Metzger J.V. — Thiazole and Its derivatives (Part 2) :: Электронная библиотека попечительского совета мехмата МГУ

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Metzger J.V. — Thiazole and Its derivatives (Part 2)

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Название: Thiazole and Its derivatives (Part 2)

Автор: Metzger J.V.

Аннотация:

General introduction to protomeric thiazoles; aminothiazoles and their derivatives; and mercaptothiazoles, hydroxythiazoles, and their derivatives

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1979

Количество страниц: 590

Добавлена в каталог: 21.09.2006

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Предметный указатель

Oxalate      121
Oxalyl chloride, with aminothiazoles      50
Oxidation of $\Delta$ -4-thiazoline-2-thione      374 393 413
Oxidation of 2-thiazolyl sulfides      405 414 415
Oxidation of 5-thiazolyl sulfides      415 418
Oxidation of 5-thiocyanato-thiazole      418
Oxidation of leucobase      45
Oxidation of nitrosulfonamides      115
Oxidation of Photinus pyralis luciferin      420
Oxidation, of hydrazinothiazoles      102
Oxime of $\Delta$ -2-thiazoline-4-one      425
Oxime, Beckmann rearrangement of      16
p-Dimethylaminobenzaldehyde, reaction with 2-methyl- $\Delta$ -2-thiazoline-4-one      425
P-Dimethylaminoethyl chloride, reaction with, $\Delta$ -4-thiazoline-2-thione anion      396
p-Nitrobenzenesulfenylchloride      403 418
P.E.S.      21
P.E.S. and CNDO calculations      22
P.E.S. and kinetic data      63
P.E.S., $\Delta$ -4-thiazoline-2-thione      381
P.P.P. approximation, and U.V. spectra      21
P.P.P. approximation, charge diagrams calculations by      17
P.P.P. approximation, of $\Delta$ -4-thiazoline-2-one      389 390
P.P.P. approximation, of $\Delta$ -4-thiazoline-2-thione      389
Paints      170
Palladium complexes      108 155 159 161
Paper-chromatography, of 2-aminothiazoles      30 124
Paper-chromatography, of 2-iminothiazolines      124
Paper-chromatography, of complexes      104
Paper-chromatography, of sulfathiazole      116
Paper-chromatography, of thiazolyl thioureas      94
Paper-electrophoretic      107
Paraformaldehyde      129
Paraformaldehyde in synthesis of amines      14
Parasiticide      133
Parkinsonism      152
Penicillin derivatives      152
Perbromides, in bromination      77
Perchlorate      121
Peroxide, in mechanism of luciferin oxidation      421
Pesticide      134 137 440 441 442
pH, in ambident reactivity, influence in paper electrophoresis      30
Pharmaceutical applications      132
Phase transfer catalysis      432
Phenethylchloride, with 2-aminothiazole      35
Phenones, with aminothiazoles      42
Phenyl lithium      429
Phenylhydrazone, of $\Delta$ -2-thiazoline-4-one      425
Phenylmagnesium bromide      428
Phenylmagnesium bromide with 2-azidothiazoles      113
Phosphate, chlorodiethylthio      401
Phosphate, chlorodietliyl      401
Phosphoric acid, diazotization with      66
Phosphorous compounds, with 2-aminothiazoles      68 69
Phosphorus oxychloride, reaction with, $\Delta$ -2-thiazoline-4-one      423
Phosphorus pentachloride, $\Delta$ -4-thiazoline-2-one      402
Phosphorus pentachloride, reaction with      401
Phosphorus pentasulfide, in transformation of $\Delta$ -4-thiazoline-one to thiazoline-thione      373
Phosphorus tribromide      426
Photochemical rearrangement, of 4-hydroxy-thiazolium innersalt      375
Photochemistry, mass spectra fragmentation analogy with, of 2-imino-4-thiazolines      27
Photoelectron spectroscopy      see P.E.S.
Photographic applications      132 159
Photographic emulsions      439
Photographic processes      438 440 441
Photographic processes with metal salts of $\Delta$ -4-thiazoline-2-thiones      412
Photographic processes with seleno-2-thiazole      370
Photographic processes with thiazolyl disulfides      412
Photometric studies      108
Photosensitive      159
Phthalic anhydride, as protecting group      104
Phthalimidoethyl bromide, alkylation with      35
Physical methods      29
Physiochemical properties, of aminothiazoles      17
Phytopathogenic microorganisms      136
Picrates, of amidines      99
Pigments      156—168
Piperidine      46
Piscaine      146
Plant growth regulator      133 134 137
Plastics      170
Platelet aggregation inhibition      145 150 152
Platinum complexes      161
Polarographic studies      153 154
Polarographic studies of 2-aminothiazoles      29
Polarographic studies of 2-anilinothiazoles      30
Polarographic studies of 2-azothiazoles      107 108
Polyacrylonitrile      105 163 164 167
Polyamines      156—168
Polycaprolactam      156—168
Polyesters      163 165 166 167
Polyhalogenothiazole, reactivity of      408—409
Polymers, $\epsilon$ -caprolactam, butadiene      438
Polymorphism, of sulfathiazole      116
Positive colored image      440
Postemergence activity      134
Potassium salts, of acetamido thiazoles      90
Potentiometric measurements and amino-imino equilibrium      21
Potentiometric measurements, and amido-imido equilibrium      116
Preemergence herbicide      137
Propargyl amine, reaction with carbon disulfide      372
Protactinium complexes      161
Protecting group, phthalic anhydride as      104
Protective action      170
Proteus vulgaris      152
Protomeric equilibrium      18
Protomeric equilibrium and HMO treatment, 2 2-hydroxythiazole      377
Protomeric equilibrium with thiazolyl carbamates      97 see
Protomeric equilibrium, $\Delta$ -2-thiazoline-4-ones, infrared      421
Protomeric equilibrium, $\Delta$ -2-thiazoline-4-ones, NMR study      421 422
Protomeric equilibrium, $\Delta$ -2-thiazoline-4-ones, solvent effect      412
Protomeric equilibrium, $\Delta$ -2-thiazoline-5-ones, infrared      430
Protomeric equilibrium, $\Delta$ -2-thiazoline-5-ones, infrared, NMR      430
Protomeric equilibrium, $\Delta$ -2-thiazoline-5-ones, infrared, solvent effect      430—431
Protomeric equilibrium, $\Delta$ -2-thiazoline-5-ones, infrared, substituent effect      430—431
Protomeric equilibrium, $\Delta$ -2-thiazoline-5-ones, infrared, U.V.      431
Protomeric equilibrium, $\Delta$ -2-thiazoline-5-thione      417
Protomeric equilibrium, $\Delta$ -4-thiazoline-2-one, dipole moment study of      389
Protomeric equilibrium, $\Delta$ -4-thiazoline-2-one, infrared spectra      387
Protomeric equilibrium, $\Delta$ -4-thiazoline-2-one, NMR study      389
Protomeric equilibrium, $\Delta$ -4-thiazoline-2-one, solvent effect on      389
Protomeric equilibrium, $\Delta$ -4-thiazoline-2-one, ultra-violet spectra      387
Protomeric equilibrium, 2-mercaptothiazole      377
Protomeric equilibrium, acetamido-acetimido      91
Protomeric equilibrium, associated species in      5
Protomeric equilibrium, azohydrazone-hydrazone      107
Protomeric equilibrium, biprotomeric      1
Protomeric equilibrium, determination of pK, from in $\Delta$ -4-thiazoline-2-one      389
Protomeric equilibrium, general      1
Protomeric equilibrium, in $\Delta$ -4-thiazoline-2-thione, HMO treatment of substituent effect      377 378
Protomeric equilibrium, in $\Delta$ -4-thiazoline-2-thione, IR studies      378
Protomeric equilibrium, in $\Delta$ -4-thiazoline-2-thione, NMR studies      379
Protomeric equilibrium, in $\Delta$ -4-thiazoline-2-thione, solvent effect      379
Protomeric equilibrium, in $\Delta$ -4-thiazoline-2-thione, steric effect on      380
Protomeric equilibrium, in $\Delta$ -4-thiazoline-2-thione, ultra violet spectra      378
Protomeric equilibrium, medium effects on      5
Protomeric equilibrium, substituent effects on      2
Protozoicide      140 440
Pseudomonas aeruginosa      152
Pseudooctahedral stereochemistry      120
Psychotropics      146 147
Purification, of 2-aminothiazoles      30
Pyridine      421
Pyridines      55 57 58 71 79 81
Pyridines, coupling with      112
Pyridines, nitration of      72
Pyridones, from diazonium salts      67
Pyrimidin derivatives      54 56 57 58 119 123 124
Pyrocatechol      155
Pyrocatechol, coupling with      112
Quaternarization      see Alkylation

Quaternary salts, in synthesis of aminothiazoles      15
Quaternary salts, in synthesis of imino-4-thiazolines      32 122
Radical intermediates from azothiazoles      108
Radical intermediates in rearrangement      83
Radical intermediates with lead dioxide      101
Radical intermediates, amino free radical      31 71
Radical intermediates, radical anions      87
Radioactive radiations, protection against      439
Radioprotective action      148 152
Raman spectra of $\Delta$ -4-thiazoline-2-thione      381
Raman spectra of 2-aminothiazoles      24
Raney nickel      40 86
Raney nickel in relation with 4-thiazole sulfonic acid      413
Raney nickel, desulfurization of $\Delta$ -4-thiazoline-2-thione      399
Raney nickel, desulfurization of 5-acetylthiothiazoles      417
Rat paw edema inhibition      144
Rate constants and steric effects      32
Rate constants of 2-dialkylaminothiazoles with %lCH_3$      32
Rate constants of quaternarization of 2-aminothiazoles      32
Rate constants, of coupling      112
Rearrangement      70
Rearrangement in alkylation reactions      34
Rearrangement in diazonium coupling      77
Rearrangement in nitrosatiori      68
Rearrangement of 2-imino-4-thiazolines      130
Rearrangement of 3-aminomethyl to 5-aminomethyl- $\Delta$ -4-thiazohne-2-thione      400
Rearrangement of 5-aminothiazoles      86
Rearrangement of alkylaminothiazoles      80
Rearrangement of hydrazinothiazoles      102 104
Rearrangement of nitramino intermediates      73 113
Rearrangement of sulfenamidothiazoles      82
Rearrangement of sulfonamide thiazoles      69
Rearrangement of thiazolylthioureas      95
Rearrangement sulfonic-sulfamic acid      70 75
Reduction by       16
Reduction by activated iron      16
Reduction by Na in       86
Reduction by Zn      16 74
Reduction of $\Delta$ -4-thiazoline-2-one with Zn dust      402
Reduction of 2-thiazolylthioether      405
Reduction of 4-alkylidene- $\Delta$ 2-thiazoline-5-one      427 428
Reduction of 5-acetylthio-thiazole      417
Reduction of 5-thiocyanato thiazole      416
Reduction of alkylaminothiazoles      87 88
Reduction of dimethylsulfoxide      376
Reduction of heterocyclic systems      86 115
Reduction of thiazolylamidines      99
Reduction with sodium borohydride      91
Reduction with sodium lithium hydride      92
Reduction, of 2-acetamidothiazole sulfonyl chloride      413
Reimer — Tiemann reactions, on $\Delta$ -4-thiazo-line-2-ones      402
Retro — Hantzsch, mechanism of      84 85 102
Rhodanine, alkylation of      419
Rhodanine, ambident reactivity of      419
Rhodanine, reaction with aryldiazonium salts      419
Rhodanine, reaction with halogenothiazoles      79
Rice cultures      135 136 137
Ring opening, of $\Delta$ -2-thiazoline-5-one      433
Ring transformation, $\Delta$ -2-thiazohne-5-one      417 418
Ring transformation, $\Delta$ -4-thiazoline-2-thione      373
Ring transformation, 1,3,4-thiadiazole-2-thione to $\Delta$ -4-thiazo-line-2-thione      372
Ring transformation, 1,3-dithiole-2-thione to $\Delta$ -4-ihiazoline-2-thione      372
Ring transformation, 2-imino-1,3-oxythiolan derivatives to $\Delta$ -4-thiazoline-2-one      374 375
Ring transformation, 5 amino- $\Delta$ -4-thiazo-line-2-thione to 4-mercapto-imidazoline-2-thione      399
Ring transformation, 5,5-diphenyl-2,4-thiazolidinedithione, to 4,5-diphenyl- $\Delta$ -4-thiazoline-2-thione      373
Ring transformation, 5-methylenethiazolidine-2-thione to $\Delta$ -2-oxazoline-5-one      417 418
Ring-chain tautomerism      113
Rubber, synthetic      439 441
Ruthenium complexes      161
Salicylaldehyde, Schiff base with      99
Salmonella typhi      152
Salts, of acetamido thiazoles      91
Sandmeyer reaction, in halothiazoles synthesis      12
Schiff bases      256—259 268 270
Schiff bases from amiriothiazoles      98
Schiff bases in reduction by       14
Schiff bases in reduction by       14
Schiff bases to amines      40
Schiff bases with 2-amino thiazoles      30 40
Schiff bases, complexes of      99
Schiff bases, cyclization to      42
Schiff bases, IR spectra of      41
Schiff bases, UV spectra of      41 see
Schistosomacidal      141
Schistosomiasis japonica      145
Schotten — Bauman reaction      51 123
Sedative      145 148 438
Selective herbicide      135
Self association, effect of, $\Delta$ -4-thiazoline-2-one, relation with protomery      377
Self association, effect of, $\Delta$ -4-thiazoline-2-thione, relation with protomery      377
Self association, effect of, $\Delta$ -4-thiazoline-2-thione, substituent effect on      384
Self association, effect of, on UV spectra of $\Delta$ -4-thiazoline-2-thione      381
Sigma values, correlation with       19
Sigma values, correlation with , and IR spectroscopy      24
Silicon compounds, with 2-aminothiazoles      68
Silk      163
Silver complexes      104 108
Silver halide emulsions, miscellaneous      438
Silver halide emulsions, with seleno-2-thiazole      370
Silver nitrate      108
Sodium acetate, catalysis by      81
Sodium acetate, rearrangements with      130
Sodium acetate, to 2-acetamidothiazoles      52
Sodium acetate, with thiazolylureas      93
Sodium amide, in 2-aminothiazole alkylation      35
Sodium amide, in Chichibabin reaction      12
Sodium azide, on diazonium salts      113
Sodium bicarbonate, in preparation of sulfathiazoles      115
Sodium bicarbonate, in rearrangement      86 130
Sodium borohydride      428 429
Sodium borohydride, reduction of 2-aminothiazoles      91
Sodium borohydride, reduction of Schiff bases      14
Sodium carbonate, in preparation of sulfathiazoles      115
Sodium cyanide, in synthesis of 5-amino-thiazole      16
Sodium ethoxide      35
Sodium hydride      37 50 93 432
Sodium lithium hydride, reduction with      92
Sodium nitrite, with 2-imino-4-thiazolines      126
Sodium nitrite, with azothiazoles      111
Sodium salts, of acetamido thiazoles      90
Sodium t-butylate      61
Sodium, in       86
Sodium-mercury amalgam, reaction with, 2-thiazolyl sulfonic acid      414
Soft acid or base      see HSAB theory
Solid state reactions      52
Solvent effect and UV spectra      21
Solvent effect in diazotization      68
Solvent effect in extraction      154
Solvent effect in halogenation      77
Solvent effect in paper chromatography      30
Solvent effect in tautomerism      113
Solvent effect on protomerism, of $\Delta$ -2-thiazoline-4-ones      422
Solvent effect on protomerism, of $\Delta$ -2-thiazoline-5-ones      430
Solvent effect on protomerism, of $\Delta$ -4-thiazoline-2-one      389
Solvent effect on protomerism, of $\Delta$ -4-thiazoline-2-thione      379
Solvent effect on rearrangement      82
Solvent effect, aprotic solvents in alkylation      35
Solvent effect, on alkylation of $\Delta$ -4-thiazo-line-2-thione, with diazomethane      395
Solvent effect, on ambident reactivity      40
Solvent effect, on ambident reactivity, of rhodanine      419
Spectroscopic properties      17 154 155 156 157 158 160 161
Spectroscopic properties of alkylated aminothiazoles      38
Spectroscopic properties of alkylated iminothiazolines      38
Spectroscopic properties of aminothiazoles      17
Spin      121 122
Spot test reagents      150 155 156—168
Stabilizer      170
Stain, complexes of      120
Stain, hydrogenation with      116
Staphylococcus aureus      139 140 141 152

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