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Àâòîðèçàöèÿ |
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Ïîèñê ïî óêàçàòåëÿì |
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Israelachvili J.N. — Intermolecular and surface forces |
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Ïðåäìåòíûé óêàçàòåëü |
Addivity 180 188 267
Addivity of van der Waals forces 89 106 177—179 202
Adhesion and surface energy 163 267 270 334 336—337
Adhesion of deformable surfaces 326 414—416
Adhesion of elastic bodies 326—327 336—337 414—416
Adhesion, bilayer 309 397 414—416 421
Adhesion, effect of adsorbed layers 207
Adhesion, effect of capillary forces 330—333 335
Adhesion, effect of meniscus 330—333 335
Adhesion, effect of solvation force 267—270
Adhesion, effect of surface asperities 323 329 333
Adhesion, effect of surface roughness 329 333
Adhesion, effect of tension 309
Adhesion, effect of water 210 271 333 336
Adhesion, energy 144 163 179 201 210 267—268 270 312—313
Adhesion, force 9—10 163 172 210 267 270 327 328 414—416
Adhesion, hysteresis 322—323
Adhesion, measurement 165—168 172 270 333 415
Adhesion, mechanics 326—329
Adhesion, membrane 397 414—416 421
Adhesion, specific 410—412
Adhesion, theoretical aspects 9—10 163 267—2.68 334 414—416
Adhesion, vesicle 414—416
Adhesion, work of 313
Adsorbed film 149—151 195 198 206 210
Adsorbed film of liquid 192—195 198 210
Adsorbed film, effect on adhesion 207 323
Adsorbed film, effect on contact angle 322—323
Adsorbed film, liquid helium 192—194
Adsorbed film, non-wetting 284
Adsorbed film, theoretical aspects 149—151 192—195
Adsorption on surfaces 147—151 195 206 236
aggregates see “Amphiphilic structures” “Micelle” “Self-assembly”
aging effects 303
Alder transition 93
Amphiphilic molecules 135 342—343
Amphiphilic molecules in biological membranes 342—343
Amphiphilic molecules, biological 342—343 387
Amphiphilic molecules, critical chain length 370
Amphiphilic molecules, exchange 346 375
Amphiphilic molecules, forces between 361 341
Amphiphilic molecules, lifetime in micelle 346 375—376
Amphiphilic molecules, lifetimes in aggregates 346 375
Amphiphilic molecules, melting temperatures 378
Amphiphilic molecules, optimal area 368—370
Amphiphilic molecules, packing of 370
Amphiphilic molecules, pK values 342
Amphiphilic molecules, self-assembly of 345
Amphiphilic molecules, structure 344
Amphiphilic molecules, unsaturated 342—343 387
Amphiphilic structures 344 346 371 380—381
Amphiphilic structures, bicontinuous 392
Amphiphilic structures, effect of temperature 380 382
Amphiphilic structures, effect of two chains 375
Amphiphilic structures, forces between 276 395 414—416
Amphiphilic structures, inverted 379 392 420
Amphiphilic structures, periodic 392
Amphiphilic structures, phase equilibrium 367
Amphiphilic structures, phase transisions 353
Amphiphilic structures, polydispersity 358—362 373—374 385
Amphiphilic structures, size distribution 354—362 373—374 385
Amphiphilic structures, transitions between 380—382 362—364 392
Amphoteric surfaces 236—238 280
Angle-averaged potential 60 61 66 74
Anisotropic interaction see “Orientation dependent interaction”
Archimedes’ Principle 145
Area of contact 143
Area of headgroups 380
Area of interaction 143 159 174
Area, effective, for spheres 143 174
Associated liquid 26 59—60 125—127 268
Association of molecules 133 139 141 142
Association of molecules and particles 133 139—142 145—146 151
Association of particles 141 142 145
Atmosphere, earth’s 21
Atmosphere, ionic see “Double-layer”
Atom-surface interaction 14—15 155—157 176—178
Atomic force microscopy (AFM) 10 14 15 173
Atomic size 110
Bare ion radius 55
Barometric distribution law 21
Bending modulus of membrane 383 308—309 382—385
Bernal — Fowler rules 286
Bilayer 344 375—378
Bilayer, diffusion in 376
Bilayer, dimensions 344 376
Bilayer, elasticity 308—309 377 382—385 421
Bilayer, flip-flop 376
Bilayer, fluid states of 37
Bilayer, fluidity of 383
Bilayer, forces between 199 226—228 252 256 257 276—277 284—285 304—309 311 395—399 403—409 419
Bilayer, free and supported 403
Bilayer, fusion 409 416—419
Bilayer, lipid diffusion 376
Bilayer, lipid dynamics in 377
Bilayer, solute diffusion across 344
Bilayer, structure 344 376
Bilayer-vesicle transition 364
Biocontinuous structures 392
Biological membrane 385—392
Biological membrane in cells 386
Biological membrane, composition 386
Biological membrane, fusion 409 416—419
Biological membrane, interactions 413
Biological membrane, properties 389
Biological membrane, structure 390—394 413
Bohr atom 84 88 179
Bohr radius 84
Boiling temperature and intermolecular forces 25—27 87 115—116
Boltzmann distribution 20—22 27 119 215
Boltzmann distribution of ions 231—233
Boltzmann factor 20—22 27
Boltzmann statistics 23
Boltzmann-averaged potential 60—62
Bond, chemical 31
Bond, covalent 31—32
Bond, directionality of 31—32
Bond, energy 19 32
Bond, hydrogen see “Hydrogen bond”
Bond, ionic 44 32—37
Bond, length 110—111
Bond, metallic 31—32
Bond, moment 49
Bond, physical 32
Bond, polarizability 69
Bond, strength 32
Born 160
Born energy 37—38 42—44 63—64 73—74
Born energy, limits of applicability 73—74
Born repulsion 109—112
Born, electrostatic 256—257
Born, entropic 407
Born, hard core 175
Born, head-group 256 311 399 405—408 414—416
Born, hydration 229 256—257
Born, solvation 145
Born, steric 160 175
Born, van der Waals 188—196 256
Boundary lipids 389
Bridging force between biopolymers 411—42
Bridging force of polymers 297 299—302 411—412
Bridging force, ionic 410
Brownian collisions 47 154—155
Brush, polymer 291
Brush, polymer, theory of 295
Bubble coalescence 281
Capacitor 34—35
Capillarity 5—8
Capillary, condensation 330
Capillary, effect on adhesion 330—333
| Capillary, forces 330 333
Capillary, rise, of liquids 5—8 229
Carbon 173
Casimir Polder equation 108
Cavity, energy 17 318
Cavity, nucleation of 286 334
Cellular membrane see “Biological membrane”
Chain-melting temperature 378
Chaotropic agent 135
Charge density of surfaces 213—215
Charge electroneutrality 34
Charge regulation 230 235—236 243
Charge reversal 237
Charge-dipole interaction 50—64
Charge-fluctuation force 83
Chemical bond 32 46
chemical potential 20
Chemical potential in chemical equilibrium 20—22
Chemical potential in intermolecular interactions 20—22
Chemical potential in self-assembly 345
Chemical potential of gas 23
Chord theorem 143
Classification of forces 11—12 27—29
Clathrate 130
Clausius — Mossotti equation 79 82 102 123
Clays, forces between 226—228 276
Clays, hydration effects 226—227 276
Clays, surfaces of 276
Clays, swelling 172 226—227 279 281
Close packing 117
Close packing of colloidal particles 92—93
Close packing, nonspherical molecules 115—116
Close packing, random 120
Close packing, spherical molecules 92—93 120
Cluster 317 (see also “Droplet”)
Co-ions 214
Co-polymers 296
Co-surfactant 382
Coagulation 120 168
Coagulation, critical concentration of 247—248
Coagulation, rate 154—155
Cohesion, work of 313
Cohesive energy 18 26 143
Cohesive energy of atoms and molecules 18—20 25—26 86—89
Cohesive energy, molar 25—26 86—89
Colloid, order in 92 93 227
Colloidal particles, coagulation 154—155 247—250
Colloidal particles, DLVO forces between 247—250
Colloidal stability and instability 120 247—250 253 257 280 287 310—311 333
Combining relations 139 144 200
Computer simulation 44—447 220—221
Computer simulation of adsorbed polymers 292
Computer simulation of ions near surface 220—221 239—240
Computer simulation of liquids 265
Computer simulation of solvation forces 265—266
Constant charge interaction 245—246
Constant potential interaction 245—246
Contact angle 149—151 319 321—324 334—335 412
Contact angle of adhering vesicles 414—416
Contact angle, advancing and receding 321—324
Contact angle, hysteresis 321—324
Contact angle, low values 322
Contact angle, theoretical aspects 149—151 321 334
Contact area 159
Contact mechanics 326—329
Contact value theorem 11 225 265 308
Continuum theories 43
Continuum theories, limitations of 42—44
Cooperative interactions 127 318
Correlations in position 118
Coulomb, force 11 27—28 32—37 39 43—44
Coulomb, interaction 11 32—39 43—44 46 52 58 64 121 126
Coulomb, law 33
Counterion 214
covalent bond 31—32
creep 325
Critical aggregation concentration (CAC) 351—352 364
Critical coagulation concentration (CCC) 347—348
Critical micelle concentration (CMC) 348 351—352 375
Critical micelle concentration (CMC), effects on 355 392—393
Critical micelle concentration (CMC), increment per group 354—355
Critical micelle concentration (CMC), values for 355
Critical packing parameter 371—372
Critical point wetting 151
Curvature of surface 394
Curvature, elastic modulus of 382—385
de Broglie wavelength 23
Debye length 199 238 243
Debye length in van der Waals force 199
Debye unit 49
Debye — Hueckel equation 239
Debye — Hueckel theory 239
Debye — Langevin equation 70 79 82 97 123
Debye-induction interaction 75—76 94—95 182
Deformation, during adhesion, of particles 326—329
Deformation, during adhesion, of vesicles 414—416
Density distribution in liquids 18—19 117—119 261—264
Density distribution of molecules 18—19 261—264
Density distribution of polymer layer 292
Density distribution, function 19 117—118
Depletion force 302—303 310—311
Derjaguin approximation 161—164 172 175 243 270 326
Derjaguin — Landau — Verwey — Overbeek (DLVO) theory 246—250 (see also “DLVO forces”)
Derjaguin — Landau — Verwey — Overbeek (DLVO) theory, limitations 252—254
Desorption 147—151
Detergent action 7 336
dielectric constant 29 41 44 79—80
Dielectric constant, limitation at small distances 42—44 79—82
Dielectric constant, role in interactions 42—44 79—81
Dielectric constant, temperature-dependence of 80—81
Dielectric constant, values 41
Dielectric sphere in medium 77—81
Diffuse double-layer see “Double-layer”
Diffuse interface 92 288
Dipolar interactions 50—64 128
Dipolar ions 40 48
Dipolar molecule see “Polar molecule”
Dipole 27 48
Dipole moment 48—49
Dipole moment of bond 49
Dipole moment, water 37
Dipole, effect on forces 273
Dipole, field 74 254—256
Dipole, forces between 256
Dipole, induced 67—73 84
Dipole, interactions 50—64 128
Dipole, lattice 254—256
Dipole, permanent 48—49
Dipole, rotating 80 82
Dipole, self-energy 50
Dipole, surface 254—256
Dipole-dipole interaction 57—66 128 256
Directionality of bonds 127—128
Directionality of van der Waals force 89 115
Discrete charge effects 254—256
Disjoining pressure 192—194 229
Dispersion interaction 83—89 (see also “Van der Waals interaction”)
Distribution function 19
Distribution function, density 117—118
Distribution function, radial 117—118
Divalent ion effects 228
Divalent ion effects on forces 257 397
Divalent ion effects on surface charge and potential 237
DLVO forces 246—253 277
DLVO forces between bilayers 256 397—398
DLVO forces in colloidal stability 247—250
DLVO forces in non-aqueous liquids 273—274
DLVO forces, measurements 250—253 397
DLVO theory see “Derjaguin — Landau — Verwey — Overbeek theory”
Double-layer 214
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