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Metzger J.V. — Thiazole and Its derivatives (Part 2)
Metzger J.V. — Thiazole and Its derivatives (Part 2)



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Название: Thiazole and Its derivatives (Part 2)

Автор: Metzger J.V.

Аннотация:

General introduction to protomeric thiazoles; aminothiazoles and their derivatives; and mercaptothiazoles, hydroxythiazoles, and their derivatives


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1979

Количество страниц: 590

Добавлена в каталог: 21.09.2006

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Hydrogen sulfide, with 2-bromo-4-methylthiazole      370
Hydrogen sulfide, with 2-iminothiazolium salts      371
Hydrogen sulfide, with 2-thiazolylcyanamides      94
Hydrogenation, with Ni catalyst      116
Hydrolysis, acidic conditions      92 99
Hydrolysis, of 2-dimethylaminothiazolium salts      373
Hydrolysis, of 2-halogenothiazolium salts      373
Hydrolysis, of 2-imino-$\Delta$-4-thiazoline      374
Hydrolysis, of 2-thiazolylcyanamide      92
Hydrolysis, of 3-methyl-$\Delta$-4-thiazoline-2-one      401
Hydrolysis, of 5-thiazolylthiouronium salts      516
Hydrolysis, of thiazolium salts      85
Hydrolysis, of thiazolylamidines      99
Hydrolysis, to sulfathiazoles      315
Hydroxyethylamine, with 2-chlorothiazole      34
Hydroxylamme      426
Hypnotic properties      138
Hypocholesterolemic      438
Hypoglycemic      440
Hypohalous acids      127
Hypotensive agent      146 147 149 153
Ignition      170
Imidazole, $PPh_3$ mixture      90
Imidazole, biheterocycle derivative      99
Imino-amino equilibrium      see amino-imino
Indazole derivatives, by cyclization      47
Indicators      156—168
Indium complexes      157 158 160
Indolyl derivatives, with aminothiazoles      48
Infrared spectroscopy      23
Infrared spectroscopy and deuterated aminothiazoles      23
Infrared spectroscopy and dichroism      23
Infrared spectroscopy and Hammett constants      24
Infrared spectroscopy and isotopic substitution      23
Infrared spectroscopy and protomeric equilibria      23
Infrared spectroscopy and vibration-rotation bands      23
Infrared spectroscopy of $\Delta$-2-thiazoline-4-ones, in relation with protomerism      422
Infrared spectroscopy of $\Delta$-4-thiazoline-2-one, in relation with protomerism      387
Infrared spectroscopy of $\Delta$-4-thiazoline-2-one, in relation with self-association      390
Infrared spectroscopy of $\Delta$-4-thiazoline-2-one, representative data      390
Infrared spectroscopy of $\Delta$-4-thiazoline-2-thione      381
Infrared spectroscopy of 2-thiazolylsulfide      409
Infrared spectroscopy of 2-thiazolylsulfones      415
Infrared spectroscopy of 5-thiazolylsulfone      415
Infrared spectroscopy of azothiazoles      107
Infrared spectroscopy of complexes      104 120
Infrared spectroscopy of hydrazinothiazoles      105
Infrared spectroscopy of Schiff bases      41 99
Infrared spectroscopy of sulfonamidothiazoles      116
Infrared spectroscopy of sulfonylthiazoles      75
Infrared spectroscopy of thiazolyl thiourea      94 96
Infrared spectroscopy of thiazolylcarbamates      97
Infrared spectroscopy of thiazolylureas      93
Infrared spectroscopy, assignments in N-N-dialkylaminothiazoles      23
Infrared spectroscopy, frequencies and assignments      24
Infrared spectroscopy, protomerism studies      379
Inhibition of phosphatase      152
Insecticides      133 134 136 137 152 441 442
Intermediates in acylation reactions      47
Intermediates in acylation reactions in diazonium coupling      77
Intermediates in acylation reactions in mercuration      81
Intermediates in acylation reactions in N-oxides reactions      119
Intermediates in acylation reactions, carbinolamine as      41
Intermediates in acylation reactions, enamine-like      85
Intermediates in acylation reactions, formaldehyde Mannich base as      44
Intermediates in acylation reactions, hetaryne as      67
Intermediates in acylation reactions, nitramino      73
Intermediates in acylation reactions, open-chain      50 91
Intermediates in acylation reactions, perbromides      77
Intermediates in acylation reactions, tetrahedral      57. See also Amide ions; Anions; Carboca-tions; and Radical intermediates
Intestinal antiseptic      152
Intramolecular reactivity      see Heterocyclizatione
Iodide      121
Iodine, as catalyst of rearrangement      406
Iodmation      77
Iodmation of $\Delta$-4-thiazoline-2-one      402
Ion pair mechanism, in reaction of benzene-thiolate with 2-halothiazole      404
Ion pairs, in ambident reactivity      40
Ionization potential, relation with nucleo-philic reactivity of $\Delta$-4-thiazoline-2-thione      384
Iron      153
Iron, complexes      104 108 120 122
Iron, metabolism      152
Iron, reduction by      16 116
Isoamyl nitrite, in diazotizations      67
Isocyanate, Me      431
Isocyanate, phenyl      431
Isocyanates      58
Isocyanates to mesoionic compounds      65
Isocyanates to thiazolyl urea      58 92
Isocyanates with 2-imino-4-thiazolines      125
Isocyanates with hydrazinothiazoles      100 106
Isocyanates, acyl isocyanates      92
Isocyanates, alkyl isocyanates      92 118
Isocyanates, aryl versus alkyl      118
Isoindolenine derivative      56
Isomerism, E-Z equilibrium      23
Isomerization, catalyst in $\alpha, \beta$-unsaturated acids      438
Isopropanol, with aminothiazoles      47
Isothiocyanates with 2-aminothiazoles      65
Isothiocyanates with azirines      15
Isothiocyanates with sulfathiazole      117
Isothiouronium salt      95
Isotopic labeling      370 410
Isotopic labeling and rearrangement      113
Isotopic labeling, $O^{18}$ in firefly luciferin      421
Ketone, reactions with, $\Delta$-2-thiazoline-5-ones      432
Kinetic studies of ambident reactivities      63
Kinetic studies of Claisen rearrangement in 2-allyloxy-thiazole      410
Kinetic studies of nucleophilic attack      18
Kinetic studies, N-alkylation in 2-thiazolyl-thioethers      405
Kinetic studies, nitration of $\Delta$-thiazoline-2-one      403
Kinetic studies, of rearrangement      73 113
Kinetic studies, reaction of 2-halothiazoles, with alcohols      408—409
Kinetic studies, reaction of 2-halothiazoles, with mercaptans      405
Kinetic studies, S-alkylation in $\Delta$-4-thiazoline-2-thione      384 391 392
Labeled compounds, $D_3$-$\Delta$-4-thiazoline-2-thione, IR, Raman spectra      381
Lactames, reaction with, $\Delta$-4-thiazoline-2-thione anion      396
Lead acetate      96
Lead dioxide, desulfurization with      98
Lead dioxide, oxidation by      45
Lead dioxide, radical with      101
Lead solutions      158
Leather      164
Leaving groups and diazonium salts      110
Leaving groups and sulfathiazole      117
Leaving groups, in acylations      47
Lettuces      136
Leucobase, oxidation of      45
Ligand in octahedral complex      108
Ligand, acetamidothiazoles as      70 120
Ligand, field effect      120 122
Linear free energy relationships      138
Lithium aluminum hydride, in reduction of Schiff bases      14
Lithium aluminum hydride, in reduction of thiazolines      127
Lithography printing plates      438
lminium salts, action of ammonia on      14
lsothiocyanates      58
lsothiocyanates with 2-aminobenzothiazoles      59
lsothiocyanates with 2-imino-4-thiazolines      58 125
m-Chloroperbenzoic acid, oxidation with      415
Magnesium sulfate      117
Magnetic moments      120
Magnetic susceptibilities, of 2-aminothiazole      29
Magnetic susceptibilities, of 2-imino-4-thiazolines      29
Magnetic susceptibilities, of Schiff bases      99
Maleic acid      40
Maleic anhydride      433
Malonic esters, acylation with      55
Malonyl chloride, acylation with      49
Mannich base as intermediate      44 91
Mannich reaction      44
Mannich reaction of $\Delta$-4-thiazoline-2-ones      403
Mannich reaction of $\Delta$-4-thiazoline-2-thiones      394
Mass spectra      27
Mass spectra of 2-aminothiazoles      27
Mass spectra of 2-cyclohexyldithiomethylthiazoles, in relation with vulcanization activity      412
Mass spectra of 2-hydrazinothiazoles      105
Mass spectra of acylaminothiazoles      91
Mass spectra of deuteroaminothiazoles      27
Mass spectra of Schiff bases      99
Mass spectra of thiazolyl-2-oxides      409
Mass spectra of thiazolylthioureas      94
Mass spectra, analogy with photochemistry      27
Mechanism, of electrophilic reactions      71 87 88
Mechanism, of halogenations      78
Mechanism, of Hantzsch reaction      122
Mechanism, of nitration      85
Mechanism, of nitrosation reactions      68
Mechanism, of rearrangement      73 82 83 95 113 130
Mechanism, of reduction      86 87
Mechanism, of retro-Hantzsch      84 102
Mercaptans, reaction with, 2-halothiazolcs      404
Mercaptans, reaction with, 5-bromothiazoles      418
Mercuration      81 129
Mercuric acetate      82 129
Mercuric acetate, reaction with $\Delta$-4-thiazoline-2-thione      374
Mercuric bromide, complexes with $\Delta$-4-thiazoline-2-thione      396
Mercuric halides      108
Mercuric oxide, with hydrazinothiazoles      100
Mercury      157 158 160
Mercury, complexes of      70 98 104 122
Mercury, complexes of, reaction with $\Delta$-4-thiazoline-2-thiones      394
Mesoionic hydroxythiazole, rearrangement of      375
Mesoionic protomer, in $\Delta$-2-thiazoline-4-one      422
Mesoionic xanthine, from alkylamino-thiazole      55 60 65
Metabolite, from 2-aminothiazole      42
Metabolite, in urine      85
Metabolite, radiolabeled      138
Metal complexes      154
Methoxy-4-methykhiazole, pKa in relation with protomerism      389
Methyl chloroformate      130
Methyl iodide, reactions with dialkyl-amino-thiazoles      32. See also Alkylation
Methylarmne      98
Methylarmne from 3-methyl-$\Delta$-4-thiazoline-2-one hydrolysis      401
Methylation, of sulfathiazole      37. See also Alkylation
Methylvinylketone, reaction of, with ambident anion of $\Delta$-4-thiazoline-2-thione      394
Michael addition, on $\Delta$-2-thiazoline-5-one, 4-phenyl-1,2,4-triazolin-3,5-dione      433
Michael addition, on $\Delta$-2-thiazoline-5-one, with diethylazodicarboxylate      433
Michael addition, on $\Delta$-2-thiazoline-5-one, with maleic anhydride      433
Microreversibility principle      85
Miticide      440
Mitodepressive      149 150
Mn complexes      104
Moessbauer studies      122
Molecular orbital calculations      17
Molecular orbital calculations and ambident reactivity      61 62
Molecular orbital calculations and amino-imino equilibrium      18
Molecular orbital calculations and electrophilic substitution      18
Molecular orbital calculations and HSAB      18
Molecular orbital calculations and nucleophilic substitution      18
Molybden complexes      98 155 158
Monoelectron transfer      409
Morphine tolerance inhibition      138
Muscle relaxant      150
Mutagenetic activity      153
Mycardiol $\beta$-stimulant      441
N,N-Dimethylthiocarbamoylchloride, reaction with, $\Delta$-4-thiazoline-2-thione anion      396
N-bromosuccinimide, bromination with      77
Naphthalene, polarographic behavior      107
Narcotic      146
Nematocide      136 440
Neoplasm inhibitor      148
Nervous system action      138
Nickel      153 155 156 157 161
Nickel, catalyst      116
Nickel, complexes of      70 99 104 108 120
Niobium complexes      158
Niridazole      138
Nitraminothiazoles      112 113
Nitraminothiazoles by nitration      72 112
Nitraminothiazoles with diazomethane      37 112
Nitraminothiazoles, alkylation of      112
Nitraminothiazoles, nitration of      74
Nitraminothiazoles, rearrangement of      73 83 113
Nitrate anion      121
Nitration      72—75
Nitration in pyridine series      72
Nitration of $\Delta$-4-thiazoline-2-one, kinetic investigations      402—403
Nitration of 2-azidothiazoles      113
Nitration of 2-imino-4-thiazolines      125
Nitration of 2-thiazolyloxide (kinetics)      410
Nitration of 2-thiazolylsulfone      415
Nitration of 5;thiazolyloxide      436
Nitration of ammothiazoles      72
Nitration of heterocyclic molecules      71
Nitration, mechanism of      85
Nitric acid, in diazotation      65
Nitric acid, in nitration      72
Nitric acid, in nitrosation      65
Nitric acid, in oxidation      102 103
Nitrification inhibition      133 138
Nitro group, activation by      12
Nitro group, desactivation in diazotization      67
Nitro group, in antibacterial properties      136
Nitro group, in antiparasitic properties      136
Nitro group, reduction of      115
Nitrometry      116
Nitrosation      72—75
Nitrosation and diazotization      65 67
Nitrosation of 2-imino-4-thiazolines      125
Nitrosation of secondary amines      68
Nitrosation, mechanism of      68
Nitrosoimino-4-thiazoline      126
Nitrosulfonamides, oxidation of      115
Nitrous acid, with 2-hydrazinothiazoles      100
Nucleophilic additions, to double bonds      40
Nucleophilic substitution      417
Nucleophilic substitution and molecular orbital calculations      18
Nucleophilic substitution at oxygen in $\Delta$-2-thiazoline-4-one      423 424
Nucleophilic substitution by oxygen in $\Delta$-2-thiazoline-5-one, with acetyl chloride      43
Nucleophilic substitution by oxygen in $\Delta$-2-thiazoline-5-one, with benzoyl chloride      43
Nucleophilic substitution by oxygen in $\Delta$-2-thiazoline-5-one, with carbamoyl chloride      43
Nucleophilic substitution by oxygen in $\Delta$-2-thiazoline-5-one, with isocyanate      43
Nucleophilic substitution on alcohol generated carbocations      39
Nucleophilic substitution on copper complex      12
Nucleophilic substitution on thiazolium salts      84
Nucleophilic substitution, activation by amino group of      18
Nucleophilic substitution, kinetic studies of      18
Nucleophilic substitution, nitrogen nucleophilicity in 2-thiazolyl-thioethers, kinetics      405
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, preparative aspects      see Alkylation
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, quantitative aspects, Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, rate constants of      391
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, relation with ionization potential      384
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, solvent effect on diazomethane reaction      395
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, steric effect on      391 392
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, substituent effect on      391 392
Nucleophilic substitution, sulfur nucleophilicity in $\Delta$-4-thiazoline-2-thione, transition state of      391 392
Nylon      163
Octahedral stereochemistry      120
Oleum, in nitration      72
Oleum, in sulfonation      75 113
Open-chain intermediates      91 102
Optical activity, in $\Delta$-2-thiazoline-5-one      427
Optical activity, in 2-aminothiazole derivatives      71
Oral bactericid      148
Oral schistosomicidel      140
Organometallics, in preparation of 2-hydrazinothiazoles      99
Osazones      100
Oscillopolography      116
Ouinazoline derivatives      123
Oxadiazole derivatives      1 32
1 2 3 4 5 6 7 8 9
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