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| Ïîèñê ïî óêàçàòåëÿì |
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| Mukamel S. — Principles of nonlinear spectroscopy |
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| Ïðåäìåòíûé óêàçàòåëü |
Rotating wave approximation, multilevel manifold with relaxation and 158—159
Rotating wave approximation, nonlinear response in momentum space and 126—127
Rotating wave approximation, physical  function pulse and 129—130
Rotor (curl) 104
Scalar function 104
Scalar product 56 91
Scalar product in Hilbert space vs. Liouville space 58t
Scalar product of polarization 87
Scalar product of two states 15
Scalar product of two vectors 40
Scalar product rules, for linear vector spaces 41—42
Scalar product, definition of 42
Scattered field, in spontaneous light emission spectroscopy 265
Scattering matrix, expression for two-exciton Green function 518—519
Schroedinger equation 23 35 51 54 57
Schroedinger equation for wavefunction 144
Schroedinger equation, time-independent (stationary) 15
Schroedinger picture 27 29—30 63 140 484
Schroedinger picture, cumulant expansion and 212
Schroedinger picture, time-dependent density operator in 483
Schwartz inequality 40t 41 48
Second harmonic generation signal 173
Second-order nonlinear processes 116
Self energy operator 36 68
Self interaction term  88—89
Self-action 103
Self-adjointed operators (Hermitian operators) 21 117
Self-focusing 174
Semiclassical simulations approximations 188
Semiclassical simulations approximations for anharmonic systems 357
Semiclassical simulations, inhomogeneous cumulant expansion and 239—244 243f
Semiclassical simulations, motivation for using 188
Sequential pump-probe spectroscopy 322 326—328 327f 336
Sine function, phase matching condition and 98f
Single-frequency techniques, examples of 173—175 174f
SLE spectroscopy see Spontaneous light emission spectroscopy (SLE)
Slow modulation limit 222 306
Small particle response functions, correlation function expressions for 111—118 115f
Smoluchowski equation 233 357 362
Snapshot doorway wavepackets 379
Snapshot spectrum 372 377—382 450
Snapshot spectrum, off-resonant 455—456
Snapshot window wavepackets 379
Sodium, energy level scheme,  173 174f
Spatial dispersion 112
spatial resolution 13
Spectral density 214 219
Spectral density, symmetries of 214—217
Spectral diffusion 203 224 306 309—310 333
Spectral diffusion and vibrational relaxation with spontaneous light emission spectroscopy 286—287
Spectral diffusion, hole-burning spectroscopy and 385—389 387f 389f
Spectral distribution function 435
Spectral line broadening 169 187 224 see Inhomogeneous
Spin decoupling 295
Spin-Boson Hamiltonian see Brownian oscillator model
Spontaneous emission 13
Spontaneous light emission spectroscopy (SLE) 4f 261 265—271 266f 268f
Spontaneous light emission spectroscopy using phase-locked pulses 310—313
Spontaneous light emission spectroscopy with spectral diffusion and vibrational relaxation 286—287
Spontaneous light emission spectroscopy, electromagnetic field decomposition 265
Spontaneous light emission spectroscopy, fluorescence component 261—262 271—279 272f—279f
Spontaneous light emission spectroscopy, frequency domain 267—271
Spontaneous light emission spectroscopy, incoming field 265
Spontaneous light emission spectroscopy, Liouville space pathways 267 268f
Spontaneous light emission spectroscopy, phase-locked 295 310—313 340 341
Spontaneous light emission spectroscopy, Raman component 261—262 262f 263f 271—279 272f—279f
Spontaneous light emission spectroscopy, scattered field 265
Spontaneous Raman spectroscopy 133
Spontaneous Raman spectroscopy, absorption of quantum field 262—264 263f
Spontaneous Raman spectroscopy, coherent analogues of see Coherent anti-Stokes Raman spectroscopy (CARS) Coherent
Spontaneous Raman spectroscopy, excitation profile 283
Spontaneous Raman spectroscopy, frequency-domain 417—429
State of system see Ket
State vector 75
Static polarization structure factor 253 254
Stationary absorption lineshape 183
Statistical mixture see Mixed states
Steady-state solution 183
Stimulated photon echo (SPE) 295 303
Stimulated Raman 305
Stochastic Gaussian Markov modulation, of electronic energy gap 225
Stochastic lineshape function 225—226 226f
Stochastic process 225f
Stokes shift 250—252 308 308f 333
Stokes shift in aggregates 503
Stokes shift, absence in Stochastic models 226
Stokes shift, parameter 237
Stokes shift, time-dependent 234 333 369 377
Stokes shift, Time-dependent, in hole—burning and fluorescence line narrowing 372
Superlattices, periodic structure in k space, optical susceptibilities of 496—498
Superoperators 54—55 57
Superposition, of two states 15
Superradiance 479
Susceptibilities 125
System density operator 177
System operator dynamics 49
System timescales, distribution of 188
Taylor series 17 18 30 212 222 414
Taylor series, expansion 115—116 246
Taylor series, transition moment in 210
Temperature, Wigner representation and 73—74
Temporal convolution 382
Tensor, dipole-dipole 463
Tensor, rank of 445
Tetradic matrix (superoperator) 54—55
Tetradic notation and Liouville space 53—58 58f
Thermal bath 130 132 143 149
Thermal population 145
Third harmonic generation 4 173
Third-harmonic hyperpolarizabihty 173 174f
Thomas — Reiche — Kuhn (oscillator-strength) sum rule 165
Three-pulse echo 308
Three-pulse phase-locked pump-probe absorption 338—339
Three-wave mixing 4
Time evolution operator 25—26 200
Time evolution operator in Hilbert space vs. Liouville space 58f
Time evolution operator in interaction picture, Magnus expansion of 26—31
Time evolution operator in Liouville space 59—61
Time evolution operator with time-independent Hamiltonians 15—22
Time evolution operator, definition of 16—17
Time evolution operator, tetradic 60
Time ordering 112
Time ordering in Hilbert space 23f 23—25 24f
Time ordering in Liouville space 61 62
Time ordering, partial control of 322 324 324f 325f 326
Time variables for nonlinear response functions 114—115 115f
Time variables in time-ordered expansion 23f
Time-dependent friction 228
Time-dependent perturbation theory 136—137
Time-dependent phase 192
Time-dependent transition dipole 192
Time-domain spectroscopy 187 321 322
Time-domain spectroscopy, analogue, of degenerate four-wave mixing and 510—512 511f 512f
Time-domain spectroscopy, ideal 129
Time-domain spectroscopy, impulsive coherent anti-Stokes Raman 420 421f
| Time-domain spectroscopy, Liouville space pathways in 118—120
Time-domain spectroscopy, measurements 117
Time-domain spectroscopy, Raman techniques, dynamic approach to coherent Raman scattering and 414—422 421f
Time-domain spectroscopy, response function 144
Time-domain spectroscopy, techniques 13
Time-domain spectroscopy, techniques, vs. frequency-domain techniques 5f—7f 5—7
Time-domain spectroscopy, vs. frequency domain techniques, for nonlinear response functions 128—131
Time-independent effective Liouville operator 181
Time-ordered exponential 191
Time-ordered exponential operator, cumulant expansion applied to see Magnus expansion
Time-ordering in Liouville space 132—133
Time-ordering, Liouville space pathways and 132—133
Total charge density 83
Total detected intensity 99
Total polarization field 88
Trace 49
Trace of  49f
Trace of commutators 46
Trace of matrix 42
Trace, properties of 46
Transient dichroism, of iodine in n-hexane 454f
Transient experiments 12
Transient grating 4 322 479
Transient grating with heterodyne detection, vibrational contribution to 450—451
Transient grating with heterodyne detection, wavepacket representation of 408
Transient grating, coherent Raman scattering and 414
Transient grating, phase-locked 324 324f 325f 326
Transient grating, third-order nonlinearities and 4
Transient grating, time-domain analogue of degenerate four-wave mixing and 510—512 511f 512f
Transition frequency (energy) 144 243
Transition frequency (energy), distribution of 188
Transition frequency (energy), fast modulation of 188
Transition frequency (energy), shifts, electric-field-induced 292f
Transition frequency (energy), static distribution of 188
Transmission 144
Transverse delta function 81
Transverse electric field 495
Transverse Maxwell field 111
Transverse polarization 86
Transverse radiation field 111
Transverse relaxation time 180
Transverse vector fields 104—105
Triple Fourier transformation 246
Two-electronic level systems 210—212 296
Two-electronic level systems, absorption and emission lineshapes 219—220 250—252
Two-electronic level systems, interacting with strong monochromatic field 181
Two-electronic level systems, optical response, Condon approximation for 210—212
Two-electronic level systems, resonant, non-time-ordered four-wave mixing 323—324
Two-electronic level systems, scheme, for spontaneous light emission 266 266f
Two-exciton resonances, and enhanced nonlinear susceptibilities in molecular aggregates 498—504 503f—506f 506—507
Two-exciton scattering matrix 493 496
Two-exciton variables, for Green function solution, factorized approximations for 489—490
Two-level model absorption lineshape 193
Two-photon absorption, nonlinear 502 503f 504 505f
Two-photon resonances 280 416
Two-pulse photon echo (PE) 295
Two-state jump model 226
Two-time correlation function of electronic energy gap 214
Two-time correlation function of polarizability 417
Ultracold molecules in supersonic beams 290 291f
Ultrafast pulses, interferometric autocorrelation measurement 6f
Ultrafast pulses, sources, development of 5 5f
Ultrafast pulses, time-resolution, development of 6f
Unit operator, in Wigner representation 72—73
Unit operator, in Wigner representation, in Hilbert space vs. Liouville space 58t
Unitary operator 22 46
Urbach tail 194
Vacuum state 265
Van der Waals interaction 87
Vector fields 79
Vector fields, longitudinal 104—105
Vector fields, transverse 104—105
Vector model 10
Vector potential 81
Vector potential operator 80
Vector,bra 56
Vibrational coherence 294 455
Vibrational contribution, to heterodyne-detected transient grating 450—451
Vibrational dephasing 169—170 225
Vibrational dephasing, homogeneous 419—420
Vibrational dephasing, processes 306 454
Vibrational dephasing, rates 283
Vibrational dephasing, timescale 422
Vibrational frequency 305
Vibrational quantum beats 330
Vibrational relaxation, and spectral diffusion, with spontaneous light emission spectroscopy 286—287
Vibrational spectroscopy, N-dimensional 414
Vibronic eigenstate representation for nuclear motions 369
Vibronic state representation 365—366
Voigt profile 223—224 293 304 338
Wannier excitons 514
Wave-mixing techniques, off-resonant conditions 10
Wavefunction, formulation of nonlinear response, vs. density-operator formulation 136—138
Wavepacket analysis, of nonimpulsive measurements 369 370f—372f 371—373
Wavepacket analysis, of nonimpulsive measurements for overdamped Brownian oscillator 385—391 389f 391f—393f
Wavepacket analysis, of nonimpulsive measurements, of pump-probe spectra in three-electronic-level system 393—406 394ft 398f—402f
Wavepacket analysis, of nonimpulsive measurements, snapshot spectrum and related limiting cases 372 377—385
Wavepackets dynamics in Liouville space 345—346
Wavepackets in bound molecular system 371f
Wavepackets, semiclassical 322
Wavevector 125
Wavevector selection (phase matching) 12
Wavevector, dependence, of response functions 112
Wavevector-dependent dielectric function 95
Wick’s theorem 218
Wiener — Khinchin theorem 241 255—256
Wigner phase space representation 369 380 423
Wigner phase space representation for eigenstates of harmonic oscillator 74f
Wigner phase space representation in snapshot limit 396—397 400f 402f
Wigner phase space representation, canonical quantum density operator 73
Wigner phase space representation, classical Liouville equation and 68—75
Wigner phase space representation, exciton transport in phase space and 508—510
Wigner phase space representation, Franck — Condon principle and 403—404
Wigner phase space representation, of density operator 72 132
Wigner phase space representation, path integral representation and 345—346
Wigner phase space representation, phase averaging and 350
Wigner phase space representation, quantum harmonic oscillator, Hamiltonian for 73
Wigner phase space representation, response functions and 257
Wigner phase space representation, significance of 74—75
Wigner phase space representation, temperature and 73—74
Wigner phase space representation, unit operator in 72—73
Wigner transform 73 75
Wigner — Jordan transformation 514
Wigner — Weiskopf model 36—37 37f
Window wavepackets 369 372 see
Window wavepackets amplitude 397
Window wavepackets for off-resonant birefringence and dichroism 455
Window wavepackets in snapshot limit 379 396—398
Window wavepackets, ground-state 362
Window wavepackets, second-rank tensor 452
Zero background 99
Zero order Green function 34
Zero point motion 188
Zero vector 40 41
Zero-order field 130
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