Miessler G., Tarr D.A. — Inorganic Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Miessler G., Tarr D.A. — Inorganic Chemistry

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Название: Inorganic Chemistry

Авторы: Miessler G., Tarr D.A.

Аннотация:

A brief, reader-friendly survey of inorganic chemistry. Uses a molecular-orbital approach to explain structure and reactivity. Features strong coverage of molecular symmetry/group theory. Includes special topics such as bioinorganic, environmental inorganic, organometallic, and solid-state chemistry. Applications show the relevance of core material to problems of contemporary interest. For anyone needing a brief introduction to inorganic chemistry.

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Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 3-rd

Год издания: 1991

Количество страниц: 480

Добавлена в каталог: 19.02.2007

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Buckminsterfullerene, $C_{60}$       4 265
Buckminsterfullerene, $C_{60}$ , as ligand      493—495
Buckminsterfullerene, $C_{60}$ , structure      265
Buckyball, $C_{60}$       265
Burdett, J.K.      162
Burns, G.      237
Butanal synthesis from propene      538
C — O, stretching modes      108—110 468—471 504 506
Calcite structure      218
Calorimetric methods      192
Cannizzaro, S.      16
Capped octahedral geometry      331
Capped square antiprismatic structure      333
Capped trigonal prismatic geometry      331
Carbaboranes      577—582
Carbene (alkylidene) complexes      496 498—501
Carbene (alkylidene) complexes and heteroatoms      498
Carbene (alkylidene) complexes, $\pi$ bonding      499
Carbene (alkylidene) complexes,       499
Carbene (alkylidene) complexes, Fischer-type      498
Carbene (alkylidene) complexes, methoxycarbene      498
Carbene (alkylidene) complexes, nomenclature      498
Carbene (alkylidene) complexes, Schrock-type      498
Carbide clusters      455 456 584 587 588
Carbide clusters, bonding      588
Carbide, structure      268
Carbon      261
Carbon 13 NMR of organometallic complexes      507 508
Carbon 5-coordinate      267
Carbon dioxide, electron-dot diagram      57
Carbon dioxide, geometry      57
Carbon dioxide, hybrid orbitals      158
Carbon dioxide, molecular orbitals      143—147
Carbon dioxide, properties      268
Carbon dioxide, vibrational levels and greenhouse effect      268
Carbon monoxide (CO)      267
Carbon monoxide (CO), infrared spectrum      470
Carbon monoxide (CO), molecular orbitals and photoelectron spectrum      136 138
Carbon monoxide (CO), stretching modes      108 109
Carbon monoxide (CO), symmetry      89
Carbon, $^{14}C$       9
Carbon, isotopes      7 262
Carbon-centered clusters      456 577 588
Carbon-nitrogen cycle      7
Carbonate $\mathrm{(CO_3^{2-})}$ , electron-dot structure and resonance      52
Carbonate $\mathrm{(CO_3^{2-})}$ , structure and dipole moment      68
Carbonic anhydrase      595 607
Carbonic anhydrase, mechanism      608
Carbonyl (CO) complexes      467—474
Carbonyl (CO) complexes, binary      472—474
Carbonyl (CO) complexes, bonding      467—474
Carbonyl (CO) complexes, bridging      470—472
Carbonyl (CO) complexes, C — O distance      469
Carbonyl (CO) complexes, clusters      582 583
Carbonyl (CO) complexes, hydride complexes      477
Carbonyl (CO) complexes, IR spectra      468—471 503—507
Carbonyl (CO) complexes, main group parallels      556
Carbonyl (CO) complexes, synthesis of binary      473 474
Carbonyl insertion reactions, mechanism      528—532
Carbonyl stretching vibrations, cis- and trans-dicarbonyl square planar complexes      108
Carbonyl stretching vibrations, IR spectra      506
Carboranes      259 577—582
Carboranes, analogues of ferrocene      582
Carboranes, classification      578
Carborundum, properties      271
Carboxypeptidase, mechanism      595 606 607
Carbyne (afkylidyne) complexes      496—498 501 502
Carbyne (afkylidyne) complexes, bonding in      501 502
Carbyne (afkylidyne) complexes, nomenclature      498
Carbyne (afkylidyne) complexes, synthesis      534
Cartesian coordinates      28
Cat litter      236
Catalases      595 600
Catalysts, organometallic      534—551
Catalytic converters      627
Catalytic deuteration      535
Cations, acidity      197—199
Cativa process, acetic acid synthesis      540
Ceruloplasmih      595 608 609
Cesium chloride structure      214
CFSE (crystal field stabilization energy)      345
Chalcogens (Group 16)      17 279
Chalcophiles      10
Character of a matrix      96
Character of irreducible representations, properties      98
Character of molecular motions      104
Character tables      97 99—101 681—690
Character tables for octahedral complexes      346
Character tables, features      99—101
Character tables, notation      99—101
Characterization of organometallic complexes      509 510
Characters, for cis- $\mathrm{ML_2(CO)_2}$       108
Charge transfer spectra      407
Charge transfer spectra and acid-base behavior      178
Charge transfer to ligand (CTTL)      408
Charge transfer to metal (CTTM)      407 408
Chatt, J.      182
Chauvin mechanism, olefin metathesis      544
Chelate rings      307
Chelate rings, conformations      318
Chelate rings, isomers      315
Chelates      304
Chelating ligands      304
Chemical properties and the periodic table      244
Chemical properties and the periodic table, diagonal similarities      245
Chemical properties and the periodic table, first row anomaly      245
Chemical properties and the periodic table, hydrogen      248
CHFClBr, symmetry      84 85
Chiral complexes, assigning handedness      316
Chiral isomers      316
Chiral rings, labeling      317
Chirality      102 103 311 313
Chirality, octahedral molecules      311
Chirality, tetrahedral molecules      311
Chlorin      600
Chlorine bleach      286 287
Chlorine, isolation      285
Chlorofluorocarbons, and ozone layer      632
Chlorophyll a      13
Chlorophylls      255 597 600
Chothia, C      598
Chromate $\mathrm{(CrO_4^{2-})}$ , acidity      198 199
Chrysotile      236
Circular dichroism (CD), and chiral molecules      319 323
Cisplatin, antitumor agent      311 618
Cisplatin-DNA complex, structure      621
Class (a) metal ions      182
Class (b) metal ions      182
Class, group theory      98 100
Classes, of crystals      208
Classification, of molecule’s point group      82
Clathrates      71
Clathrates of noble gases      292
Close-packed structures      210—213
Closo borane definition      574
Cluster compounds      454 455 572—589
Cluster compounds, carbide      587 588
Cluster compounds, main group      572—579 585—587
Cluster compounds, metallaboranes and metallacarboranes      579—582
Cluster compounds, transition metal      582—585
Cluster structures, classification      577
CNCT (fulminate), VSEPR and structure      54 55
CO (carbon monoxide)      267
CO (carbon monoxide), infrared spectrum      470
CO (carbon monoxide), molecular orbitals and photoelectron spectrum      136 138
CO (carbon monoxide), stretching modes      108 109
CO (carbon monoxide), symmetry      89
CO (carbonyl) complexes      467—474
CO (carbonyl) complexes, binary      471 472
CO (carbonyl) complexes, bonding      467—474

CO (carbonyl) complexes, bridging      470—472
CO (carbonyl) complexes, C — O distance      469
CO (carbonyl) complexes, clusters      582 583
CO (carbonyl) complexes, hydride complexes      477
CO (carbonyl) complexes, IR spectra      468—471 504 506
CO (carbonyl) complexes, main group parallels      556
CO (carbonyl) complexes, synthesis of binary      473
CO dissociation      474 521
Cobalamin      602
Cobalamin, catalysis      603
Cobaltocene      489 490
Coenzyme $B_{12}}$       13
Coenzyme $\mathrm{B_{12}}$ , vitamin      602—604
Coinage metals      17
Collman, J.P.      527 551
Collman’s reagent $\mathrm{(Na_2Fe(CO)_4)}$       527
Colors, complementary      380
Colors, coordination compounds      379
Colors, gemstones      379
Complex ions      299 302
Conditions for high and low oxidation numbers      445
Conduction band in solids      223
Conductivity, and metallic character      241
Conductivity, diamond      213
Conductivity, insulators      223 224
Conductivity, metals      213 223 224
Conductivity, semiconductors      223 224
Conductivity, temperature dependence      224 228
Conductor, band structure      223 224
Cone angle, ligand      523
Configurational isomers      310
Conformations, ligand ring      318 319
Conjugate acids and bases      167
Conjugate base mechanism      426 427
Constant electron density surfaces      33
Constitutional isomers      310
Cooke, M.P.      527
Cooper pairs in superconductors      229
Coordinate covalent bond      299
Coordinate system for octahedral orbitals      353
Coordinate system for square planar orbitals      356
Coordinate system for tetrahedral orbitals      361
Coordinate system, spherical      28
Coordination compounds      299
Coordination compounds, acid-base definition      171
Coordination compounds, crystal field theory      304
Coordination compounds, defined      299
Coordination compounds, history      299—302 304
Coordination compounds, isomerism      309—313 315 316 318—320 322 323
Coordination compounds, ligand field theory      304
Coordination compounds, nomenclature      299—302 304 305 307 308
Coordination compounds, valence bond theory      304
Coordination geometry      2
Coordination isomers      309 310 320
Coordination number (CN)      2 323—333
Coordination number (CN) and electronic structure      342
Coordination number (CN) in solids      209 210 212 213 215 217—219
Coordination number (CN), CN 1, 2, and 3      323 326 327
Coordination number (CN), CN 4      327
Coordination number (CN), CN 5      328
Coordination number (CN), CN 6      329—331
Coordination number (CN), CN 7      331
Coordination number (CN), CN 8      332
Coordination number (CN), CN larger than 8      333
Coordination sphere      302
Copper enzymes      608
Correlation diagram      132 133 390—392
Correlation diagram for homonuclear diatomic molecules      132 133
Correlation diagram for octahedral transition metal complexes      391 392
Cosmic rays      9
Cossee — Arlman mechanism      533 549
Cotton effect, in ORD and CD      323 324
Cotton, F.A.      14 110 162 636
Coulomb energy $(\prod_c)$ , electron repulsion      35 36
Coulomb energy $(\prod_c)$ , transition metal complexes      347—349 351
Counting electrons, 18-electron rule      460—463
Counting electrons, 18-electron rule, donor pair method      460
Counting electrons, 18-electron rule, neutral ligand method      460
Covalent character, and acid-base reactions      181 182
Covalent radii      44 45
Cowan, J.A.      635
Cox, P.A.      14 237
Cr(II), Jahn — Teller effect      372
Creation of the universe      5
Creswick, R.J.      237
Critical temperature for superconductivity      228
Crown ether, alkali metal complexes      251
Cryptand, alkali metal complexes      251
Crystal field splitting      344
Crystal field stabilization energy (CFSE)      345
Crystal field theory      12 304 342 344
Crystal radii      46 47
Crystal structures, binary compounds      214—217
Crystal structures, body centered cubic      210
Crystal structures, close-packed      210—213
Crystal structures, CsCl      215
Crystal structures, cubic close packed      210 212
Crystal structures, diamond      213
Crystal structures, face centered cubic      209 210 212 213
Crystal structures, fluorite $\mathrm{(CaF_3)}$       216
Crystal structures, hexagonal close packed      210 212
Crystal structures, NaCl      215
Crystal structures, NiAs      217
Crystal structures, primitive cubic      209
Crystal structures, rutile $\mathrm{(TiO_2)}$       217
Crystal structures, wurtzite      215 216
Crystal structures, zinc blende      215
Crystallization, fractional, for separation of isomers      322
CS (thiocarbonyl)      475
CsCl structure      215
CSe (selenocarbonyl)      475
Cu(II), Jahn-Teller effect      372
Cubic close packing (ccp)      210—213
Cubic geometry and VSEPR      59
Cyanate, $\mathrm{OCN^-}$ , structure      54
Cyanide $\mathrm{(CN^-)}$ as ligand      353 354 456 475
Cyanide $\mathrm{(CN^-)}$ , molecular orbitals      353 354
Cyanogen, NCCN, as pseudohalogen      290
Cyclic $\pi$ systems      480—482 485 486 489—491
cyclo- $\mathrm{C_3H_3}$ , as ligand      480—482
Cyclobutadiene, as ligand      481
Cyclometallation reactions      525
Cyclooctadiene complexes      484
Cyclopentadienyl (Cp)      485
Cyclopentadienyl (Cp) as ligand      458—460 485 486 489—491
Cyclopentadienyl (Cp), complexes      485 486
Cytochromes      595 597 599 600
d Orbital interactions      569
d Orbitals in octahedral complexes, energies      364 366
Dalton, John      15 16
Davies, N.R.      182
de Broglie, L., equation      19
Degenerate orbitals      36 127 133
Degrees of freedom, molecular motion      103 104
Delta $(\delta)$ bond      1
Delta $(\delta)$ orbitals, from d orbitals      120
Democritus      15
Denitrification      612
Density of states, N(E), in solids      223 224
Deuterium       6 247
Dextrorotatory      102
Diamagnetic compounds, magnetic susceptibility      125 339
Diamminedichloroplatinum(II), $\mathrm{[PtCl_2(NH_3)_2]}$ , cis and trans isomers      308
diamond      214 263 364
Diastereomers      310
Diatomaceous earth      269
Diazene $\mathrm{(N_2H_2)}$       274 275
Diborane $\mathrm{(B_2H_6)}$ , bonding      256—258
Dicarbide ion, structure      268
Dickerson, R.E.      598

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