Miessler G., Tarr D.A. — Inorganic Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

LUMO (lowest unoccupied molecular orbital)      127 137
LUMO (lowest unoccupied molecular orbital) and electron affinity      187
LUMO (lowest unoccupied molecular orbital), $\mathrm{BF_3}$       155 170
LUMO (lowest unoccupied molecular orbital), $\mathrm{CO}$       138
Lux — Flood acid-base definition      166
Lyman series, hydrogen spectrum      20
Madelung constant      220 221
Magic Acid      203
Magnesium properties and compounds      255
Magnetic levitation      229
Magnetic moment $(\mu)$       125 340
Magnetic moment $(\mu)$ , spin only      340 341
Magnetic quantum number       26
Magnetic susceptibilityof complexes      339 341
Magnetic susceptibilityof complexes, diamagnetic compounds      339
Magnetic susceptibilityof complexes, paramagnetic compounds      339
Magnitudes of $e_{\sigma}$ , $e_{\pi}$ and $\Delta$       368—370
Main group compounds, carbonyl complex parallels      556
Malachite, copper ore      11
Manhattan project      12
Mantle of Earth      10
Mathematical group      96
Matrices      92—97
Matrices, block diagonalized      96 99
Matrices, multiplication      93
Matrices, representation of a group      96
Maximum multiplicity, Hund’s rule      386 387
McCleverty, J.A.      450 636
McWeeny, R.      161
Mechanisms of substitution reactions      415
Mechanisms of substitution reactions, associative      419 425
Mechanisms of substitution reactions, conjugate base      426 427
Mechanisms of substitution reactions, dissociative      417
Mechanisms of substitution reactions, interchange      417 418
Medicinal compounds, inorganic      618 620
Mefhoxycarbene complex      499 500
Megatubes, carbon, structure      266
Meissner effect      228 229
Melting points, and adduct formation      192
Mendeleev, D.I., periodic table      11 12 16
Mercury, Arctic studies      626
Mercury, environmental      624 626
Mercury, lake studies      626
Metal alkyls      497
Metal clusters, carbon-centered      4
Metal hydroxides, solubility and acid-base strength      198
Metal to ligand $(M \rightarrow L)$ $\pi$ bonding      354 355
Metal to ligand charge transfer (MLCT)      408
Metal-carbon bonds      1 3
Metal-containing enzymes      5
Metal-metal bonds      1 566—570 572
Metal-metal bonds, multiple      567—570 572
Metallaboranes      579—581
Metallacarboranes      579—581
Metallacrowns      251
Metallacycles      497
Metallacyclobutadiene      547
Metallacyclobutane      547 549
Metallacyclobutane, synthesis      546
Metallaporphyrin      597
Metallocenes      485 489 490
Metalloids      242
Metals, properties      213
Metathesis      547
Metathesis, catalysts      546
Metathesis, Grubbs catalysts      545
Metathesis, olefin      544 545
Metathesis, ring-closing      545
Metathesis, Schrock catalysts      545
Methane, and greenhouse effect      634
Methionine synthetase      595
Methyl amine reactions      200
Methylation, by mefhylcobalamin      603
Methylcobalamin      603
Methylcobalamin and mefhylmercury synthesis      626
Meyer, L, periodic table      11 16
MICA      236
Microscopic reversibility, principle of      530
Microstate table      383
Microstates and quantum numbers      382—385 387
Miiller, K.A.      230
Millikan, R.A., electronic charge      17
Minamata Bay tragedy      625
Mine tailings      628
Minerals, types      10
Mirror planes      78 81 82 87 88
Mirror planes, dihedral      87 88
Mirror planes, horizontal      87
Mirror planes, reflection operation      101
Mirror planes, vertical      87 88
Mixing of orbitals      124 125 137
Mn(III), Jahn — Teller effect      372
mno rule      586
Molar absorptivity      381
Molecular dipoles      67 68
Molecular motions, character of      104
Molecular orbital theory      116
Molecular orbitals      76 117 122 160
Molecular orbitals and acid-base adducts      170—174
Molecular orbitals and band structure in solids      223—228
Molecular orbitals and photoelectrom spectrum of $\mathrm{CO}$       136 138
Molecular orbitals and photoelectron spectrum of $\mathrm{N}_2$       131
Molecular orbitals and photoelectron spectrum of $\mathrm{O}_2$       131
Molecular orbitals,       139 143
Molecular orbitals, $\mathrm{BF_3}$       156
Molecular orbitals, $\mathrm{CO_2}$       143 145—147
Molecular orbitals, $\mathrm{CO_3^{2-}}$       156
Molecular orbitals, $\mathrm{CO}$       135—137 468
Molecular orbitals, $\mathrm{Cr(CO)_6}$       464
Molecular orbitals, $\mathrm{H_2O}$       148 151
Molecular orbitals, $\mathrm{LiF}$       139
Molecular orbitals, $\mathrm{Li_2}$       127
Molecular orbitals, $\mathrm{NH_3}$       153 154
Molecular orbitals, $\mathrm{Ni(CO)_4}$       360 361
Molecular orbitals, $\mathrm{NO}_3^-$       156
Molecular orbitals, $\mathrm{SO}_3$       156
Molecular orbitals, azide ion, $\mathrm{N_3^-}$       147
Molecular orbitals, calculations for mechanistic studies      595
Molecular orbitals, cyanide ion      353
Molecular orbitals, energy match for formation      122 145
Molecular orbitals, framework, boranes      572
Molecular orbitals, from d orbitals      120 121
Molecular orbitals, from p orbitals      119
Molecular orbitals, homonuclear diatomic molecules      127—130
Molecular orbitals, hydrogen bonding in       175
Molecular orbitals, isolobal fragments      559 563
Molecular orbitals, linear triatomic species      146
Molecular orbitals, octahedral complexes      345—347
Molecular orbitals, skeletal, boranes      572
Molecular orbitals, solid state      207
Molecular orbitals, square planar complex      356 357 466
Molecular orbitals, tetrahedral complexes      360 361
Molecular rearrangement processes      509
Molecular shapes and electronic structure      342
Molecular sieves      236
Molecular vibration, infrared active and inactive      104 106 108 109
Molecular wave function      116
Molina, M.J.      633
Mond process      473
Mond, L.      457
Monsanto Acetic Acid Process      538 539
Montmorillonite      236
Moore, E.      237
Moore, J.W.      450
Moseley, H.G.J.      100
Mulliken, R.S., electronegativity      64 187
Mulliken, R.S., electronegativity and acid-base theory      187
Multiple bonds and VSEPR      62 63
Multiple bonds in Be and B compounds      56 57
Multiple reflections      100

Multiplicity      35
Mutagenic agents, requirements for      620
Myoglobin      597—599
Myoglobin, oxygen binding curve      598
n, principal quantum number      18 26 27 29
N-type semiconductor      225
Nano “onions”, fullerene      266
Nanotubes, structure      266
Natta, G., polymerization catalyst      12
Natural bond orbital method      161
Natural resonance theory      161
Neutrino      6
Neutron      6
Newton, D.E.      636
Ni(II) complexes      327
Nickelocene      489 490
Nido borane definition      574
Nitrate $\mathrm{(NO_3^-)}$ structure and dipole moment      68
Nitrate reductase      595 612
Nitric acid, properties      276
Nitric oxide synthase oxygenase      616 617
Nitric oxide, $\mathrm{NO}$       276
Nitric oxide, $\mathrm{NO}$ in biochemistry      616 618
Nitric oxide, $\mathrm{NO}$ , biosynthesis      616
Nitric oxide, $\mathrm{NO}$ , vasodilator      616
Nitride clusters      584
Nitrification      612
Nitrite reductase      595 612
Nitrite reductase, mechanism      613—615
Nitrite reductase, structure      615
Nitrogen      272—274
Nitrogen fixation      611
Nitrogen hydrides      274 275
Nitrogen isotopes      7
Nitrogen oxides      276
Nitrogen oxides and acid rain      630
Nitrogen oxides and ozone depletion      281
Nitrogen oxides and photochemical smog      630
Nitrogen oxides, reactions      276
Nitrogen-oxygen compounds      277
Nitrogenase enzymes      14 274 595 611
Nitrogenase enzymes, reactions      612
Nitrogenase enzymes, structure      611
Nitroglycerine, source of $\mathrm{NO}$       617
Nitrous oxide, $\mathrm{N_2O}$       276
NMR Spectra, of complexes      507 508
Noble gases (Group 18)      17
Noble gases (Group 18), chemistry      240 292
Noble gases (Group 18), compounds and ions      293
Noble gases (Group 18), electronegativity      65
Noble gases (Group 18), properties      292
nodes      29 30 32—34
Nodes in $\pi$ systems      480
Nodes, angular      32—34
Nodes, particle in a box      32
Nodes, planes, $\mathrm{C_5H_5}$       486
Nodes, spherical (radial)      32 33
Nomenclature, coordination compounds      304 305 307 308
Nomenclature, organometallic      458 459
Nonaqueous solvents and acid-base strength      201 202
Nonbonding orbitals      118 120
Nonbonding orbitals,       143
Nonbonding orbitals, octahedral complexes      346
Nonbonding orbitals, square planar complexes      356
Nonbonding pairs      51
Noncrossing rule      133
Nonhydrogenated oxygen atoms and acid strength      196 197
Nonsuperimposability      102
Normalization, wave function      22 23
Normalizing factor, N      117
Norton, J.R.      551
Nova      7
NS (thionitrosyl)      477
NS (thionitrosyl), complexes      476
Nuclear charge and atomic number      17
Nuclear magnetic resonance, and acid-base reactions      192
Nuclear reactions      6—8
Nuclear stability      7 8
Nuclear waste disposal      629
Nucleophilic discrimination factor      437
Nucleophilic displacement      526 527
Nucleophilic reactivity constant      437
Nyholm, R.S.      343
Nyholm, R.S., and VSEPR      57
OA (oxidative addition)      521 524 525 534 537 539
OA (oxidative addition), square planar complexes      524 525
Ochiai, E.I.      600
Octahedral complexes      329
Octahedral complexes, molecular orbitals      345—347
Octahedral complexes, octahedral geometry      2
Octahedral complexes, VSEPR      58 61—63
Octahedral holes in crystal lattice      210
Octahedron, tetragonal distortion      330
Octet rule      52 53 55 56
Octet rule, Be and B compounds      56
Oil absorbent      236
Operator, Hamiltonian      21
Optical activity      76 102
Optical isomers      302 310
Optical rotatory dispersion (ORD) and chiral molecules      319 322 323
Orbital angular momentum quantum number (L)      384—387
Orbital angular momentum, total      382
Orbital interactions in octahedral complexes      345
Orbital mixing      124 125
Orbital potential energies      134 135
Orbital splitting $(\Delta_0)$ and electron spin      346
Orbital splitting $(\Delta_0)$ for aqueous ions      349
Orbitals      21 22 24—30 32 33
Orbitals, representations      101
Orbitals, shapes      26—30 32—34
Orbitals, used in bonding      76
Orbits, electron      21
Order of a group      98 100
Ore deposits      10
Organometallic catalysts      534
Organometallic chemistry      1 454
Organometallic compounds      3 454
Organometallic compounds,       508 509
Organometallic compounds, $^{13}CNMR$       506 508
Organometallic compounds, catalysts      5 12
Organometallic compounds, characterization      509 511
Organometallic compounds, defined      299
Organometallic compounds, IR spectra      503 504 506
Organometallic compounds, main group parallels      556
Organometallic compounds, reactions      520
Organometallic nomenclature      458 459
Orgel, L.E., ligand field theory      12 304 343
Origin of the universe      5
Orthogonality of representations      98 100
Osmium tetroxide adducts      492
Ostwald, W., ions in aqueous solution      166
Outer orbital complexes      343
Overlap of atomic orbitals      117
Oxidation states and reaction rates      422
Oxidation states in organometallic compounds      521 524
Oxidation states, conditions for high and low      445
Oxidation-reduction reactions      245
Oxidation-reduction reactions of coordination compounds      440—442 444 445
Oxidation-reduction reactions, Frost diagram      246
Oxidation-reduction reactions, half reactions      245
Oxidation-reduction reactions, inner sphere mechanism      440—442 444 445
Oxidation-reduction reactions, Latimer diagram      245 246
Oxidation-reduction reactions, outer sphere mechanism      440—442 444 445
Oxidative addition (OA)      521 524 525 534 537 539
Oxidative addition (OA), square planar complexes      524 525
Oxide minerals      10
Oxo process      535 537
Oxonium ion      167
Oxyacids, strength of      196
Oxygen      280

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