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| Ïîèñê ïî óêàçàòåëÿì |
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| Israelachvili J.N. — Intermolecular and surface forces |
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| Ïðåäìåòíûé óêàçàòåëü |
Repulsive potential 112
Reservoir, salt, electrolyte solution 231
Residence time of amphiphiles 375
Residence time of bound ions 55—56
Residence time of water 55—56
Retarded van der Waals forces 106—108 194 196
Rotating dipolar molecules 60—64 81
Rotational correlation time, water 56
Roughness of surfaces 260 263 273 288
Roughness of surfaces, dynamic 273 288
Roughness of surfaces, effect on adhesion 329 333
Roughness of surfaces, effect on interaction potential 273
Roughness of surfaces, static 273 288
SAPpHiRe 172
Sapphire, forces between 252
Scaling, force with radius 143
Schroedinger equation 11
Schultz — Hardy rule 249—250
Screened electric field 37
Screening of electrostatic forces 37 199
Secondary minimum 247—248 398
self-assembly 345—350 (see also “Amphiphilic structures”)
Self-assembly, theoretical aspects 348
Self-assembly, thermodynamics of 345 365
Self-association see “Self-assembly”
Self-energy 18
Self-energy and solubility 103—104
Self-energy, atom 18 103—105
Self-energy, dipole 50
Self-energy, ion 37 42 63 73
Shape, molecular 115—116 270—272
Short-range forces 5—8 11—12 152 228
Short-range forces between amphiphilic molecules 361
Short-range order 117—118
Silica surface 172 320
Silica surface, forces between 252 279
Silica surface, hydrophilicity of 281 320
Silica surface, water films on 320
Silica surface, wetting films on 229 281 320
Silica, colloidal properties of 275
Size distribution of aggregates 354—362 382
Size distribution of micelles 360
Size distribution of vesicles 384—385
Sizes of atoms and molecules 22—23 109—112
Soap film 276
Soap film, forces within 252
Solid-liquid transition 92
Solubility 22—23 40 64 96 102—105 136 142
Solubility in small volumes 209
Solubility, continued, in water 22—23 38—42 54—57 129—131 136 353
Solubility, continued, of hydrocarbons 22—23 65 129—132 136
Solubility, continued, of ions 38—42 47 54—57 65
Solubility, continued, of water 131 136
Solubility, continued, parameter 102—105
Solubility, continued, units of 136
Solute-solvent miscibility 102
Solvation force 17 56—57 228 261 265—275
Solvation force between ions 121
Solvation force of mixtures 271
Solvation force, addivity of 281
Solvation force, computer simulation of 121 265—266
Solvation force, effect of surface structure 260—261 273
Solvation force, effect on surface energy 267 270
Solvation force, measurement 269—275 278—279
Solvation force, origin 17 265
Solvation force, oscillatory 121 261 265—266 278—279
Solvation force, properties of 269—275
Solvation force, theories 265—266
Solvation zone 57
Solvent effect 16—17 29 144
Solvent structure 17 54 57
Solvent, effects on interactions 16—19 142—146
Solvent, effects on steric forces 300
Solvent, ideal 291
Solvent, ideal, for polymers 289
Solvent, theta 291
Solvents, solubilities in 22—23 40 47 136
Solvents, “good” and “bad” 291
Specific interaction 128 410
Specific interaction, biological 411
Specific interaction, bridging 411
Specific interaction, ionic 410
Specific interaction, ligand-receptor 411—412
Specific interaction, “lock and key” 411—412
Spheres, interactions of 157 161 177
Stability of colloidal dispersion 120 247 253 257 280 287 310 333
Steric interactions (hard core) 160 175
Steric interactions (hard core) of atoms and molecules 112—116 160
Steric interactions (hard core) of head-groups 311 405—408
Steric interactions (hard core) of surfaces 175
Steric interactions (polymers) 29 115 276 288 293 408
Steric interactions (polymers) between bilayers 311 399 402 405
Steric interactions (polymers) between brushes 295—296 302 311
Steric interactions (polymers) between chemisorbed layers 297 302
Steric interactions (polymers) between grafted layers 297 299—302
Steric interactions (polymers) between physisorbed layers 297 299—302
Steric interactions (polymers) in polymer melts 298
Steric interactions (polymers) in poor solvents 299 302
Steric interactions (polymers), attractive 299
Steric interactions (polymers), effect of coverage 294 299—302
Steric interactions (polymers), effect of molecular weight 296 299—302
Steric interactions (polymers), effect of solvent 298—302
Steric interactions (polymers), effect of temperature 299—302
Steric interactions (polymers), hysteresis effects in 297 299
Steric interactions (polymers), intersegment forces 299
Steric interactions (polymers), non-equilibrium aspects of 303—304
Steric interactions (polymers), range of 298 302
Steric interactions (polymers), repulsive 109
Steric interactions (polymers), scaling 299 302
Steric interactions (polymers), time effects in 297 303—304
Steric stabilization 294 310—311
Stern layer 214 222
Stern layer, effect on DLVO forces 221—223 252—253
Stern layer, potential 222—223
Strength of bonds 32
Strength of different forces, compared 76 127—128
Stress distribution in adhesive contact 328
Structural force 17 56—57
Structure of liquids 17 117—119 203 270—272
Structure of surfaces 203 323
Structured surfaces 203 287 323
Surface energy 65 144—145 163 179 201—204 258 267 312—317
Surface energy in adhesion 163 178—179 270 313
Surface energy of clusters 317—318 336
Surface energy of curved surface 270 317 333 336
Surface energy of metals 204 264 313 318.
Surface energy of small droplets 317—318 336
| Surface energy of transfer 317
Surface energy, theoretical aspects 163 179 201—204 258 267 313 317—319
Surface forces apparatus (SFA) 169
Surface lattice of charges, dipoles, forces between 254—256
Surface roughness, dynamic 273 288
Surface roughness, effect on forces 273
Surface roughness, static 273 288
Surface structure 203
Surface structure, effect on forces 205 273
Surface tension 8 131 201—204 258 312—313
Surface tension, values for 315
Surface, amphoteric 236—238 280
Surface, charge 213—215 233—238 255—258
Surface, charge density 217 219 239
Surface, charge regulation 230 235—236
Surface, charges, discrete 254—256
Surface, dipoles, discrete 254—256
Surface, hydrophilic 133 276
Surface, hydrophobic 133 282 320
Surface, melting at 319
Surface, potential 233—236 239—240
Surface, roughness 260 263 288 333
Surface, structured 203 255 287 323
Surfaces used in force measurements 14 173
Surfactant see “Amphiphilic molecules”
susceptibility 74
Swelling 253
Swelling, bilayer 226—227
Swelling, clay 226—227
Temperature, chain melting 378
Temperature, effect on forces 61—64 285 404
Temperature, theta 291
Thermal energy 24—27
Thermal fluctuation forces see “Fluctuation forces”
Thermodynamic equilibrium 16 150 163 212 231 244
Theta solvent 291
Theta temperature 291
Three-body forces 107
Tip-surface interaction 14
Transition temperature of chains 378
Trivalent ions, adsorption of 237
Trouton’s rule 26 30 115
Twist angle between two surfaces 205
Two dimensions, equations of state 29 91
Two dimensions, interactions in 65—66
Two dimensions, phase transitions 29 66
Undulation force 307—309 403—407
Unification of forces 75—76
Van der Waals force 8 29 76 94 225 228 246
van der Waals force at small separations 267—268
van der Waals force between atoms, and molecules 93—96 128 196
van der Waals force between bilayers and membranes 199 212 225 395—396
van der Waals force between hydrocarbons 88—89 201—204 395—396
van der Waals force between macroscopic bodies 169 177
van der Waals force between metals 185 201—204
van der Waals force in adhesion 178—179 201—204
van der Waals force in relation to other interactions 128
van der Waals force in salt solutions 199 395—396
van der Waals force of alkanes 88—89
van der Waals force of chain molecules 88—89
van der Waals force, across thin films 192—194 202
van der Waals force, additivity of 89 106 177—179 202
van der Waals force, calculation 86—87 95 180—182
van der Waals force, contribution to surface energy 178—179 201—204
van der Waals force, dispersion contribution 83—89 93 128
van der Waals force, effect of adsorbed films 206
van der Waals force, effect of medium 99—102 180—182 188—192
van der Waals force, Lifshitz theory of 179—192
van der Waals force, measurement 169 186—191 197—199 207—209 396
van der Waals force, origin 84
van der Waals force, potential 62
van der Waals force, repulsive 192—198
van der Waals force, retardation of 106 108 194 196—198 208 396
van der Waals force, screening of 199 396
van der Waals force, simple expression for 85 94 101 177 395—396
van der Waals force, strength of 85—87 94 128 178—179
van der Waals force, theories of 85 96 179
van der Waals, bond energy 88 104
van der Waals, dispersion force 83—89
van der Waals, equation of state 8 23—24 66 90 112
van der Waals, gas 8 23
van der Waals, liquid 85—86
van der Waals, radius 109—112
van der Waals, self-energy 50 103—105
Van der Waals, solid 85—86
Vapour pressure 26—27 194—195 229 331
Vesicle 344 361 378—379 382—385
Vesicle, adhesion of 172 414—416
Vesicle, critical aggregation concentration 364
Vesicle, deformation 416
Vesicle, dimensions 379 344
Vesicle, forces between 172 417
Vesicle, fusion 415—417
Vesicle, interactions 414—416
Vesicle, size 379—385
Vesicle, size distribution 384—385
Vesicle, theoretical aspects 378—379 382—385
Viscosity, effect on forces 47
Water see “Hydration forces”
Water as solvent 52—53 65
Water at surfaces 217—218
Water, adsorbed films 256—257
Water, bound lifetime 55—56
Water, dielectric constant 82 123
Water, effect on adhesion 271
Water, hydrogen bonds in 59—60 286
Water, Lennard-Jones potential for 126
Water, models for 125—126
Water, orientation effects 64
Water, proton mobility in 123 286
Water, rotational correlation time 56
Water, small clusters of 319
Water, solubility 22—23 65 103
Water, special interactions of 59—60 64 122—125 281—286
Water, special properties of 59 79 82 94 96 103 116 122—125 135—136 275
Water, structure 129—131 135 217
Water, “ST2” model 126
Weak overlap approximation 242
Wetting see “Adsorbed liquid film”
Wetting, critical point 151
Wetting, films 149—151 192—194 198 210 229 257 281 319 322
Work of adhesion 313
Work of cohesion 313
Young equation 150 321
Young — Dupre equation 150 321
Zwitterion 48 52 342—344
Zwitterion, interactions of 256 277 402 404
“Pull-off” force see “Adhesion force”
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