, oxidation by, 2-thiazolylsulfide 415
, 18
, and amino-imino equilibrium 19
, and substituents effects 19 91
, of -2-thiazoline-4-one, from UV experiments, from potentiometry 423
, of -4-thiazoline-one 389
, of 2-methoxy-4-methylthiazole 389
, of 2-methylthiothiazole, in relation with nucleophilicity 405
, of 2-thiazolyl-oxides 409
, of acylaminothiazoles 91
, of azothiazoles 107
, , correlation with sigma values 19
, , representative values 20
, chlorination with 77
mechanism, and halothiazoles 18
, reduction by 16
-Chloracetamide, with acetamidothiazoles 33
-Haloesters, reaction with, -4-thiazolinc-2-thione anion 396
-Naphthol, coupling with 112
-Adrenergic receptor, blocking agents 440 441
-Chloropropionyl chloride, with 2-hydrazinothiazoles 102
-Chloropropionyl chloride, with aminothiazoles 50
-Ketoesters, acylation with 53
-Ketoesters, with hydrazinothiazoles 102
-Naphthol, coupling with 112
-2-Oxazoline-5-one to -2-thiazoline-5-one 429
-2-Oxazoline-5-one, cycloaddition reactivity 436
-2-Oxazoline-5-one, to 5-acetylthiothia-zole 417—418
-2-Thiazoline-4-one, measurement 423
-2-Thiazoline-4-one, measurement, from potentiometry 423
-2-Thiazoline-4-one, measurement, from UV data 423
-2-Thiazoline-4-one, 1,3-dipolar cyclo additions 425 426
-2-Thiazoline-4-one, 1,3-dipolar cyclo additions, with dimethyl acetylene dicarboxylate 426 427
-2-Thiazoline-4-one, 1,3-dipolar cyclo additions, with dimethyl fumarate 425 426
-2-Thiazoline-4-one, 1,3-dipolar cyclo additions, with dimethyl maleate 425 426
-2-Thiazoline-4-one, 2-alkylthio derivatives, hydrolysis 423
-2-Thiazoline-4-one, 2-alkylthio derivatives, reaction with amines 424
-2-Thiazoline-4-one, 2-amino derivatives, reaction with secondary amines 424
-2-Thiazoline-4-one, 2-chloro derivatives, hydrolysis of 423
-2-Thiazoline-4-one, 2-chloro derivatives, reaction with amines 424
-2-Thiazoline-4-one, 2-methyl-5-substituted derivatives, reaction with 425
-2-Thiazoline-4-one, 2-phenyl derivatives, dimers of 420 423
-2-Thiazoline-4-one, 2-phenyl derivatives, structure of 419
-2-Thiazoline-4-one, 5-benzylidene derivatives from 425
-2-Thiazoline-4-one, acylation 423
-2-Thiazoline-4-one, dimerization of 2-phenyl derivatives 423
-2-Thiazoline-4-one, hydrolysis, of 2-alkylthio derivatives 423 424
-2-Thiazoline-4-one, hydrolysis, of 2-chloro derivatives 423 424
-2-Thiazoline-4-one, infrared 422
-2-Thiazoline-4-one, methylation of 423
-2-Thiazoline-4-one, NMR of 422
-2-Thiazoline-4-one, nucleophilic reactivity at C-5, self condensation in relation with 425
-2-Thiazoline-4-one, nucleophilic reactivity at C-5, with aryldiazonium salts 425
-2-Thiazoline-4-one, nucleophilic reactivity at C-5, with arylnitroso derivatives 425
-2-Thiazoline-4-one, nucleophilic reactivity at C-5, with benzaldehyde 425
-2-Thiazoline-4-one, nucleophilic reactivity at C-5, with benzoselenazolium salts 424
-2-Thiazoline-4-one, nucleophilic reactivity at C-5, with benzothiazolium salts 424
-2-Thiazoline-4-one, nucleophilic reactivity of oxygen 423 424
-2-Thiazoline-4-one, preparation of, from 4-aminothiazole 421
-2-Thiazoline-4-one, preparation of, general 419 426
-2-Thiazoline-4-one, protomeric equilibrium 421
-2-Thiazoline-4-one, protomeric equilibrium, infrared study of 421
-2-Thiazoline-4-one, protomeric equilibrium, NMR study of 421
-2-Thiazoline-4-one, protomeric equilibrium, solvent effect on 422
-2-Thiazoline-4-one, stability of 420 421
-2-Thiazoline-4-one, syntheses, 2-alkylthio derivatives 419
-2-Thiazoline-4-one, syntheses, 2-aryl-derivatives 419 420
-2-Thiazoline-4-one, syntheses, 2-arylthio derivatives 419
-2-Thiazoline-4-one, table of compounds 531—535
-2-Thiazoline-4-one, to 2,4-thiazolinediones 423 424
-2-Thiazoline-4-one, ultraviolet 422
-2-Thiazoline-4-thione 416
-2-Thiazoline-5-one, 2-benzylthio(oxo)-deiivatives, ring opening of 433 434
-2-Thiazoline-5-one, 2-phenyl-4-substituted derivatives, ring opening 433
-2-Thiazoline-5-one, 4-phenylazo derivatives, rearrangement in thiazoline 435
-2-Thiazoline-5-one, 4-phenylazo derivatives, ring opening 434
-2-Thiazoline-5-one, chloration of 432
-2-Thiazoline-5-one, cycloadditions reactions with, alkenes 436
-2-Thiazoline-5-one, cycloadditions reactions with, alkynes 436
-2-Thiazoline-5-one, dimerization catalyzed by 432
-2-Thiazoline-5-one, enolisation with NaH 431
-2-Thiazoline-5-one, infrared data 430
-2-Thiazoline-5-one, mesoionic protomeric form 430
-2-Thiazoline-5-one, Michael addition of, 4-phenyl-1,2,4-triazolin-3,5-dione 433
-2-Thiazoline-5-one, Michael addition of, diethylazodicarboxylate 433
-2-Thiazoline-5-one, Michael addition of, maleic anhydride 433
-2-Thiazoline-5-one, NMR data 430
-2-Thiazoline-5-one, optically active 427
-2-Thiazoline-5-one, preparation of 426 427
-2-Thiazoline-5-one, preparation of, from -2-oxazoline-5-one 429
-2-Thiazoline-5-one, preparation of, from 4-alkylidene or 4-arylidene -2-thiazoline-5-one 427 428
-2-Thiazoline-5-one, preparation of, from 5-alkoxythiazole 430
-2-Thiazoline-5-one, preparation of, from N-thioacyl derivatives of amino acids 426
-2-Thiazoline-5-one, preparation of, optically active 427
-2-Thiazoline-5-one, protomeric equilibrium of, infrared 430
-2-Thiazoline-5-one, protomeric equilibrium of, NMR 430
-2-Thiazoline-5-one, protomeric equilibrium of, solvent effect on 430
-2-Thiazoline-5-one, protomeric equilibrium of, substituent effect on 431
-2-Thiazoline-5-one, protomeric equilibrium of, UV 430 431
-2-Thiazoline-5-one, reaction with, acetyl chloride 431
-2-Thiazoline-5-one, reaction with, aldehyde 432
-2-Thiazoline-5-one, reaction with, benzoyl chloride 431
-2-Thiazoline-5-one, reaction with, carbamoyl chloride 431
-2-Thiazoline-5-one, reaction with, enamines 432 433
-2-Thiazoline-5-one, reaction with, isocyanate 431
-2-Thiazoline-5-one, reaction with, ketone 432
-2-Thiazoline-5-one, reaction with, thioacetic acid 417 418
-2-Thiazoline-5-one, ring opening, 2-benzylthio(oxo)derivatives with, 434
-2-Thiazoline-5-one, ring opening, 2-benzylthio(oxo)derivatives with, amines 433
-2-Thiazoline-5-one, ring opening, 2-phenyl-4-substituted derivatives with, amino acids 433
-2-Thiazoline-5-one, ring opening, 2-phenyl-4-substituted derivatives with, hydrazine 433
-2-Thiazoline-5-one, ring opening, 2-phenyl-4-substituted derivatives with, peptides 433
-2-Thiazoline-5-one, ring opening, 4-phenylazo derivatives with amines 434
-2-Thiazoline-5-one, tables of compounds 526 527
-2-Thiazoline-5-one, transformation in triazoline derivatives 435
-2-Thiazoline-5-one, UV data 431
-2-Thiazoline-5-thione, alkylation of, reaction with unsaturated compounds 417
-2-Thiazoline-5-thione, preparation of, from 5-acetylthiothiazole 416
-2-Thiazoline-5-thione, preparation of, from 5-thiocyanato thiazoles 416
-2-Thiazoline-5-thione, preparation of, general 416
-2-Thiazoline-5-thione, table of compounds 493—496
-2-Thiazoline-5-thione, tautomerism of 417
-3-Thiazoline 86 87
-4-Imidazoline-2-thione (diMel-3),methylation of 391
-4-thiazoline-2-one 402
-4-Thiazoline-2-one by hydrolysis 130
-4-Thiazoline-2-one in bacterial culture medium 390
-4-Thiazoline-2-one, 389
-4-Thiazoline-2-one, acylation of 402
-4-Thiazoline-2-one, ambident anion, behavior in 398
-4-Thiazoline-2-one, ambidentreactivity 401
-4-Thiazoline-2-one, charge diagram, from HMO method 390
-4-Thiazoline-2-one, charge diagram, from PPP method 389 390
-4-Thiazoline-2-one, chlorination of 402
-4-Thiazoline-2-one, dimerization of 403
-4-Thiazoline-2-one, dipole moment, in relation with protomerism 389
-4-Thiazoline-2-one, electrophilic reactivity, in relation with PPP calculations 390
-4-Thiazoline-2-one, Friedel — Crafts reactions of 402
-4-Thiazoline-2-one, Gattermann reaction on 402
-4-Thiazoline-2-one, hydrolysis of 401
-4-Thiazoline-2-one, infrared, in relation with protomerism 387
-4-Thiazoline-2-one, infrared, in relation with self association 389 390
-4-Thiazoline-2-one, infrared, representative data 390
-4-Thiazoline-2-one, iodination 402
-4-Thiazoline-2-one, Mannich reaction of 403
-4-Thiazoline-2-one, nitration of, kinetic of 402 403
-4-Thiazoline-2-one, nitration of, kinetic of, conformational analysis by 390
-4-Thiazoline-2-one, nitration of, kinetic of, in relation with protomerism 387
-4-Thiazoline-2-one, nitration of, kinetic of, representative data 390 385
-4-Thiazoline-2-one, preparation of 372—377
| -4-Thiazoline-2-one, preparation of, by oxidation of -4-thiazoline-2-thione 374 397
-4-Thiazoline-2-one, preparation of, from 2-biomo thiazolium salts 373
-4-Thiazoline-2-one, preparation of, from 2-dim ethylamino thiazolium salts 373
-4-Thiazoline-2-one, preparation of, from 2-imino--4-thiazoline 374
-4-Thiazoline-2-one, preparation of, from 2-thiazole sulfonic acid 375
-4-Thiazoline-2-one, preparation of, from 2-thiazolyldiazonium salts 375
-4-Thiazoline-2-one, preparation of, from 2-unsubstituted thiazolium salts 375
-4-Thiazoline-2-one, preparation of, from thiazolyl-2-oxide 409 410
-4-Thiazoline-2-one, protomeric equilibrium, dipole moment studies 389
-4-Thiazoline-2-one, protomeric equilibrium, general 377
-4-Thiazoline-2-one, protomeric equilibrium, infrared studies 387
-4-Thiazoline-2-one, protomeric equilibrium, relation with self association 389
-4-Thiazoline-2-one, protomeric equilibrium, solvent effect on 389
-4-Thiazoline-2-one, protomeric equilibrium, ultraviolet studies 387
-4-Thiazoline-2-one, reaction with, alkylating agents 401
-4-Thiazoline-2-one, reaction with, chlorodiethylphosphate 401
-4-Thiazoline-2-one, reaction with, chlorodiethylthiophosphate 401
-4-Thiazoline-2-one, reaction with, diazonium salts 403
-4-Thiazoline-2-one, reaction with, hydrazine 402
-4-Thiazoline-2-one, reaction with, phosphorus chloride 401
-4-Thiazoline-2-one, reaction with, phosphorus pentasulfide 373
-4-Thiazoline-2-one, reaction with, phosphoryl chloride 401
-4-Thiazoline-2-one, reaction with, sulfenyl chloride 403 418
-4-Thiazoline-2-one, reduction of, with zinc dust 402
-4-Thiazoline-2-one, Reimer — Tiemann reaction on 402
-4-Thiazoline-2-one, sel association, in relation with protomerism 377
-4-Thiazoline-2-one, sulfonation of 402
-4-Thiazoline-2-one, tables of compounds, 3,4,5-trisubstituted 520—523
-4-Thiazoline-2-one, tables of compounds, 3,4-disubstituted 519
-4-Thiazoline-2-one, tables of compounds, 3,5-disubstituted 520
-4-Thiazoline-2-one, tables of compounds, 3-pyrimidinylmethyl derivatives 523 524
-4-Thiazoline-2-one, tables of compounds, 3-substituted 518
-4-Thiazoline-2-one, tables of compounds, 4,5-disubstituted 515—518
-4-Thiazoline-2-one, tables of compounds, 4-substituted 513 514
-4-Thiazoline-2-one, tables of compounds, 5-substituted 513
-4-Thiazoline-2-one, tables of compounds, miscellaneous 524 525
-4-Thiazoline-2-one, to 2-imino-4-thiazolines 123
-4-Thiazoline-2-one, transformation in, 2-chlorothiazole 402
-4-Thiazoline-2-one, transformation in, 2-chlorothiazole, thiochrome 402
-4-Thiazoline-2-one, transformation in, 2-chlorotliiazoles 401
-4-Thiazoline-2-one, transformation in, 2-chlorotliiazoles, 2-thiazolyloxides 401
-4-Thiazoline-2-one, transformation in, 2-chlorotliiazoles, 2-unsubstituted thiazoles 402
-4-Thiazoline-2-one, transformation in, 2-chlorotliiazoles, N-substituted derivatives 401
-4-Thiazoline-2-one, ultraviolet, in relation with protomerism 387
-4-Thiazoline-2-one, ultraviolet, representative data 389
-4-Thiazoline-2-one, uses 438
-4-Thiazoline-2-selenone, photographic processes 370
-4-Thiazoline-2-selenone, properties of 370
-4-Thiazoline-2-selenone, silver halide emulsion 370
-4-Thiazoline-2-selenone, table of compounds 536
-4-Thiazoline-2-thione 123
-4-Thiazoline-2-thione, ambident anion of, charge diagram from PPP calculation 390
-4-Thiazoline-2-thione, ambident anion of, reactivity 394
-4-Thiazoline-2-thione, ambident anion of, reactivity, in Mannich reaction 394
-4-Thiazoline-2-thione, ambident anion of, reactivity, steric effect on 394
-4-Thiazoline-2-thione, ambident anion of, reactivity, with -haloesters 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with -dimethylaminomethyl chloride 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with 1,4-dichloro-2-butene 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with 1,4-dichloro-2-butyne 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with 2-chloro-propionitrile 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with acrylonitrile 394
-4-Thiazoline-2-thione, ambident anion of, reactivity, with acyl chlorides 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with alkyl halides 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with aryl halides 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with cyanuric chloride 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with halogenothiazoles 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with lactones 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with methylvinylketone 394
-4-Thiazoline-2-thione, ambident anion of, reactivity, with N,N-dimethylthiocarbamoyl chloride 396
-4-Thiazoline-2-thione, ambident anion of, reactivity, with tetra-O-acetyl-D-glucopyranosyl bromide 394
-4-Thiazoline-2-thione, ambident anion of, reductive ring opening in 397
-4-Thiazoline-2-thione, aryl derivatives, by isomerization reactions 373
-4-Thiazoline-2-thione, charge diagrams, CNDO 385
-4-Thiazoline-2-thione, charge diagrams, PPP 385 389
-4-Thiazoline-2-thione, circular dichroism 380
-4-Thiazoline-2-thione, CNDO calculations 380 385 389
-4-Thiazoline-2-thione, complexes with, 396
-4-Thiazoline-2-thione, complexes with, Ag 386
-4-Thiazoline-2-thione, complexes with, Cd 412
-4-Thiazoline-2-thione, complexes with, Cu 412 386
-4-Thiazoline-2-thione, complexes with, Mg 412
-4-Thiazoline-2-thione, complexes with, Ni, Co 412
-4-Thiazoline-2-thione, complexes with, Pb 412
-4-Thiazoline-2-thione, complexes with, transition metals 386
-4-Thiazoline-2-thione, complexes with, Zn 412
-4-Thiazoline-2-thione, conformational analysis of alkyl substituents 385
-4-Thiazoline-2-thione, desulfurization 393 397 399
-4-Thiazoline-2-thione, dipole moment, in relation with protomerism merism 379
-4-Thiazoline-2-thione, dynamic NMR 384—385
-4-Thiazoline-2-thione, from 2-immo-4-thiazolihes 126
-4-Thiazoline-2-thione, hetero-association of, with 4-chlorophenol 377
-4-Thiazoline-2-thione, hetero-association of, with DMSO 377
-4-Thiazoline-2-thione, infrared spectra 381
-4-Thiazoline-2-thione, metal salts, asgennidices 412
-4-Thiazoline-2-thione, metal salts, in analysis 412
-4-Thiazoline-2-thione, metal salts, in photographic processes 412
-4-Thiazoline-2-thione, metal salts, in rubber industry 412
-4-Thiazoline-2-thione, NMR, data 384 385 388
-4-Thiazoline-2-thione, NMR, barrier to rotation of alkyl substituent 384 385
-4-Thiazoline-2-thione, NMR, representative data 384
-4-Thiazoline-2-thione, oxidation of, with 393
-4-Thiazoline-2-thione, oxidation of, with ammonium persulfate 394 397
-4-Thiazoline-2-thione, oxidation of, with hydrogen peroxide 374 383 397
-4-Thiazoline-2-thione, oxidation of, with iodine 393
-4-Thiazoline-2-thione, oxidation of, with mercuric acetate 374
-4-Thiazoline-2-thione, oxidation of, with NaOCl in presence of amine 411
-4-Thiazoline-2-thione, oxidation of, with nitric acid andsodium nitrite 393
-4-Thiazoline-2-thione, photoelectron spectra 381
-4-Thiazoline-2-thione, PPP calculations 380 385 389
-4-Thiazoline-2-thione, preparation of, by isomcrization of 5-methylenethiazoli-dine-2-thione 372 373
-4-Thiazoline-2-thione, preparation of, by rearrangement of thiazolyl-2-thioethers 406
-4-Thiazoline-2-thione, preparation of, from -4-thiazoline-2-one and 373
-4-Thiazoline-2-thione, preparation of, from 1,3,4-thiadiazole-2-thione and alkyne 372
-4-Thiazoline-2-thione, preparation of, from 1,3-dithiolane and alkyne 372
-4-Thiazoline-2-thione, preparation of, from 1,3-dithiole-2-thione and amine 372
-4-Thiazoline-2-thione, preparation of, from 2-aminothiazole 370
-4-Thiazoline-2-thione, preparation of, from 2-benzylthiothiazolcs 405
-4-Thiazoline-2-thione, preparation of, from 2-bromothiazole and thiourea 370
-4-Thiazoline-2-thione, preparation of, from 2-iminothiazole and 371
-4-Thiazoline-2-thione, preparation of, from 2-iminothiazolium salts and 371
-4-Thiazoline-2-thione, preparation of, from 2-thiazolyldiazonium salts and potassium -4-Thiazoline-2-thione, preparation of, ethylxanthate or thiourea 370
-4-Thiazoline-2-thione, preparation of, from 2-thiocyanothiazole 370
-4-Thiazoline-2-thione, preparation of, from 2-unsubstituted thiazoliumsalts 375
-4-Thiazoline-2-thione, preparation of, from deoxybenzom and 373
-4-Thiazoline-2-thione, preparation of, from dithiazolylsulfidehydrochloride 405
-4-Thiazoline-2-thione, preparation of, from thiazolyl-2-disulfides 412
-4-Thiazoline-2-thione, preparation of, propargyl amine and 372
-4-Thiazoline-2-thione, protomeric equilibrium, general 377
-4-Thiazoline-2-thione, protomerism, IR studies of 378
-4-Thiazoline-2-thione, protomerism, RMN studies of 379
-4-Thiazoline-2-thione, protomerism, solvent effect on 379
-4-Thiazoline-2-thione, protomerism, ultraviolet studies 378
-4-Thiazoline-2-thione, Raman spectra 381
-4-Thiazoline-2-thione, reaction with, alkylation agents, quantitative aspects, alcohols in -4-Thiazoline-2-thione, reaction with, alkylation agents, quantitative aspects, acidic medium 392
-4-Thiazoline-2-thione, reaction with, alkylation agents, quantitative aspects, alkenes 392
-4-Thiazoline-2-thione, reaction with, alkylation agents, quantitative aspects, alkyl halides 391
-4-Thiazoline-2-thione, reaction with, alkylation agents, quantitative aspects, dihalogenoalkanes 391. See also Nucleophilic substitution
-4-Thiazoline-2-thione, reaction with, mercury complexes 394
-4-Thiazoline-2-thione, reaction with, mercury complexes, tin complexes 394
-4-Thiazoline-2-thione, reactivity of, thiocarbonyl nudeophilicity 384 391—393
-4-Thiazoline-2-thione, rearrangement of 3-ammomethyl derivatives 400
-4-Thiazoline-2-thione, table of compounds, 3,4,5-trisubstituted 486—491
-4-Thiazoline-2-thione, table of compounds, 3,4-disubstituted 480—484
-4-Thiazoline-2-thione, table of compounds, 3,5-disubstituted 485
-4-Thiazoline-2-thione, table of compounds, 3-pyrimidinylmethyl derivatives 492
-4-Thiazoline-2-thione, table of compounds, 3-substituted 479 480
-4-Thiazoline-2-thione, table of compounds, 4,5-disubstituted 477—479
-4-Thiazoline-2-thione, table of compounds, 4-substituted 474 475
-4-Thiazoline-2-thione, table of compounds, 5-substituted 476
-4-Thiazoline-2-thione, thin-layer chromatography 385
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