Miessler G., Tarr D.A. — Inorganic Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.

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Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

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Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

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Предметный указатель

$\sigma$ -donor interactions, angular overlap      362
$\sigma$ -donor ligands, octahedral complexes      362—364 366
$\sigma$ -donor orbitals      463
$\sigma_d$ , mirror plane      101
$\sigma_h$ , perpendicular mirror plane      101
$\sigma_v$ , mirror plane      101
$\theta$ , angular function      28
$^{13}C$ NMR of complexes      507 508
$^{13}C$ NMR spectrometry      262
$^{14}C$ and radiocarbon dating      262
of complexes      508 509
(Dipicolinato)oxovanadate(V), insulin-like activity      622
1, 3, 5, 7—Tetrafluorocyclooctatetraene, symmetry      87 88
1, 3-butadiene, as ligand      480
1, 5-DibromonaphthaIene, symmetry      87
Abel, E.W.      551
Absolute electronegativity $(\chi)$       187—189
Absolute hardness $(\eta)$       187—189 674 675
Absorbance      381
Absorption of light      380
Absorption spectra, $[\mathrm{Cr(H_2O)_6}]^{2+}$       401
Absorption spectra, $[\mathrm{Cr(H_2O)_6}]^{3+}$       402
Absorption spectra, $[\mathrm{Cu(H_2O)_6}]^{2+}$       398^101
Absorption spectra, $[\mathrm{Fe(H_2O)_6}]^{2+}$       401
Absorption spectra, $[\mathrm{M(H_2O)_6}]^{n+}$       397 398
Absorption spectra, $[\mathrm{Mn(H_2O)_6}]^{2+}$       397 405
Absorption spectra, $[\mathrm{Ni(H_2O)_6}]^{2+}$       402
Absorption spectra, $[\mathrm{Ti(H_2O)_6}]^{3+}$       398 401
Absorption spectra, $[\mathrm{V(H_2O)_6}]^{3+}$       394 404
Absorption spectra, Bohr atom      18
Absorption spectra, coordination compounds      388
Absorption spectra, Tetrahedral complexes      390 406
Abstraction reactions      534
Abundances of the elements, cosmic      8
Acetaldehyde, synthesis from ethylene      541
Acetic acid dissociation, thermodynamics      193
Acetic acid process, Monsanto      538 539
Acetylene $(\mathrm{C_2H_2})$ , symmetry      91
Acetylide, structure      268
Acid and base strength      203
Acid rain      630
Acid-base activity, changed by coordination      595
Acid-base concepts as organizing concepts      165
Acid-base concepts, Arrhenius      166—168
Acid-base concepts, Bronsted — Lowry      166—168
Acid-base concepts, frontier orbitals      171—174
Acid-base concepts, Ingold — Robinson      166
Acid-base concepts, Lavoisier      165 166
Acid-base concepts, Lewis      166 170 171
Acid-base concepts, Liebig      165 166
Acid-base concepts, Lux — Hood      166
Acid-base concepts, solvent system      166 168—170
Acid-base concepts, summary      166
Acid-base concepts, Usanovich      166
Acid-base definitions      166
Acid-base parameters, quantitative      187—194
Acid-base properties, binary hydrogen compounds      194
Acid-base properties, binary hydrogen compounds and frontier orbitals      171—174
Acid-base properties, binary hydrogen compounds, quantitative measures of      187—194
Acid-base strength      192—202
Acid-base strength of cations      197—199
Acid-base strength of cations and nonaqueous solvents      201 202
Acid-base strength of cations and solvation      200 201
Acid-base strength of cations and solvents      200
Acid-base strength of cations, inductive effects      196
Acid-base strength of cations, inherent      184 186 188 191 199
Acid-base strength of cations, oxyacids      196 197
Acid-base strength of cations, proton affinity      194
Acid-base strength of cations, quantitative measures      187—194
Acid-base strength of cations, steric effects      199 200
Acid-base strength of cations, thermodynamic measurement      193 194
Acid-base strength, binary hydrogen compounds      194 195
Acidity and electronegativity, trends      195
Acids and bases with parallel changes in E and C      191
Aconitase      595
Actinides      17
Activation energies and reaction enthalpies      421
Addition reactions      521 524 525
Addition to unsaturated species, halogens and carbonyl compounds      557
Adduct formation      192
Adduct formation, acid-base      170—176 178 179 181 182 186
Adenosine triphosphate (ATP)      600
Ahrland, S.      182
Alchemy      11
Alcohol dehydrogenase      595
Alizarin red dye      299
Alkali metals (Group 1)      17 249—253
Alkali metals (Group 1), anions      240 251
Alkali metals (Group 1), chemical properties      249 250
Alkali metals (Group 1), combustion products      250
Alkali metals (Group 1), cryptands      252
Alkali metals (Group 1), isolation      249
Alkali metals (Group 1), properties      249
Alkali metals (Group 1), solutions in liquid ammonia      250
Alkalides      251
Alkaline earth metals (Group 2)      17 253
Alkaline earth metals (Group 2), chemical properties      254
Alkaline earth metals (Group 2), sources      253
Alkaline earth metals (Group 2), uses      254
Alkenyl (vinyl) ligands      498
Alkyl complexes      497
Alkyl complexes, bonding      496
Alkyl complexes, synthesis      496 497
Alkyl groups, bridging      1 3
Alkyl groups, effect on base strength      196
Alkyl groups, terminal      1 3
Alkyl ligands      496 497
Alkyl migration mechanism      528—532
Alkyne metathesis      547
Alkynyl ligands      498
Allen, L.C., electronegativity      64
Allene $\mathrm{(C_3H_4)}$ , symmetry      90
Allred, A.L., electronegativity      64
Allyl complexes      483 484
Aluminosilicates      10
Aluminosilicates, kaolinite      234
Aluminosilicates, montmorillonite      236
Aluminosilicates, pyrophyllite      234
Aluminosilicates, structure      234 236 237
Aluminosilicates, zeolites      236
Aluminum compounds, bridged      259
Aluminum, properties      260
Ambidentate isomerism      309
Amethyst, color      379
Amide ion $\mathrm{(NH_2^-)}$ structure and shape      62
Amine oxidases      595
Amines, basicity of      196
Ammonia, basicity and frontier orbitals      172
Ammonia, boiling point      69
Ammonia, bond angle      59 60
Ammonia, dimer      70
Ammonia, electron repulsion in      60
Ammonia, group orbitals      151
Ammonia, Haber — Bosch process      13
Ammonia, hybrid orbitals      158
Ammonia, hydrogen bonding      70
Ammonia, molecular orbitals      152—154
Ammonia, symmetry operations      92
Ammonia, synthesis      13 274
Ammonia, synthesis by nitrogenase      611
Ammonia, uses      274
Ammonium ion $\mathrm{(NH_4^+)}$ structure and shape      62
Ammonium nitrate, uses      276
Amphibole asbestos      236
Amphoteric      201
Anation      422
and molecular orbitals of $\mathrm{CO}$       136
and molecular orbitals of $\mathrm{O_2}$       131
Anesthesia, theory of      71
Angels      32

Angular functions, $\Phi$       26 29
Angular functions, $\Theta$       26 29
Angular functions, Y      33
Angular momentum quantum numbers, J      384—387
Angular momentum quantum numbers, l      26 27 29
Angular nodal surfaces      30 32 33
Angular overlap model      342
Angular overlap model, $\pi$ acceptor interactions      364 365 367
Angular overlap model, $\pi$ donor Interactions      366 367
Angular overlap model, $\sigma$ donor interactions      362—365
Angular overlap model, 4- and 6-coordinate preferences      373 374
Angular overlap model, ligand field theory      362—368 371
Angular overlap model, magnitudes of $e_{\sigma}$ , $e_{\pi}$ , and $\Delta$       368—371
Angular overlap model, other shapes      375
Angular overlap model, parameters      371
Angular overlap model, special cases      369
Angular overlap model, trigonal bipyramidal complexes      375 376
Antibonding molecular orbitals      117 118 120
Antibonding molecular orbitals,       143
Antibonding molecular orbitals, octahedral complexes      346
Antifluorite structure      217
Antimony      272 274
Antineutrino      5 6
Antisymmetric Stretch of CO      504
Antitumor agent, cisplatin      618
Antitumor agent, cisplatin, mechanism      620
Apoferritin      604
Aprotic solvents      168 169
Aquation      422
Arachno borane definition      574
Aragonite structure      218
Argon      291
Aromatic rings as ligands      3
Arrhenius, S., acid-base definition      166
Arsenic, Bangladesh water supply      628
Arsenic, environmental      628
Arsenic, properties      272 274
Arsine $\mathrm{(AsH_3)}$ bond angle      66
Arsines $\mathrm{(AsH_3)}$       276
Arthritis treatment, auranofin      622
Aryl ligands      498
Asbestos      236
Ascorbate oxidase      595
Associative interchange mechanism       415
Associative mechanism (A)      419
Associative mechanism (A), evidence for      435—437
Associative mechanism (A), Ru(III) compounds      425
Associative mechanism (A), substitution in octahedral complexes      425
Associative property, in a group      93
Astatine      285
Atmophiles      10
Atomic orbitals      27 33
Atomic orbitals, mathematics of      26 28 29
Atomic orbitals, order of filling      38
Atomic orbitals, positive and negative signs      117—122
Atomic orbitals, shapes      25 27—29 31—33
Atomic theory, historical development      15—19 21 22
Atomic wave functions      21—30 32 33
Atoms and molecules, concept      11
ATPase      595
Atwood, J.D.      450
Aufbau principle      34
Auranofin, antiarthritis treatment      622
Aureolin $\mathrm{(K_3[Co(NO_2)_6]\dot 6H_20)}$       299
Avogadro, A.      16
Background radiation      6
Bacon, Roger      11
Bailar twist      434
Bailey, R.A.      635
Baldwin, J.      598
Ball and chain dimers, fullerene      266
Balmer series, hydrogen spectrum      17—20
Band gap in solids      223 225—227
Band structure in solids      223 225—227
Bardeen, J.      229
Base strength, inherent      184
Basolo, R      435 450
Bauxite (hydrated $\mathrm{Al_2O_3)}$       10
Becquerel, H., radioactivity      11 17
Bednorz, J.G.      230
Beer — Lambert absorption law      380 381
Bennett, W.E.      314
Benzene and borazine comparison      261
Benzene, symmetry      90
Berg, J.M.      635
Bertini      1.
Beryllium      254
Beta elimination      533
Bethe, H.A., crystal field theory      12 304 344
Bidentate ligands      307
Big bang theory      5
Big bang theory, background radiation      6
Bimolecular mechanism      522
Binary carbonyl complexes      472 473
Binary hydrogen compounds, acidity and basicity      194 195
Bismuth      272 274
Bleach, chlorine and bromine      286
Block diagonalized matrix      96 97
Blomstrand, C.W., chain theory      300
Bockris, J.O’M.      635
Body-centered cubic      209—213 216 217
Bohr atom      17—19
Bohr magneton $(\mu_B)$       340
Bohr radius       29
Bohr, N., atomic theory      11 18 19
Boiling point and adduct formation      171 192
Boiling point and hydrogen bonding      70
Bond angles and electronegativity      66
Bond angles and size of central atom      66
Bond angles, $\mathrm{CH}_4$       59
Bond angles, $\mathrm{H_2O}$       59—61
Bond angles, $\mathrm{NH_3}$       60 61
Bond angles, VSEPR      58—63 65—67
Bond dipoles      67—69
Bond lengths, and VSEPR      66 67
Bond order      123
Bond order and electron count, dimetal clusters      570
Bond polarity      67 68
Bonding in ionic crystals      231
Bonding interactions between metal d orbitals      569
Bonding molecular orbitals      118 120
Bonding of $\mathrm{C_{60}}$ to metal      493
Bonding orbitals,       143
Bonding orbitals, octahedral complexes      346
Bonding pair-bonding pair (bp-bp) repulsion, VSEPR      57 59—63
Bonding pair-lone pair (bp-lp) repulsion, VSEPR      60—63
Bonding, $\mathrm{H_2}$       118
Boranes      259 572 574 577
Boranes, classification      574 577
Boraphosphabenzenes      261
Borazine and benzene, comparison      261
Born — Haber cycle      220
Boron nitride (BN) properties      261
Boron trifluoride-diethyl ether, adduct, $\mathrm{BF_3}\dot$ \mathrm{O(C_2H_5)_2}$      171
Boron trihalides as Lewis acids      260
Boron, compounds      256
Boron, hydrides, see boranes      572
Boron, isotopes      259
Boron, properties      256
Boron, uses      259
Bravais lattices      208
Bridging ligands, alkyl groups      1 2
Bridging ligands, carbonyls (CO)      240 473
Bridging ligands, hydrogen atoms      1—3 240
Bridging modes of CO      470 471
Bromine      285
Bronsted — Lowry acid-base, definition      166—168
Bronsted, J.N      166 167
Brosset, C      567
Brown, H.C      199

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