Àâòîðèçàöèÿ
Ïîèñê ïî óêàçàòåëÿì
Slater J.C. — Introduction To Chemical Physics
Îáñóäèòå êíèãó íà íàó÷íîì ôîðóìå
Íàøëè îïå÷àòêó? Âûäåëèòå åå ìûøêîé è íàæìèòå Ctrl+Enter
Íàçâàíèå: Introduction To Chemical Physics
Àâòîð: Slater J.C.
Àííîòàöèÿ: It is probably unfortunate that physics and chemistry over were separated. Chemistry is the science of atoms and of the way they com bine. Physics deals with the interatomic forces and with the large-scale properties of matter resulting from those forces. So long as chemistry was largely empirical and nonmathematical, and physics had not learned how to treat small-scale atomic forces, the two sciences seemed widely separated. But with statistical mechanics and the kinetic theory on the one hand and physical chemistry on the other, the two sciences began to come together. Now that statistical mechanics has led to quantum theory and wave mechanics, with its explanations of atomic interactions, there is really nothing separating them any more. A few years ago, though their ideas were close together, their experimental methods were still quite different chemists dealt with things in test tubes, making solutions, pre cipitating and filtering and evaporating, while physicists measured every thing with galvanometers and spectroscopes. But even this distinction has disappeared, with more and more physical apparatus finding its way into chemical laboratories. A wide range of study is common to both subjects. The sooner we realize this the better. For want of abetter name, since Physical Chemistry is already preempted, we may call this common field Chemical Physics. It is an overlapping field in which both physicists and chemists should be trained. There 4 seems no valid reason why their training in it should differ. This book is an attempt to incorporate some of the material of this common field in a unified presentation. What should be included in a discussion of chemical physics Logi cally, we should start with fundamental principles. We should begin with mechanics, then present electromagnetic theory, and should work up to wave mechanics and quantum theory.
ßçûê:
Ðóáðèêà: Ôèçèêà /
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k: ed2k stats
Ãîä èçäàíèÿ: 1939
Êîëè÷åñòâî ñòðàíèö: 521
Äîáàâëåíà â êàòàëîã: 18.08.2009
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
Ïðåäìåòíûé óêàçàòåëü
Elastic vibrations of solids, and specific heat 222—255
Electron affinity 338
Electron gas, and Fermi — Dirac statistics 81
Electron gas, and metallic structure 475—484
Electron volt, numerical value 132—133 318
Electrons and atomic structure 337—351
Electrons and atomic structure and structure of metals 472—501
Electrostatics, and field in metal 472—489
Electrostatics, and interatomic forces 353—367
Electrostatics, and ionic crystals 385—390
Emission of radiation 309—310 317—320 322—333
Emissive power 309—310 325—326
Energy see “Conservation of energy; Internal energy; Kinetic energy; Potential energy“
Energy bands in metals 493—501
Energy density, in radiation 310—316 324—326
energy levels 41—42
Energy levels of atomic systems 322 338—344
Energy of activation 159—164 257
Ensemble see “Assembly”
Enthalpy, and Joule — Thomson effect 197—198
Enthalpy, and latent heats 175—178
Enthalpy, and thermodynamics 20—21
Entropy, and equilibrium of phases 170—173
Entropy, and fluctuations 107
Entropy, and kinetic method 89—91 98—99
Entropy, and phase change of second order 291—304
Entropy, and phase equilibrium in binary systems 272—290
Entropy, and statistical mechanics 32—35 43—51
Entropy, and thermodynamics 9—14 17—18 21
Entropy, in Fermi — Dirac and Einstein — Bose statistics 69—72
Entropy, of diatomic gas 140
Entropy, of fusion 171—180 258—269
Entropy, of mixture of gases 121—123 128—129
Entropy, of perfect gas 117—119 127
Entropy, of perfect gas, Fermi — Dirac statistics 78—79
Entropy, of solids 207—218
Entropy, of vaporization 171—180
Equation of state, and phase equilibrium 169—170
Equation of state, and radiation 325
Equation of state, and thermodynamics 16—18 22—23 29—30
Equation of state, between liquid and solid 266—269
Equation of state, between metals and electron gas 463—464
Equation of state, between phases 166—181 184—190
Equation of state, between phases in binary systems 270—290
Equation of state, chemical 150—165
Equation of state, of imperfect gases 182—198
Equation of state, of ionic crystals 385—396
Equation of state, of metals 450—456 479—480
Equation of state, of perfect gas 58—61
Equation of state, of perfect gas Fermi — Dirac statistics 82
Equation of state, of solids 199—221
Equation of state, thermal 13—15 23 37—38 46—51 96 98
Equilibrium, between atoms and electrons 333—335
Equipartition of energy, and Maxwell's distribution 57—58
Equipartition of energy, and specific heat, of polyatomic gases 134 144 146
Equipartition of energy, and specific heat, of solids 213
Ethane, heat of vaporization 434
Ethane, hindered rotation 147—148
Ethane, structure of molecule 402 420—421
Ethane, Van der Waals constants 408
Ethyl alcohol, data regarding melting point 259
Ethyl alcohol, heat of vaporization 434
Ethyl alcohol, Van der Waals constants 408
Ethyl ether, heat of vaporization 434
Ethyl ether, structure of molecule 427
Ethyl ether, Van der Waals constants 408
Ethylene, structure of molecule 402 428
Ethylene, Van der Waals constants 408 411
Eutectic 284—285
Exchange, and interatomic forces 367—374
Excitation of atoms 321—333 343
Exclusion principle 342
Exclusion principle and interatomic forces 369—372
Explosion 158—159
External work 3 7—9 17 21—22
External work and statistical mechanics 49
Face-centered cubic structure, and metals 445—447
Face-centered cubic structure, and molecular vibrations 232
Face-centered cubic structure, and order-disorder 293
Face-centered cubic structure, description and figure 415
Face-centered cubic structure, in inert gases 416
Fermi-Dirac statistics 52 65—85
Fermi-Dirac statistics and atomic structure 342
Fermi-Dirac statistics and exchange effect 369
Fermi-Dirac statistics and fluctuations 108—109
Fermi-Dirac statistics and kinetic method 96—100
Fermi-Dirac statistics and metals 471 475—484
Fermi-Dirac statistics and perfect gas 126
ferromagnetism 292—293
Fibers, silicate 439
Field, electric, and interatomic forces 359—360 366
Field, in metal 472—501
First law of thermodynamics 7—8 19
First law of thermodynamics and statistics 49—51
Fluctuations 32 101—111
Fluorite structure 396—397
Forces between molecules 130—133
Forces between molecules and Van der Waals' equation 182—184 194—196
Forces between molecules in solids 271—277
Forces between molecules interpretation from atomic theory 352—376
Formic acid, structure of molecule 427
Free electrons in metals 475—489
Free energy, Gibbs, and chemical equilibrium 154—158
Free energy, Gibbs, and equilibrium of phases 170—180
Free energy, Gibbs, and melting 265—269
Free energy, Gibbs, and phase changes of second order 296—304
Free energy, Gibbs, and phase equilibrium in binary systems 270 278—290
Free energy, Gibbs, and thermionic emission 463—464
Free energy, Gibbs, and thermodynamics 22—23
Free energy, Gibbs, and Van der Waals' equation 184—189
Free energy, Gibbs, of diatomic gas 140
Free energy, Gibbs, of mixture of gases 123—124
Free energy, Gibbs, of perfect gas 120
Free energy, Gibbs, of solids 205—211
Free energy, Helmholtz, and Fermi — Dirac and Einstein — Bose statistics 73 79 82
Free energy, Helmholtz, and melting 265—269
Free energy, Helmholtz, and second virial coefficient 193—194
Free energy, Helmholtz, and statistical mechanics 50—51
Free energy, Helmholtz, and thermodynamics 21—22
Free energy, Helmholtz, of perfect gas 119 126
Free energy, Helmholtz, of solids 205—211 216—218
Free expansion of gas 30 196—198
Freezing see “Melting”
Frequency of oscillation, diatomic molecule 141
Frequency of oscillation, molecular solid 241—255
Frequency of oscillation, solid 213—240
Friction 3
Fusion 23 166—169 171—176 256—269
Gallium, crystal structure 447
Gallium, data regarding melting point 259
Gas constant 33
Gas constant numerical values 60
Gases, and equilibrium with other phases 166—180
Gases, imperfect, and Van der Waals' equation 182—198
Gases, perfect 17 30
Gases, perfect and Maxwell — Boltzmann distribution 53—64
Gases, perfect, chemical equilibrium in 150—165
Gases, perfect, polyatomic 130—149
Gases, perfect, thermodynamic and statistical treatment 115—129
Gases, perfect, translational energy levels in quantum theory 54—55
Gases, Van der Waals constants 408
Gauss error curve 106
Germanium, crystal structure 444 447—449
Germanium, melting point 449
Gibbs 32 44 107
Gibbs free energy see “Free energy Gibbs”
Gibbs's paradox 129
Glass 256—258
Glass structure 442
Glass variability of composition 273
Gliding 457
Gold, crystal structure 447
Gold, data regarding melting point 259
Gold, Debye temperature 237
Gold, equation of state and energy 451 454
Gold, order-disorder in alloys 293—294
Graphite structure 429
Gravity 4
Gruneisen, of ionic crystals 392—394
Gruneisen, of metals 451—456
Gruneisen, thermal expansion 217—221 238—240
H theorem 90
Hafnium, crystal structure 447
Hafnium, equation of state 451
Halogens, and homopolar bonds 400—408
Halogens, and organic compounds 425—426
Halogens, characteristic temperature, for rotation 136
Halogens, characteristic temperature, for vibration 142
Halogens, data regarding melting point 259
Halogens, heat of dissociation, interatomic distance, Morse constant 132
Heat absorption 7—9 12—13 20
Heat absorption and statistical mechanics 49
heat capacity see “Specific heat”
heat engine 13 172
Heat flow 12—13
Heat, latent see “Latent heat of of
Heat, of dissociation, and equilibrium of ions and electrons 334
Heat, of dissociation, diatomic molecules, table 132
Heat, of reaction 156—158
Heat, specific see “Specific heat”
Heitler — London method 367—368
Helium, specific heat 130
Helium, Van der Waals constants 408
Helmholtz free energy see “Free energy Helmholtz”
Hexagonal close-packed structure, and metals 445—447
Hexagonal close-packed structure, and molecular vibration 232
Hexagonal close-packed structure, description and figure 417
Hexane, structure of molecule 423
Hindered rotation 147—149 417—418
Homopolar valence attraction 373—376 400—407
Homopolar valence attraction and organic compounds 420—434
Homopolar valence attraction and silicates 435—443
Hydrogen bromide, data regarding melting point 259
Hydrogen bromide, valence structure 404—405
Hydrogen bromide, Van der Waals constants 408
Hydrogen chloride, characteristic temperature, for rotation 136
Hydrogen chloride, characteristic temperature, for vibration 142
Hydrogen chloride, crystal structure and hindered rotation 417
Hydrogen chloride, data regarding melting point 259
Hydrogen chloride, dipole moment 358
Hydrogen chloride, heat of dissociation, interatomic distance, Morse constant 132
Hydrogen chloride, heat of vaporization 414
Hydrogen chloride, valence structure 404—405
Hydrogen chloride, Van der Waals constants 408
Hydrogen sulphide, valence structure 405
Hydrogen sulphide, Van der Waals constants 408
Hydrogen, and homopolar bonds 400—408
Hydrogen, and organic compounds 420—434
Hydrogen, characteristic temperature, for rotation 136
Hydrogen, characteristic temperature, for vibration 142
Hydrogen, combination with oxygen to form water 151—164
Hydrogen, data regarding melting point 259
Hydrogen, heat of dissociation, interatomic distance, Morse constant 132
Hydrogen, heat of vaporization 414
Hydrogen, interatomic potential 371
Hydrogen, specific heat 137—138
Hydrogen, Van der Waals constants 408 411
Ice, crystal structure 412 418—419
Ice, polymorphic forms 167—170
Ice, structure 260
Image force 461 474—475
Impenetrability of matter 130
Imperfect gases, and phase equilibrium 166—170
Imperfect gases, and Van der Waals' equation 182—198
Independent variables 17—18
Indium, crystal structure 447
Indium, data regarding melting point 259
Induced emission 325
Inelastic collisions 327
Inert gases, and periodic table 345—350
Inert gases, crystals 416
Inert gases, volumes of atoms 384
Insulators, and energy bands 495—501
Integrals independent of path 8 13
Interatomic distances, in crystals of inert gases 416
Interatomic distances, in crystals, and formulas for thermodynamic quantities 212—213
Interatomic distances, in diatomic molecules, table 132
Interatomic distances, in ionic crystals, table 381—382
Interatomic distances, in metals 447
Interatomic distances, in organic compounds 420—434
Interatomic forces 130—133
Interatomic forces, and second virial coefficient 191—196
Interatomic forces, and Van der Waals' equation 182—184
Interatomic forces, and vibrations of atoms in crystals 211—240
Interatomic forces, in ionic crystals 385—390
Interatomic forces, in metals 451—456
Interatomic forces, in organic compounds 433
Interatomic forces, interpretation from atomic theory 352—376
Interference of light, and quantum theory 319—320
Intermolecular forces, in gases 410—414
Internal energy 6—9 17
Internal energy and melting 258—269
Internal energy and phase change of second order 295 301
Internal energy at absolute zero 179
Internal energy of mixture of gases 123
Internal energy of perfect gas, Boltzmann statistics 117
Internal energy of perfect gas, Fermi — Dirac statistics 77—78 81—82
Internal energy of solids 205—220
Internal energy of solutions 275—277
Internal pressure 182—184
Iodine, and homopolar bond 400—408
Iodine, and organic compounds 426
Iodine, characteristic temperature, for rotation 136
Iodine, characteristic temperature, for vibration 142
Iodine, crystal structure 418
Iodine, dissociation 133
Iodine, heat of dissociation, interatomic distance, Morse constant 132
Ionic crystals 375 377—399
Ionic radii 382—385
Ionization potential 322 334 343
Ionization potential, table of 348
Ionization, of atoms 321—335
Ions, and atomic structure 321—335 337—338 351
Ions, forces between 357—358
Ions, formation in solution 272—274 290
Iridium, crystal structure 447
Iron, crystal structure 447
Iron, data regarding melting point 259 261
Iron, Debye temperature 237
Iron, equation of state and crystal structure 451 454
Iron, molecular volume 261
Iron, thermal expansion 261
Irreversible process 11—13 16
Irreversible process and kinetic approach to equilibrium 86—92 96—98
Irreversible process and statistical mechanics 43—46
Isomers 423
Isothermal processes 19
Isothermals, and Van der Waals equation 184—186
Isothermals, of solid 200
Isotopes 336—337
Joule 5
Joule — Thomson effect 195—198
Joule's law 30 115
Kinetic energy, and exchange effect 369
Kinetic energy, and exchange effect and Maxwell — Boltzmann law 60
Kinetic energy, and exchange effect of polyatomic molecules 134 144
Kinetic theory 15 86—100
Kinetic theory and chemical reactions 151—154 158—165
Kinetic theory and radiation 324—333
Kinetic theory and thermionic emission 465—471 480—484
Ðåêëàìà