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| Ïîèñê ïî óêàçàòåëÿì |
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| Levine I.N. — Molecular Spectroscopy |
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| Ïðåäìåòíûé óêàçàòåëü |
 case in NMR 349—352
 case in NMR 348—349 352—354
a levels 181 287
a-type transition 219
AB case in NMR 339—346
Ab initio methods 70 (see also “Hartree — Fock method”)
Abel, N. 387
Abelian group 389 392 393 406—407
Absolute value 13
Absorption of radiation 118
Accidental degeneracy 253 415
Acetaldehyde, NMR spectrum of 352 353
Acetylene, degenerate normal modes 275 276
Acetylene, nuclear statistical weights 288
Adiabatic ionization potential 316
Adjoint of a matrix 85
Adjoint of an operator 107—108
Allerhand, A. 364
Alternant hydrocarbons 73 380
Ammonia in interstellar space 231
Ammonia in planetary atmospheres 269
Ammonia, inversion in 228—229 282
Ammonia, vibrational potential for 244—245
Angstrom 23 132
Angular momentum in diatomics 58—59
Angular momentum, addition of 49
Angular momentum, ladder operators for 30—32
Angular momentum, orbital 27—29 49
Angular momentum, rotational 203 204—208 209
Angular momentum, rotational, operators for 204—208
Angular momentum, spin 42—45 58 59
Angular momentum, total 50
Angular momentum, vibrational 271 273—277 451
Anharmonic oscillator 150—156
Anharmonicity in diatomics 156 159
Anharmonicity in polyatomics 254—255 274—275
Anthracene ions 380
Anti-Stokes lines 186
Antisymmetric function 45
Arnold, J.T. 331
Associativity 12 387
Astrophysics 231 269
Asymmetric top 199 200—202
Asymmetric top, correlation with symmetric-top levels 21
Asymmetric top, definition of 199
Asymmetric top, degeneracy for 215
Asymmetric top, energies of 213—216
Asymmetric top, microwave spectrum of 218—219
Asymmetric top, selection rules for 218—219 258 259—260
Asymmetric top, wave functions of 213—215 440
Atomic spectroscopy 130
Atomic units 23
Atoms, many-electron 47—51
Atoms, one-electron 41—42 124—126
Atoms, selection rules for 127—128
Auroras 129
Average value 2
AX case in NMR 346—347
Axes of inertia 198—202
Axial vector 434
Axis of symmetry 53
b-type transition 219
Band head 172 303—304
Band origin 168
Band spectra 297
Band structure of electronic transitions 303 306—307
Barrier to internal rotation 226—228 364—365
Barrier to inversion 228—229
Bartholome, E. 268
Basis functions 64 65 66 96
Basis functions in group theory 409—412
Basis vectors 97
Benzene and Jahn — Teller theorem 314
Benzene negative ion 314 367 374 375 378
Benzene, character table of 406
Benzene, Fermi resonance in 279
Benzene, Hartree — Fock calculation for 317
Benzene, HMO treatment of 72—73
Benzene, NMR spectrum of 348
Benzene, normal modes of 438—139
Benzene, ordering of orbitals in 317
Benzene, photoelectron spectrum of 317
Benzene, pi MOs of 427
Benzene, symmetry number of 289
Benzene, symmetry orbitals for 426—427
Benzene, symmetry species of normal modes of 438—439
Benzene, terms of excited configuration of 451—452
Beveridge, D.L. 380
Binomial coefficients 351 374
Biochemical applications of ESR 380—381
Biochemical applications of IR spectroscopy 268
Biochemical applications of NMR 357 363—364
Biochemical applications of Raman spectroscopy 270—271
Birge — Sponer extrapolation 304—305
Blackbody radiation 121—122
Bloch, F. 328
Block-diagonal form 15
Bohr (unit) 23
Bohr magneton 51 368
Bohr radius 42
Bolometer 260
Boltzmann distribution law 121 135 361
Bond lengths 222—223
Born — Oppenheimer approximation 56—57 300—301
Born, M. 94
Boron trifluoride normal modes 281 290
Boson 46
Bracket notation 5
Branches 171—173 188 218 303
Brillouin’s theorem 311
Broad-line NMR 359
Broadening of spectral lines 133—135
Butadiene excited states 312—313
c-type transition 219
Canonical orbitals 69 310
Carbon dioxide, Fermi resonance in 278—279
Carbon dioxide, IR bands, table of 264
Carbon dioxide, normal modes 242 248 262 265
Carbon dioxide, nuclear statistical weights for 287—288
Carbon dioxide, vibrational constants of 275
Carbon dioxide, vibrational levels of 253
Carbon dioxide, vibrations of, and group theory 449—451 456
Carbon monoxide, Cameron system of 298
Carbon monoxide, fundamental IR band of, table of 174
Carbon monoxide, rotational transitions of, table of 168
Carbon—13 NMR 356—357
Cartesian displacement coordinates 236
Case (a) coupling 188—189 212
Case (b) coupling 190—191 212
Cayley, A. 78 387
Center of symmetry 53
Central-force problem 38
Centrifugal distortion in diatomics 158 166—167
Centrifugal distortion in polyatomics 213 216 218
Chain rule 20—21
Character tables 402—409
Character tables for some point groups 458—462
Characters of direct product 443
Characters of elements in same class 403
Characters of symmetric direct product 445—446
Characters, complex 416—417 429—430
Characters, definition of 403
Characters, theorems on 403—404
Chemical analysis 130 231 319—320
Chemical lasers 137—138
Chemical shifts in ESCA 319—320
Chemical shifts in NMR 331—337
Chemical shifts, chart of 338
Chemically equivalent nuclei 348
Chromophores 310
| Class of a group 393 406 407
Classically forbidden region 27
Cleeton, C.E. 219
Closure 387 388
CNDO method 71 75 76
CNDO method and electronic spectra 313
CNDO method and force constants 245
CNDO method and ionization potentials 318
CNDO method and quadrupole coupling constants 231
Cofactor 14
Coherent radiation 139
Collision broadening 134
Collision of the first kind 129
Collision of the second kind 129
Column matrix 79
Column vectors 80 82
Column vectors, orthogonal 86
Column vectors, orthonormal 86
Combination level 252
Commutator 8 13
Commuting operators 8
Complete set 4
Complete set, expansion in terms of 6—8
Complex conjugate 13—14
complex numbers 13—14
Computer of averaged transients 330
Computers 76
Computers and asymmetric-top secular equation 216
Computers and NMR spectra 355
Computers and vibrational secular equation 244
Configuration 48 58 66
Configuration interaction 69—70 311 312—313
Conformational isomers 229
Conjugate group elements 392—393
Conjugated molecules 71—75
Continuum states 6
Conversion factors for energy, table of 468
Coordinate transformation 22 87 394—398
Core hamiltonian 64
Correlation diagram for asymmetric top 216 217
Correlation energy 69
Costain, C.C 223
Coulomb operator 64
Coupling constants, ESR 372 374 376—380
Coupling constants, ESR, calculation of 380
Coupling constants, NMR 339 345—346 352—354
Coupling constants, NMR,  357
Coupling constants, NMR, in liquids and gases 359—360
Coupling constants, NMR, in olefins 346
Coupling constants, NMR, in solids 357—359
Coupling constants, NMR, , proton- 356
Coupling constants, NMR, , proton- 345 357
Coupling constants, NMR, , proton-proton 345—346
Coupling constants, NMR, absolute signs of 360
Coupling constants, NMR, calculation of 360
Cramer’s Rule 16
Cross product 12
CW laser 137
Cyclobutadiene 269
Davis, R.E. 320
Degeneracy 6
Degeneracy and group theory 412—115 416—417
Degeneracy for asymmetric top 215
Degeneracy for particle in a cubic box 25
Degeneracy for spherical top 210
Degeneracy for symmetric top 211
Degeneracy for two-particle rigid rotor 41
Degeneracy of atomic levels 50
Degeneracy of vibrational levels 252—253 271—277 451
Degeneracy, accidental 253 415
Degeneracy, molecular electronic 58—62 313—314 417—418
Degeneracy, orbital 61 62
Degenerate perturbation theory 36—38
Degenerate vibrational modes 241 246—247 271—276 430
Degrees of freedom 235
DEL 12
Delta chemical-shift scale 335—336 356
Delta function 18 371
Density matrix 108
Determinants 14—15 78 84
Dewar, M.J.S. 75
Diagonal form 15
Diagonal matrix 83
Diagonalization of matrices 92 101 102
Diamagnetic contribution to shielding constant 332
Diatomic molecules and nuclear spin 178—185
Diatomic molecules, dissociation of 156—157
Diatomic molecules, electronic spectra of 298—306
Diatomic molecules, electronic structure of 57—59
Diatomic molecules, energy of 148 155
Diatomic molecules, normal mode of 242—244
Diatomic molecules, nuclear motion in 142—159
Diatomic molecules, parity of wave functions 175—178
Diatomic molecules, rotational energies of 188—191
Diatomic molecules, rotational spectra of 165—167
Diatomic molecules, table of constants for 160
Diatomic molecules, vibration-rotation spectra of 168—174
dictionary order 441
Difference operator 170
Differential equations 18—19
Dimension of representation 399 403 404
Dipole moment, electric 62—63 69
Dipole moment, electric and transitions 164
Dipole moment, electric of asymmetric top 218—219
Dipole moment, electric of HD 190
Dipole moment, electric of hydrocarbons 225
Dipole moment, electric of methane 225
Dipole moment, electric of symmetric top 217
Dipole moment, electric, induced 187
Dipole moment, electric, measurement of 225
Dipole-moment function 164—165
Dipole-moment operator 62
Dirac delta function 18 371
Direct product 440—458
Direct product and totally symmetric representation 444—445
Direct product of matrices 441—443
Direct product of three representations 444
Direct product, characters of 443
Direct product, definition of 441
Direct product, symmetric 445—447 449
Direct sum of representations 402
Direction cosines 21—22 257 394—397
Dissociation energy 304—306
Dobosh, P.A. 380
Doppler broadening 134 135
Dot product 11
Double resonance 354 356
DPPH 369
Dummy variable 81
Dunham coefficients 158 159
Dye lasers 138
Eigenfunctions 2 98—102
Eigenvalues 2 5 98—102
Eigenvalues of a matrix 88—92 99—102
Eigenvalues, continuous 7
Eigenvectors 88—92 99—102
Einstein coefficients 121—122
electric dipole moment see “Dipole moment electric”
Electric potential 230
Electric quadrupole moment 229—231 365—366
Electric-dipole transition 123
Electric-field-gradient tensor 230
Electric-quadrupole transition 123 127
Electromagnetic radiation 114—117 (see also “Radiation electromagnetic”)
Electromagnetic spectrum 115
Electron spectroscopy for chemical analysis (ESCA) 319—320
Electron spin resonance (ESR) 130 366—381
Electron spin resonance (ESR) and rate processes 380
Electron spin resonance (ESR) of organic radicals in solution 367—381
Electron spin resonance (ESR) of paramagnetic ions 367
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