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Metzger J.V. — Thiazole and Its derivatives (Part 2)
Metzger J.V. — Thiazole and Its derivatives (Part 2)



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Название: Thiazole and Its derivatives (Part 2)

Автор: Metzger J.V.

Аннотация:

General introduction to protomeric thiazoles; aminothiazoles and their derivatives; and mercaptothiazoles, hydroxythiazoles, and their derivatives


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1979

Количество страниц: 590

Добавлена в каталог: 21.09.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
$\Delta$-4-Thiazoline-2-thione, thiocyanation of      400
$\Delta$-4-Thiazoline-2-thione, to 2-imino-4-thiazolines      123
$\Delta$-4-Thiazoline-2-thione, transformation in, $\Delta$-4-thiazoline-2-one      374
$\Delta$-4-Thiazoline-2-thione, transformation in, 2-chlorothiazoles      393
$\Delta$-4-Thiazoline-2-thione, transformation in, 2-imino-4-thiazolyl derivatives      398
$\Delta$-4-Thiazoline-2-thione, transformation in, 2-thiazolylsulfonic acid      393 413
$\Delta$-4-Thiazoline-2-thione, transformation in, 2-thiazolylsulfonylchloride      393 414
$\Delta$-4-Thiazoline-2-thione, transformation in, 2-unsubstituted thiazoles      413 393 397
$\Delta$-4-Thiazoline-2-thione, transformation in, sulfcnamidothiazoles      411
$\Delta$-4-Thiazoline-2-thione, transformation in, thiazolyl disulfide      393 397 399
$\Delta$-4-Thiazoline-2-thione, transition metal complexes      386
$\Delta$-4-Thiazoline-2-thione, ultraviolet spectra      378
$\Delta$-4-Thiazoline-2-thione, uses      438 439
$\Delta$-4-Thiazoline-2-thione, UV spectra, CNDO calculation      380
$\Delta$-4-Thiazoline-2-thione, UV spectra, effect of self-association on      381
$\Delta$-4-Thiazoline-2-thione, UV spectra, PPP calculation      380
$\Delta$-4-Thiazoline-2-thione, UV spectra, steric effect on      381
$\Delta$-4-Thiazoline-2-thione, X-ray determination      385 386
$\epsilon$-Caprolactam polymers      438
$\gamma$-Chlorobutyryichloride, with aminothiazoles      50
$^{15}$C-NMR$ spectroscopy, representative data, in $\Delta$-4-thiazoline-2-one      390
$^{15}$C-NMR$ spectroscopy, representative data, in $\Delta$-4-thiazoline-2-thione      388
1,2,4-Triazolin, 4-phenyl-3,5-dione      433
1,2,4-Triazolin, from $\Delta$-2-thiazolin-5-ones      435—436
1,2-Dithiole-3-thione, methylation of      391
1,3,4-Thiadiazole-2-thione, reaction with alkynes      372
1,3,5-Oxadiazine-2,4,6-trione, to biuret derivatives      56
1,3-Diester, of 2-imino-4-thiazoline      123
1,3-Dipolar cyclo additions, of $\Delta$-2-thiazoline-4-one      425 426
1,3-Dipolar cyclo additions, with dimethyl acetylenodicarboxylate      426 427
1,3-Dipolar cyclo additions, with methyl fumarate      425 426
1,3-Dipolar cyclo additions, with methyl maleate      425 426
1,4-Dichloro-2-butene, reaction with, $\Delta$-4-thiazoline-2-thione anion      396
2,4-Dichlorothiazole, 2,5-dichlorothiazole      408
2,4-Thiazolidinedithione, isomerization with $AlCl_3$      373
2,4-Thiazoline diones, from $\Delta$-2-thiazoline-4-ones      423 424
2-(6'-Hydroxybenzothiazol-2'-yl)-4-hydroxythiazole      420—421
2-Acetylamino, 5-bromo-thiazole, reactionwith sodium thiophenoxide      418
2-Acetylamino-thiazole, reaction with sulfonylchloride derivatives      418
2-Alkylimino-4-thiazolines      127
2-Alkylthio-thiazolium salts, preparation of, from N-substituted $\Delta$-4-thiazoline-2-thiones and alkylating agents      391 392
2-Allyloxythiazole      410
2-Amino-3-thiazolines, by bromination      78
2-Amino-4-methyl-thiazole anion, behavior in Na/$NH_3$      398
2-Amino-5-bromothiazole, reaction with hydrogen sulfide      417
2-Aminothiazole, to 2-mercaptothiazoie      370
2-Aminothiazole, with acetaldehyde      42
2-Aminothiazoles      12
2-Aminothiazoles, acidity of      90
2-Aminothiazoles, acylations of, with $\beta$-chloropropionylchioride      50
2-Aminothiazoles, acylations of, with $\gamma$-chlorobutyrylchloride      50
2-Aminothiazoles, acylations of, with acetic acid      53
2-Aminothiazoles, acylations of, with acetic anhydride      52
2-Aminothiazoles, acylations of, with acyl halides      48
2-Aminothiazoles, acylations of, with chloracetyl chloride      49
2-Aminothiazoles, acylations of, with esters      53
2-Aminothiazoles, acylations of, with ethyl acrylate      54
2-Aminothiazoles, acylations of, with indoiyi derivatives      48
2-Aminothiazoles, acylations of, with malonic esters      55
2-Aminothiazoles, acylations of, with malonyl chloride      49
2-Aminothiazoles, acylations of, with oxalyl chloride      50
2-Aminothiazoles, acylations of, with sodium acetate      52
2-Aminothiazoles, acylations of, with unsaturated acyl chloride      49
2-Aminothiazoles, additions to-double bonds      40
2-Aminothiazoles, alkylations, rate constants of      32
2-Aminothiazoles, alkylations, with 2-chloropropionicacid      32
2-Aminothiazoles, alkylations, with 2-propynyl bromide      32
2-Aminothiazoles, alkylations, with alcohols      38
2-Aminothiazoles, alkylations, with benzyhydryl chloride      34
2-Aminothiazoles, alkylations, with benzyl chloride      80
2-Aminothiazoles, alkylations, with chloracetic acid      33
2-Aminothiazoles, alkylations, with chloracetic esters      33
2-Aminothiazoles, alkylations, with dialkylaminoalkyl halides      33
2-Aminothiazoles, alkylations, with dimethylaminoethylchloride      35
2-Aminothiazoles, alkylations, with ethyl iodide      33
2-Aminothiazoles, alkylations, with ethylene oxide      34 38
2-Aminothiazoles, alkylations, with phenethyl chloride      35
2-Aminothiazoles, alkylations, with tosyl chloride      69
2-Aminothiazoles, ambident reactivity of      30 31 38 39 61—64
2-Aminothiazoles, anaesthetic properties of      42 43
2-Aminothiazoles, and acrylophenone      42
2-Aminothiazoles, and phenone      42
2-Aminothiazoles, basicity of      90
2-Aminothiazoles, biheterocychc structures from      33 42
2-Aminothiazoles, by Chichibabin reaction      12
2-Aminothiazoles, by hydrolysis      92
2-Aminothiazoles, by mercapto group replacement      13
2-Aminothiazoles, colorimetric analysis of      30
2-Aminothiazoles, complexes of      120
2-Aminothiazoles, dialkylation of      37
2-Aminothiazoles, diazotization of      66 67
2-Aminothiazoles, dipole moment of      29
2-Aminothiazoles, electrophilic centers substitution by      32
2-Aminothiazoles, extraction of      30
2-Aminothiazoles, from 2-halothiazoles      12
2-Aminothiazoles, gas-liquid-chromatography of      30
2-Aminothiazoles, in biological samples      30
2-Aminothiazoles, in blood      30
2-Aminothiazoles, in feeds      30
2-Aminothiazoles, in Ullman synthesis      115
2-Aminothiazoles, in urine      30
2-Aminothiazoles, in wine      30
2-Aminothiazoles, magnetic susceptibilities of      29
2-Aminothiazoles, Mannich bases from      91
2-Aminothiazoles, mass spectra of      27
2-Aminothiazoles, metabolite from      42
2-Aminothiazoles, molecular orbital calculations of      61 62
2-Aminothiazoles, NMR spectra of      25 26
2-Aminothiazoles, ozonolysis of      71
2-Aminothiazoles, paper electrophoresis of      30
2-Aminothiazoles, polarographic data      29
2-Aminothiazoles, purification of      30
2-Aminothiazoles, quaternary salts of      32
2-Aminothiazoles, reduction of      91
2-Aminothiazoles, Schiff bases with      30
2-Aminothiazoles, solid state reactions with      52
2-Aminothiazoles, sublimation of      30
2-Aminothiazoles, synthesis of      12
2-Aminothiazoles, thin layer chromatography of      30
2-Aminothiazoles, titration of      30
2-Aminothiazoles, to iminothiazolines      38 47
2-Aminothiazoles, to iminothiazolines, IR spectra of      24
2-Aminothiazoles, to sulfonamido thiazoles      69
2-Aminothiazoles, toward electrophilic reagents      71—84
2-Aminothiazoles, toward electrophilic reagents, alkylation      80
2-Aminothiazoles, toward electrophilic reagents, coupling with diazonium      76
2-Aminothiazoles, toward electrophilic reagents, general trends      87 88
2-Aminothiazoles, toward electrophilic reagents, halogenation of      77
2-Aminothiazoles, toward electrophilic reagents, nitration of      72
2-Aminothiazoles, toward electrophilic reagents, nitrosation of      74
2-Aminothiazoles, toward electrophilic reagents, sulfonation of      75
2-Aminothiazoles, transition metal complexes of      70
2-Aminothiazoles, with $\beta$-trichloromethyl-$\beta$-propiolactone      55
2-Aminothiazoles, with 1-imino-3-amino-isoindolenine      56
2-Aminothiazoles, with 2-chloronicotinic acid      57
2-Aminothiazoles, with 8-hydroxyquinolme      44
2-Aminothiazoles, with aldehydes      98
2-Aminothiazoles, with aromatic aldehydes      40
2-Aminothiazoles, with benzaldehyde      45
2-Aminothiazoles, with caibonyl derivatives      40
2-Aminothiazoles, with carbon disulfide      60
2-Aminothiazoles, with chloracetyl chloride      33
2-Aminothiazoles, with cyanamide      58
2-Aminothiazoles, with dicyandiamide      57
2-Aminothiazoles, with halocarbonyl derivatives      33
2-Aminothiazoles, with isothiocyanate      61 65 93
2-Aminothiazoles, with oxadiazine      56
2-Aminothiazoles, with picryl halides      56
2-Aminothiazoles, with pyridyl formimidate      55
2-Aminothiazoles, with salicylaldehyde      41
2-Aminothiazoles, with silicon compounds      68
2-Aminothiazoles, with sulfonamido thiazoles      69
2-Aminothiazoles, with terephthaldehyde      41
2-Aminothiazoles, with thiourea      79
2-Aminothiazoles, with trimethyiene tribromide      33
2-Aminothiazoles, with urea      56
2-Aminothiazoles, X-Ray of      29
2-Anilinothiazoles, with acetic anhydride      53
2-Arylsulfenamidothiazoles, rearrangement of      82
2-Benzylthiothiazoles, transformation in, $\Delta$-4-thiazoline-2-thiones      405
2-Bromo-4-aminothiazole derivatives, biological activity of      138
2-Bromo-4-methylthiazole, reaction with, 2-mercaptothiazole      370
2-Bromo-4-methylthiazole, reaction with, hydrogen sulfide      370
2-Bromothiazole, reaction with thiourea      370
2-Bromothiazole, to $\Delta$-4-thiazoline-2-thione      370
2-Chloronicotinic acid, with 2-aminothiazoles      57
2-Chlorothiazole, from $\Delta$-4-thiazoline-2-one and $PCl_5$      401
2-Chlorothiazole, from $\Delta$-4-thiazoline-2-one and HCl      402
2-Chlorothiazole, from $\Delta$-4-thiazoline-2-thione and $Cl_2$      393
2-Chlorothiazole, preparation of, from dithiazolylsulfide (HCl)      405
2-Dimethylamino thiazoliufn salts, hydrolysis      373
2-Disubstituted aminothiazoles      259—267
2-Halogenothiazole, $\Delta$-4-thiazoline-2-thione anion      396 404
2-Halogenothiazole, mercaptan      404
2-Halogenothiazole, metal sulfinate      415
2-Halogenothiazole, reaction with, alcohol      408
2-Halogenothiazolium salts, hydrolysis (of) to $\Delta$-4-thiazoline-one      373
2-Haloimino-4-thiazolines      127
2-Hydrazinothiazoles      99 248—254
2-Hydrazinothiazoles, bromination of      103 106
2-Hydrazinothiazoles, HMO treatment of      100
2-Hydrazinothiazoles, IR spectra of      106
2-Hydrazinothiazoles, organometallics in preparation of      99
2-Hydrazinothiazoles, oxidation of      102
2-Hydrazinothiazoles, reactions with, $\beta$-chloropropionyl chloride      102
2-Hydrazinothiazoles, reactions with, $\beta$-ketoesters      102
2-Hydrazinothiazoles, reactions with, 1,3-diketones      102
2-Hydrazinothiazoles, reactions with, acetic anhydride      101 106
2-Hydrazinothiazoles, reactions with, arylhalides      101
2-Hydrazinothiazoles, reactions with, benzaldehyde      100
2-Hydrazinothiazoles, reactions with, Grignard reagents      100
2-Hydrazinothiazoles, reactions with, hydrazine      106
2-Hydrazinothiazoles, reactions with, isocyanate      100 106
2-Hydrazinothiazoles, reactions with, mercuric oxide      100
2-Hydrazinothiazoles, reactions with, methyl sulfate      106
2-Hydrazinothiazoles, reactions with, nitrous acid      100
2-Hydrazinothiazoles, reactions with, sugar      101
2-Hydrazinothiazoles, reactions with, thiocyanate      100
2-Hydrazinothiazoles, rearrangement of      101 102 104
2-Hydroxythiazole      see $\Delta$-4-Thiazo]ine-2-one
2-Imino-$\Delta$-4-thiazoline, nitroso derivatives      374 375
2-Imino-$\Delta$-4-thiazoline, to $\Delta$-4-thiazoline-2-one      374
2-Imino-4-thiazolyl derivatives, preparation of, from $\Delta$-4-thiazoline-2-one      402
2-Imino-4-thiazolyl derivatives, preparation of, from $\Delta$4-thiazoline-2-thione      398
2-Imino-l,3-oxythiolan derivatives, ring transformation of      374 375
2-Iminothiazole, to $\Delta$-4-thiazoline-2-thione      37
2-Iminothiazolidine-4-one, preparation of      424
2-Iminothiazolium salts, to $\Delta$-4-thiazoline-2-thione      372
2-Lithium thiazolyl, reaction with, disulfides      404
2-lmino-4-thiazolines      274—283
2-lmino-4-thiazolines, acetylation of      124 132
2-lmino-4-thiazolines, alkylation of      129
2-lmino-4-thiazolines, by nitration      74
2-lmino-4-thiazolines, coupling with diazoniums      128
2-lmino-4-thiazolines, dipole moment of      29
2-lmino-4-thiazolines, from aminothiazoles      38 47
2-lmino-4-thiazolines, from aminothiazolium salts      32
2-lmino-4-thiazolines, hydrolysis of      130
2-lmino-4-thiazolines, nitration of      125
2-lmino-4-thiazolines, nitrosation of      125
2-lmino-4-thiazolines, NMR spectra of      25 38 26
2-lmino-4-thiazolines, rearrangement of      130
2-lmino-4-thiazolines, sulfonation of      124
2-lmino-4-thiazolines, synthesis of      122
2-lmino-4-thiazolines, to 1,3,4-oxadiazoles, protomeric studies by IR      24
2-lmino-4-thiazolines, to disulfonamido thiazoles      69
2-lmino-4-thiazolines, to thioureas      125
2-lmino-4-thiazolines, UV spectra of      38
2-lmino-4-thiazolines, versus 2-aminothiazoles identification      35 38
2-lmino-4-thiazolines, with $\beta$-trichloromethyl-$\beta$-propiolactone      55
2-lmino-4-thiazolines, with 2-chlorothiazole      57
2-lmino-4-thiazolines, with carbon disulfide      126
2-lmino-4-thiazolines, with isocyanates      125
2-lmino-4-thiazolines, with isothiocyanates      58 125
2-Meicaptothiazoles in synthesis of 2-aminothiazoles      13
2-Meicaptothiazoles, reaction with hydrazine      99
2-Meicaptothiazoles, reaction with morpholine      13
2-Mercaptothiazole      see $\Delta$-4-Thiazoline-2-thione
2-Methylamino-4-methylthiazole anion, behavior in $Na/NH_3$      398
2-Methylthio-3-methylthiazolium salts, as catalyst for methylthiothiazole rearrangement      406
2-Nitroresorcinol, coupling with      112
2-Propynyl bromide, quaternarization with aminothiazole      32
2-Pyridone, derivatives, from $\Delta$-2-thiazoline-4-one      426—427
2-Substituted aminothiazole      211—212
2-Sulfenamidothiazoles (or 2-sulfenylthia-zoles), rearrangement of      114
2-Sulfenamidothiazoles (or 2-sulfenylthia-zoles), synthesis of      69 113
2-Sulfenyl thiazoles      see Sulfenamidothiazoles
2-Thiazolyl diazonium      109
2-Thiazolyl diazonium by diazotization of aminothiazoles      110
2-Thiazolyl diazonium with potassium ethylxanthate      370
2-Thiazolyl diazonium with potassium thiocyanatc      370 408
2-Thiazolyl diazonium with thiourea      370
2-Thiazolyl diazonium with water      375
2-Thiazolyl diazonium, diazo coupling with      110 112
2-Thiazolyl diazonium, ionic scission of      110
2-Thiazolyl diazonium, radicals from      110
2-Thiazolyl diazonium, reactions      110 111 112
2-Thiazolyl disulfides, physical properties      412
2-Thiazolyl disulfides, table of compounds      468—471
2-Thiazolyl disulfides, uses of      441
2-Thiazolyl dithio carbamates      96
2-Thiazolyl dithio carbamates, synthesis of      60 246
2-Thiazolyl dithiocarbonic acids and esters      246
2-Thiazolyl oxides, nitration      410
2-Thiazolyl oxides, physical properties, mass spectra      409
2-Thiazolyl oxides, physical properties, NMR      409
2-Thiazolyl oxides, physical properties, pKa      409
2-Thiazolyl oxides, physical properties, UV      409
2-Thiazolyl oxides, preparation of, alkylation of $\Delta$-4-thiazoline-2-ones      408
2-Thiazolyl oxides, preparation of, Williamson reactions      408
2-Thiazolyl oxides, reaction with methoxide ion (nucleophilic addition)      410
2-Thiazolyl oxides, rearrangement of, 2-allyloxythiazole      410
2-Thiazolyl oxides, rearrangement of, 2-methoxythiazole      409
2-Thiazolyl oxides, tables of compounds, 4,5-disubstituted derivatives      511—512
2-Thiazolyl oxides, tables of compounds, 4-substituted derivatives      507—508
2-Thiazolyl oxides, tables of compounds, 5-substituted derivatives      509—510
2-Thiazolyl oxides, tables of compounds, unsubstituted derivatives      505—506
2-Thiazolyl oxides, uses of      441
2-Thiazolyl sulfenyl chloride, transformation to, thiazolyl disulfides      412
2-Thiazolyl sulfide, in hydrocarbon synthesis      406
2-Thiazolyl sulfide, oxidation of, with $CrO_2$      415
2-Thiazolyl sulfide, oxidation of, with $H_2O_2$      405 415
2-Thiazolyl sulfide, oxidation of, with $KMnO_4$      415
2-Thiazolyl sulfide, oxidation of, with m-chloroperbenzoic acid      415
2-Thiazolyl sulfide, physical properties, infrared      405
2-Thiazolyl sulfide, physical properties, NMR      404
2-Thiazolyl sulfide, physical properties, pKa      404
2-Thiazolyl sulfide, physical properties, ultraviolet      404
2-Thiazolyl sulfide, preparation of, from $\Delta$-4-thiazoline-2-thione and alcohols      391
2-Thiazolyl sulfide, preparation of, from $\Delta$-4-thiazoline-2-thione and alkenes      392
2-Thiazolyl sulfide, preparation of, from $\Delta$-4-thiazoline-2-thiones and halo-derivatives      391 392 404
2-Thiazolyl sulfide, preparation of, from 2-halothiazoles and mercaptans      403—404
2-Thiazolyl sulfide, preparation of, from 2-lithium thiazolyl and disulfides      404
2-Thiazolyl sulfide, reaction with, haloalkanes (kinetics of)      405
2-Thiazolyl sulfide, rearrangement in N-alkyl-$\Delta$-4-thiazoline-2-thiones      406
2-Thiazolyl sulfide, reduction of, by aluminum mercury amalgam      405
2-Thiazolyl sulfide, reduction of, by zinc powder      405
2-Thiazolyl sulfide, ring opening in $Na/NH_3$      406
2-Thiazolyl sulfide, tables of compounds, 4,5-disubstituted      456—467
2-Thiazolyl sulfide, tables of compounds, 4-substituted      445—449
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