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Slater J.C. — Introduction To Chemical Physics
Slater J.C. — Introduction To Chemical Physics



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Íàçâàíèå: Introduction To Chemical Physics

Àâòîð: Slater J.C.

Àííîòàöèÿ:

It is probably unfortunate that physics and chemistry over were separated. Chemistry is the science of atoms and of the way they com bine. Physics deals with the interatomic forces and with the large-scale properties of matter resulting from those forces. So long as chemistry was largely empirical and nonmathematical, and physics had not learned how to treat small-scale atomic forces, the two sciences seemed widely separated. But with statistical mechanics and the kinetic theory on the one hand and physical chemistry on the other, the two sciences began to come together. Now that statistical mechanics has led to quantum theory and wave mechanics, with its explanations of atomic interactions, there is really nothing separating them any more. A few years ago, though their ideas were close together, their experimental methods were still quite different chemists dealt with things in test tubes, making solutions, pre cipitating and filtering and evaporating, while physicists measured every thing with galvanometers and spectroscopes. But even this distinction has disappeared, with more and more physical apparatus finding its way into chemical laboratories. A wide range of study is common to both subjects. The sooner we realize this the better. For want of abetter name, since Physical Chemistry is already preempted, we may call this common field Chemical Physics. It is an overlapping field in which both physicists and chemists should be trained. There 4 seems no valid reason why their training in it should differ. This book is an attempt to incorporate some of the material of this common field in a unified presentation. What should be included in a discussion of chemical physics Logi cally, we should start with fundamental principles. We should begin with mechanics, then present electromagnetic theory, and should work up to wave mechanics and quantum theory.


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Ðóáðèêà: Ôèçèêà/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Ãîä èçäàíèÿ: 1939

Êîëè÷åñòâî ñòðàíèö: 521

Äîáàâëåíà â êàòàëîã: 18.08.2009

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Elastic vibrations of solids, and specific heat      222—255
Electron affinity      338
Electron gas, and Fermi — Dirac statistics      81
Electron gas, and metallic structure      475—484
Electron volt, numerical value      132—133 318
Electrons and atomic structure      337—351
Electrons and atomic structure and structure of metals      472—501
Electrostatics, and field in metal      472—489
Electrostatics, and interatomic forces      353—367
Electrostatics, and ionic crystals      385—390
Emission of radiation      309—310 317—320 322—333
Emissive power      309—310 325—326
Energy      see “Conservation of energy; Internal energy; Kinetic energy; Potential energy“
Energy bands in metals      493—501
Energy density, in radiation      310—316 324—326
energy levels      41—42
Energy levels of atomic systems      322 338—344
Energy of activation      159—164 257
Ensemble      see “Assembly”
Enthalpy, and Joule — Thomson effect      197—198
Enthalpy, and latent heats      175—178
Enthalpy, and thermodynamics      20—21
Entropy, and equilibrium of phases      170—173
Entropy, and fluctuations      107
Entropy, and kinetic method      89—91 98—99
Entropy, and phase change of second order      291—304
Entropy, and phase equilibrium in binary systems      272—290
Entropy, and statistical mechanics      32—35 43—51
Entropy, and thermodynamics      9—14 17—18 21
Entropy, in Fermi — Dirac and Einstein — Bose statistics      69—72
Entropy, of diatomic gas      140
Entropy, of fusion      171—180 258—269
Entropy, of mixture of gases      121—123 128—129
Entropy, of perfect gas      117—119 127
Entropy, of perfect gas, Fermi — Dirac statistics      78—79
Entropy, of solids      207—218
Entropy, of vaporization      171—180
Equation of state, and phase equilibrium      169—170
Equation of state, and radiation      325
Equation of state, and thermodynamics      16—18 22—23 29—30
Equation of state, between liquid and solid      266—269
Equation of state, between metals and electron gas      463—464
Equation of state, between phases      166—181 184—190
Equation of state, between phases in binary systems      270—290
Equation of state, chemical      150—165
Equation of state, of imperfect gases      182—198
Equation of state, of ionic crystals      385—396
Equation of state, of metals      450—456 479—480
Equation of state, of perfect gas      58—61
Equation of state, of perfect gas Fermi — Dirac statistics      82
Equation of state, of solids      199—221
Equation of state, thermal      13—15 23 37—38 46—51 96 98
Equilibrium, between atoms and electrons      333—335
Equipartition of energy, and Maxwell's distribution      57—58
Equipartition of energy, and specific heat, of polyatomic gases      134 144 146
Equipartition of energy, and specific heat, of solids      213
Ethane, heat of vaporization      434
Ethane, hindered rotation      147—148
Ethane, structure of molecule      402 420—421
Ethane, Van der Waals constants      408
Ethyl alcohol, data regarding melting point      259
Ethyl alcohol, heat of vaporization      434
Ethyl alcohol, Van der Waals constants      408
Ethyl ether, heat of vaporization      434
Ethyl ether, structure of molecule      427
Ethyl ether, Van der Waals constants      408
Ethylene, structure of molecule      402 428
Ethylene, Van der Waals constants      408 411
Eutectic      284—285
Exchange, and interatomic forces      367—374
Excitation of atoms      321—333 343
Exclusion principle      342
Exclusion principle and interatomic forces      369—372
Explosion      158—159
External work      3 7—9 17 21—22
External work and statistical mechanics      49
Face-centered cubic structure, and metals      445—447
Face-centered cubic structure, and molecular vibrations      232
Face-centered cubic structure, and order-disorder      293
Face-centered cubic structure, description and figure      415
Face-centered cubic structure, in inert gases      416
Fermi-Dirac statistics      52 65—85
Fermi-Dirac statistics and atomic structure      342
Fermi-Dirac statistics and exchange effect      369
Fermi-Dirac statistics and fluctuations      108—109
Fermi-Dirac statistics and kinetic method      96—100
Fermi-Dirac statistics and metals      471 475—484
Fermi-Dirac statistics and perfect gas      126
ferromagnetism      292—293
Fibers, silicate      439
Field, electric, and interatomic forces      359—360 366
Field, in metal      472—501
First law of thermodynamics      7—8 19
First law of thermodynamics and statistics      49—51
Fluctuations      32 101—111
Fluorite structure      396—397
Forces between molecules      130—133
Forces between molecules and Van der Waals' equation      182—184 194—196
Forces between molecules in solids      271—277
Forces between molecules interpretation from atomic theory      352—376
Formic acid, structure of molecule      427
Free electrons in metals      475—489
Free energy, Gibbs, and chemical equilibrium      154—158
Free energy, Gibbs, and equilibrium of phases      170—180
Free energy, Gibbs, and melting      265—269
Free energy, Gibbs, and phase changes of second order      296—304
Free energy, Gibbs, and phase equilibrium in binary systems      270 278—290
Free energy, Gibbs, and thermionic emission      463—464
Free energy, Gibbs, and thermodynamics      22—23
Free energy, Gibbs, and Van der Waals' equation      184—189
Free energy, Gibbs, of diatomic gas      140
Free energy, Gibbs, of mixture of gases      123—124
Free energy, Gibbs, of perfect gas      120
Free energy, Gibbs, of solids      205—211
Free energy, Helmholtz, and Fermi — Dirac and Einstein — Bose statistics      73 79 82
Free energy, Helmholtz, and melting      265—269
Free energy, Helmholtz, and second virial coefficient      193—194
Free energy, Helmholtz, and statistical mechanics      50—51
Free energy, Helmholtz, and thermodynamics      21—22
Free energy, Helmholtz, of perfect gas      119 126
Free energy, Helmholtz, of solids      205—211 216—218
Free expansion of gas      30 196—198
Freezing      see “Melting”
Frequency of oscillation, diatomic molecule      141
Frequency of oscillation, molecular solid      241—255
Frequency of oscillation, solid      213—240
Friction      3
Fusion      23 166—169 171—176 256—269
Gallium, crystal structure      447
Gallium, data regarding melting point      259
Gas constant      33
Gas constant numerical values      60
Gases, and equilibrium with other phases      166—180
Gases, imperfect, and Van der Waals' equation      182—198
Gases, perfect      17 30
Gases, perfect and Maxwell — Boltzmann distribution      53—64
Gases, perfect, chemical equilibrium in      150—165
Gases, perfect, polyatomic      130—149
Gases, perfect, thermodynamic and statistical treatment      115—129
Gases, perfect, translational energy levels in quantum theory      54—55
Gases, Van der Waals constants      408
Gauss error curve      106
Germanium, crystal structure      444 447—449
Germanium, melting point      449
Gibbs      32 44 107
Gibbs free energy      see “Free energy Gibbs”
Gibbs's paradox      129
Glass      256—258
Glass structure      442
Glass variability of composition      273
Gliding      457
Gold, crystal structure      447
Gold, data regarding melting point      259
Gold, Debye temperature      237
Gold, equation of state and energy      451 454
Gold, order-disorder in alloys      293—294
Graphite structure      429
Gravity      4
Gruneisen, of ionic crystals      392—394
Gruneisen, of metals      451—456
Gruneisen, thermal expansion      217—221 238—240
H theorem      90
Hafnium, crystal structure      447
Hafnium, equation of state      451
Halogens, and homopolar bonds      400—408
Halogens, and organic compounds      425—426
Halogens, characteristic temperature, for rotation      136
Halogens, characteristic temperature, for vibration      142
Halogens, data regarding melting point      259
Halogens, heat of dissociation, interatomic distance, Morse constant      132
Heat absorption      7—9 12—13 20
Heat absorption and statistical mechanics      49
heat capacity      see “Specific heat”
heat engine      13 172
Heat flow      12—13
Heat, latent      see “Latent heat of of
Heat, of dissociation, and equilibrium of ions and electrons      334
Heat, of dissociation, diatomic molecules, table      132
Heat, of reaction      156—158
Heat, specific      see “Specific heat”
Heitler — London method      367—368
Helium, specific heat      130
Helium, Van der Waals constants      408
Helmholtz free energy      see “Free energy Helmholtz”
Hexagonal close-packed structure, and metals      445—447
Hexagonal close-packed structure, and molecular vibration      232
Hexagonal close-packed structure, description and figure      417
Hexane, structure of molecule      423
Hindered rotation      147—149 417—418
Homopolar valence attraction      373—376 400—407
Homopolar valence attraction and organic compounds      420—434
Homopolar valence attraction and silicates      435—443
Hydrogen bromide, data regarding melting point      259
Hydrogen bromide, valence structure      404—405
Hydrogen bromide, Van der Waals constants      408
Hydrogen chloride, characteristic temperature, for rotation      136
Hydrogen chloride, characteristic temperature, for vibration      142
Hydrogen chloride, crystal structure and hindered rotation      417
Hydrogen chloride, data regarding melting point      259
Hydrogen chloride, dipole moment      358
Hydrogen chloride, heat of dissociation, interatomic distance, Morse constant      132
Hydrogen chloride, heat of vaporization      414
Hydrogen chloride, valence structure      404—405
Hydrogen chloride, Van der Waals constants      408
Hydrogen sulphide, valence structure      405
Hydrogen sulphide, Van der Waals constants      408
Hydrogen, and homopolar bonds      400—408
Hydrogen, and organic compounds      420—434
Hydrogen, characteristic temperature, for rotation      136
Hydrogen, characteristic temperature, for vibration      142
Hydrogen, combination with oxygen to form water      151—164
Hydrogen, data regarding melting point      259
Hydrogen, heat of dissociation, interatomic distance, Morse constant      132
Hydrogen, heat of vaporization      414
Hydrogen, interatomic potential      371
Hydrogen, specific heat      137—138
Hydrogen, Van der Waals constants      408 411
Ice, crystal structure      412 418—419
Ice, polymorphic forms      167—170
Ice, structure      260
Image force      461 474—475
Impenetrability of matter      130
Imperfect gases, and phase equilibrium      166—170
Imperfect gases, and Van der Waals' equation      182—198
Independent variables      17—18
Indium, crystal structure      447
Indium, data regarding melting point      259
Induced emission      325
Inelastic collisions      327
Inert gases, and periodic table      345—350
Inert gases, crystals      416
Inert gases, volumes of atoms      384
Insulators, and energy bands      495—501
Integrals independent of path      8 13
Interatomic distances, in crystals of inert gases      416
Interatomic distances, in crystals, and formulas for thermodynamic quantities      212—213
Interatomic distances, in diatomic molecules, table      132
Interatomic distances, in ionic crystals, table      381—382
Interatomic distances, in metals      447
Interatomic distances, in organic compounds      420—434
Interatomic forces      130—133
Interatomic forces, and second virial coefficient      191—196
Interatomic forces, and Van der Waals' equation      182—184
Interatomic forces, and vibrations of atoms in crystals      211—240
Interatomic forces, in ionic crystals      385—390
Interatomic forces, in metals      451—456
Interatomic forces, in organic compounds      433
Interatomic forces, interpretation from atomic theory      352—376
Interference of light, and quantum theory      319—320
Intermolecular forces, in gases      410—414
Internal energy      6—9 17
Internal energy and melting      258—269
Internal energy and phase change of second order      295 301
Internal energy at absolute zero      179
Internal energy of mixture of gases      123
Internal energy of perfect gas, Boltzmann statistics      117
Internal energy of perfect gas, Fermi — Dirac statistics      77—78 81—82
Internal energy of solids      205—220
Internal energy of solutions      275—277
Internal pressure      182—184
Iodine, and homopolar bond      400—408
Iodine, and organic compounds      426
Iodine, characteristic temperature, for rotation      136
Iodine, characteristic temperature, for vibration      142
Iodine, crystal structure      418
Iodine, dissociation      133
Iodine, heat of dissociation, interatomic distance, Morse constant      132
Ionic crystals      375 377—399
Ionic radii      382—385
Ionization potential      322 334 343
Ionization potential, table of      348
Ionization, of atoms      321—335
Ions, and atomic structure      321—335 337—338 351
Ions, forces between      357—358
Ions, formation in solution      272—274 290
Iridium, crystal structure      447
Iron, crystal structure      447
Iron, data regarding melting point      259 261
Iron, Debye temperature      237
Iron, equation of state and crystal structure      451 454
Iron, molecular volume      261
Iron, thermal expansion      261
Irreversible process      11—13 16
Irreversible process and kinetic approach to equilibrium      86—92 96—98
Irreversible process and statistical mechanics      43—46
Isomers      423
Isothermal processes      19
Isothermals, and Van der Waals equation      184—186
Isothermals, of solid      200
Isotopes      336—337
Joule      5
Joule — Thomson effect      195—198
Joule's law      30 115
Kinetic energy, and exchange effect      369
Kinetic energy, and exchange effect and Maxwell — Boltzmann law      60
Kinetic energy, and exchange effect of polyatomic molecules      134 144
Kinetic theory      15 86—100
Kinetic theory and chemical reactions      151—154 158—165
Kinetic theory and radiation      324—333
Kinetic theory and thermionic emission      465—471 480—484
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