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                    | Bell S. — Forensic Chemistry | 
                  
                
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                    | Ïðåäìåòíûé óêàçàòåëü | 
                  
                
                    
                          (lorazepam)      378  
  (flurazepam)      378  
 -Tetrahydrocannabinol, structure of      303t  
 -Tetrahydrocannabinol, structure of      303t  
 -Tetrahydrocannabinolic acid, structure of      303t  
       259 260f  
  (acid reaction)      89  
 , (base reaction)      89  
  (octanol-water partition coefficient)      92—95  
  (dissolution reaction)      89  
       259 260f  
% error, definition of      20—22  
1, 3, 5-Triamino—2, 4, 6-trinitrobenzene, structure and detonation speed of      417t  
1-(1-Phenylcyclohexyl)ethylamine (PCE), structure of      376t  
1-(1-Phenylcyclohexyl)pyrrolidine (PHP), structure of      376t  
1-Phenylcyclohexalamine, structure of      375t  
1-Piperidinocyclohexane carbonitrile (PCC), structure of      375t  
2, 4, 6-Trinitrotoluene (TNT), function and formula of      449t  
2, 4, 6-Trinitrotoluene, structure and detonation speed of      415t  
2-Nitrodiphenlyamine, function and formula of      450t  
2-Propanol, characteristics of      100t  
3, 4, 5-Trimethoxyphenethylamine, structure of      348t  
3, 4-Methylenedioxyamphetamine, structure of      359t  
3, 4-Methylenedioxyethylamphetamine, structure of      359t  
3, 4-Methylenedioxymethamphetamine, structure of      359t  
4-Nitrodiphenylamine, function and formula of      450t  
6-O-Monoacetylmorphine (6-MAM), formation of      334 336f  
6-O-Monoacetylmorphine (6-MAM), structure of      330t  
95% confidence interval, definition of      26  
AAFS (American Academy of Forensic Sciences)      11  
AAS (atomic absorption spectrometry)      173—178  
ABC (American Board of Criminalistics)      11  
ABFT (American Board of Forensic Toxicology)      11  
Absolute error, definition of      20  
Absolute uncertainty      16  
Absorbance, spectroscopy and      154 155f  
Absorption      247—249 249f  
Accelerants, in arson and fire investigation      433—434  
Accreditation, of laboratory      69  
Accuracy, definition of      65  
Acetaminophen, structure of      315f  
Acetate fibers, description of      576t  
Acetic anhydride, formation of      334 334f  
Acetone, characteristics of      100t  
Acetonitrile, characteristics of      100t  
Acetylcodeine, structure of      330t  
Acetylsalicylic acid, structure of      315f  
Achromatic color      273  
Acid-base-neutral extractions      104—106 105f 106f  
Acidic drugs, forensic drug analysis of      296—315  
acids      267 268f  
Acrylic fibers, description of      576t  
ACS (American Chemical Society)      11  
Active headspace methods, of partitioning      107  
Addiction, physical      223  
Addition polymers      548 548f  
Additive color systems      473—474 474f  
Adhesives, forensic analysis of      609—611 610b 611f  
Adiabatic combustion      392  
Adulterants in profiling      236 238—239  
Adulterants, definition of      228  
Adversarial system      3 4f  
AES (atomic emission spectroscopy)      178—179  
Affinity, relative      96  
Aging of inks and paints, analysis for      521—524 522f 523f 524f  
Aging of paper      572—574  
Aliquot      71  
Alkaloids, analysis of      329—356  
Alkaloids, as natural products      216  
Alkaloids, ergot, analysis of      345—354 (see also “Hallucinogens”)  
Alkaloids, opiate      see also “Opiate alkaloids”  
Alkaloids, opiate, analysis of      329—338 329f 330—332t 333f 334f 336f  
Alkaloids, opiate, tropane      338—345 (see also “Cocaine”)  
Alkaloids, opiate, tryptamine, analysis of      346 349  
Alkaloids, opiate, xanthine, analysis of      354 356 356f  
Alkyd resins, in paints      501  
Allocaine, structure of      339t  
Alprazolam, structure of      377t  
Alto, in mechanical printing      497  
Alumina A, characteristics of      110t  
Alumina B, characteristics of      110t  
Alumina N, characteristics of      110t  
Alzarin, structure of      485t  
American Academy of Forensic Sciences (AAFS)      11  
American Board of Criminalistics (ABC)      11  
American Board of Forensic Toxicology (ABFT)      11  
American Chemical Society (ACS)      11  
American Society for Testing and Materials (ASTM), standards of, for fire debris analysis      435t  
American Society for Testing and Materials (ASTM), standards of, for paint and ink analysis      509  
American Society of Crime Laboratory Directors LAB program (ASCLD)      11  
Aminopropyl, characteristics of      110t  
Amitriptyline, structure of      378t  
Ammunition, types of      425f  
Amorphous solid      529 532f  
Amphetamines      356t (see also “Methamphetamine”)  
Amphetamines, analysis of      356—375  
Amphetamines, history of      357  
Amphetamines, precursors of      360—361 364f  
Amphetamines, structure of      358t  
Amphoteric drugs, extraction and partitioning in      103—104  
Amylopectin      534 535 538f 539f  
Amylose      534—535 538f 539f  
Anabolic steroids, analysis of      306—314 307f 308f 309b 309f 310f 311—313t  
Analgesics      217—219  
Analyst, certification of      69  
Analytical balances, calibration of      74  
Analytical chemistry, statistics for      17—42  
Analytical errors, types of      72—74 73f  
Analytical protocols, in method validation      68  
Analytical separations, history of      92b  
Androstane, structure of      310f  
Anesthetics, dissociative, analysis of      375—376 375—376t 377f  
Anesthetics, dissociative, structure of      269f  
ANFO in Oklahoma City explosion      420b  
Angel dust      see “Phencyclidine (PCP “angel  
Angle aperture, in microscopy      142 143f 144  
Anhydroglucose polymers      534  
Anidex fibers, description of      578t  
Anion binding, characteristics of      110t  
Anionic polymerization      550 553—554b 553f  
Anisotropic materials, retardation and      147  
Anisotropy, in fiber analysis      582—583  
Anomeric carbon      532 533 533f 534f  
Anthraquinones, colors and examples      481t  
Anthraquinones, structure and example of      485t  
Anti-Drug Abuse Act of 1986      224  
Antibody(ies) in immunoassay      121  
Antibody(ies), monoclonal, production of      122—123 122f  
Antifoaming agents in inks      488  
Antifoaming agents in paints      502—503  
Antigen, in immunoassay      121  
Antiserum, production of      121—122  
Antiserum, titer of      121 121b  
Aperture(s) in Kohler illumination      141  
Aperture(s), angle, in microscopy      142 143f 144  
Aperture(s), numerical, of objective lenses      144  
Aramid fibers, description of      578t  
Arsenic, metallic, isolation of, historical      239—240b  
Arson and fire investigation      433—441  
Arson and fire investigation, accelerants in      433—434  
Arson and fire investigation, forensic analysis of fire debris in      434—440 434t 435t 436f 437f 438f 439f 440—441b 441t  
Arson and fire investigation, incendiary devices in      433—434  
Arson, solid-phase microextraction and      114 115  
Aryl groups      278  
ASCLD (American Society of Crime Laboratory Directors), LAB program      11  
Aspirin, history of      217b  
Aspirin, toxicological factors for      253f  
ASTM      see “American Society for Testing and Materials (ASTM)”  
ASTM E122 -  , in subset sample selection      36  
Athletes, sample analysis for banned substances in      222b  
 | Atomic absorption spectrometry (AAS)      173—178  
Atomic emission spectroscopy (AES)      178—179  
ATR (attenuated total reflectance)      166—167 166f 168f  
Attenuated total reflectance (ATR)      166—167 166f 168f  
Attenuated total reflectance (ATR) in fiber analysis      601  
Attenuated total reflectance (ATR) in fiber color analysis      596  
Automotive paints      503—506 504—506b 504f  
Auxochrome      274 274f 275f  
Average, definition of      19  
Aza linkage      278  
Aziridine, formation of, in Emde synthesis      370 371f  
Azlon fibers, description of      577t  
Azo coupling      278  
Azo dyes and pigments      278 279f  
Azo dyes and pigments, colors and examples      481t  
Azo dyes and pigments, structure and examples of      485t  
Balances, analytical, calibration of      74  
Ballpoint pen inks      492  
Bandwidth, spectral      159 159f 160f  
Barbiturates, analysis of      314  
Barbiturates, structure of      268f  
Barbituric acid, structure of      314f  
Baseline resolution, of spectral peaks      159 160f  
Basic drugs      269f  
Basic drugs, critical review of      323—328  
Basic drugs, forensic drug analysis of      320—383  
Basic drugs, physiological effects of      320 322  
Basic drugs, sources of      320  
Basic drugs, stereochemistry of      323—328  
batch      70  
Bathochromic shift      274 275f  
Bayesian statistics      41—42  
Beating, in paper production      545—546 545f  
Becke line technique, in determining refractive index of fiber      583 584f  
Beer’s law      152 273  
Bell curve      19 23f  
Benzidine yellow, structure of      481t  
Benzocaine, structure of      340t  
Benzodiazepines, analysis      376—379 377—378t  
Benzodiazepines, structure of      269f 321f  
Benzoylecgonine, structure of      268f  
Bertrand lens      141—142  
Bias, definition of      65  
Bicomponent fibers, fabrication of      562 563b  
Binding agents, in paints/coatings      498 501—502 501f 502f 503f  
Binding strength, in immunoassay      121  
Binomial distribution      37—39  
Biopolymers      528 529f 532—547  
Birch method, of methamphetamine synthesis      364f 365 367—368 370 370f 371f  
Birefringence      147—148  
Birefringence in fiber analysis      583  
Blackbody radiator      461  
Blank samples      70  
Blanks, in calibration checks      75  
Bleaching agents, in profiling cocaine      342  
Bleaching, in paper production      545 545f  
Blind controls      70—71  
Blood-brain barrier      250b  
Boldenone, structure of      311t  
Boltzmann distribution      174—176  
Bonds, polarizable      169—171 170f  
Bouyant flames      412  
Bright-field illumination, in fiber analysis      581  
Brisance      418  
BSTFA, in derivatization of gamma hydroxybutyric acid      299  
Bulk methods, of elemental analysis      179  
Bullets, characterization of      446—447b  
Caffeine, as heroin diluent/adulterant      335  
Caliber      427 428b  
Calibration      74—81  
Calibration checks      71  
Calibration of instruments      75—81 78f 79f 80f 81f  
Calibration-check sample      75 78f  
Camphor, function and formula of      449t  
Cannabidiol (CBD), color of, with Fast Blue B      305  
Cannabidiol (CBD), structure of      303t  
Cannabinoids, analysis of      299—306 300f 301f 302f 303—304t 305f  
Cannabinoids, half-life of      254t  
Cannabinoids, legal issues and questions on      305—306  
Cannabinoids, structures of      303—304t  
Cannabinol (CBN), color of, with Fast Blue B      305  
Cannabinol (CBN), structure of      303t  
Capillary electrophoresis (CE)      188—189b 188—191 190f 191f 192f  
Capillary electrophoresis (CE) in analysis of explosives      456—457  
Capillary zone electrophoresis (CZE)      189  
Carbitol, synthesis of      489 489f  
Carbocations      280b 281  
Carbon, anomeric      532 533 533f 534f  
Carbonyls      279  
Carbonyls, structure and example of      485t  
Cassegrain system, in microspectrophotometry      182 182f 183f  
Cathine in khat      372  
Cathine, structure of      359t  
Cathinone in khat      372  
Cathinone, structure of      359t  
Cathode lamp, hollow      176 176f  
Cationic dyes and pigments, structure and example of      486t  
Cationic polymerization      550 552f  
CBD (cannabidiol), color of, with Fast Blue B      305  
CBD (cannabidiol), structure of      303t  
CBN (cannabinol), color of, with Fast Blue B      305  
CBN (cannabinol), structure of      303t  
CDTA (Chemical Diversion and Trafficking Act)      224—225 363  
CE      see “Capillary electrophoresis (CE)”  
Cellophane      528—529 529f  
Cellophane, forensic analysis of      610  
Celluloid      543b  
Cellulose      528 536—537 539—541 540f 541f 542f  
Cellulose acetate      543b 544  
Cellulose, degrading of      574  
Cellulose, linkages in      536—537 540f  
Cellulose, reformulated      542—544  
Cellulose, regenerated      542—544 542f  
Cellusolve, synthesis of      489 489f  
Central nervous system (CNS), depressants of      219  
Central nervous system (CNS), opiate effects on      218 218f  
Central nervous system (CNS), stimulants of      221  
Certification of analyst      69  
Certification of forensic professional      11  
CFT (crystal field theory)      289  
Chain of custody      6  
Chain-growth polymers      548—553 548f 549f 550f 551—552t 552f 553f 554f  
Chemical Diversion and Trafficking Act (CDTA)      224—225 363  
Chemical fingerprinting      229—239 (see also “Profiling of drug sample”)  
Chemistry, origins of      2b  
Chemistry, precedent in      3—4  
Chemometrics, definition of      48  
Chiral separations      205—206 206f  
Chitin      534 537f  
Chloroform, characteristics of      100t  
Cholesterol, structure of      310f  
Chroma      469 470  
Chromates, colors and examples      482t  
Chromatic color      273  
Chromaticity diagram      467—470 468f 470f  
Chromatographic inlets, in electrophoretic instruments      192—196 194f 195f  
Chromatography in analysis of explosives      455  
Chromatography in fiber analysis      588 590  
Chromatography in forensic analysis      7  
Chromatography, history of      119b  
Chromatography, planar      116—119 (see also “Thin-layer chromatography (TLC)”)  
Chromatography, thin-layer      116—119 117f 118f 120f  
Chromophore      273—274  
Chromophore, dyes and pigments grouped by      485—187t  
CIE system of color quantification      461—473  
CIE system of color quantification, chromaticity diagram in      467—470 468f 470f  
CIE system of color quantification, illumination in      461—463 462f  
CIE system of color quantification, observer contribution to      463—464 463f 464f  
CIE system of color quantification, tristimulus values in      461 464  
CIELAB system      470—473 470f 471f 472f  
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