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| Àâòîðèçàöèÿ |
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| Ïîèñê ïî óêàçàòåëÿì |
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| Israelachvili J.N. — Intermolecular and surface forces |
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| Ïðåäìåòíûé óêàçàòåëü |
Double-layer interaction 223 241 401
Double-layer interaction at constant change 244—246 257
Double-layer interaction at constant potential 242—246
Double-layer interaction between bilayers and membranes 225—226 257 396 401
Double-layer interaction between planar surfaces 221—226 245—246 257
Double-layer interaction in thin films 229
Double-layer interaction, charge regulation in 230 244—246 401
Double-layer interaction, computed values for 245—246
Double-layer interaction, expressions for 242—244 257
Double-layer interaction, measurement 225—226 250—253 257 274 397 401
Double-layer interaction, theory 223—225 241—242
Double-layer, effect on surface energy 258
Double-layer, thickness of 238
Droplet, surface energy of 317—318 336
Droplet, water 319
Dupre equation 314
Effective area of interaction 143 159 175
Elasticity of membranes 308—309 382—385
Elasticity of surface 175
Electric Dipole see “Dipole”
Electric double-layer see “Double-layer”
Electric field of charge 33—35
Electric field of dipole 74
Electric field, image 72 180
Electric field, near a surface 34—35 47 217—220 239
Electric field, reflected 72
Electric field, screened 37 199
Electric field, strength 33—35 217—218
Electric potential 21 34—35
Electric potential at surface 220
Electrolyte, asymmetrical 239
Electrolyte, symmetrical 239
Electromagnetic force 3—5 11
Electroneutrality 34 217 222
Electronic polarizability 67—70 74
Electrostatic energy 37 43—44
Electrostatic interaction 11 27 223 421
Electrostatic interaction between ions in solution 221—223
Electrostatic interaction between surfaces in water 221—226
Electrostatic interaction, range 36—37
Electrostatic potential see “Electric potential”
Energy of bonds 19 32
Energy, adhesion see “Work of adhesion”
Energy, Born 37—38 42—44 63—64
Energy, crystal lattice 36 46
Energy, dissipation in adhesion 323 329
Energy, self 18 103—105
Energy, surface see “Surface energy”
Energy, thermal 24—27
Engulfing 147—148 183
Entropic effects 63—64
Entropic effects in interactions 129 259 421
Entropic interactions 223 265 282 288 302—304 405—408
entropy 20 63
Entropy of association 133
Entropy of confinement 20
Entropy of dilution 20
Entropy of mixing 20
Entropy, configurational 20
Entropy, effects 63—64
Entropy, excluded volume 23—24
Entropy, role in interactions 63—64 129 259 421
Equation of state, two dimensional 29 65—66 91
Equation of state, Van der Waals 8 23—24 90—91 112 368
Equation, Boltzmann distribution 20—22
Equation, Casimir — Polder 108
Equation, Clausius — Mossotti 79 82 102 123
Equation, Coulomb law 32—39
Equation, Debye — Hueckel 239
Equation, Debye — Langevin 70 79 82 97 123
Equation, Derjaguin approximation 161—164
Equation, Dupre 314
Equation, Gibbs — Helmholtz 62
Equation, Grahame 234
Equation, Guoy — Chapman 239
Equation, Kelvin 331
Equation, Langmuir 229
Equation, Laplace 195 331
Equation, Lennard-Jones potential 9 14 44 46 175
Equation, Lifshitz 181 197
Equation, London 85 88 99 101 104 108 113—114
Equation, Lorentz — Lorentz 79 102
Equation, McLachlan 96
Equation, Mie potential 8
Equation, Nernst 21
Equation, Poisson 215
Equation, Poisson — Boltzmann 215 219 222
Equation, Schroedinger 11
Equation, Young 150 321
Equation, Young — Dupre 150 321
Equilibrium 20—21 153
Excess polarizability 77 99 181
exchange interaction 29 109
Exchange rate of lipids 346 375—377
Exchange rate of water 55—56
Excluded area 91
Excluded volume 23—24 90—93
Falling bodies 13
Fermi length 205
Field see “Electric field”
Field of charge 33—36
Field of dipole 74
film see “Adsorbed film”
First-hydration shell 61
Flip-flop 376 377
Flocculation see “Coagulation”
Flock, particle density in 120
Flory radius 289
Fluctuation forces 276 288 304 405—408
Fluidity 387
Fluidity of hydrocarbon chains 404
Fluidity of micelles 383
Fluidity of vesicles 383
Fluidity, effect on forces 404
force see “Interaction” “Intermolecular
Force in relation to energy 161—164
Force measuring techniques 165—174
Force measuring techniques, atomic force microscopy (AFM) 14—15 173
Force measuring techniques, compression (pressure) cell 168
Force measuring techniques, direct methods 14—15 168—169
Force measuring techniques, dynamic interactions 172
Force measuring techniques, indirect methods 165
Force measuring techniques, mica" experiments 169—173
Force measuring techniques, osmotic pressure (OP) 168 226
Force measuring techniques, surface forces apparatus (SFA) 15 169—172
Force measuring techniques, total internal reflection microscopy (TIRM) 172—173
Force, definition 5—6
Force, interdependence of different types 155 412
Force, range 5—8 11—12 152—154
Forces, measurements of 14—15 165—174
Forces, measurements of, adhesion 14—15 166—168 172 397
Forces, measurements of, capillary 172
Forces, measurements of, colloidal 167 172—175
Forces, measurements of, DLVO 172 250—253 397
Forces, measurements of, double-layer 250—253 397 401
Forces, measurements of, entropic 172 407
Forces, measurements of, fluctuation 407
Forces, measurements of, hydration 172 275—282 401 407
Forces, measurements of, hydrophobic 282—286 409
Forces, measurements of, ion-correlation 172 397
Forces, measurements of, osmotic 407
Forces, measurements of, undulation 403 407
Forces, measurements of, van der Waals 114 169 172 197
Fusion 416—419
Fusion of bilayers 409
Fusion of biological membranes 416—419
Fusion of vesicles 415
Fusion, mechanism 418
Fusion, pathways 418
Gas, equations of state 8 23—24 90—91 112 368
| Gas, PVT data 8 23—24
Gas-liquid transition 23—26 29
Gauss’ law 35
Geometry of amphiphiles, effect on micellar structure 370 381
Geometry of molecules, effect on interaction potentials 117—119 270—272
Geometry of molecules, effect on melting and boiling points 115—116
Geometry of particles, effect on forces 159
Gibbs — Helmholtz equation 62
Glass surface see “Silica surface”
Grahame equation 234
Grain boundaries 93
Gravitational force 3—7 13—14 21 145 152 192—194 209
Guoy — Chapman equation 239
Guoy — Chapman theory 239
Hamaker constant 176—180 189 192 212 267 395
Hamaker constant for metals 185 204—206
Hamaker constant for polymers 196
Hamaker constant, based on addivity 178 188 202—203
Hamaker constant, based on Lifshitz theory 184—188 192 197
Hamaker constant, effect of medium 188—192 396
Hamaker constant, expressions for 183—185 188 200 203—204 396
Hamaker constant, measurement 186—187 190—191 197 396
Hamaker constant, negative 190—196
Hamaker constant, nonretarded 181—182 186—187 190—191 197
Hamaker constant, retardation of 196—198 208
Hamaker constant, screening of 199 396
Hamaker constant, values 178 186—191 396
Hard core repulsion 109—114
Head-groups of amphiphiles 342—343
Head-groups, area of 367—369 380 412
Head-groups, forces between 311 369 382 405—407 420
Helium films 192—194
Hellman — Feynman theorem 11
Helmholtz layer 214 222
Hertz theory 328
History of intermolecular forces 3—13
Hydrated ions 55 65 121
Hydrated radius 55 121
Hydrated sizes of ions 42 55 121
Hydration force 56 57 121 226—227 230 256 261 276—281 403
Hydration force between bilayers and membranes 225—226 276 399—402
Hydration force between colloidal particles 275—282
Hydration force in clays 276 279
Hydration force, addivity of 281
Hydration force, attractive 282
Hydration force, intrinsic 401
Hydration force, limitation of 402—405
Hydration force, measurements 276—279 401
Hydration force, origin of 281—282 285—286
Hydration force, regulation of 279—281 400—401
Hydration force, repulsive 275—279
Hydration force, theoretical aspects 281—282 285—286 402
Hydration of ions 42—44 54—57 61 121 281
Hydration of ions, computer simulations 121 281
Hydration of ions, number 55
Hydration of ions, shell 55—57
Hydrocarbon-water interface 22—23 131—133 316
Hydrocarbons, cohesive energy 88—89
Hydrocarbons, melting and boiling points 115—116
Hydrocarbons, solubility 22—23 129—133
Hydrogen bond 59 60 116 122—125 128 132 135 142
Hydrogen bond in water 59—60 286
Hydrogen bond, directionality 124—128
Hydrogen bond, examples 124 128
Hydrogen bond, models of 126
Hydrogen bond, origin 59—60
Hydrogen bond, properties 125—128
Hydrogen bond, strength 125 128
Hydrogen bond, structure 286
Hydrogen-bonding liquids 59—60 125—127
Hydronium ion 56
Hydrophiolic 54 133
Hydrophiolic, group 133 136
Hydrophiolic, interaction 133 135
Hydrophiolic, surface 133—134 276
Hydrophobic force 131—133 196 282—286 398
Hydrophobic force between bilayers 408—409
Hydrophobic force, entropic contribution to 133
Hydrophobic force, examples of 284
Hydrophobic force, measurements 282—286 409
Hydrophobic force, origins 284
Hydrophobic, bond 132
Hydrophobic, effect 96 103 128—131 283
Hydrophobic, energy 131 354
Hydrophobic, group 129 133—136 282—283
Hydrophobic, interaction 96 103 132—133 136 282—286 367 408—409
Hydrophobic, solvation 129
Hydrophobic, surface 133—134 282 320 409
Hydrophobicity 22—23 122 128—133 283
Hygroscopic group see “Hydrophilic group”
Hysteresis in adhesion 322 323 329
Hysteresis in contact angle 322
Hysteresis in DLVO forces 303
Hysteresis in polymer forces 297
Ice, dielectric constant 82 123
Ice, hydrogen-bonds in 124
Ice, lattice 124
Ice, properties 82 122—123
Ice, proton mobility in 123
Ideal gas 8
Ideal mixing 20—22
Image, charge 180—181
Image, electrostatic 180
Image, field 72 180
Image, force 180—181 256
Immiscibility 22—23 96 102—103 129—131 196
Immiscibility of polymers 142
Incommensurate surfaces 205—206
induced dipole 67 70 84
Induced dipole, force 75 84
Induced dipole, moment 67—73
Induction force 75—76 94 107
Instabilities 14—15 46 175 210
Interaction see “Force” “Intermolecular
Interaction of polar molecules 57—58 93—95
Interaction, area of 143
Interaction, classification 11—12 27—29
Interaction, definition 12
Interaction, effect of particle geometry 155—163
Interaction, range of 5—8 11—12
Interaction, relative strengths of 76 94—95
Interdependence of forces 155 412
INTERFACE 92
Interface, liquid-liquid 22—23 313 321 324
Interface, liquid-vapour 313
Interface, solid-liquid 92 313 321 324
Interface, solid-solid 93
Interfacial energy (tension) 22—23 65 131 144—145 267 313—315 350 367
Interfacial energy (tension), effect of micelles 365
Interfacial energy (tension), values for 315
Interfacial tension 131 314
Intermolecular pair potential 5 11 16—19 28 112—115 121 118—119 139 154 266
Intermolecular pair potential in liquid 16—19 118—119 121 154 266 276 284 405—407
Intermolecular pair potential, angle-averaged 60 66 74
Intermolecular pair potential, exponential 112
Intermolecular pair potential, Lennard-Jones 9 14 113—114
Intermolecular pair potential, Mie 8
Intermolecular pair potential, power law 112
Intermolecular pair potential, summation of 6 203
Interparticle potentials 154 161—164 177 405
Interparticle potentials, attractive hydrophobic 284
Interparticle potentials, cylinders 163—165 174 177 337
Interparticle potentials, effect of particle geometry 155 161 165 177
Interparticle potentials, fluctuation 405—407
Interparticle potentials, oscillatory 266
Interparticle potentials, repulsive hydration 276
Interparticle potentials, sphere-sphere 157—159 161—164 177 242—244 257
Interparticle potentials, sphere-surface 157—158 161—164 177 242—244 257
Inverted micellar structures 379 392 420
Ion hydration 37 42—44 54—57 61 281 400—401
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