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Авторизация |
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Israelachvili J.N. — Intermolecular and surface forces |
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Предметный указатель |
Ion hydration, computer simulations 220 239 281
Ion hydration, number 55
Ion hydration, shell 55
Ion in thin films 220
Ion, adsorption 235 400—401
Ion, binding 33 213—215 243 280 400—401 410
Ion, concentration at surface 218—220 233
Ion, distribution, near a surface 218—221 231—233 239—240
Ion, exchange 214 400—401
Ion, forces between 33 36 121
Ion, hydration 42—44 56 280 400—401
Ion, size 40—41 47 110
Ion, solubility 38—42 47 65
Ion, solvation 37 42—44
Ion-correlation force 228 397
Ion-dipole interaction 50—57
Ion-solvent interactions 42—44 54—57 73—74
Ion-water interaction 37 42—44 54—57 73—74
ionic bond 33—36 44 46 410
Ionic crystal lattice 35—36 46 142
Ionic forces 33—36 410
Ionization potential 84
Irreversibility 324 (see also “Hysteresis”)
Isoelectric point 237 280
Johnson — Kendall — Roberts (JKR) theory 326
Keesom equation (in 2-D) 65
Keesom interaction 62 65 75—76 94—95 182 256
Keesom orientation force see “Keesom interaction”
Kelvin equation 331
Kelvin radius 331
kinetic energy 24—27
Kinetic stability 155
Langbein approximation 159
Langmuir equation 229
Laplace pressure, equation 195 331
Latent heat 25—27 86—87 115
Latent heat of alkanes 89
Latent heat of van der Waals solids 86—87
Lattice of charges 35—36 254—256
Lattice, dipolar 254—256
Lattice, energy 36
Lattice, ionic 35—36
Lattice, mismatch 205—206
Lattice, solid 117
Lattice, sum 35—36 254—256
Lecithin see “Phosphatidylcholine”
Lennard-Jones potential 9 14 44 46 113 175
Lifshitz equation 181 197
Lifshitz theory 179—192 (see also “Hamaker constant”)
Lifshitz theory, limitations of 209 267
Ligand-receptor interaction 411—412
Lipid 342—343 387
Lipid chains 382
Lipid chains, fluidity of 383 387
Lipid packing, biological regulation of 392
Lipid pores 394
Lipid, biological 387
Lipid, compatibility of 387
Lipid, density 413
Lipid, packing of 387
Lipid-protein interaction 388—391
Lipid-protein interaction, phase separation 413
Liposome 363 344
Liquid crystals 121 287
Liquid helium films 192—194
Liquid, associated 26 59 125—127 268
Liquid, boiling point 115—116
Liquid, computer simulations 117
Liquid, density, near surface 261—264
Liquid, freezing 117
Liquid, melting 115—18
Liquid, miscibility 22—23
Liquid, order in 117—118 121
Liquid, structure 117—119 272
Liquid, structure at surfaces 47 272—275
Lock and key binding 411—412
London dispersion interaction 90 182
London equation 85 88 99 101 104 108 113
Long-range interaction (force) 5—8 11—12 30 37 62 152—155 409
Long-range order 30 117—118
Lorenz — Lorentz equation 79 102
Lyotropic series 280
Lysolipids 342
Madelung constant 36
Magnetic force 5
Many-body effects 16—19 207
Mass action, law of 235
McLachlan equation 96
Measurements of intersurface forces 165—174
Medium effect see “Solvent effect”
Melting 30 115—116
Melting at a surface 319
Melting of alkanes 378
Melting of lipid chains 378
Membrane see “Bilayer” “Biological
Membrane, adhesion 414
Membrane, fusion 416 419
Membrane, pores in 394
Membrane, structure 392
Meniscus forces 331—333
Mesophase 362
Metal oxide surface 173
Metal surface 204—206 264
Metallic bonds 31—32 205
Micelle 344 346 354 371—372
Micelle, aggregation number 372—373
Micelle, cylindrical 374
Micelle, dimensions 372—373
Micelle, disc-like 349
Micelle, effect of temperature 380
Micelle, end-effects 374
Micelle, inverted 379 392 420
Micelle, ionic effects 412
Micelle, molecular packing in 372
Micelle, polydispersity 361 373—374
Micelle, pseudo-phase approximation 365
Micelle, rod-like 349 358—359 374
Micelle, size distribution 358—362 374
Micelle, size regulation 412
Micelle, spherical 349 373
Micelle, structure 372
Micelle, theoretical aspects 371
Microemulsion 380 382 412
Mie potential 8 266
Miscibility 102—103 142 196
Molecular aggregates 361 (see also “Aggregates”)
Molecular dynamics simulation 45 92
Molecular packing 93 115
Molecular packing in thin films 121
Molecular polarizability 77
Molecular shape 105 115 370 381
Molecular size 23 110
Molecular theories 43—46
Monolayer 91—92 65—66
Monte Carlo simulation 45 220—221 292
Multi-bilayers see “Multilayer”
Multilayer 362—363
Negative adsorption 147—148
Nernst equation 21
Non-additive potentials 84 107
Non-aqueous colloids 211
Non-aqueous liquids, forces in 402
Non-DLVO forces 228 253 260
Non-equilibrium interactions 297 299 303—304 322—325 329
Nonwetting 149—151 196—198
Olber’s paradox 14
Optimal headgroup area 367—369
Order in liquids 17 92 117—119 121
Order, long range 117—118 121 227
Ordering of molecules 92
| Ordering of molecules at surfaces 17 261—263 272—275
Ordering of molecules in thin films 261—263 275 287
Orientation force 76 94 107
Orientation-dependent interaction 60—61 64 105
Orientation-dependent interaction, dispersion force 62 105
Orientation-dependent interaction, polar molecules 60—62
Oscillatory force 118—119 121 265—266 272 278—279 284
Oscillatory force, effect of dipole moment 273
Oscillatory force, effect of liquid 261—263 275 287
Oscillatory force, effect of surfaces 273 287
Oscillatory force, potential of mean force 118—119 121
Oscillatory force, properties of 269—275
Osmotic forces 288 304
Osmotic pressure limit 230 244 306
Osmotic pressure of ions 242
Outer Helmholz plane 222 253
Overlap force 288 294 299 405—407
Oxonium ion 56
Packing of molecules 109—112 115—116 380—382
Packing, constraints for amphiphiles 370 381
Packing, mismatch effects 116
Packing, parameter 381
Pair correlation function 119
Pair potential see “Intermolecular pair potential”
Partial wetting 149—151
Particle radius (size), effect on adhesion 143
Particle-surface interactions 14 147
Partitioning of ions 38 103
Partitioning of molecules 103 104
Pauli exclusion principle 29
periodic structure 362 392
Peristaltic force 307—309 405—407
Phase diagrams in relation to forces 120
Phase diagrams of hydrophobic substances 136
Phase separation 353
Phase separation of polymers 196
Phase separation, lipid-protein 413
Phase transitions 65—66 93 353
Phase transitions in monolayers 65—66
Phase transitions, gas-liquid 65—66 91—93
Phase transitions, liquid-solid 92
Phase transitions, order-disorder 91—92
Phosphatidylcholine 342—343
Phospholipid 342—343 387
Phospholipid, structure 344
Physical bond 32 46
Point of zero charge 237
Poisson equation 215
Poisson — Boltzmann equation 215—216 219 222
Poisson — Boltzmann equation, limitations of 227—229
Polar molecule 48—49
Polar molecule, interactions of 50—64 93—95
Polar molecule, polarizability of 70
Polar molecule, self-energy 50
Polar molecule, solubility 40 65
Polarizability in medium 76—78 96 99
Polarizability of bonds 69
Polarizability, atomic and molecular 67—71 79—81 96—98
Polarizability, electronic 67—69
Polarizability, excess 76—78 99
Polarizability, molecular 69—70 76—81
Polarizability, negative 77—78
Polarizability, orientational 70
Polarizability, oscillator model 97
Polarizability, values for 69
Polarization force 27 75—76
Polydispersity in micelle distribution 358—362
Polydispersity, effect on forces 272
Polymer 290 (see also “Steric interactions”)
Polymer, abbreviations for 290
Polymer, adsorption 291 293
Polymer, bridging 291
Polymer, brush 291—292
Polymer, coverage 292—293
Polymer, grafted 291—292
Polymer, immiscibility 196
Polymer, interactions see “Steric interactions”
Polymer, loop 291
Polymer, melt 290 298
Polymer, mushroom 291—292
Polymer, random coil 289—291
Polymer, surface layer 172
Polymer, tail 291
Polymer, train 291
Polymer-covered surfaces 292
Potential distribution theorem 60
Potential function 6—10 16—19 109 113 153
Potential function between ions 121
Potential function in liquids 16—19 119
Potential function, exponential 109
Potential function, hard sphere 109
Potential function, Lennard-Jones 9 175
Potential function, power-law 109
Potential function, repulsive 175
Potential of mean force see “Intermolecular pair potential”
Potential of Stern — Helmholz layer 223
Pressure between charged surfaces in solution 221—223
Pressure between ions in solution 221—223
Pressure distribution in adhesive contact 328
Pressure, disjoining 192 229
Pressure, Laplace 195—331
Pressure, osmotic limit 230 244 306
Primary minimum 247—248
Protein 172 389
Protein in biological membranes 389 392 413
Protein, aggregation 388 413
Protein, interactions 389 413
Protein, structure 391
Proton hopping in ice, water, etc. 123 286
Protrusion of molecules, decay length 264 305—307
Protrusion of molecules, energy 263
Protrusion of molecules, force 304—307 405—407
Quantum mechanical interaction 11
Quantum theory 11
Quartz surface see “Silica surface”
Radial distribution function 19 117
Radius of gyration 289
Radius of ions 40—41 55 109—112
Radius, anion 40—41 55 110
Radius, atom 109—112
Radius, bare ion 40—42 47 55 110
Radius, calculations of 23 112
Radius, cation 40—41 55 110
Radius, covalent bond 110
Radius, Flory 289
Radius, hard sphere 109—112
Radius, hydrated, of ions 42 55 109—112
Radius, Kelvin 331
Radius, micelle 379
Radius, molecule 23 109—112
Radius, packing 109—112
Radius, van der Waals 109—112
Radius, vesicle 379
Random close packing 120
Random coil 289—291
Range of forces 5—8 11—12 36—37 62 152—155 160 174 321
Raoult’s Law 103
Rate of exchange see “Exchange rate”
Rayleigh limit 46
Reaction field 72
Reference state 36 54
Reflected field 72 180
Refractive index in relation to polarizability 79—81
Regulation of hydration forces 279
Regulation of surface charge 230 235—236
Relative strength of different interactions 76
Repeptization 253
Reptation 92
Repulsive force 145 175 192—194 241 256
Repulsive force between polymers 196
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