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Sidgwick N.V. — The electronic theory of valency
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Название: The electronic theory of valencyАвтор: Sidgwick N.V. Аннотация: This book aims at giving a general account of the principles of valency and molecular constitlltion, founded on tI1e Rutherforcl-Bohr atom. In dev'eloping the theory of valency there are two courses open to the chemist. He may use symbols ,with no definite physical connotation to express the reacti,rity of the atoms in a molecule, and may leave it to the subseqtlent progress of science to discover what realities these symbols represent: or he may adopt the concepts of atomic physics-electrons, nuclei, and orbits-and try to explain the chemical facts in terms of these. But if he takes the latter course, as is done in this book, he must accept the physical conclusions in full, and must not assign to these entities properties which the physicists have found them not to possess: he must not use the terminology of pl1ysics unless he is prepared to recognize its laws. I have endeavoured to conform to this principle, and not to lay mysetf open to the reproach of an eminent physicist, that when chemists talk about electrons they tlSe a different lang'uage from physicists. I have been careful to avoid as far as possible the introduction of any physical llypotllcses wllich are not already sanctioned by those who are best qualified to judge of them.
Язык: Рубрика: Физика /Статус предметного указателя: Готов указатель с номерами страниц ed2k: ed2k stats Издание: 1st editionГод издания: 1929Количество страниц: 310Добавлена в каталог: 30.08.2009Операции: Положить на полку |
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Предметный указатель
"Lone pairs" 61 "Natural Angle" 237 239 "Natural Angle" for singly and doubly linked atoms 238 "Natural solubility" 141 "Non-polar" and "polar" liquids 133 "Normal atom" of Bohr, definition of 46 "Polar" and "Non-Polar" liquids 133 120 147 4 Abegg, R., rule of eight 53 Abnormal liquids 133 Absolute valency 182 Acceptor liquids 137 Acceptors 116 Acetates, simple and complex 254 255 Acetic acid, polymerization of 253 Acetylacetonates, hydrated 169 Acetylacetone 120 Acidity and chelation 250 Aggregates, crystalline 186 Alkali metals 258 259 Alkali metals, alkyl derivatives of 154 Alkali metals, magnetic moment of, in vapour 210 Alkaline earth metals 263 Aluminium 266 Aluminium, stereochemistry of 224 Aluminium, structure of atom in compounds 172 Alums, structure of 188 Amine oxides, co-ordinated 71 Amine oxides, optical activity of 220 Amines, as pure donors 138 Amines, basicity of 97 Ammines, stability of 200 Ammonia of crystallization 200 Ammonia, combination with salts 201 Ammonia, compounds with cuprous and silver halides 203 Ammoniates, lattice energy of 202 Ammonium bases, molecular state of 97 Ammonium, ion, hydration of 194 Ammonium, radical 65—68 Ammonium, true dissociation constant of 97 Ampere, theory of magnetism 204 Andrade, E.N., da C. 31 204 Angermann, L. 221 Anions and cations, mutual influence in hydration 196 Anions, hydration of 194 Antimony 278 Antimony, pentachloride, parachor of 130 note Arc spectra 36 Aronberg, L. 12 Arrhenius, S. 51 55 94 Arsenic 278 Arsenic, 4-covalent, stereochemistry of 225 Arsenic, 6-covalent, stereochemistry of 224 Association, molecular Chapter VIII 132 Association, molecular, and co-ordination 134 Association, molecular, and conductivity 133 Association, molecular, and dielectric constant 135 Association, molecular, and donor atoms 149 Association, molecular, and ionization 137 Association, molecular, and solubility 138 144 Association, molecular, and the mixture law 136 Association, molecular, and volatility 135 Association, molecular, cryoscopic evidence of 149 Association, molecular, of water 135 Association, molecular, two kinds of 134 Aston, F.W. 102 Atomic and molecular magnetism Chapter XII 204 Atomic number 7 Atomic number and nuclear atom Chapter I 1 Atomic number of inert gases (Rydberg) 28 Atomic number, effective 163 Atomic rays, magnetic moment of 208 Atoms, composition of 8 Atoms, core of 63 170 176 Atoms, dimensions of 9 Atoms, table of structures 48—50 Atoms, types of 45 Auric compounds 262 Auwers, K. 134 148 Azimuthal and radial quantum numbers 25 note Azo-dyes and chelation 235 Back, E. 34 Baeyer, A., Strain theory 99 236 Bain, A.M. 221 Balmer, J.J. 21 36 Barkla, C.G. 6 Baudiscii, O. 215 217 Bauer, E. 211 Becquerel, H. 2 Bennett, G.M. 251 note Benzyl, sodium 260 Berthoud, A. 130 Beryllium 263 Beryllium, basic acetate 222 Beryllium, ion, hydration of 192 Beryllium, stereochemistry of 221 Beryllium, structure of 38 Berzelius, J.J. 51 Biltz, W., conductivity of fused halides 105 289 Biltz, W., references 93 169 230 Biltz, W., solvation 187 197 201 202 Bischoff, C.A. 220 Bismuth 278 Bismuth, inert pair of electrons in 181 278 Boeseken, J. 222 Bohr, N., "normal atom" 47 Bohr, N., atomic structure and covalency rule 167 Bohr, N., atomic structure, theory of Chapter II 14 Bohr, N., helium, metastable form of 257 Bohr, N., hydrogen atom, theory of 14 Bohr, N., magneton 207 Bohr, N., periodic table 39 Bohr, N., references 34 40 Bohr, N., theory of atom and periodic classification Chapter III 25 Boric acid, weakness of 266 Born, M. 202 Borofluorides 68 69 Boron 265 Boron, co-ordination of 67 Boron, halides, abnormal volatility of 245 Boron, hydrides, structure of 103 Boron, maximum covalency 155 Boron, stereochemistry of 222 Boron, structure of 38 Bose, E. 134 Bowen, I.S. 37 Brackett series of hydrogen 21 Bragg, W.H. and W.L. 88 90 92 222 Brazier, S.A. 252 Brewer, F.M. 145 155 Brown, F.S. 135 Bruehl, J.W. 252 Burgess, H. 221 Burrows, G.J. 225 Bury, C.R., association 135 Bury, C.R., atomic structure and the periodic table 29 Cabrera, B. 213 Cadmium 263 Callow, R.K. 147 152 Carbon 270 Carbon, divalent 180 Carbon, stereochemistry of 219 Carbonato-compounds 243 Carbonyl compounds, diamagnetism of 216 Carbonyl group, hydration of 195 Carboxyl group and co-ordination 252 Carnelley, T. 141 Cations and anions, mutual influence in hydration 196 Cations, hydration of 192 Cerium 267 Cerium, hydrate of acetylacetonate 169 note Chadwick, H. 162 Challenger, F. 225 Chelate compounds and acidity 250 Chelate compounds of azo-dyes 235 Chelate compounds of mordant dyes 234 Chelate compounds of sodium 146 Chelate compounds of thallium 146 Chelate compounds, nature of 119 Chelate rings Chapter XIV 233 Chelate rings in 147 Chelate rings in ortho-substituted phenols 147 Chelate rings, evidence for 233 Chelate rings, types of 239 Chlorine 292 Chromium 287 Chromium, comparison with sulphur 80 Clarke, S.G. 228 Clinch, J.A. 169 Co-ordinate links 52 Co-ordinate links, conditions of formation 116 Co-ordinate links, definition of 60 Co-ordinate links, dipole character of 71 122 Co-ordinate links, Lewis's mechanism of 59 Co-ordinate links, properties of 121 Co-ordinate links, symbol of 60 Co-ordinate links, weakness of 121 Co-ordination Chapter VII 109 Co-ordination and association 134 Co-ordination and change of electrovalency 111 Co-ordination and dielectric constant 124 Co-ordination and molecular volume 124 Co-ordination and parachor 127 Co-ordination and the carboxyl group 252 Co-ordination and volatility 123 Co-ordination of hydrofluoric acid 72 Co-ordination of hydrogen 72 117 Co-ordination of ions 69 Co-ordination of water 72 Co-ordination, electronic interpretation of 112 Co-ordination, number, Werner's 109 Co-ordination, Werner's theory of 109 Cobalt 297 Cobalt, 4-covalent, supposed plane symmetry of 230 Colour of rare earth metals 41 Colour of transitional elements 43 Combination principle, Ritz's 20 Complete groups, definition of 171 note Complex ions, magnetism of 214 Conductivity of associated liquids 133 Conductivity of fused halides 105 289 copper 260 Copper, magnetic moment of, in vapour 210 Copper, stereochemistry of 226 Copper, transitional properties of 42 Core of transitional elements 77 176 Core, atomic 63 170 176 Core, distribution of electrons in 165 Core, fixed, changes of valency with 177 Core, stable forms of 76 Coster, D. 47 Covalency and electrovalency Chapter VI 83 Covalency and the periodic table 104 Covalency maxima Chapter IX 152 Covalency maxima and the Bohr theory 167 Covalency maxima in first short period 153 Covalency maxima of boron 155 Covalency maxima of fluorine 153 Covalency maxima of hydrogen 153 Covalency maxima of nitrogen 154 Covalency rule 152 Covalency rule and hydrolysis of halides 156 Covalency rule, apparent exceptions 160 Covalency, actual and possible 161 Covalency, criteria of 84 86 Covalency, isomerism a proof of 86 Covalency, odd 161 Covalency, stereoisomerism a proof of 86 Covalency, transition to electrovalency 92 Covalency, volatility a proof of 87 Covalent links of one electron 102 Covalent links of two electrons 57 Covalent links, Fajans's theory of formation 104 191 202 Crookes, W. 2 Crowther, J.A. 6 Cryoscopic evidence of association 149 Crystal structure and ionization 90 92 106 Crystal structure and ionized lattices 91 Crystal structure and X-rays 90 Crystallization, ammonia of 200 Crystallization, water of 189 Cupric compounds 261 Cuprous salts, conditions of stability of 260 Curie, P. 205 211 212 213 Dalton, J. 1 Darwin, C.G. 9 de Forcrand, R. 187 Debye, P., Theory of strong electrolytes 94 190 Debye, P., X-rays and crystal structure 90 Delepine, M. 223 Dhar, N. 190 Diamagnetism 204 206 Diamagnetism of carbonyl compounds 216 Diamagnetism of simple ions 212 Diamine compounds 243 247 Diazo-compounds, stereochemistry of 221 Dielectric constant and association 135 Dielectric constant and ionization 132 Dielectric constant, effect of co-ordination on 124 Dimensions of atom, electron, and proton 9 Dipole character of co-ordinate link 71 122 Displacement law, electronic 66 Displacement law, radioactive 7 Displacement law, spectroscopic 37 Dissociating solvents 130 Dissociation constants of ammonium bases 97 Divalent carbon 180 272 Donors, definition 116 Donors, donor atoms and association 149 Donors, donor liquids 137 Donors, pure donors 137 Double salts 118 Double water molecules 188 199 Doubly linked atoms, rotation of 99 Drew, H.D.K. 119 Drucker, K. 135 Drude, P. 52 55 Duff, J.C. 251 Dumas, J.B.A. 51 Eddington, A.S. 34 Effective atomic number and paramagnetism 215 Effective atomic number of platinammines 165 Effective atomic number of transitional triads 166 Effective atomic number, definition 163 Effective valency 114 164 Ehrenfest, P. 209 Eight-membered rings 251 Einstein, A. 19 209 Electrolytes, strong, Debye's theory of 94 Electrolytes, weak, condition of 93 Electronic formulae of compounds 64 Electronic increment 164 Electrons, application of, to valency 52 Electrons, charge of 3 Electrons, dimensions of 9 Electrons, displacement law 66 Electrons, groups, subgroups, and grouplets of 31 Electrons, mass of 3 Electrons, negative character of 2
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