Miessler G., Tarr D.A. — Inorganic Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.

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Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

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Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

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Предметный указатель

Square-planar complexes, sixteen-electron      465 466
Square-pyramidal complexes      328
Stability constants of complexes      337 338
Stability of nuclei, curve      7 8
Stannane, structure      271
State, defined      385
Steam reforming      550
Stereochemistry of reactions      428—435
Stereochemistry of reactions of acid aquation      429—431
Stereochemistry of reactions of base substitution      429—431
Stereoisomerism      310
Steric effects      199 200
Steric number $\mathrm{(SN)}      57
Stibine $\mathrm{(SbH_3)} bond angle      66
Stibines $\mathrm{(SbR_3)}      276
Stone, F.G.A.      551
Strong and weak acids and solvent      202
Strong field limit      391
Strong ligand field      347
Strong-field ligands      346
Structural isomers      310
Subatomic particles      17
Sublimation      138
Sublimation, Born — Haber cycle      220
Substituted pyridines      199
Substitution mechanisms, classification      415
Substitution reactions      424
Substitution reactions in trans complexes      430 431
Substitution reactions of $\mathrm{[Co(NH_3)_(H_2O)]^{3+}}$       424
Substitution reactions of cis complexes      432 433
Substitution reactions of square-planar complexes      434 435
Substitution reactions on $\mathrm{[Co(en)_2(H_2O)X]^{n+}}$ , rates      432
Substitution reactions, effect of cis-ligands on rates      425
Substitution reactions, effect of entering group on rates      425
Substitution, ligand      521 522
Substitutions in crystals      232
Sulfide minerals      10
Sulfite oxidase      595
Sulfur dioxide, from coal burning      630
Sulfur oxides      284 285
Sulfur oxides and acid rain      630
Sulfur oxides from smelting      630
Sulfur oxides, reactions      283
Sulfur trioxide, dipole moment      68
Sulfur trioxide, geometry      58
Sulfur, allotropes      282
Sulfur, environmental      629
Sulfur, properties      279
Sulfur, sources      279
Sulfuric acid      203
Sulfuric acid, dissociation      168 169 197 201
Sulfuric acid, properties      285
Sulfuric acid, synthesis      283
Superacids      203
Superconductivity      228—230
Superconductivity, BCS theory      229
Superconductivity, high-temperature      230
Superconductivity, low-temperature      228
Superconductivity, Type I      228
Superconductivity, Type II      229 230
Superoxide dismutase      595 608—611
Superoxide dismutase, reactions      610
Superoxide dismutase, structure, active site      609
Superoxide ion ( $\mathrm{O_2^-}$ )      128 281 609
Symmetric stretch of $\mathrm{CO}$       504
Symmetry in architecture      77
Symmetry in art      77
Symmetry in nature      77
Symmetry labels for configurations      399
Symmetry of molecular motions of water      106
Symmetry, applications      102 104 106—110
Symmetry, elements      76
Symmetry, elements and operations, table of      81
Symmetry, operations      76
Symmetry, operations and characters for ammonia      92
Symmetry, operations and characters for cis- $\mathrm{ML_2(CO)_2}$       108 109
Symmetry, operations and characters for water      95—97
Symmetry, operations, matrix representation      94
Symmetry-adapted linear combinations (SALCs)      140
Synthesis gas (syn gas)      550
Talc      235
Tanabe — Sugano diagrams      390 393—395 401
Tanabe — Sugano diagrams, high spin and low spin      395
Tanabe — Sugano diagrams, strong field and weak field      395
Tellurium      279 280
Temperature dependence of equilibrium constants      192
Temperature dependence of resistivity in semiconductors, metals      228
Temperature, critical, magnetic      228
Tempering of metals      214
Template reactions      448
Template reactions, Schiff base      449
Term, defined      385
Tetraefhyllead $\mathrm{(Pb(C_2H_5)_4)}$       262 627
Tetraefhyllead $\mathrm{(Pb(C_2H_5)_4)}$ , antiknock compound      627
Tetragonal distortions of the octahedron      330
Tetrahedral complexes      3 327
Tetrahedral complexes and electronic structure      342
Tetrahedral complexes, $\pi$ bonding      360 361
Tetrahedral complexes, $\sigma$ bonding      360
Tetrahedral complexes, absorption spectra      390
Tetrahedral complexes, molecular orbitals      360 361
Tetrahedral geometry, VSEPR      60 62—65
Tetrahedral holes in crystal lattice      210 213
Tetramminecopper(II)      299
Thallium      260
Thermodynamic measurements of acid-base interaction      193
Thermodynamics of complex formation      337 338
Thermodynamics of crystal formation      220
Thiocarbonyl (CS)      475
Thiocyanate, , structure      54
Thionitrosyl (NS)      477
Thixotropic clays      236
Thomson, J.J., e/m ratio of electron      17
Three-center two-electron bond in       143
Three-center two-electron bond in $\mathrm{B_2H_6}$       256—258
Tin allotropes      266
Titration      202
Tobacco mosaic virus, symmetry      77 78
Tolman, C.A.      523
Total pairing energy $\prod$       349
Totally symmetric representation      100
trans effect      437—440
trans effect, $\pi$ bonding effects      440
trans effect, $\sigma$ bonding effects      439

trans influence      439
trans- $\mathrm{[CoX_2(trien)]^+}$ , chiral structures      318
Transferrin      595 604
Transformation matrix      95 96 99
Transition metals      17
Transitions, electronic, H-atom      19 21
Translational representations      107
Translational symmetry      101
Tricapped trigonal prismatic geometry      333
Tricarbide ion, structure      268
Trifluoromethanesulfonic acid (triflic acid)      203
Trigonal antiprismatic geometry      330
Trigonal bipyramidal complexes      328
Trigonal bipyramidal geometry, VSEPR      58 60—63
Trigonal prismatic geometry      330 331
Triiodide ion, , structure and shape      62
Tritium, production      247
Tritium, uses      247
Tryptophan dioxygenase      595
Twist mechanisms for isomerization      434
Tyrosinase      595
Ultraviolet spectra and acid-base reactions      192
Ungerade, orbital symmetry      124
Unimolecular mechanism      522
Unit cell      207 209 210 212—214
Uranyl $\mathrm{(UO_2^+)}$ , acidity      198
Usanovieh, acid-base definition      166
V(IV) compounds, anticancer agents      623
Valence band in solids      223
Valence bond theory      342 344
Valence bond theory, coordination compounds      304
valence electrons      52
Valence orbital potential energies      134 135
Valence shell electron pair repulsion theory (VSEPR)      57 58 60—63
Valentine, J.S.      635
van Vleck, J.H.      304 344
Vanadyl ion $\mathrm{(VO_2^+)}$ , acidity      198
Vaska’s complex      466
Verkade, J.G.      161
Vibrational modes      108
Vibrational modes of water      105 106
Vibrational modes, IR-active      107 109
Vibrational modes, representations      107 109
Vibrational spectra      76 103 104 106 108—110
Vibronic coupling      390
Visible spectra and acid-base reactions      192
Vitamin $B_{12}$ coenzyme      13 458 459 602—604
Volatron, E      162
VS and band structure      231
VSEPR      159
VSEPR and multiple bonds      62 63
VSEPR, 5-coordinate molecules      58
VSEPR, 7-coordinate molecules      58
VSEPR, distorted T geometry      61
VSEPR, square antiprism      59
Wacker (Smidt) process      541
Wade, K.      575
Wade’s rules, boranes      575
Wade’s rules, metallaboranes      579—582
Wade’s rules, metallacarboranes      579—582
Wang, J.H.      598
Water exchange rate and ion radius      422
Water exchange rate and LFSE      421
Water exchange rate and oxidation state      421
Water gas reaction      549
Water gas shift reaction, homogeneous catalysis      551
Water, boiling point      69
Water, bond angle      66
Water, dipole moment      68
Water, electron repulsion in      60
Water, electron-dot structure      52
Water, hybrid orbitals      158
Water, hydrogen bonding      69 71
Water, symmetry      103 104 106 148
Water, symmetry of molecular motions      103 104 106
Water, symmetry operations      96 97
Water, vibrational modes      105 106
Water, vibrational motions      103 104 106
Water, VSEPR and bond angle      60
Wave equation, H-atom      21—23
Wave equation, particle in a box      23 24
Wave function $\Psi$       21 22 116
Wave function $\Psi$ , properties      22 23
Wave function $\Psi$ , real and complex      27
Wayland, B.B.      189
Weak ligand field      347
Weak-field ligands      346
Wells, A.E      14 237
Werner, A.      12 300 301 567
Werner, A., theory of coordination compounds      300—302
Wilkinson, F      450
Wilkinson, G.      14 450 551 636
Wilkinson’s catalyst, $\mathrm{(RhCl(PPh_3)_3)}$       466 542
Work-hardening of metals      213
Wulfsberg, G.      14
Wurtzite, ZnS, structure      216
X-ray crystallography, for isomer identification      322
Xanthine oxidase      595
Xe as ligand      294
Xe, oxygen compounds      295
Xenon      291—195
Xenon fluorides as fluorinating agents      295
Xenon fluorides, structures      293 294
Xenon hexafluoride, structure      294
Xenon, compounds      292—294
Xenon, reactions      295
Z*, effective nuclear charge      38 40 41
Z*, effective nuclear charge and electronegativity      64
Zeise, W.C      457
Zeise’s salt, $\mathrm{K[Pt(C_2H_4)Cl_3]\dot H_2O}$       457 482 483
Zeolites      236
Zeolites, cat litter      237
Zeolites, oil absorbent      237
Ziegler — Natta polymerization      549
Ziegler — Natta polymerization, Cossee — Arlman Mechanism      549
Ziegler — Natta polymerization, metallacyclobutane intermediate      548
Ziegler, K.      548
Ziegler, K., polymerization catalyst      12
Zinc blende structure      214 216
Zinc enzymes      606—608
Zintl ions      585
ZnS, radius ratio      219
[Mabcdef] isomers      313
“Cage” organometallic complexes      495

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