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| Àâòîðèçàöèÿ |
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| Ïîèñê ïî óêàçàòåëÿì |
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| Levine I.N. — Molecular Spectroscopy |
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| Ïðåäìåòíûé óêàçàòåëü |
Electron spin resonance (ESR) of radicals in solids 367
Electron spin resonance (ESR) of triplet-state molecules 367
Electron spin resonance (ESR), biochemical applications of 380—381
Electron spin resonance (ESR), coupling constants in 376—380
Electron spin resonance (ESR), electron spin-nuclear spin interactions in 369—380
Electron spin resonance (ESR), electron- interaction in 375
Electron spin resonance (ESR), electron- interaction in 375—376
Electron spin resonance (ESR), energy levels for 368 373
Electron spin resonance (ESR), experimental procedures in 368—369
Electron spin resonance (ESR), hyperfine structure in 369—380
Electron spin resonance (ESR), selection rules for 373
Electron volt 131
Electronic energy 57 64 148
Electronic spectra 130 296—314
Electronic spectra and molecular structure 311
Electronic spectra of diatomics 298—306
Electronic spectra of polyatomics 71—72 73 75 306—314
Electronic spectra, selection rules for 297—301 306—307
Electronic structure of molecules 56—76
Ellipsoid of inertia 198—202 439—440
Emission of radiation, spontaneous 121—122
Emission of radiation, stimulated 118 120 122 135—139
Energy conversion factors 468
Energy-localized orbitals 69 103—104
Equilibrium frequencies 147 262
Equivalent representations 400
Ethane, deuterated, dipole moment of 225
Ethane, rotational barrier in 226—228
Ethanol NMR spectrum 331 333—334 337 352 353 365
Ethyl radical 375
Ethylene, normal modes of 291
Ethylene, nuclear statistical weights of 288
Ethylene, structure of 265
Eulerian angles 203—204 257
Even function 32 33
Exchange operator 64
Excited-state wave functions 311—313
Extended basis set 66
Extended Huckel (EH) method 71 73—74 231
FE MO method 71—72
Fermi contact term 371—372
Fermi resonance 278—279
Fermion 46
Fine-structure constant 45
Fingerprint region 266
First-order NMR approximation 349—352
Flame spectroscopy 296
Fluorescence 128
Forbidden transitions 123
Force constant(s) 25
Force constant(s) for diatomics 146
Force constant(s) for polyatomics 237 244—245
Force constant(s), calculation of 245
Formaldehyde, ellipsoid of inertia 198 200
Formaldoxime 223—224 225
Formamide 225
Formic acid 264
Fourier transform IR 331
Fourier transform NMR 330—331 356
Franck — Condon factor 303
Franck — Condon principle 302—303 307
Free particle 25
Free radicals 269 296
Free-electron molecular-orbital (FE MO) method 71—72
Fundamental band 169 262
Fundamental frequencies 262
Fundamental level 252
g factor, electron 45 376
g factor, nuclear 324
Galois, E. 387
Gauss (unit) 52
Gaussian line shape 135 369
Gaussian units 23
Gaussian-type orbitals 66
Golay cell 260
Group and isomorphism 392
Group frequencies 266—268 270
Group of symmetry operations 53—56 388—389
Group theory 387—462
Group theory and degeneracy 412—415 416—417
Group theory and electronic structure 417—427
Group theory and evaluation of integrals 453—455
Group theory and molecular rotation 439—440
Group theory and molecular vibration 427—439 447—451 455—457
Group theory and normal modes 430—439
Group theory and quantum mechanics 412—417
Group theory and selection rules 455—458
Group, abelian 389 392 393 406—4107
Group, classes of 393 406 407
Group, definition of 387—388
Group, elements of 3 87
Group, multiplication table of 389—392
Group, order of 388
Group, representations of 399—409
Group, rule of combination for 387
Group, structure of 392
Group, subgroup of 392
Gwinn, W.D. 244
Half-width 133
Hamiltonian operator 3 4—5 47 56—57
harmonic oscillator 25—27 124 251
Harmonic oscillator, matrix elements for 152—155
Hartree (unit) 23
Hartree — Fock method 52 63—70 102
Hartree — Fock method and force constants 245
Hartree — Fock method and inversion barriers 229
Hartree — Fock method and ionization potentials 318
Hartree — Fock method and oscillator strengths 313
Hartree — Fock method and quadrupole coupling constants 231
Hartree — Fock method and rotational barriers 229
Hartree — Fock method for benzene 317
Hartree — Fock method for excited states 311—312
Hartree — Fock method, restricted 312
Hartree — Fock method, unrestricted 311—312
Hartree — Fock operator 63—64
Hartree — Fock — Roothaan method 64—68
Heisenberg, W. 93—94
Helium 47 128
Helium-neon laser 137
Helmholz, L. 73
Hemoglobin 131
Hermite polynomials 25—26
Hermitian conjugate of a matrix 85
Hermitian matrix 84—85 89—90 91—92 96
Hermitian operators 4 5—8
Herschel, W. 260
Hertz (unit) 132
High-resolution NMR 331
HMO method 71 72—73 313 379
Hoffmann, R. 73
Homogeneous linear equations 16
Hot bands 170 262
Huckel molecular-orbital (HMO) method 71 72—73 313 379
Hughes, R.H. 220
Hund, F. 188
Hund’s coupling cases 188—191
Hydrocarbons, conjugated 71—75
Hydrocarbons, dipole moments of 225
Hydrocarbons, radicals of 367 376—380
Hydrogen atom 41—42 124—126 374
Hydrogen bonding 264 334 366
Hydrogen chloride IR bands, table of 171
Hydrogen deuteride 190
hydrogen molecule 148 150 159 184—185
Hydrogen molecule, chemical shift in 335 337
Hydrogen molecule, molecular orbitals of 68
Hydrogen molecule, ortho and para forms of 185
Hydrogen molecule, rotation in liquid and solid phases 263
Hydrogen molecule, symmetry orbitals for 420—423
Hyperfine coupling constant 372
| Hyperfine structure 52 129 374
Hyperfine structure in ESR 369—380
Identity element 387—388
Identity operation 54 395
Improper axis of symmetry 53
Improper rotation 396
Index of refraction 132
INDO method 71 75—76
INDO method and ESR coupling constants 380
INDO method and force constants 245
INDO method and ionization potentials 318
INDO method and NMR coupling constants 360
Induced dipole moment 187
Inertia tensor 201
Inertial defect 224—225
Infrared spectroscopy 130 260—269
Infrared spectroscopy and astrophysics 269
Infrared spectroscopy and group frequencies 266—268 270
Infrared spectroscopy and lasers 261—262
Infrared spectroscopy and matrix isolation method 269
Infrared spectroscopy and molecular structure 265
Infrared spectroscopy, biochemical applications of 268
Infrared spectroscopy, experimental procedures in 260—261
Infrared spectroscopy, Fourier transform method in 331
Infrared spectroscopy, rotational fine structure in 171—174 259—260 265
Inhomogeneous linear equations 16
Inner product 98
Integrals and group theory 453—455
Intensity distribution in IR band 173—174
Intensity of a transition 122
Intensity of radiation 115 119
Intersteller space, molecules in 231
Inverse of a group element 388
Inverse of a matrix 84
Inverse of an operator 108
Inversion of molecules 228—229 282
Inversion operation 393 395 405
Ionization potentials 317—320
Irreducible representations 402 403—409 415—416
Isobutane, dipole moment of 225
Isomorphic groups 392
Isotopes, table of properties of 470
Isotopic substitution in ESR 379
Isotopic substitution in IR spectroscopy 244
Isotopic substitution in microwave spectroscopy 221—223
Isotopic substitution in NMR 354—355
j-jcoupling 51
Jacobi method 101
Jahn — Teller theorem 313—314
Javan, A. 137
Jolly, W.L. 320
Jordan, P. 94
Karplus, M. 360
Ket notation 5
Ketene 226
kinetic energy 3
Klystron 219—220 368
Koopmans, T.C 318
Koopmans’ theorem 318
Kraitchman, J. 223
Krebiozen 268
Kronecker delta 6
Kronecker product 441
l-type doubling 277
Ladder operators 30—32 44 327
Lambda-type doubling 59 277
Laplacian 3
Laporte rule 126
Lasers 135—140
Lasers in electronic spectroscopy 296
Lasers in IR spectroscopy 261—262
Lasers in Raman spectroscopy 270 271
Lasers, chemical 137—138
Lasers, CW 137
Lasers, dye 138
Lasers, helium-neon 137
Lasers, pulse 137 139
Lasers, ruby 135—137
Lasers, semiconductor 138
Lasers, tunable 138
LCAO MO 65
Left form 282
Levels, atomic 50
Levels, diatomic 59
Lifetime 122
Light see “Radiation electromagnetic”
Light, speed of 140
Line shape 133—134 135
Line spectra 297
line width 133—134 139
Line width in NMR 362—363
Linear independence 16
Linear molecules, nuclear statistical weights for 284—288
Linear molecules, parity of wave functions of 280
Linear molecules, rotational energy of 211—212
Linear momentum 27
Linear operator 3
Linear variation method 34—35
Localized orbitals 69 103—104 309—310
Lorentzian shape 133—134 135 369
Lowering operator 30
Magnetic dipole moment 29 45
Magnetic field strength 51—52
Magnetic flux density 51—52
Magnetic induction 51
Magnetic moment, electron spin 45 368
Magnetic moment, nuclear 323—325
Magnetic resonance 129—130 323—381 “Electron
Magnetic-dipole transition 123 127 221 326
Magnetically equivalent nuclei 348
Magnetogyric ratio 325
Maiman, T.H. 137
Maser 137
Mass-weighted Cartesian displacement coordinates 236 239
Matrix (-ces) 78—104 187
Matrix (-ces) and coordinate transformations 394—398
Matrix (-ces) and quantum mechanics 93—102
Matrix (-ces), addition of 79
Matrix (-ces), adjoint of 85
Matrix (-ces), associate 85
Matrix (-ces), column 79
Matrix (-ces), complex conjugate of 85
Matrix (-ces), determinant of 84
Matrix (-ces), diagonal 83
Matrix (-ces), diagonalization of 92 101 102
Matrix (-ces), direct product of 441—443
Matrix (-ces), direct sum of 402
Matrix (-ces), eigenvalues of 88—92 99—102
Matrix (-ces), eigenvectors of 88—92 99—102
Matrix (-ces), elements of 78
Matrix (-ces), Hermitian 84—85 89—90 91—92 96
Matrix (-ces), Hermitian conjugate of 85
Matrix (-ces), inverse of 84
Matrix (-ces), modal 106
Matrix (-ces), multiplication of 80—82 152
Matrix (-ces), nonsingular 84
Matrix (-ces), nuU 83
Matrix (-ces), order of 82
Matrix (-ces), orthogonal 85—86 87
Matrix (-ces), partitioned 88
Matrix (-ces), principal diagonal of 82
Matrix (-ces), real 84
Matrix (-ces), row 79
Matrix (-ces), similar 101—102
Matrix (-ces), square 82
Matrix (-ces), symmetric 84
Matrix (-ces), trace of 82—83
Matrix (-ces), transpose of 85 236
Matrix (-ces), unit 83
Matrix (-ces), unitary 85—86 87
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