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Sidgwick N.V. — The electronic theory of valency
Sidgwick N.V. — The electronic theory of valency



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Название: The electronic theory of valency

Автор: Sidgwick N.V.

Аннотация:

This book aims at giving a general account of the principles of valency and molecular constitlltion, founded on tI1e Rutherforcl-Bohr atom. In dev'eloping the theory of valency there are two courses open to the chemist. He may use symbols ,with no definite physical connotation to express the reacti,rity of the atoms in a molecule, and may leave it to the subseqtlent progress of science to discover what realities these symbols represent: or he may adopt the concepts of atomic physics-electrons, nuclei, and orbits-and try to explain the chemical facts in terms of these. But if he takes the latter course, as is done in this book, he must accept the physical conclusions in full, and must not assign to these entities properties which the physicists have found them not to possess: he must not use the terminology of pl1ysics unless he is prepared to recognize its laws. I have endeavoured to conform to this principle, and not to lay mysetf open to the reproach of an eminent physicist, that when chemists talk about electrons they tlSe a different lang'uage from physicists. I have been careful to avoid as far as possible the introduction of any physical llypotllcses wllich are not already sanctioned by those who are best qualified to judge of them.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 1st edition

Год издания: 1929

Количество страниц: 310

Добавлена в каталог: 30.08.2009

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Предметный указатель
Transitional elements, paramagnetism of      41 212
Transitional elements, stereochemistry of      223
Transitional triads (Group VIII)      295
Transitional triads (Group VIII), effective atomic numbers of      166
Transitional triads (Group VIII), peculiarities of      82
Traube, I.      124 125
Triads, transitional      see "Transitional triads"
Tricovalent atoms, stereochemistry of      228
Trouton, F.T.      87
Tschugaeff, L.      233 247 248 249 250
Tungsten      288
Turner, E.E.      225
Turner, W.E.S.      132
Typical elements, resemblance to A and B subgroups      78
Uhlenbeck, G.E.      34
Ullmann, G.      135
Unsoeld, A.      34
Uranium      288
v. Halban, H.      96
v. Helmholtz, H.      1
v. Laue, M.      90
v. Wartenberg, H.      90
Valency and the periodic table      51 Chapter 74
Valency groups, limits of      62
Valency groups, pure and mixed      170
Valency groups, size of, and the parachor      129
Valency groups, stable      Chapter X 163
Valency, absolute, definition of      182
Valency, Berzelius's theory of      51
Valency, changes of      177 178
Valency, chemical evidence for      52
Valency, effective      114 164
Valency, forced      178
Valency, fundamental principles of      Chapter IV 51
van den Broek, A.      7
van der Waals, J.D.      122 134
van't Hoff, J.H.      55 110 132 219 236
Vanadic acid      281
Vanadium      281
Vapour pressure , positive curves      140 142
Vapour pressure and hydration of salts      197
Vapour pressure and solubility      139
Vapour pressure, negative curves      140 143
Vernon, R.H.      231
Vieweg, E.      221
Villard, E.      187
Volatility and association      135
Volatility and co-ordination      123
Volatility and covalency      87
Volatility and structure of halides      88
Volatility and structure of hydrides      87
Volatility of nitro-compounds and nitrites      123
Volatility of tetrahalides      175
Volatility, abnormal, of boron halides      245
Wadsworth, C.      12
Wahl, W.      224
Walden, P.      134 144
Warren, E.H.      66 220
Water, action of, on halides      156—158
Water, association of      135
Water, co-ordination of polymerized      72
Water, double molecules      188 199
Weak electrolytes, condition of      93
Weighted means      132
Weinland, R.F.      255
Weiss, P., law of magnetism      212 214
Weiss, P., magneton      207 208
Welo, L.A.      215 217
Werner, A., chelate compounds      120 233 234 246
Werner, A., co-ordination number      84 165
Werner, A., co-ordination theory      52 109 114 115
Werner, A., covalency maximum in first short period      153
Werner, A., references      58 85 185 221 239 244
Werner, A., stereochemistry of transition elements      223 229
Werner, A., water of crystallization      160 187 193 199
Whittaker, H.      125
Wiechert, E.      2
Wilkins, H.      125
Wilsdon, B.H.      101
Wilson, C.T.R.      3
Winmill, T.F.      97
Wislicenus, J.      236
Wood, R.W.      23
X-rays and atomic structure      4 7
X-rays and crystal structure      90
X-rays, absorption edges      32
X-rays, spectra, origin of      32
Young, S.      135
Zeeman effect      4
Zinc      263
Zinc, stereochemistry of      226
Zirconium      274
Zirconium, hydrate of acetylacetonate of      169
1 2 3 4
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