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Sidgwick N.V. — The electronic theory of valency
Sidgwick N.V. — The electronic theory of valency



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Название: The electronic theory of valency

Автор: Sidgwick N.V.

Аннотация:

This book aims at giving a general account of the principles of valency and molecular constitlltion, founded on tI1e Rutherforcl-Bohr atom. In dev'eloping the theory of valency there are two courses open to the chemist. He may use symbols ,with no definite physical connotation to express the reacti,rity of the atoms in a molecule, and may leave it to the subseqtlent progress of science to discover what realities these symbols represent: or he may adopt the concepts of atomic physics-electrons, nuclei, and orbits-and try to explain the chemical facts in terms of these. But if he takes the latter course, as is done in this book, he must accept the physical conclusions in full, and must not assign to these entities properties which the physicists have found them not to possess: he must not use the terminology of pl1ysics unless he is prepared to recognize its laws. I have endeavoured to conform to this principle, and not to lay mysetf open to the reproach of an eminent physicist, that when chemists talk about electrons they tlSe a different lang'uage from physicists. I have been careful to avoid as far as possible the introduction of any physical llypotllcses wllich are not already sanctioned by those who are best qualified to judge of them.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 1st edition

Год издания: 1929

Количество страниц: 310

Добавлена в каталог: 30.08.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Nuclear atom, importance of charge      6 8
Nuclear atom, Rutherford's      5
Nucleus, charge of, effect on orbits      38 40
Nucleus, intensity of magnetic field near      204
Nucleus, structure of      12
Number, atomic, and nuclear atom      Chapter I 1
Octet, formation of      173
Octet, fully shared, stability of      175
Octet, fully shared, state of      101
Octet, mixed      173 276
Octet, theory of Langmuir      62
Octet, theory of Lewis      62
Odd covalencies      161
Odd molecules      178
Odd molecules, paramagnetism of      211
Oersted, H.C.      204
One-electron covalencies      102
One-electron covalencies and parachor      131
Onnes, H.K.      211
optical spectra      36
Orbits, electronic, dimensions of, for hydrogen      20
Orbits, electronic, influence of nuclear charge on      38 40
Orbits, electronic, magnetic moment of      205 207
Orbits, electronic, of shared electrons      98 100
Orbits, electronic, precession of      25
Orbits, electronic, types of      26 27
Ortho-substituted phenols, chelate structure of      147
Osmium      296
Osmium tetroxide      296 297
Osmium tetroxide and covalency rule      160
Osmium tetroxide, parachor and structure of      128
Ostwald, W.      85
Oxalate ion, hydration of      195
Oxalato-compounds      239
Oximes, stereochemistry of      221
Oxonium compounds      66 283
Oxygen      283
Oxygen, comparison with sulphur      284
Oxygen, paramagnetism of      211
Oxygen, stereochemistry of      222
Palladium      298
Palladium, structure of      47
Paneth, F.      87
Parachor      124
Parachor and molecular volume      124
Parachor and size of valency group      129
Parachor and surface tension      125
Parachor and the co-ordinate link      127
Parachor and the one-electron link      131
Parachor of antimony pentachloride      130
Parachor of osmium tetroxide      128
Parachor of phosphorus pentachloride      130
Parachor of sulphur trioxide      129
Parachor, values of, for elements      126
Paraffins, hydrates of      187
Paraffins, minute solvent power of      150
Paramagnetism and effective atomic number      215
Paramagnetism and imperfect electronic groups      213
Paramagnetism and molecular structure      216
Paramagnetism of complex ions      214
Paramagnetism of gases      211
Paramagnetism of nitric oxide      211
Paramagnetism of odd molecules      211
Paramagnetism of oxygen      211
Paramagnetism of rare earth metals      43 213
Paramagnetism of simple ions      211
Paramagnetism of transitional elements      41 212
Pascal, M.P.      206
Paschen series of hydrogen      21
Paschen, F.      23 34 37
Pauli, W.      208
Peachey, S.J.      219 226 227
Perhalides      292
Periodic classification and the Bohr theory      Chapter III 25
Periodic groups      Chapter XV 256
Periodic table and atomic structure      29 40
Periodic table and covalency      104
Periodic table and valency      Chapter V 74
Periodic table, Bohr's form of (diagram)      39
Periodic table, development of (Bury)      29
Periodic table, distribution of ions in      77 104
Periodic table, Mendeleeff's form modified (diagram)      75
Permanganates      294
Perrin, J.      2
Pfeiffer, P.      198
Phenols, ortho-substituted, chelate structure of      147
Phillips, H.      228 229
Phipps, T.E.      210
Phosphorus atom, structure of, in compounds      173
Phosphorus, pentachloride, parachor      130
Phosphorus, stereochemistry of      225
Piccard, A.      211
Pickering      22 23
Pickering series of ionized helium      22
Planck, M., theory of quanta      15 16 18 19
Plane symmetry of 4-covalent atoms, cobalt (supposed)      230
Plane symmetry of 4-covalent atoms, platinum      229
Plane symmetry of 4-covalent atoms, tellurium      231
Platinammines, effective atomic number      165
Platinammines, ionization      111
Platinum      298
Plato, W.      223
Poincare, H.      15
Polar links      52
Polar links, Kossel's theory of      54
Polynuclear co-ordination compounds      244
Pope, W.J.      219 226 227 228 248
Positive electrons or protons      6
Positive vapour pressure curves      140 142
Precession of orbits of electrons      25 26
Precession of orbits of shared electrons      100
Price, T.S.      252
Proton, definition of      6
Proton, dimensions of      9
Pure and mixed valency groups      170
Quantum number of shared electrons      100 164
Quantum number, azimuthal and radial      25
Quantum number, third      34
Quantum theory, Bohr's application to atom      17
Quantum theory, evidence for      15
Quantum theory, Planck's theory      16
Quinones, stability of      250 note
Radial and azimuthal quantum numbers      25
Radioactive displacement law      7
Ramsay, W.      1 114 135
Raper, R.      225
Rare earth metals      266
Rare earth metals, colour of      43
Rare earth metals, paramagnetism of      43 213
Rare earth metals, structure of      43
Rayleigh, Lord      1
Rays, atomic, magnetic moment of      208
Reed, J.B.      125
Reihlen, H.      230
Residual rays or Reststrahlen      90
Rhodium      297
Richards, T.W.      12
Richardson, O.W.      34
Riesenmolekuele      90
Rings, chelate, 4-membered      243
Rings, chelate, 5-membered      245
Rings, chelate, 6-membered      247
Rings, chelate, 6-membered, with two double links      248
Rings, chelate, 7- and 8-membered      251
Rings, chelate, stability of, and size of atoms      239
Rings, chelate, types of      239
Ritz, W., combination principle      20
Rodebush, W.H.      98
Roentgen, W.C.      1
Rosenbohm, E.      215
Rosenheim, A.      223
Rotation of doubly linked atoms      99
Rubens, H., Reststrahlen      90
Ruehle, C.      130
Russell, A.S., radioactive displacement law      7
Ruthenium      296
Ruthenium, tetroxide and covalency rule      160
Rutherford, E., nuclear atom      5 6 14
Rydberg, J.R., atomic numbers of inert gases      28
Rydberg, J.R., constant      21
Rydberg, J.R., spectral series      22
Salicylic acid, structure of derivatives of      242
Scandium      266
Scandium, structure of      40
Scattering of rays by atoms      5
Scheibler, H.      180
Schlenk, W.      154 260
Schoenmaker, P.      130
Schultz, G.      234
Selenium      285
Selenium, covalency maximum      156 158
Selenium, stereochemistry      227
Semi-polar link      60 71
Seven-membered rings      251
Shared electrons,distinction of, in formulae      164
Shared electrons,Lewis's theory of      56
Shared electrons,orbits of      98
Shared electrons,precession of orbits of      100
Shared electrons,quantum numbers of      100 164
Sidgwick, N.V.      112 145 147 148 152 155 156 193 197
Siegbahn, M.      33
Silicofluorides      68
Silicon      272
Silicon atom, structure of, in compounds      172
Silicon, chains, hydrolysis of      159
Silicon, stereochemistry of      225
Silver      260
Silver, halides, compounds with ammonia      203
Silver, magnetic moment of, in vapour      209
Six-membered rings      247
Size of atoms      9
Size of atoms and stability of rings      239
Size of ions and hydration      197
Size of ions and lattice energy of ammoniates      202
Smedley, I.      252
Smiles, S.      227
Smith, H.G.      46
Smith, J.D. Main      34 101 178
Smits, A.      130
Soddy, F., isotopes      11
Soddy, F., radioactive displacement law      7
Sodium      259
Sodium, alkyl and aryl derivatives      260
Sodium, chelate compounds      146
Solubility      138
Solubility and association      138 144
Solubility and heat of fusion      140
Solubility and structure      89 145
Solubility and vapour pressure      139
Solubility, "natural"      141
Solubility, essential conditions of      139
Solubility, mutual, of metals      151
Solution, apparent heat of      148
Solution, evidence of solvation in      190
Solvation      Chapter XI 185
Sommer, L.A.      42 44 45 46
Sommerfeld, A., Atomic Structure      42 46
Sommerfeld, A., crystal structure and ionization      92 105 107
Sommerfeld, A., definition of valency      182
Sommerfeld, A., fine structure of hydrogen lines      23 25 34
Sommerfeld, A., inert pair of electrons      179
Sommerfeld, A., references      37 101 208
Space quantization      209
Spark spectra      36
Spectra, arc and spark      36
Spectra, displacement law      37
Spectra, hot spark      37
Spectra, multiplets in      37
Spectra, optical      36
Spectra, series of hydrogen      21
Spectra, series of ionized helium      22
Spectra, X-ray absorption      32
Spinning electron      34
Stability of atomic structures      38
Stable valency groups      Chapter X 163
Stannic chloride, ionized or covalent      92
Stark, J.      44 53
Stationary states      18
Stationary states of hydrogen atom      20
Staudinger, H.      154
Stereochemical relations      Chapter XIII 219
Stereoisomerism a proof of covalency      86
Stern and Gerlach, magnetic moments of atomic rays      209
Stern, O.      208 209
Stock, A.      103
Stoner, E.C., magnetic relations      204 215
Stoner, E.C., references      206 208 209 267
Stoner, E.C., scheme of distribution of electrons      34 46 101 178
Strain in rings      238
Strain, theory of Baeyer      236
Strong electrolytes, Debye's theory of      94
Subgroups of electrons      31
Sugden, S., parachor      124—131
Sugden, S., references      65 153 228
Sulphate ion, hydration of      195
Sulphato-compounds      239 243
Sulphonium compounds      283
Sulphur      283
Sulphur atom, structure of, in compounds      173
Sulphur, comparison with chromium      80
Sulphur, comparison with oxygen      284
Sulphur, dioxide, a pure donor      137
Sulphur, hexafluoride, valency group of      62
Sulphur, stereochemistry of      227
Sulphur, tricovalent, stereochemistry of      228
Sulphur, trioxide, parachor and structure      129
Sulphuric acid, structure      286
Surface tension and parachor      125
Tantalum      281
Taylor, J.B.      210
Taylor, T.W.J.      249 251
Telluric acid, structure      286
Tellurium      286
Tellurium, 4-covalent, plane symmetry of      231
Tetrahalides, volatility of      175
Thallium      267
Thallium, chelate compounds of      146
Thallium, inert pair of electrons in      180
Thallium, magnetic moment of, in vapour      210
Thiele, J.      250
Third quantum number      34
Thomson, J.J., atomic model      4 14 18
Thomson, J.J., dielectric constant and ionizing power      132
Thomson, J.J., the electron and valency      52
Thomson, J.J., theory of the electron      2
Tin      270
Tin, stereochemistry of      226
Tin, tetrachloride, structure of      92
Townsend, J.S.E.      3
Transference of electrons in salts      54
Transition between electrovalencies and covalencies      92
Transitional elements in second long period      42
Transitional elements, characteristics of      41
Transitional elements, chemical peculiarities of      80 81
Transitional elements, colour of      41
Transitional elements, copper, transitional properties of      42
Transitional elements, core of      76 171 176
Transitional elements, definition of      45
Transitional elements, form no mixed octets      174
Transitional elements, hydration of ions of      216
1 2 3 4
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