Miessler G., Tarr D.A. — Inorganic Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

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Предметный указатель

Oxygen, isolation      280
Oxygen, isotopes      7
Oxygen, properties      280
Oxygen, storage agents, hemoglobin and myoglobin      597—599
Oxygen-bonded carbonyls (isocarbonyls)      474
Oxyhemoglobin, electronic structure      599
Oyama, S.T.      551
Ozone $\mathrm{(O_3)}$ as oxidizing agent      281
Ozone $\mathrm{(O_3)}$ , properties      280 281
Ozone layer      632—634
Ozone layer, chlorofluorocarbons      632
Ozone layer, depletion by chlorine, compounds and nitrogen oxides      281 632—634
Ozone layer, formation      632
Ozone layer, hole, Antarctic      632—634
Ozone layer, hole, Arctic      634
Ozone layer, protective action      281 632
Ozonide ion      281
p-dichlorobenzene, symmetry      82
p-n junction      226
P-type semiconductor      225
Pairing energy for aqueous ions      349
Pairing energy, electron      36
Paramagnetic compounds      125
Paramagnetic compounds, magnetic susceptibility      339
Paramagnetism of $\mathrm{O_2}$       128 280
Particle in a box      23—25
Particle in a box, probability densities      25
Particle in a box, wave equation      23—25
Partington, J, R.      47
Paschen series, hydrogen spectrum      20
Pauli exclusion principle      35
Pauling, L.      304 343
Pauling, L., electronegativity      64
Pauling, L., strength of oxyacids      196 197
Pauson, P.L.      457
Pd(II) complexes      327
Pearson, R.G.      187 435 450
Pearson, R.G., electronegativity      64
Pearson, R.G., hard and soft acids and bases      183 187
Pentagonal bipyramidal geometry      331
Pentagonal bipyramidal geometry, VSEPR      58 60
Perchloric acid      203
Periodic properties of atoms      43 44 46 47
Periodic table      16 17
Periodic table, families, groups, periods      17
Permanganate $\mathrm{(MnO_4^-)}$ , acidity      198
Peroxidases      595 600
Peroxide ion $\mathrm{(O_2^{2-})}$       128 281
Peroxyacetyl nitrate and photochemical smog      632
peroxynitrite       278
Phosphine $\mathrm{(PH_3)}$ , bond angle      66
Phosphine $\mathrm{(PH_3)}$ , properties      275
Phosphine dissociation      522
Phosphine ligands, $\pi$ -acceptor ability      506
Phosphine ligands, $\sigma$ -donor ability      506
Phosphohydrases      595
Phosphoric acid $\mathrm{(H_3P0_4)}$ synthesis      279
Phosphorus      272 273
Phosphotransferases      595
Photochemical smog      627
Photochemical smog, formaldehyde      631
Photochemical smog, hydroxyl radical      630
Photochemical smog, nitrogen oxides      630
Photochemical smog, ozone      631
Photoelectron spectra and molecular orbitals of $\mathrm{N_2}$       131
photons      6
Photosynthesis      600
Photovoltaic effect      226 227
Phthalocyanine synthesis      448
Pitts, J.N., Jr.      636
Planar trigonal geometry, VSEPR      58 60 62 63
Planck’s constant      18
Plane-polarized light      103
Planets, formation      8
Plastocyanin      595
Point groups      82—92
Point groups, assignment      82—92
Point groups, diagram      83
Point groups, examples      82—92
Polar bonds      67 134 138
Polarizability, and acid-base properties      183
Polonium      280
Polyatomic halide ions      288
Polyiodide ions      288
Polymerization of ethylene      12
Polymerization, metallacyclobutane intermediate      547 549
Polymerization, metallacyclobutane of norbornene using carbene catalyst      547
Polymers, $C_{60}$       266
Poole, C.P., Jr.      237
Porphine      596 597
Porphyrins      596
Porphyrins, iron      597—600
Porphyrins, similar ring compounds      600 603 604
Portland cement      255
Positron      6 7
Potential energy, in quantum mechanics      21 22
Powell, H.M., VSEPR      57
Primitive cubic crystal structure      209
Principal axis      78 86
Principal quantum number (n)      18 26 27 29
probability      21
Probability, densities, particle in a box      25
Proper rotation axis       77
Properties and representations of groups      92
Properties of metals      213
Properties of solvents      169
Proteins, $\alpha$ -helix      71 72
Proteins, metal-containing      595
Proteins, pleated sheet      71 72
Protic solvents      169
Proton      5 6
Proton affinity      194 200
Protonated species, formation of      192
Prussian blue $\mathrm{(KFe[Fe(CN)_6])}$       299 379
Pseudohalogens      290
Pseudorotation      434
Pt(II) complexes      327
Pyridine, as solvent      203
Pyridines, basicity of substituted      199
Pyrocatechase      595
Pyrophyllite      235
Pyruvate phosphokinase      595
Quadruple bonds between metal atoms      1 568—572
qualitative analysis      12 185
Quantum numbers and atomic wave functions      25—29 32—34
Quantum numbers, angular momentum (l)      26—28
Quantum numbers, magnetic       26—28
Quantum numbers, microstates      382—385 387
Quantum numbers, multielectron atoms      382—385 387
Quantum numbers, particle in a box      24 25
Quantum numbers, principal (n)      18 24 26—28
Quantum numbers, properties      26
Quantum numbers, spin       26—28
Quantum numbers, total angular momentum (J)      384—387
Quantum numbers, total orbital angular momentum (L)      340 384—387
Quantum numbers, total spin angular momentum (S)      340 384—387
Quantum theory of the atom      18
Quartz structure      233
Radial function, R      27—29
Radial nodes      32
Radial probability functions      29 32
Radial wave function      28—30 32
Radioactive waste      629
Radioactivity      8 11
Radius ratio      215 218 219
Radius ratio and coordination number      219
Radius, covalent      44 45
Radius, crystal      44—47
Radius, ionic      44—47 668—671
Radon      291 292

Rate constants for $\mathrm{[Ru(II)(EDTA)(H_2O)]^{2-}}$ , substitution      426
Rate constants for leaving groups      437
Rate constants for reactions of $\mathrm{[Co(en)_2(H_2O)X]$ {n+}}$      432
Rate constants for [Ru(III)(EDTA)( $\mathrm{H_2O}$ )r, substitution      426
Ratio of $\mathrm{He}/\mathrm{H}$ in universe      6
RE (Reductive elimination)      521 524 525 534 539
Redox potentials      245
Redox potentials, changed by coordination      595
Redox potentials, chlorine      288
Redox potentials, hydrogen      245
Redox potentials, nitrogen      278
Redox potentials, oxygen      246
Reduced mass, $\mu$       18 469
Reducible representations      96 97 104—107
Reducible representations, characters of      96 97
Reducible representations, hybrid orbitals      159 160
Reducible representations, reducing to irreducible representations      105—107
Reductive carbonylation      474
Reductive elimination (RE)      521 524 525 534 539
Reflection operation ( $\sigma$ )      78 79 81—84 87 88 90—95
Reflection operation ( $\sigma$ ), dihedral      79 87 88 101
Reflection operation ( $\sigma$ ), horizontal      79 87 88 101
Reflection operation ( $\sigma$ ), vertical      79 87 88 101
Replacement, ligand      521
Representations      96
Representations of octahedral ligand orbitals      345 346 353
Representations of point groups      94—97
Representations of square planar complexes      357
Representations of tetrahedral complexes      360
Representations, irreducible      96—97
Representations, notation      101 102
Representations, reducible      96 97
Representations, reducing      105 106
Representations, rotational      105 106
Representations, totally symmetric      98
Representations, translational      105 106
Representations, vibrational      105 106 108—110
Resonance      52
Resonance, $\mathrm{CO_3^{2-}}$       52
Resonance, thiocyanate      54
Reversibility, principle of microscopic      530
Rich, R.L.      41 42
Rochow, E.G., electronegativity      64
Rotation axes      77 78 81 83 86 87
Rotation operation ()      77
Rotation, effect on coordinates of a point      100
Rotation-reflection axis (improper axis, )      79 81
Rotational representations      108
Rotational symmetry ()      101 104 106
Rowland.F.S.      633
Ruby, color      379
Russell — Saunders coupling      382
Rutherford, E., nuclear atom      17
Rutile $\mathrm{(TiO_2)}$ crystal structure      217
Rydberg constant      18
S, quantum number      340
SALC, symmetry-adapted linear combinations      140
Sanderson, R T., electronegativity      64
Sandwich compounds      4 454 455 485
Sandwich compounds, examples      455
Sandwich compounds, multiple-decker      4
Sasol plants in South Africa      550
Schrieffer, J.R.      229
Schrock metathesis catalysts      545
Schrock-type carbene complexes      498
Schrodinger equation, three- dimensional      25
Schrodinger, E., quantum mechanics      11
Schrodinger, E., wave equation      21—24 26—29 32—36 38 40 41 43
Schwederski, B.      635
Seesaw geometry, VSEPR      61
Selection rules, spectra      390
Selenium      279 280 285
Selenocarbonyl (CSe)      475
Self-interstitials      232
Semiconductors, conductance      224
Semiconductors, defined      224
Semiconductors, doped      224
Semiconductors, energy bands, temperature dependence      225
Semiconductors, Fermi level      225—227
Semiconductors, intrinsic      224
semiconductors, N-type      225
semiconductors, P-type      225
Semiconductors, temperature dependence of conductance      224
Semimetals      242
Seven-coordinate molecules      58
Shannon, R.D      46
Shape memory metals      214
shielding      38 40 41 43
Shielding constant S      38 40 41
Siderochromes      605
Siderophiles      10
Sidgwick, N.V., and VSEPR      57
Silanes, comparison with carbon compounds      271
Silanes, structure      271
Silica gel      269
Silica, $\mathrm{SiO_2}$ , structure      232 233
Silicates, minerals      10
Silicates, structures      232—237 269 270
Silicon carbide $\mathrm{(SiC)}$ structure      271
Silicon compounds      269
Silicon dioxide $\mathrm{(SiO_2)}$       232 233
Silicon, isolation      262
Silver chloride solubility, thermodynamics      222
Silver halide solubility and acid-base properties      179
Sixteen-electron complexes, square planar      465—467
Skeletal bonding orbitals      572
Slater’s rules, shielding      38 40
Slow reactions (inert complexes), electronic structures      415
Smart, L.      237
Snowflake, symmetry      77 78
Sodium chloride structure      214 215
Sodium hydroxide      203
Soft acids and bases      180—186
Softness of acid or base      188
Solid-state laser      227 228
Solubility and HSAB      183 185 222
Solubility and ion size      222
Solubility of metal hydroxides      198 199
Solubility product constants      198
Solvation and acid-base strength      200 201
Solvent isomers      309
Solvent system, acid-base definition      166 168
Somorjai, G.A.      551
Spectra of with different bases      180
Spectral analysis of organometallic complexes      503
Spectrochemical series      367 368
Spherical coordinates      28
Spherical nodes      32 33
Spin angular momentum quantum number, S      384—387
Spin angular momentum, total      382
Spin magnetic moment      340
Spin quantum number,       26 27
Spin states and ligand field strength      348
Spin, electron      27
Spin-allowed transitions      390
Spin-orbit coupling      387
Splitting of free ion terms in octahedral symmetry      392
Splitting, F, octahedral symmetry      403
Splitting, Jahn — Teller distortion      400
Square antiprismatic geometry      332 333
Square antiprismatic geometry, VSEPR      58—60
Square-planar complexes      3 327 328
Square-planar complexes, complexes, OA reactions      524 525
Square-planar complexes, $\pi$ bonding      357 360
Square-planar complexes, $\sigma$ bonding      360
Square-planar complexes, electron counting      465 466
Square-planar complexes, electronic structure      342
Square-planar complexes, isomers      310
Square-planar complexes, molecular orbitals      356—360 466
Square-planar complexes, Pd(II) and Pt(II) complexes      327

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