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Galwey A.K. — Thermal Decomposition of Ionic Solids
Galwey A.K. — Thermal Decomposition of Ionic Solids



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Название: Thermal Decomposition of Ionic Solids

Автор: Galwey A.K.

Аннотация:

The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.
Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 1

Год издания: 1999

Количество страниц: 597

Добавлена в каталог: 05.03.2010

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Silver carbonate, decomposition, doping      354 357
Silver carbonate, in silver oxide      300
Silver chlorate, decomposition      368 371 374
Silver chlorite, decomposition      368 374
Silver formate, decomposition      442 485
Silver fulminate      338
Silver fumarate, decomposition      474
Silver maleate, decomposition      474
Silver malonate decomposition      474 542—543
Silver nitrite, decomposition      395
Silver oxalate, decomposition      456—457
Silver oxide, decomposition      299—300
Silver oxide, reduction      300
Silver perchlorate, decomposition      368
Silver periodate, decomposition      370
Silver permanganate, decomposition      388
Silver permanganate, decomposition, additives      388
Silver squarate, decomposition      469
Silver, catalysis by      320
Sintering      24 32 38—40 51 190 571G
Sintering, Group IIA metal oxides      273
Sites, surface      43 46
Smith — Topley effect      221 224—228 232 246 248 261
Smith — Topley effect and sublimation model      560
Smoothing of data      140
Sodium aluminium hydride      317
Sodium azide, decomposition      334 339
Sodium bicarbonate, decomposition      351—352 358
Sodium bicarbonate, subsurface nucleation      352
Sodium calcium sulfate trihydrate, dehydration      234
Sodium carbonate monohydrate, dehydration      241
Sodium carbonate-calcium carbonate reaction      356—357
Sodium chlorate, decomposition      370
Sodium chlorite, decomposition      374
Sodium hydrogen phosphates, decompositions      396
Sodium hyponitrite, decomposition      395
Sodium metaperiodate, decomposition      369
Sodium nickel phosphate hydrate, dehydration      397
Sodium perchlorate, decomposition      366—367
Sodium perchlorate, dehydration      366
Sodium permanganate, decomposition      386—387
Sodium peroxide, decomposition      297
Sodium sulfate, decomposition      399
Sodium superoxide, decomposition      297—298
Sodium thiosulfate pentahydrate, dehydration      245
Sodium tungstate dihydrate, dehydration      245
Solid decompositions, autocatalysis      557
Solid decompositions, crystal structures      555
Solid decompositions, experimental techniques      552—554
Solid decompositions, future development      552—555
Solid decompositions, isomorphic crystals      555—556
Solid solutions      12 192 283
Solids, classification      4—7
Spectroscopic studies      538 554
Spectroscopy      175—190
Squarates, metal, decompositions      467—469
Stability of coordination compounds      517—520
Stoichiometry      221
Stoichiometry, complex reactions      535
Stoichiometry, deviation from      292
Stoichiometry, simple reactions      535
Strain and decomposition rate      513 515
Strain field      126
Strontium acetate, decomposition      450
Strontium azide, decomposition      332—333 339
Strontium carbonate, decomposition      350 358
Strontium hydroxide octahydrate, dehydration      273
Strontium iodate, decomposition      372
Strontium oxalate, decomposition      462
Strontium perchlorate tetrahydrate, dehydration      368
Strontium perchlorate, decomposition      368
Structural dehydroxylations      283
Structural reorganization      225—226 258—259
Structure collapse in strain      279
Styphnate, barium, trihydrate, dehydration      252
Styphnate, lead, monohydrate, dehydration      252—253
Styphnates, barium and lead, decompositions      477—478
Styphnates, metal, hydrates, dehydrations      252—253
Sublimation      3 32 40—48 51 134
Sublimation in ammonium salt decompositions      418—419 431 434
Sublimation model for solid decompositions      559—560
Sulfate decompositions, kinetics      398—399
Sulfate decompositions, mechanisms      398—399
Sulfates, Group IIA metal, decompositions      399—400
Sulfates, metal, decompositions      398—409
Sulfates, transition-metal, decompositions      400—401
Sulfides, metal, decompositions      321—323
Sulfite, calcium, decomposition      402—403
Surface area, potassium permanganate      382
Surface area, reactant      190 246 260
Surface chemistry of reactant      534 554
Surface controlling reactions      313 316 324
Surface mobility      24 224
Surface modification during reactions      534 554 558
Surface reactions      47 534 554
Surface reactions, binary compounds      313 324
Surface reactivity      534 554 558
Surface species, concentrations      541
Surface textures      238—239 276
Surfaces      9 15
Surfaces and nucleation      534 554
Talc, dehydration      286
Talc, product orientation      286
Tartrates, lithium potassium, hydrates, dehydrations      547
Temperature and reaction rate      117—134
Temperature measurement      64—65
Temperature, sample      65
Thallium azide, decomposition      337 339
Thallium bromate, decomposition      373
Thallium chlorate, decomposition      368 371
Thallium chlorite, decomposition      368
Thallium cyanamide      338
Thallium perchlorate, decomposition      369
Thermal decomposition of solids      3 6 44 45 51 569G
Thermal stabilities      1 542 547 555—558
Thermal stability, prospects for theory      527 553 555—560
Thermochemical measurements      538 554
Thermochemical measurements, modulated DSC      538
Thermochemistry      66—68
Thermodynamics of bromate decompositions      373
Thermodynamics of reactions      50—59
Thermogravimetry (TG)      62
Thermomagnetometry (TM)      63 192
Theta $(\theta)$ rule      130—133 569G
Thorium formate, decomposition      446
Thorium hydride, decomposition      315
Thorium oxalate, decomposition      463
Tin oxide, decomposition      301
Tin(IV) hydroxides, dehydration      277
Titanium hydride, decomposition      315
Topochemical processes      292—293 306—308
Topochemistry      48
Topotactic preparation      49
Topotactic reactions      48—49 64 282 287
Topotactic relationships      175 189 196 199 537 554
Transition state theory      46 48 67—68 528—529 557
Transition state theory in carbonate decompositions      360
Transition state theory, perchlorate decompositions      366
Transition, displacive      34
Transition, reconstructive      34—35
Transition-metal oxides, decompositions      302—305
Transport in oxides      293 307
Trioxalatoferrate(III) potassium salt, decomposition      516
Uranium formate, decomposition      446
Uranium oxides, decompositions      305—306
Uranium oxyhydroxide, decompositions, uranyl acetate, decomposition      450—451
Uranyl formate, decomposition      446
Uranyl nitrate hydrates, dehydration      241—242
Uranyl oxalate, decomposition      459—460
Uranyl sulfate, decomposition      402 408
Valence bond      6 16—22
Vanadium pentoxide, decomposition      305
Vaporization      41—46
Vaporization, principles      40
Vaterite-calcite transition      345—346
Vermiculite, dehydration      253
Volatile species      40
Wadsley defects      307
Water bond ing      218—219
Water of crystallization      217
Water of crystallization, precursor dehydration      175 208
Water vapour atmosphere      231 271—272 275—276 284—285
Water vapour pressure      231—232
Water vapour, equilibrium pressure      271
Water, diffusion      231 242 250 258
X-ray diffraction (XRD)      64 174—175
X-ray radiolysis      179—180
X-ray topography      184—186
Yttrium formate dihydrate, dehydration      250
Zero-order rate equation      92—93 105 108—110
Zinc carbonate, decomposition      354—355
Zinc carbonate, decomposition in water vapour      354—355
Zinc formate, decomposition      445
Zinc hexacyanoferrate, decomposition      510
Zinc hydroxide, dehydration      276
Zinc hydroxide, electron beam      276
Zinc oxalate, decomposition      458—459 485
Zinc oxide, decomposition      300—301
Zinc sulfate heptahydrate, dehydration      235
Zinc sulfate, decomposition      401—2 407
Zinc sulfide, decomposition      322—323
1 2 3 4 5
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