Metzger J.V. — Thiazole and Its derivatives (Part 2) :: Электронная библиотека попечительского совета мехмата МГУ

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Metzger J.V. — Thiazole and Its derivatives (Part 2)

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Название: Thiazole and Its derivatives (Part 2)

Автор: Metzger J.V.

Аннотация:

General introduction to protomeric thiazoles; aminothiazoles and their derivatives; and mercaptothiazoles, hydroxythiazoles, and their derivatives

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1979

Количество страниц: 590

Добавлена в каталог: 21.09.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

2-Thiazolyl sulfide, tables of compounds, 5-nitro      454 455
2-Thiazolyl sulfide, tables of compounds, 5-nitro-2-heteroaryl      453
2-Thiazolyl sulfide, tables of compounds, 5-substituted      450
2-Thiazolyl sulfide, tables of compounds, 5-substituted benzylideneamino      451 452
2-Thiazolyl sulfide, tables of compounds, S-naphtoquinonyl derivatives      504
2-Thiazolyl sulfide, transformation in, 2-thiazolyl sulfones      405 415
2-Thiazolyl sulfide, transformation in, 2-unsubstituted thiazoles      405
2-Thiazolyl sulfide, uses of      440
2-Thiazolyl sulfinicacid, decomposition of      413
2-Thiazolyl sulfinicacid, preparation of, from $\Delta$ -4-thiazoline-2-thione and       393 413
2-Thiazolyl sulfinicacid, preparation of, from 2-acetamidothiazole sulfonyl chloride      413
2-Thiazolyl sulfinicacid, table of compounds      472—473
2-Thiazolyl sulfonic acids, preparation of, from $\Delta$ -4-thiazoline-2-thione and       397 413
2-Thiazolyl sulfonic acids, preparation of, from $\Delta$ -4-thiazoline-2-thione and       393 413
2-Thiazolyl sulfonic acids, preparation of, from direct sulfonation      413
2-Thiazolyl sulfonic acids, tables of compounds      472 473
2-Thiazolyl sulfonic acids, transformation in, $\Delta$ -4-thiazolme-2-one      375
2-Thiazolyl sulfonic acids, transformation in, 2-N-alkylaminothiazole      414
2-Thiazolyl sulfonic acids, transformation in, 2-unsubstituted thiazole      414
2-Thiazolyl sulfonyl chloride, preparation of, from $\Delta$ -4-thiazoline-2-thione      414
2-Thiazolyl sulfonyl chloride, transformation to, sulfonamides      414
2-Thiazolyl sulfoxides, table of compounds      471
2-Thiazolyl-sulfones, bromination of      415
2-Thiazolyl-sulfones, nitration of      415
2-Thiazolyl-sulfones, preparation of, from 2-halothiazole      415
2-Thiazolyl-sulfones, preparation of, from 2-thiazolyl sulfide      405 415
2-Thiazolyl-sulfones, tables of compounds      472—473
2-Thiazolyl-sulfones, thiocyanation of      415
3-Allyl- $\Delta$ -4-thiazoline-2-one      410
3-Amino-2-iminothiazoline, from thiazolium salts      130
3-Amino-2-iminothiazoline, nicotinoylation reaction with      131
3-Amino-2-iminothiazoline, to, 1,3,4-oxadiazole      132
3-Amino-2-iminothiazoline, with acid chlorides      131
3-Amino-2-iminothiazoline, with carbon disulfide      131
3-Amino-2-iminothiazoline, with cyanogen bromide      131
3-Amino-2-iminothiazoline, with ethyl orthoformate      131
3-Bromo-2-butanone      85
3-Chloropropionic acid, quaternization with aminothiazoles      32
3-Ethyl-4-hydroxy- $\Delta$ -4-oxazoline-2-thione      407
4,5-Dialkyl-2-ammothiazoles      186
4,5-Diaryl-2-aminothiazoles      193—199
4,5-Dihetaryl-2-aminothiazole      193—199
4,5-Disubstituted-2-aminothiazoles      186—192
4,5-Disubstituted-2-substituted aminothiazoles      215—218
4-Alkyl-2 aminothiazoles      172
4-Alkylidene- $\Delta$ -2-thiazoline-5-one      427
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, Friedel — Ctafts reaction on      428
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, Grignard reaction on      429
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, preparation of, from $\Delta$ -2 thiazoline-5-one and enamines      432
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, preparation of, from $\Delta$ -2-thiazoline-5-one and aldehyde      432
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, preparation of, from $\Delta$ -2-thiazoline-5-one and ketone      432
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, reaction with phenyl lithium      429
4-Alkylidene- $\Delta$ -2-thiazoline-5-one, reduction of      427
4-Aminothiazole-2,5-diphenyl, to 2,5 di-phenyl- $\Delta$ -2-thiazoline-4-one      421
4-Aminothiazoles      295 296
4-Aminothiazoles, ambident reactivity of      31
4-Aminothiazoles, with $\beta$ -diketones      46
4-Aminothiazoles, with benzaldehyde      47
4-Aminothiazoles, with chlorovinyl ketones      46
4-Aminothiazoles, with isocyanates      60
4-Aminothiazoles, with isothiocyanates      60
4-Aryl-2-aminothiazoles      178—182
4-Aryl-2-aminothiazoles, mercuration of      81
4-Aryl-2-aminothiazoles, nitration of      72
4-Aryl-2-aminothiazoles, reduction of      86
4-Aryl-2-aminothiazoles, Schiff bases from      99
4-Bromothiazole      426
4-Chloro-4-methyl-2-phenyl- $\Delta$ -2-thiazoline-5-one      432
4-Chloro-4-methyl-2-phenyl- $\Delta$ -2-thiazoline-5-one from 4-methy]-2-phenyl- $\Delta$ -2-thiazoline-5-one      432
4-Chloro-4-methyl-2-phenyl- $\Delta$ -2-thiazoline-5-one, reaction with thioacetic acid      432
4-Chlorophenol, hydrogen bonding, with $\Delta$ -4-thiazoline-2-thione      377
4-Formyl pyridine      398
4-Hetaryl-2-aminothiazoles      178—182
4-Hydroxythiazole      see $\Delta$ -2-Thiazolirie-4-one
4-Mercapto-imidazoline-2-thione, from 5-amino- $\Delta$ -4-thiazoline-2-thione      399
4-Methyl-5- $\beta$ -chloroethylthiazole      375
4-Methylthiazole, preparation of, from reduction of 4-methyl- $\Delta$ -4-thiazoline-2-thione      397
4-Substituted-2-aminothiazoles      172—177
4-Substituted-2-arylaminothiazoles      204—209
4-Substituted-2-hetarylaminothiazoles      210
4-Substituted-2-substituted amino-thiazoles      200—203
4-Thiazolyl oxides, NMR of      426
4-Thiazolyl oxides, preparation of      426
4-Thiazolyl oxides, tables of compounds      530
4-Thiazolyl oxides, uses of      442
4-Thiazolyl oxides, UV of      426
4-Thiazolyl sulfide, table of compounds      502—503
4-Thiazolyl-aryl sulfone, preparation of      416
4-Thiazolyl-aryl sulfone, table of compounds      503
5-Alkyl-2-aminothiazoles      183
5-Aminomethyl- $\Delta$ -4-thiazoline-2-thione derivatives, from rearrangement of 3-aminomethyl- $\Delta$ -4-thiazoiine-2-thione      400
5-Aminothiazoles      292—295
5-Aminothiazoles, ambident reactivity of      31
5-Aminothiazoles, by reduction of nitrothiazoles      74
5-Aminothiazoles, rearrangement      86
5-Aminothiazoles, synthesis of      16
5-Halogenothiazole, reaction with, metal sulfinate      415
5-Hydroxythiazole      see $\Delta$ -2-Thiazoline-5-one
5-Mercaptothiazole      see $\Delta$ -2-Thiazoline-5-thione
5-Methylenethiazolidine-2-thione, preparation of, from propargyl amine and       372 373
5-Nitro-2-aminothiazoles, pharmaceutical activity of      72
5-Nitro-2-aminothiazoles, rearrangement to      83
5-Substituted-2-aminothiazole      183—185
5-Substituted-2-substituted aminothiazoles      213 214
5-Thiazolyl oxides, bromination of      436
5-Thiazolyl oxides, cleavage to $\Delta$ -2-thiazoline-5-one      430
5-Thiazolyl oxides, flavoring properties      436
5-Thiazolyl oxides, nitration of      436
5-Thiazolyl oxides, physical properties      436
5-Thiazolyl oxides, preparation of      436
5-Thiazolyl oxides, sulfonation of      436
5-Thiazolyl oxides, tables of compounds      528 529
5-Thiazolyl oxides, uses of      442
5-Thiazolyl sulfides, bis-5-thiazolyl sulfide, oxidation of      415
5-Thiazolyl sulfides, bis-5-thiazolyl sulfide, oxidation of, 5-(2-hydroxythiazolyl)phenyl sulfide case      418
5-Thiazolyl sulfides, bis-5-thiazolyl sulfide, oxidation of, general      418
5-Thiazolyl sulfides, physical properties      418
5-Thiazolyl sulfides, preparation of      417—418
5-Thiazolyl sulfides, table of compounds      493—496
5-Thiazolyl sulfides, uses of      442
5-Thiazolyl sulfmic acid, preparation of      413
5-Thiazolyl sulfmic acid, table of compounds      498—501
5-Thiazolyl sulfones, physical properties, IR      415
5-Thiazolyl sulfones, physical properties, NMR      415
5-Thiazolyl sulfones, preparation of, from 5-halogenothiazole      415
5-Thiazolyl sulfones, preparation of, from 5-thiazolyl sulfide      415 418
5-Thiazolyl sulfones, table of compounds      498—501
5-Thiazolyl sulfonyl chloride, preparation of, from 2-substituted thiazoles      414
5-Thiazolyl sulfonyl chloride, transformation to, sulfonamides      414
5-Thiazolyl sulfoxides, table of compounds      498
5-Thiazolyl thiouronium salts, preparation of      417
5-Thiazolyl thiouronium salts, to $\Delta$ -2-thiazoline-5-thione      416
5-Thiazolyl-acetate, preparation of      426
8-Hydroxyquinoline, with aminothiazoles      44
Acaricide      442
Acetamido-acetimido, protomeric equilibrium      91
Acetamidothiazoles      220—241
Acetamidothiazoles from acetic acid      53
Acetamidothiazoles from acetic anhydride      52 91
Acetamidothiazoles from acyl halides      48—51 90
Acetamidothiazoles to acetylimino-4 thiazolines      91
Acetamidothiazoles, alkylations      35
Acetamidothiazoles, alkylations, ambident reactivity in      37
Acetamidothiazoles, alkylations, general pattern      91
Acetamidothiazoles, alkylations, with $\alpha$ -chloroacetamide      33
Acetamidothiazoles, aminoalkylation of      44
Acetamidothiazoles, as ligands      70 120
Acetamidothiazoles, bromination of      79
Acetamidothiazoles, by heterocyclization methods      90
Acetamidothiazoles, from esters      53

Acetamidothiazoles, from sodium acetate      52
Acetamidothiazoles, from thiazolylureas      93
Acetamidothiazoles, IR spectra of      23
Acetamidothiazoles, mass spectra of      28
Acetamidothiazoles, mercuration of      81
Acetamidothiazoles, nitration of      72 74
Acetamidothiazoles, reduction of      92
Acetamidothiazoles, salts of      91
Acetamidothiazoles, sulfonation of      75
Acetamidothiazoles, urinary metabolite      85
Acetic acid, with 2-aminothiazole      53
Acetic acid, with ethylene oxide      38
Acetic anhydride      421 426 431
Acetic anhydride in solid state reactions      52
Acetic anhydride to 2-acetamidothiazoles      52
Acetic anhydride with 2-hydrazinothiazoles      101 106
Acetic anhydride with carbamates      16
Acetic anhydride with sulfenamidothiazoles      114
Acetic anhydride with thiazolyl ureas      93
Acetoacetamidothiazole      53
Acetophenone, by reduction      86
Acetophenone, from 4-phenyl- $\Delta$ -4-thiazoline-2-thione      399
Acetophenone, in Mannich reaction      44
Acetophenone, in synthesis of amines      14
Acetyl chloride, with aminothiazoles      48
Acetylated amino thiazoles      see Acetamidothiazoles
Acetylations      see Acylations
Acetylimino-4-thiazolines      91 283—291
Acid (carboxylic), in heterocyclization s      129
Acid (carboxylic), to acylaminothiazoles      90
Acid (carboxylic), with 2-aminothiazoles      47
Acid catalysis      32 38
Acid catalysis in ammonolysis of halothiazoles      13
Acid catalysis in nitrations      73
Acid catalysis of chelate formation      95
Acid catalysis of heterocyclization      91
Acid catalysis of hydrolysis      92 99 105
Acid catalysis of rearrangement      102 130
Acid chlorides, with $\Delta$ -2-thiazoline-5-one anion      432
Acid chlorides, with $\Delta$ -4-thiazoline-2-thione anion      396
Acid chlorides, with 3-amino-2-iminothiaz-oline      131
Acid chlorides, with aminothiazoles      48 90
Acid halides, with aminothiazoles      47
Acidity, of 2-aminothiazoles      90
Acrylic fibers      105
Acrylonitrile, reaction of, with ambident anion of $\Delta$ -4-thiazoline-2-thione      394
Acrylophenone, with aminothiazoles      42
Activation, by amino group of nucleophilic substitution      18
Activation, by nitro group      12
Activation, by protomeric equilibrium      18
Acyl-2-imino-4-thiazolines, reduction of      127
Acylaminothiazoles      90 220—241
Acylaminothiazoles from acids      90
Acylaminothiazoles from acyl chloride      90
Acylaminothiazoles from anhydrides      90
Acylaminothiazoles from azidothiazoles      90
Acylaminothiazoles, of      91
Acylaminothiazoles, alkylation, general patterns      91
Acylaminothiazoles, by heterocyclization      90
Acylaminothiazoles, Curtius degradation to      90
Acylaminothiazoles, hydrolysis of      92
Acylaminothiazoles, Mannich bases from      91
Acylaminothiazoles, mass spectra of      91
Acylation of $\Delta$ -4-thiazoline-2-one      402
Acylations      47
Additive, for antifouling point      440
Additive, for lubricant      442
Additive, for oil      438
Adrenergic activities, of 1-alkylamino-3-(2 thiazoloxy)-2-propanol derivatives      410
Adrenergic activities, relation with conformation in      410
Adsorption      170
Agricultural applications      132
Alcohol, by oxydation      45
Alcohol, in alkylations, of $\Delta$ -4-thiazoline-2-thiones      392
Alcohol, in alkylations, of alkylaminothiazoles      48
Alcohol, in alkylations, of aminothiazoles      38
Aldehydes, with $\Delta$ -2-thiazohne-5-ones      432
Aldehydes, with aminothiazoles      98
Alga scenedesmus acutus      134
Algicide      438
Alkali amides      see Amide ions
Alkenes, in alkylation of $\Delta$ -4-thiazoline-2-thiones      392
Alkenes, in cycloaddition with $\Delta$ -2-thiazoline-5-one      436
Alkyl halides, reaction with, $\Delta$ -4-thiazoline-2-thiones anion      392 396
Alkyl-acetamidothiazoles, with benzaldehyde      46
Alkylaminothiazoles, aminoalkylation of      81
Alkylaminothiazoles, from thiazolyl amidines      99
Alkylaminothiazoles, rearrangement of      80
Alkylaminothiazoles, reduction of      87
Alkylaminothiazoles, structure determination of, by chemical methods      37
Alkylaminothiazoles, structure determination of, by spectroscopic methods      38
Alkylaminothiazoles, to mesoionic xanthine      60
Alkylaminothiazoles, with acetic anhydride      55
Alkylaminothiazoles, with alcohols      47
Alkylaminothiazoles, with alkali amides      43
Alkylaminothiazoles, with malonate esters      55
Alkylation, and chemical structure determination      37
Alkylation, and rearrangements      33
Alkylation, at nitrogen in $\Delta$ -4 thiazoline-2-one, reactivity of ambident anion      401
Alkylation, at nitrogen in $\Delta$ -4 thiazoline-2-one, selectivity of      401
Alkylation, at nitrogen in $\Delta$ -4-thiazoline-2-thione, in relation with ambident reactivity      394—396
Alkylation, at nitrogen in $\Delta$ -4-thiazoline-2-thione, reaction with diazoalkanes      394
Alkylation, at nitrogen in $\Delta$ -4-thiazoline-2-thione, reaction with methylvinylketones      394
Alkylation, at oxygen in $\Delta$ -2-thiazoline-4-one      423
Alkylation, at oxygen in $\Delta$ -4-thiazoline-2-one, diazomethane reaction      401
Alkylation, at oxygen in $\Delta$ -4-thiazoline-2-one, steric effect on      401
Alkylation, at sulfur in $\Delta$ -2-thiazoline-5-thione      416
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, preparative aspects, with alcohol      392
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, preparative aspects, with alkenes      392
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, preparative aspects, with alkylhalides      391 396
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, preparative aspects, with diazomethane      395
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, preparative aspects, with dihalogenoalkanes      391
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, preparative aspects, with methyliodide      391
Alkylation, at sulfur in $\Delta$ -4-thiazoline-2-thione, quantitative aspects      see Nucleophilic substitution
Alkylation, in aprotic solvents      35
Alkylation, of 2-acetamidothiazoles      35 37
Alkylation, of alkylaminothiazole      34
Alkylation, of alkylaminothiazole, with alcohols      47 80 90
Alkylation, of aminothiazoles, with 2-propynyl bromide      32
Alkylation, of aminothiazoles, with 3-chloropropionic acid      33
Alkylation, of aminothiazoles, with alcohols      38
Alkylation, of aminothiazoles, with benzyl chloride      33
Alkylation, of aminothiazoles, with chloracetic acid      33
Alkylation, of aminothiazoles, with chloracetic esters      33
Alkylation, of aminothiazoles, with dimethylaminoethylchloride      35
Alkylation, of aminothiazoles, with ethyl iodide      33
Alkylation, of aminothiazoles, with ethylene oxide      34 38
Alkylation, of aminothiazoles, with phenethyl chloride      35
Alkylation, of azothiazoles      105
Alkylation, of dialkylaminothiazoles      32
Alkylation, of nitraminothiazoles      37
Alkylation, of sulfathiazoles      116
Alkylation, of thiazolylureas      93
Alkylation, with alkali amides      34 35
Alkylation, with phthalimidoethylbromide      35
Alkylthiazoles, quaternary salts of      15
Alkyne in cycloaddition reaction with $\Delta$ -2-thiazoline-5-one      436
Alkyne in cycloaddition reaction with $\Delta$ -2-thiazoline-5-one, 1,4-dichloro-2-butyne, reaction with $\Delta$ -4-thiazoline-2-thione anion      396
Alkyne in cycloaddition reaction with $\Delta$ -2-thiazoline-5-one, in synthesis of $\Delta$ -4 thiazoline-2-thione      372
Allergy prevention      148
Aluminum chloride, isomerization of 5,5-diphenyl-2,4 thiazolidine      373
Aluminum complexes      161
Aluminum-mercury amalgam, reduction of 2-thiazolylsulfide      405
Ambident reactivity and HSAB theory      5
Ambident reactivity and kinetic data      63
Ambident reactivity and molecular orbital calculations      61 62
Ambident reactivity and PES      63
Ambident reactivity and single electron transfer      6
Ambident reactivity and steric effects      63
Ambident reactivity in nitration reactions      72

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