Miessler G., Tarr D.A. — Inorganic Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

, molecular orbitals      127
(cyanide), as ligand      475
axes, perpendicular      86 87 101
, molecular orbitals      127
, , , and values      190
axis      82
, hydrogen bonding      174
, molecular orbitals      140—143 175
, molecular orbitals      127 128
, symmetry      90
, critical magnetic field for superconductivity      228
      53
, spectra in different solvents      178
, magnetic quantum number      26
, spin quantum number      26 27
, symmetry      90
(cyanate ion), VSEPR and structure      54
(peroxynitrite), structure      278
(thiocyanate) VSEPR and structure      54
hybrids in water      158
, rotation-reflection operation      80
CB mechanism      426 427
lim mechanism      416
lim mechanism      416
$S_{2n}$ , axes      83 88
isomers      313
$\beta$ decay      8
$\Delta H^0$ from temperature dependence of equilibrium constant      192 193
$\Delta S^0$ from temperature dependence of equilibrium constant      193
$\Delta_0$ in octahedral complexes      346
$\Delta_0$ in octahedral complexes, determining from spectra      393—395 401 402
$\mathrm{(AsBr_3)}$ , bond angle      66
$\mathrm{(AsCl_3)}$ , bond angle      66
$\mathrm{(AsF_3)}$ , bond angle      66
$\mathrm{(AsH_3)}$ , bond angle      66
$\mathrm{(AsH_3)}$ , bond angle, VSEPR and structure      66
$\mathrm{(C_5H_5)_2Fe}$ , ferrocene      457
$\mathrm{A1_2(CH_3)_6}$ structure      296
$\mathrm{Al_3N_3}$ ring      261
$\mathrm{Al_4(OH)_8Si_4O_{10}}$ (kaolinite)      234
$\mathrm{Au(PPh_3)}$ fragment      566
$\mathrm{B(OH)_3$ , symmetry      89
$\mathrm{BeCl_2}$ , bonding      56 57
$\mathrm{BeF_2}$ , bonding      56 57
$\mathrm{Be_2}$ , molecular orbitals      127
$\mathrm{BF_3\dot NH_3}$ adduct      170 171
$\mathrm{BF_3\dot O(C_2H_5)_2}$ adduct, boiling point      171
$\mathrm{BF_3}$ , bonding      58 59
$\mathrm{BF_3}$ , molecular orbitals      154—156
$\mathrm{BF_3}$ , symmetry      89
$\mathrm{BrF_3}$       290
$\mathrm{BrF_3}$ , solvent      168
$\mathrm{BrF_3}$ , VSEPR and structure      60
$\mathrm{BrF_4^-}$       290
$\mathrm{BrF_5}$ , symmetry      89
$\mathrm{B_2H_6}$ , bonding      256—258
$\mathrm{B_3P_3}$ rings      261
$\mathrm{B_6H_6^{2-}}$ , bonding      573 574
$\mathrm{B_{12}H_{12}^{2-}}$ , symmetry      85 86
$\mathrm{CCl_4}$ , dipole moment      68
$\mathrm{CH_4}$ , dipole moment      68
$\mathrm{CH_4}$ , symmetry      85 86
$\mathrm{CH_4}$ , VSEPR and structure      59
$\mathrm{ClF_3}$       53 290
$\mathrm{ClF_3}$ , VSEPR and structure      60
$\mathrm{ClF_5}$       290
$\mathrm{ClOF_3}$ , structure      62
$\mathrm{CO_2}$ (carbon dioxide)      267
$\mathrm{CO_2}$ (carbon dioxide) and greenhouse effect      634
$\mathrm{CO_2}$ (carbon dioxide), electron-dot diagram      52
$\mathrm{CO_2}$ (carbon dioxide), geometry      52
$\mathrm{CO_2}$ (carbon dioxide), molecular orbitals      143—147
$\mathrm{CO_2}$ (carbon dioxide), symmetry      85 86
$\mathrm{CO_3^{2-}}$ (carbonate ion), electron-dot diagram      52
$\mathrm{CO_3^{2-}}$ (carbonate ion), molecular orbitals      156
$\mathrm{CO_3^{2-}}$ (carbonate ion), structure and dipole moment      68
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$       499 500
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$ ,       499
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$ , cis and trans isomers      499 500
$\mathrm{Cr(CO)_5[C(OCH_3)C_6H_5]}$ , synthesis      499
$\mathrm{Cr(CO)_6}$ and 18—electron rule      463—465
$\mathrm{Cr(CO)_6}$ , molecular orbitals      464
$\mathrm{C_2H_2Cl_2Br_2}$ , symmetry      85
$\mathrm{C_2H_2}$       90
$\mathrm{C_2H_2}$ , electron-dot diagram and geometry      52
$\mathrm{C_5H_5}$ and CO complexes      491
$\mathrm{C_5H_5}$ , cyclopentadienyl      485
$\mathrm{C_6D_6}$ synthesis      535
$\mathrm{C_{60}}$ , buckminsterfullerene      4 265
$\mathrm{C_{60}}$ , buckminsterfullerene as ligand      493—495
$\mathrm{C_{70}}$       265
$\mathrm{C_{80}}$       265
$\mathrm{Eu^{2+}}(aq)$ reactions      443
$\mathrm{fac-Mo(CO)_3(NCCH_3)_3}$ , CO stretching modes      110
$\mathrm{Fe(C_5H_5)_2}$ (staggered), symmetry      90
$\mathrm{Fe(\eta^5C_5H_5)(\eta^5C_{70}(CH_3)_3)}$       495
$\mathrm{Fe}^{3+}}$ as acid      178 197 198
$\mathrm{Fe}^{3+}}$ , halide charge-transfer complexes      179
$\mathrm{HBr}$       287
$\mathrm{HClBrC} — \mathrm{CHClBr}$ , symmetry      84
$\mathrm{HCl}$       287
$\mathrm{HCl}$ , symmetry      85 86
$\mathrm{HCN}, bonding      62
$\mathrm{HCN}, symmetry      89
$\mathrm{HCo(CO)_4}$       527
$\mathrm{HCP}$       62
$\mathrm{He_2}$ , molecular orbitals      126
$\mathrm{HRh(CO)_2(PPh_3)_3}$ , hydroformylation catalyst      537 538
$\mathrm{HS03F\dot Ta(S)_3F)_5}$       204
$\mathrm{HSO_3F\dot Nb(SO_3F)_5}$       204
$\mathrm{H_1SO_4}$ , acid strength      197
$\mathrm{H_2C} = \mathrm{CClBr}$ , symmetry      84
$\mathrm{H_2O_2}$ , symmetry      87 88
$\mathrm{H_2O}$ , bond angle      60 66
$\mathrm{H_2O}$ , symmetry      82 89
$\mathrm{H_2O}$ , VSEPR and structure      59 66
$\mathrm{H_2Se}$ , VSEPR and structure      66
$\mathrm{H_2S}$ VSEPR and structure      66
$\mathrm{H_2Te}$ , VSEPR and structure      66
$\mathrm{H_2}$ , bonding      118
$\mathrm{H_2}$ , complexes      478
$\mathrm{H_2}$ , molecular orbitals      125
$\mathrm{H_2}$ , source      275
$\mathrm{H_3CCH_3}$ , symmetry      87 88
$\mathrm{H_3PO_4}$ , acid strength      197
$\mathrm{H_3^+}$ ion, molecular orbitals      143
$\mathrm{ICl}_4^-$       290
$\mathrm{IOF_3}$ , symmetry      90
$\mathrm{IOF_4}$       62
$\mathrm{KrF_2}$       295
$\mathrm{K[Pt(C_2H_4)Cl_3]\dot H_2O}$ , Zeise’s salt      457 482 483
$\mathrm{LiAlH_4}$       248
$\mathrm{Li_2}$ , molecular orbitals      127
$\mathrm{Ma_2b_2cd}$ isomers      314
$\mathrm{Mg(OH)_2\dot Si_2O_5}$ Minerals, structure      235
$\mathrm{Mg_3(OH)_4Si_2O_5}$       234
$\mathrm{NaCl}$ , radius ratio      219
$\mathrm{NaCl}$ , structure      215
$\mathrm{Na_2Fe(CO)_4}$ (Collman’s reagent)      527
$\mathrm{NC1_3}$ , bond angle      66
$\mathrm{Ne_2}$ , molecular orbitals      127 129
$\mathrm{NF_3}$ , bond angle      66
$\mathrm{NH_3}$       87 88
$\mathrm{NH_3}$ , character table      99
$\mathrm{NH_3}$ , molecular orbitals      151—153
$\mathrm{NH_3}$ , symmetry      87 88 99
$\mathrm{NH_3}$ , synthesis      274
$\mathrm{NH_3}$ , VSEPR and structure      60 61 66 68
$\mathrm{NH_4^+}$ , molecular energy levels      172
$\mathrm{Ni(CO)_4}$       457

$\mathrm{Ni(CO)_4}$ , molecular orbitals      360 361
$\mathrm{Ni(CO)_4}$ , synthesis      473
$\mathrm{NiAs}$ crystal structure      217
$\mathrm{NO_2}$ , nitrogen dioxide      276
$\mathrm{NO_3^-}$ (nitrate ion), molecular orbitals      156
$\mathrm{NO_{\chi}}$ and acid rain      276
$\mathrm{NO}$ (nitrosyl), as ligand      476
$\mathrm{NO}$ (nitrosyl), as ligand, complexes      476
$\mathrm{NO}$ (nitrosyl), as ligand, linear and bent bonding modes      476
$\mathrm{N}_2$ complexes      475
$\mathrm{N}_2$ , molecular orbitals      128
$\mathrm{N}_2$ , photoelectron spectrum and molecular orbitals      131
$\mathrm{N}_2$ , symmetry      90
$\mathrm{N}_2H_4$ , , symmetry      89
$\mathrm{N}_2O$ , , product of catalytic converters      628
$\mathrm{N}_2^{2-}$ ,      structure
$\mathrm{N}_3^-$ , , molecular orbital diagram      147
$\mathrm{N}_5^+$ , synthesis and structure      272
$\mathrm{OCl_2}$ , bond angle      66
$\mathrm{OF_2}$ , bond angle      66
$\mathrm{Os(C_5H_5)_2}$ (eclipsed), symmetry      89
$\mathrm{O_2^+}$ (dioxygenyl ion)      128
$\mathrm{O_2^-}$ (superoxide ion)      128
$\mathrm{O_2^{2-}}$ (peroxide ion)      128
$\mathrm{O_2}$ (dioxygen)      128
$\mathrm{O_2}$ (dioxygen), molecular orbitals      127 128
$\mathrm{O_2}$ (dioxygen), paramagnetic      128 280
$\mathrm{O_2}$ (dioxygen), photoelectron spectrum and molecular orbitals      131
$\mathrm{P(C_6H_5)_3}$ , symmetry      89
$\mathrm{PBr_3}$ , bond angle      66
$\mathrm{PC1_3}$ , bond angle      66
$\mathrm{PC1_3}$ , symmetry      89
$\mathrm{PCl_6^-}$ , structure      62
$\mathrm{PF_3}$ , bond angle      66
$\mathrm{PF_5}$ , symmetry      87
$\mathrm{PH_3}$ , VSEPR and structure      66
$\mathrm{POF_3}$       55
$\mathrm{P_4O_{10}}$ , and phosphoric acid synthesis      279
$\mathrm{P_4}$ , electronic equivalents      557
$\mathrm{P_4}$ , structure      273
$\mathrm{RhCl(PPh_3)_3}$ , Wilkinson’s catalyst      542
$\mathrm{RnF_2}$       295
$\mathrm{Ru_3(CO)_9(\mu_3-\eta^2, \eta^2, \eta^2-C_{60})}$       495
$\mathrm{SbBr_3}$ , bond angle      66
$\mathrm{SbCl_3}$ , bond angle      66
$\mathrm{SbF_3}$ , bond angle      66
$\mathrm{SbF_4^-}$       62
$\mathrm{SbF_5}$ as acid      168
$\mathrm{SbH_3}$ , VSEPR and structure      66
$\mathrm{SC1_2}$ , bond angle      66
$\mathrm{Sc_3N@C_{80}}$       496
$\mathrm{SeF_3^-}$       62
$\mathrm{SeOCl_2}$       62
$\mathrm{SF_2}$ , bond angle      66
$\mathrm{SF_4}$ , symmetry      90
$\mathrm{SF_4}$ , VSEPR and structure      60 61
$\mathrm{SF_5^-}$       62
$\mathrm{SF_6}$ and natural orbital bonding      161
$\mathrm{SF_6}$ , structure      53 58
$\mathrm{SF_6}$ , symmetry      85 86
$\mathrm{SOCl_2}$ , structure      62
$\mathrm{SOF_4}$       55
$\mathrm{SO_3F^-}$       55
$\mathrm{SO_3}$ , dipole moment      68
$\mathrm{SO_3}$ , electron-dot structure      52 56
$\mathrm{SO_3}$ , hybrid orbitals,       158
$\mathrm{SO_3}$ , molecular orbitals      156
$\mathrm{V(CO)_6}$       17-electron
$\mathrm{Xe-F}$ compounds      292
$\mathrm{XeF^+}$ , structure      294
$\mathrm{XeF_2}$ , structure      293
$\mathrm{XeF_2}$ , synthesis      293
$\mathrm{XeF_2}$ , VSEPR and structure      61
$\mathrm{XeF_4}$ , structure      293
$\mathrm{XeF_4}$ , symmetry      90
$\mathrm{XeF_4}$ , synthesis      293
$\mathrm{XeF_6}$ , structure      294
$\mathrm{XeOF_2}$ , structure      62
$\mathrm{XeO_3}$ reactions      295
$\mathrm{XeO_4}$ reactions      295
$\mathrm{YBa_2Cu_3O_7}$ , structure      230
$\mathrm{YBa_2Cu_3O_7}$ , superconductor      230
$\mathrm{[(CH_3)A1N}(2, 6—diisopropylphenyl)]_3$       261
$\mathrm{[(\eta^5-C_5H_5)Mo(CO)_2]_2}$ and bridging carbonyls      471
$\mathrm{[Co(Co(NH_3)_4(OH)_2)_3]Br_6}$ , totally inorganic optically active compound      301
$\mathrm{[Co(CO)_4]^-}$       527
$\mathrm{[Co(en)_2(H_2O)X]^{n+}}$ , rates of substitution reactions      432
$\mathrm{[Co(en)_3]^{3+}}$ , chirality of ring conformation      318
$\mathrm{[Co(en)_3]^{3+}}$ , symmetry      87 88
$\mathrm{[Co(H_2NC_2H_4NH_2)_2Cl_2]^+}$ , cis and trans isomers      301
$\mathrm{[Co(NH_3)_4Cl_2]^+}$ , cis and trans isomers      301
$\mathrm{[Co(NH_3)_5(H_2O)]^{3+}}$ , rates of substitution      424
$\mathrm{[CoX_2(trien)]^+}$ , $\alpha$ and $\beta$ forms      319
$\mathrm{[Cu(H_2O)_6]^{2+}}$ absorption spectrum      399
$\mathrm{[Cu(H_2O)_6]^{2+}}$ absorption spectrum, color      380
$\mathrm{[Fe(CN)_5(NO)]^{2-}}$ , vasodilator      477
$\mathrm{[Fe(CO)_2(CN)_4]^{2-}}$       475
$\mathrm{[Fe(CO)_3(CN)_3]^-}$       475
$\mathrm{[Fe(CO)_]^{2-}}$ , in synthesis      527
$\mathrm{[Fe(trien)]^{3+}}$ , peroxide decomposition, catalyst      600
$\mathrm{[M(H_2O)_6]^{n+}}$ , absorption spectra      397
$\mathrm{[Mn(H_2O)_6]^{2+}}$ , absorption spectrum      397 405
$\mathrm{[Mo_2Cl_8]^{4-}}$ , spectrum and bonding      570
$\mathrm{[Ni(H_2O)_6]^{2+}}$ , rates of substitution      424
$\mathrm{[Os_2Cl_8]^{2-}}$ , bonding      570
$\mathrm{[Pt(Br)(Cl)(I)(NH_3)(NO_2)(py)]}$ isomers      313
$\mathrm{[Pt(CN)_4]^{2-}}$ ion, bonding      358
$\mathrm{[Pt(CN)_4]^{2-}}$ ion, spectra and ligand field splitting      360
$\mathrm{[PtCl_4]^{2-}}$ , spectrum and ligand field splitting      360
$\mathrm{[PtCl_4]^{2-}}$ , symmetry      90
$\mathrm{[Re_2Cl_8]^{2-}}$ , $\delta$ bond      569
$\mathrm{[Re_2Cl_8]^{2-}}$ , bonding      569
$\mathrm{[Re_2Cl_8]^{2-}}$ , spectrum and bonding      570
$\mathrm{[Ru(II)(EDTA)(H_2O)]^{2-}}$ , rates of substitution reactions      426
$\mathrm{[Ru(III)(EDTA)(H_2O)]^-}$ , rates of substitution reactions      426
$\mathrm{[Ru(NH_2CH_2CH_2NH_2)_3]^{2+}}$ , symmetry      90
$\mathrm{[TaF_8]^{3-}}$ , VSEPR and structure      53 58
$\mathrm{[Ti(H_2O)_6]^{3+}}$ , absorption spectrum      400
$\mathrm{[V(H_2O)_6]^{3+}}$ , absorption spectrum      394
$\mathrm{[XeF_8]^{2-}}$ , VSEPR and structure      53
$\mathrm{[XeF_8]^{2-}}$ , VSEPR and structure, structure      294
$\phi$ , angular function      28
$\pi$ acceptor ligands      364 365 368
$\pi$ acceptor ligands of $\mathrm{CO}$       463 467—470
$\pi$ acceptor ligands, angular overlap      364 365
$\pi$ acceptor ligands, back-bonding      354 355 367 368
$\pi$ bonding and $\Delta_0$       355
$\pi$ bonding and LFSE      355
$\pi$ bonding in carbene complexes      499
$\pi$ bonding, octahedral complexes      352—355
$\pi$ bonding, orbital overlap in octahedral complexes      354
$\pi$ bonding, orbitals, square planar complexes      357
$\pi$ donor ligands      366—368
$\pi$ donor ligands, angular overlap      366
$\pi$ interactions, between $\mathrm{CO}$ and a metal      468
$\pi$ orbitals from d orbitals      120
$\pi$ orbitals from p orbitals      119 120
$\pi$ orbitals from p orbitals and group theory      134
$\pi$ -Allyl complexes      483 484
$\pi$ -allyl radical, as ligand      479
$\pi$ -bonded aromatic rings      3 4
$\pi$ -ethylene complexes      482—484
$\Psi$ , wave function      21 22 116
$\Psi$ , wave function, properties      22 23
$\sigma$ donor basicity      367
$\sigma$ interactions, between CO and a metal      468
$\sigma$ orbitals      117 118 120 122 134
$\sigma$ orbitals from d orbitals      120
$\sigma$ orbitals from p orbitals      120
$\sigma$ orbitals, square planar complexes      356

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