Àâòîðèçàöèÿ
Ïîèñê ïî óêàçàòåëÿì
Slater J.C. — Introduction To Chemical Physics
Îáñóäèòå êíèãó íà íàó÷íîì ôîðóìå
Íàøëè îïå÷àòêó? Âûäåëèòå åå ìûøêîé è íàæìèòå Ctrl+Enter
Íàçâàíèå: Introduction To Chemical Physics
Àâòîð: Slater J.C.
Àííîòàöèÿ: It is probably unfortunate that physics and chemistry over were separated. Chemistry is the science of atoms and of the way they com bine. Physics deals with the interatomic forces and with the large-scale properties of matter resulting from those forces. So long as chemistry was largely empirical and nonmathematical, and physics had not learned how to treat small-scale atomic forces, the two sciences seemed widely separated. But with statistical mechanics and the kinetic theory on the one hand and physical chemistry on the other, the two sciences began to come together. Now that statistical mechanics has led to quantum theory and wave mechanics, with its explanations of atomic interactions, there is really nothing separating them any more. A few years ago, though their ideas were close together, their experimental methods were still quite different chemists dealt with things in test tubes, making solutions, pre cipitating and filtering and evaporating, while physicists measured every thing with galvanometers and spectroscopes. But even this distinction has disappeared, with more and more physical apparatus finding its way into chemical laboratories. A wide range of study is common to both subjects. The sooner we realize this the better. For want of abetter name, since Physical Chemistry is already preempted, we may call this common field Chemical Physics. It is an overlapping field in which both physicists and chemists should be trained. There 4 seems no valid reason why their training in it should differ. This book is an attempt to incorporate some of the material of this common field in a unified presentation. What should be included in a discussion of chemical physics Logi cally, we should start with fundamental principles. We should begin with mechanics, then present electromagnetic theory, and should work up to wave mechanics and quantum theory.
ßçûê:
Ðóáðèêà: Ôèçèêà /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Ãîä èçäàíèÿ: 1939
Êîëè÷åñòâî ñòðàíèö: 521
Äîáàâëåíà â êàòàëîã: 18.08.2009
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Rayleigh — Jeans law 314
Reciprocal space 230 245
Recombination 165
Reduced mass 135 141
Reflection of electrons by metals 462 465
Relaxation time, in electrical conductivity 485—486
Representative point 36—38 65—66
Repulsive forces, and Van der Waals' equation 182—184 194—196
Repulsive forces, between atoms, and exclusion principle 369—372
Repulsive forces, between ions, ionic crystal 388—390
Repulsive forces, between molecules 130—133
Residual rays 254—255
Resistance, electrical 484—489 498—501
Resonance potential 322
Reststrahlen 254—255
Reversible processes 10—13 16
Reversible processes and statistical mechanics 44—51
Rheology 256—258
Rhodium, crystal structure 447
Richardson equation, thermionic emission 466
Rigid sphere atomic model 131
Rotator, and equipartition of energy 58
Rotator, diatomic molecule 134—140
Rotator, in quantum theory 40 42
Rubidium fluoride, chloride, bromide, iodide, data regarding crystals 381 393 395
Rubidium, compressibility 202
Rubidium, crystal structure 447
Rubidium, data regarding melting point 259
Rubidium, equation of state and energy 451 454
Rumford 5
Ruthenium, crystal structure 447
Rydberg number 3408
Saha 335
Saturation of valence 374—376
Second law of thermodynamics 12—14 16
Second law of thermodynamics and statistics 19 49—51
Second order, phase change 291—304
Second virial coefficient 190—196
Secondary emission of electrons 461—462
Selenium, crystal structure 444 447 450
Selenium, data regarding melting point 259
Shielding constant 340—342
Shot effect 108
Silica gel 438
Silicates 435—443
Silicon hydride, valence structure of molecule 405
Silicon hydride, Van der Waals constants 408
Silicon, and homopolar bonds 400
Silicon, crystal structure 444 447
Silicon, melting point 449
Silver bromide, data regarding crystals 381
Silver bromide, data regarding melting point 259—261
Silver bromide, molecular volume 261
Silver bromide, thermal expansion 261
Silver chloride, data regarding crystals 381
Silver chloride, data regarding melting point 259 261
Silver chloride, molecular volume 261
Silver chloride, thermal expansion 261
Silver fluoride, data regarding crystals 381
Silver nitrate, data regarding melting point 259
Silver, crystal structure 447
Silver, data regarding melting point 259 261
Silver, Debye temperature 237
Silver, equation of state and energy 451 454
Silver, molecular volume 261
Silver, thermal expansion 261
Simple cubic structure, and atomic vibrations 232
Sodium acetate, structure of molecule 428
Sodium bromide, iodide, data regarding crystals 381 393 395
Sodium chloride, crystal structure 378 381
Sodium chloride, data regarding crystals 381 393 395
Sodium chloride, data regarding melting point 259 261
Sodium chloride, Debye temperature 391
Sodium chloride, molecular volume 261
Sodium chloride, thermal expansion 261
Sodium chloride, water solution 285—287
Sodium fluoride, data regarding crystals 381 393 395
Sodium fluoride, data regarding melting point 259
Sodium hydroxide, data regarding melting point 259
Sodium nitrate, data regarding melting point 259
Sodium perchlorate, data retarding melting point 259
Sodium, crystal structure 447
Sodium, data regarding melting point 259 261
Sodium, Debye temperature 237
Sodium, electronic energy bands 494
Sodium, equation of state and energy 451 454—455
Sodium, equation of state and energy and thermodynamic functions 200—211
Sodium, molecular volume 261
Sodium, molecule, characteristic temperature, dissociation 133
Sodium, molecule, characteristic temperature, for rotation 136
Sodium, molecule, characteristic temperature, for vibration 142
Sodium, molecule, characteristic temperature, heat of dissociation, interatomic Sodium, molecule, distance, Morse constant 132
Sodium, thermal expansion 261
Solids, binary systems 270—290
Solids, binary systems, equation of state and specific heat 199—255
Solids, equilibrium with other phases 166—181
Solids, ionic substances 377—399
Solids, melting 256—269
Solids, metals 444—501
Solidus 281
Solutions 270—290
Space quantization 139 339
Specific heat 17—20 22—23
Specific heat and fluctuations 107—108
Specific heat and phase changes of second order 291—304
Specific heat and statistical mechanics 51
Specific heat and temperature variation of latent heat 177—178
Specific heat difference between and 30
Specific heat electronic 322
Specific heat internal, of gas 117
Specific heat of compounds 241—255
Specific heat of free electrons 471 476—479 499—500
Specific heat of ionic crystals 390—393
Specific heat of liquids 262—265
Specific heat of monatomic perfect gases 61—62
Specific heat of monatomic perfect gases Fermi — Dirac statistics 78—79
Specific heat of monatomic perfect gases of vibrational frequencies, solids 225—255
Specific heat of polyatomic gases 136—149
Specific heat of solids 203—205 213—214 222—255
Specific heat variation with pressure and volume 116
Spectrum, infrared, of crystals 254—255
Spectrum, optical, and Kirchhoff's law 309—310
Spin, electronic 339
Spin, electronic and interatomic forces 369—374
Spin, electronic and metals 476
Spontaneous emission 324
standing waves 226—231 242—252
Standing waves of electrons in metals 489—501
Stationary states, of electrons in atoms 321—323 338—344
Stationary states, of oscillator and rotator 41—42
Statistical mechanics 14 32—85
Statistical mechanics, applied to black body radiation 307—320
Statistical mechanics, applied to chemical equilibrium 154—158
Statistical mechanics, applied to equation of state of solids 211—221
Statistical mechanics, applied to equilibrium between phases and vapor pressure 178—180
Statistical mechanics, applied to melting 265—269
Statistical mechanics, applied to perfect gas 124—129
Statistical mechanics, applied to polyatomic gases 138—140 142—145
Statistical mechanics, applied to second virial coefficient 190—196
Statistical mechanics, applied to solubility and phase equilibrium 270—304
Stefan — Boltzmann law 307—313
Stirling's theorem 70—72
Streamline flow of representative points 37 94
Stresses and strains 17 199
Strontium oxide, sulphide, selenide, telluride, data regarding crystals 381
Strontium, crystal structure 447
Strontium, equation of state 451
Sugar, phase equilibrium in solution 270
Sulphate ion 357 398
Sulphur dioxide, valence structure of molecule 406
Sulphur dioxide, Van der Waals constants 408
Supercooling 181 256—258 262—264
Tantalum, crystal structure 447
Tantalum, equation of state 451
Tellurium, crystal structure 444 447 450
Temperature 9 12—14 17
Temperature and kinetic method 96
Temperature bath, and canonical assembly 46—47
Temperature bath, and fluctuations 101
Temperature of inversion, Joule — Thomson effect 198
Temperature-entropy diagram 172
Terms, spectroscopic 323
Thallium bromide, data regarding melting point 259
Thallium chloride, data regarding crystals 382
Thallium chloride, data regarding melting point 259
Thallium iodide, data regarding crystals 382
Thallium, crystal structure 447
Thallium, data regarding melting point 259
Thermal equilibrium 37—38 46—51
Thermal equilibrium and kinetic method 96 98
Thermal expansion 19 200—220 238—240 261
Thermal expansion of ionic crystals 392—394
Thermal expansion of metals 450—456
Thermal pressure 217—218
Thermionic emission 460—471 480—484
Thermodynamic formulas 16 23—30
Thermodynamic formulas, table of 27—29
Thermodynamic probability 34
Thermodynamic probability and Fermi — Dirac and Einstein — Bose statistics 69—72
Thermodynamic scale of temperature 30—31
Thermodynamics 14 16—31
Thermodynamics, applied to black-body radiation 307—320
Thermodynamics, applied to chemical equilibrium 154—158
Thermodynamics, applied to equation of state of solids 199—211
Thermodynamics, applied to equilibrium, between atoms and electrons 333—335
Thermodynamics, applied to equilibrium, between metal and gas 463—464
Thermodynamics, applied to equilibrium, between phases 174—178
Thermodynamics, applied to perfect gas 115—124
Thermodynamics, applied to solubility and phase equilibrium 270—304
Thermodynamics, applied to Van der Waals' equation 184—189
Threshold, Photoelectric 318
Tin, crystal structure 444 447—449
Tin, data regarding melting point 259
Tin, Debye temperature 237
Titanium, crystal structure 447
Transition probability 42 88
Transition probability, of atoms 322—333
Transverse waves, in electromagnetic radiation 313—314
Transverse waves, in solids 222—240
Traveling waves 226—228
Triethylamine, Van der Waals constants 408
Trimethylamine, structure of molecule 427
Trimethylamine, Van der Waals constants 408
Triple point 166—167 171—172 181
Triple point and eutectic 285
Tungsten, crystal structure 447
Tungsten, equation of state and energy 451 454
Uncertainty principle 40—41
Undetermined multipliers 48
Valence forces 130
Valence forces, explanations from atomic theory 371—376
Van der Waals constants 182—198
Van der Waals constants for molecular substances 407—414
Van der Waals forces 182—198
Van der Waals forces and atomic structure 356—374
Van der Waals forces and inert gases 385
Van der Waals forces and molecular substances 407—414
Van der Waals forces and solutions 273
Van der Waals' equation 182—198 210
Van der Waals' equation and molecular substances 407—414
Van't Hoff's equation 154—158
Vanadium, crystal structure 447
Vanadium, equation of state 451
vapor pressure 166—169 174—180
Vapor pressure and Van der Waals' equation 188—189
Vaporization 23
Vaporization and Van der Waals' equation 189 258—260
Vaporization entropy of 171—180
Vaporization heat of 171—180
Vaporization of metals 452—454
Vaporization of organic compounds, table 434
Vaporization table of 414
Velocity, of elastic waves 227—240
Velocity, of light 308
Vibration, and light waves 313—314
Vibration, of diatomic molecules 140—149
Vibration, of molecules and atoms in crystals 211—255
Vibrational degrees of freedom 146
Virial 190—196
viscosity 12 13 257
Volt, electron 132—133 318
Volta effect 467—471
Volume 17
Volume and chemical equilibrium 151—158
Volume and phase equilibrium 168—178
Volume molecular, table of 261
Volume of imperfect gases, and Van der Waals' equation 182—198
Volume of liquids, table 408
Volume of perfect gas 58—61
Volume of solids 199—221
Water glass 438
Water, and solubility 270—275 285—290
Water, crystal structure 260 418—419
Water, data regarding melting point 259
Water, dissociation into hydrogen and oxygen 151—164
Water, entropy and free energy 172—173
Water, equilibrium between phases 166—169
Water, heat of vaporization 414
Water, valence structure of molecule 401
Water, Van der Waals constants 408 412—414
Water, vapor pressure and latent heat of vaporization 188—189
Water, vibrational specific heat 146—147
Wave mechanics 41 307
Wave mechanics and electrons in periodic potential 489—501
Wave mechanics and radiation 323
Waves, elastic, in continuous media 227—234
Waves, electromagnetic, and light 308 313—320
Waves, in molecular media 241—252
Work 3 7—9 17 21—22
Work and statistical mechanics 49
Work function, thermionic and photoelectric 317—318 464 469—470 480—484
Wurtzite, crystal structure 379—380 382
X-ray diffraction, liquids 256
X-ray levels in atoms 344
Xenon, atomic volume 384
Xenon, data regarding crystals 416
Xenon, specific heat 130
Xenon, Van der Waals constants 408
Zinc oxide, sulphide, selenide, telluride, data regarding crystals 382
Zinc, crystal structure 447
Zinc, data regarding melting point 259
Zinc, Debye temperature 237
Zinc, energy 454
Zinc, order-disorder in alloys 293—304
Zinc, phase equilibrium in alloys 270 287—288
Zincblende, crystal structure 379—381 382
Zirconium, crystal structure 447
Zirconium, equation of state 451
Ðåêëàìà