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Slater J.C. — Introduction To Chemical Physics
Slater J.C. — Introduction To Chemical Physics



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Íàçâàíèå: Introduction To Chemical Physics

Àâòîð: Slater J.C.

Àííîòàöèÿ:

It is probably unfortunate that physics and chemistry over were separated. Chemistry is the science of atoms and of the way they com bine. Physics deals with the interatomic forces and with the large-scale properties of matter resulting from those forces. So long as chemistry was largely empirical and nonmathematical, and physics had not learned how to treat small-scale atomic forces, the two sciences seemed widely separated. But with statistical mechanics and the kinetic theory on the one hand and physical chemistry on the other, the two sciences began to come together. Now that statistical mechanics has led to quantum theory and wave mechanics, with its explanations of atomic interactions, there is really nothing separating them any more. A few years ago, though their ideas were close together, their experimental methods were still quite different chemists dealt with things in test tubes, making solutions, pre cipitating and filtering and evaporating, while physicists measured every thing with galvanometers and spectroscopes. But even this distinction has disappeared, with more and more physical apparatus finding its way into chemical laboratories. A wide range of study is common to both subjects. The sooner we realize this the better. For want of abetter name, since Physical Chemistry is already preempted, we may call this common field Chemical Physics. It is an overlapping field in which both physicists and chemists should be trained. There 4 seems no valid reason why their training in it should differ. This book is an attempt to incorporate some of the material of this common field in a unified presentation. What should be included in a discussion of chemical physics Logi cally, we should start with fundamental principles. We should begin with mechanics, then present electromagnetic theory, and should work up to wave mechanics and quantum theory.


ßçûê: en

Ðóáðèêà: Ôèçèêà/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Ãîä èçäàíèÿ: 1939

Êîëè÷åñòâî ñòðàíèö: 521

Äîáàâëåíà â êàòàëîã: 18.08.2009

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Rayleigh — Jeans law      314
Reciprocal space      230 245
Recombination      165
Reduced mass      135 141
Reflection of electrons by metals      462 465
Relaxation time, in electrical conductivity      485—486
Representative point      36—38 65—66
Repulsive forces, and Van der Waals' equation      182—184 194—196
Repulsive forces, between atoms, and exclusion principle      369—372
Repulsive forces, between ions, ionic crystal      388—390
Repulsive forces, between molecules      130—133
Residual rays      254—255
Resistance, electrical      484—489 498—501
Resonance potential      322
Reststrahlen      254—255
Reversible processes      10—13 16
Reversible processes and statistical mechanics      44—51
Rheology      256—258
Rhodium, crystal structure      447
Richardson equation, thermionic emission      466
Rigid sphere atomic model      131
Rotator, and equipartition of energy      58
Rotator, diatomic molecule      134—140
Rotator, in quantum theory      40 42
Rubidium fluoride, chloride, bromide, iodide, data regarding crystals      381 393 395
Rubidium, compressibility      202
Rubidium, crystal structure      447
Rubidium, data regarding melting point      259
Rubidium, equation of state and energy      451 454
Rumford      5
Ruthenium, crystal structure      447
Rydberg number      3408
Saha      335
Saturation of valence      374—376
Second law of thermodynamics      12—14 16
Second law of thermodynamics and statistics      19 49—51
Second order, phase change      291—304
Second virial coefficient      190—196
Secondary emission of electrons      461—462
Selenium, crystal structure      444 447 450
Selenium, data regarding melting point      259
Shielding constant      340—342
Shot effect      108
Silica gel      438
Silicates      435—443
Silicon hydride, valence structure of molecule      405
Silicon hydride, Van der Waals constants      408
Silicon, and homopolar bonds      400
Silicon, crystal structure      444 447
Silicon, melting point      449
Silver bromide, data regarding crystals      381
Silver bromide, data regarding melting point      259—261
Silver bromide, molecular volume      261
Silver bromide, thermal expansion      261
Silver chloride, data regarding crystals      381
Silver chloride, data regarding melting point      259 261
Silver chloride, molecular volume      261
Silver chloride, thermal expansion      261
Silver fluoride, data regarding crystals      381
Silver nitrate, data regarding melting point      259
Silver, crystal structure      447
Silver, data regarding melting point      259 261
Silver, Debye temperature      237
Silver, equation of state and energy      451 454
Silver, molecular volume      261
Silver, thermal expansion      261
Simple cubic structure, and atomic vibrations      232
Sodium acetate, structure of molecule      428
Sodium bromide, iodide, data regarding crystals      381 393 395
Sodium chloride, crystal structure      378 381
Sodium chloride, data regarding crystals      381 393 395
Sodium chloride, data regarding melting point      259 261
Sodium chloride, Debye temperature      391
Sodium chloride, molecular volume      261
Sodium chloride, thermal expansion      261
Sodium chloride, water solution      285—287
Sodium fluoride, data regarding crystals      381 393 395
Sodium fluoride, data regarding melting point      259
Sodium hydroxide, data regarding melting point      259
Sodium nitrate, data regarding melting point      259
Sodium perchlorate, data retarding melting point      259
Sodium, crystal structure      447
Sodium, data regarding melting point      259 261
Sodium, Debye temperature      237
Sodium, electronic energy bands      494
Sodium, equation of state and energy      451 454—455
Sodium, equation of state and energy and thermodynamic functions      200—211
Sodium, molecular volume      261
Sodium, molecule, characteristic temperature, dissociation      133
Sodium, molecule, characteristic temperature, for rotation      136
Sodium, molecule, characteristic temperature, for vibration      142
Sodium, molecule, characteristic temperature, heat of dissociation, interatomic Sodium, molecule, distance, Morse constant      132
Sodium, thermal expansion      261
Solids, binary systems      270—290
Solids, binary systems, equation of state and specific heat      199—255
Solids, equilibrium with other phases      166—181
Solids, ionic substances      377—399
Solids, melting      256—269
Solids, metals      444—501
Solidus      281
Solutions      270—290
Space quantization      139 339
Specific heat      17—20 22—23
Specific heat and fluctuations      107—108
Specific heat and phase changes of second order      291—304
Specific heat and statistical mechanics      51
Specific heat and temperature variation of latent heat      177—178
Specific heat difference between $C_{P}$ and $C_{V}$      30
Specific heat electronic      322
Specific heat internal, of gas      117
Specific heat of compounds      241—255
Specific heat of free electrons      471 476—479 499—500
Specific heat of ionic crystals      390—393
Specific heat of liquids      262—265
Specific heat of monatomic perfect gases      61—62
Specific heat of monatomic perfect gases Fermi — Dirac statistics      78—79
Specific heat of monatomic perfect gases of vibrational frequencies, solids      225—255
Specific heat of polyatomic gases      136—149
Specific heat of solids      203—205 213—214 222—255
Specific heat variation with pressure and volume      116
Spectrum, infrared, of crystals      254—255
Spectrum, optical, and Kirchhoff's law      309—310
Spin, electronic      339
Spin, electronic and interatomic forces      369—374
Spin, electronic and metals      476
Spontaneous emission      324
standing waves      226—231 242—252
Standing waves of electrons in metals      489—501
Stationary states, of electrons in atoms      321—323 338—344
Stationary states, of oscillator and rotator      41—42
Statistical mechanics      14 32—85
Statistical mechanics, applied to black body radiation      307—320
Statistical mechanics, applied to chemical equilibrium      154—158
Statistical mechanics, applied to equation of state of solids      211—221
Statistical mechanics, applied to equilibrium between phases and vapor pressure      178—180
Statistical mechanics, applied to melting      265—269
Statistical mechanics, applied to perfect gas      124—129
Statistical mechanics, applied to polyatomic gases      138—140 142—145
Statistical mechanics, applied to second virial coefficient      190—196
Statistical mechanics, applied to solubility and phase equilibrium      270—304
Stefan — Boltzmann law      307—313
Stirling's theorem      70—72
Streamline flow of representative points      37 94
Stresses and strains      17 199
Strontium oxide, sulphide, selenide, telluride, data regarding crystals      381
Strontium, crystal structure      447
Strontium, equation of state      451
Sugar, phase equilibrium in solution      270
Sulphate ion      357 398
Sulphur dioxide, valence structure of molecule      406
Sulphur dioxide, Van der Waals constants      408
Supercooling      181 256—258 262—264
Tantalum, crystal structure      447
Tantalum, equation of state      451
Tellurium, crystal structure      444 447 450
Temperature      9 12—14 17
Temperature and kinetic method      96
Temperature bath, and canonical assembly      46—47
Temperature bath, and fluctuations      101
Temperature of inversion, Joule — Thomson effect      198
Temperature-entropy diagram      172
Terms, spectroscopic      323
Thallium bromide, data regarding melting point      259
Thallium chloride, data regarding crystals      382
Thallium chloride, data regarding melting point      259
Thallium iodide, data regarding crystals      382
Thallium, crystal structure      447
Thallium, data regarding melting point      259
Thermal equilibrium      37—38 46—51
Thermal equilibrium and kinetic method      96 98
Thermal expansion      19 200—220 238—240 261
Thermal expansion of ionic crystals      392—394
Thermal expansion of metals      450—456
Thermal pressure      217—218
Thermionic emission      460—471 480—484
Thermodynamic formulas      16 23—30
Thermodynamic formulas, table of      27—29
Thermodynamic probability      34
Thermodynamic probability and Fermi — Dirac and Einstein — Bose statistics      69—72
Thermodynamic scale of temperature      30—31
Thermodynamics      14 16—31
Thermodynamics, applied to black-body radiation      307—320
Thermodynamics, applied to chemical equilibrium      154—158
Thermodynamics, applied to equation of state of solids      199—211
Thermodynamics, applied to equilibrium, between atoms and electrons      333—335
Thermodynamics, applied to equilibrium, between metal and gas      463—464
Thermodynamics, applied to equilibrium, between phases      174—178
Thermodynamics, applied to perfect gas      115—124
Thermodynamics, applied to solubility and phase equilibrium      270—304
Thermodynamics, applied to Van der Waals' equation      184—189
Threshold, Photoelectric      318
Tin, crystal structure      444 447—449
Tin, data regarding melting point      259
Tin, Debye temperature      237
Titanium, crystal structure      447
Transition probability      42 88
Transition probability, of atoms      322—333
Transverse waves, in electromagnetic radiation      313—314
Transverse waves, in solids      222—240
Traveling waves      226—228
Triethylamine, Van der Waals constants      408
Trimethylamine, structure of molecule      427
Trimethylamine, Van der Waals constants      408
Triple point      166—167 171—172 181
Triple point and eutectic      285
Tungsten, crystal structure      447
Tungsten, equation of state and energy      451 454
Uncertainty principle      40—41
Undetermined multipliers      48
Valence forces      130
Valence forces, explanations from atomic theory      371—376
Van der Waals constants      182—198
Van der Waals constants for molecular substances      407—414
Van der Waals forces      182—198
Van der Waals forces and atomic structure      356—374
Van der Waals forces and inert gases      385
Van der Waals forces and molecular substances      407—414
Van der Waals forces and solutions      273
Van der Waals' equation      182—198 210
Van der Waals' equation and molecular substances      407—414
Van't Hoff's equation      154—158
Vanadium, crystal structure      447
Vanadium, equation of state      451
vapor pressure      166—169 174—180
Vapor pressure and Van der Waals' equation      188—189
Vaporization      23
Vaporization and Van der Waals' equation      189 258—260
Vaporization entropy of      171—180
Vaporization heat of      171—180
Vaporization of metals      452—454
Vaporization of organic compounds, table      434
Vaporization table of      414
Velocity, of elastic waves      227—240
Velocity, of light      308
Vibration, and light waves      313—314
Vibration, of diatomic molecules      140—149
Vibration, of molecules and atoms in crystals      211—255
Vibrational degrees of freedom      146
Virial      190—196
viscosity      12 13 257
Volt, electron      132—133 318
Volta effect      467—471
Volume      17
Volume and chemical equilibrium      151—158
Volume and phase equilibrium      168—178
Volume molecular, table of      261
Volume of imperfect gases, and Van der Waals' equation      182—198
Volume of liquids, table      408
Volume of perfect gas      58—61
Volume of solids      199—221
Water glass      438
Water, and solubility      270—275 285—290
Water, crystal structure      260 418—419
Water, data regarding melting point      259
Water, dissociation into hydrogen and oxygen      151—164
Water, entropy and free energy      172—173
Water, equilibrium between phases      166—169
Water, heat of vaporization      414
Water, valence structure of molecule      401
Water, Van der Waals constants      408 412—414
Water, vapor pressure and latent heat of vaporization      188—189
Water, vibrational specific heat      146—147
Wave mechanics      41 307
Wave mechanics and electrons in periodic potential      489—501
Wave mechanics and radiation      323
Waves, elastic, in continuous media      227—234
Waves, electromagnetic, and light      308 313—320
Waves, in molecular media      241—252
Work      3 7—9 17 21—22
Work and statistical mechanics      49
Work function, thermionic and photoelectric      317—318 464 469—470 480—484
Wurtzite, crystal structure      379—380 382
X-ray diffraction, liquids      256
X-ray levels in atoms      344
Xenon, atomic volume      384
Xenon, data regarding crystals      416
Xenon, specific heat      130
Xenon, Van der Waals constants      408
Zinc oxide, sulphide, selenide, telluride, data regarding crystals      382
Zinc, crystal structure      447
Zinc, data regarding melting point      259
Zinc, Debye temperature      237
Zinc, energy      454
Zinc, order-disorder in alloys      293—304
Zinc, phase equilibrium in alloys      270 287—288
Zincblende, crystal structure      379—381 382
Zirconium, crystal structure      447
Zirconium, equation of state      451
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