding      570
$\mathrm{[Pt(Br)(Cl)(I)(NH_3)(NO_2)(py)]}$ isomers      313
$\mathrm{[Pt(CN)_4]^{2-}}$ ion, bonding      358
$\mathrm{[Pt(CN)_4]^{2-}}$ ion, spectra and ligand field splitting      360
$\mathrm{[PtCl_4]^{2-}}$, spectrum and ligand field splitting      360
$\mathrm{[PtCl_4]^{2-}}$, symmetry      90
$\mathrm{[Re_2Cl_8]^{2-}}$, $\delta$ bond      569
$\mathrm{[Re_2Cl_8]^{2-}}$, bonding      569
$\mathrm{[Re_2Cl_8]^{2-}}$, spectrum and bonding      570
$\mathrm{[Ru(II)(EDTA)(H_2O)]^{2-}}$, rates of substitution reactions      426
$\mathrm{[Ru(III)(EDTA)(H_2O)]^-}$, rates of substitution reactions      426
$\mathrm{[Ru(NH_2CH_2CH_2NH_2)_3]^{2+}}$, symmetry      90
$\mathrm{[TaF_8]^{3-}}$, VSEPR and structure      53 58
$\mathrm{[Ti(H_2O)_6]^{3+}}$, absorption spectrum      400
$\mathrm{[V(H_2O)_6]^{3+}}$, absorption spectrum      394
$\mathrm{[XeF_8]^{2-}}$, VSEPR and structure      53
$\mathrm{[XeF_8]^{2-}}$, VSEPR and structure, structure      294
$\phi$, angular function      28
$\pi$ acceptor ligands      364 365 368
$\pi$ acceptor ligands of $\mathrm{CO}$      463 467—470
$\pi$ acceptor ligands, angular overlap      364 365
$\pi$ acceptor ligands, back-bonding      354 355 367 368
$\pi$ bonding and $\Delta_0$      355
$\pi$ bonding and LFSE      355
$\pi$ bonding in carbene complexes      499
$\pi$ bonding, octahedral complexes      352—355
$\pi$ bonding, orbital overlap in octahedral complexes      354
$\pi$ bonding, orbitals, square planar complexes      357
$\pi$ donor ligands      366—368
$\pi$ donor ligands, angular overlap      366
$\pi$ interactions, between $\mathrm{CO}$ and a metal      468
$\pi$ orbitals from d orbitals      120
$\pi$ orbitals from p orbitals      119 120
$\pi$ orbitals from p orbitals and group theory      134
$\pi$-Allyl complexes      483 484
$\pi$-allyl radical, as ligand      479
$\pi$-bonded aromatic rings      3 4
$\pi$-ethylene complexes      482—484
$\Psi$, wave function      21 22 116
$\Psi$, wave function, properties      22 23
$\sigma$ donor basicity      367
$\sigma$ interactions, between CO and a metal      468
$\sigma$ orbitals      117 118 120 122 134
$\sigma$ orbitals from d orbitals      120
$\sigma$ orbitals from p orbitals      120
$\sigma$ orbitals, square planar complexes      356
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