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| Fowler R.H. — Statistical thermodynamics: A version of statistical mechanics for students of physics and chemistry |
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Íàçâàíèå: Statistical thermodynamics: A version of statistical mechanics for students of physics and chemistry
Àâòîð: Fowler R.H.
ßçûê: 
Ðóáðèêà: Ôèçèêà/
Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö
ed2k:
Ãîä èçäàíèÿ: 1956
Êîëè÷åñòâî ñòðàíèö: 701
Äîáàâëåíà â êàòàëîã: 26.03.2008
Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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| Ïðåäìåòíûé óêàçàòåëü |
Absolute activity of electrons 458
Absolute activity of gases 170
Absolute activity, statistically defined 66
Absolute temperature scale 39
Absolute zero, extrapolation of thermodynamic functions to 192—194
Absolute zero, unattainability of 224 655
Accessibility 10—17
Accessibility, effect of symmetry type on 16
Accessibility, effect of uniform integrals on 11
Accessible states for localized systems 20
Accessible states, enumerated 19—22
Activated complex in bimolecular reactions 510 535
Activation energy for transport in imperfect crystals 549
Activation energy of unimolecular reactions 520
Activity coefficients in electrolytes 381—383
Activity coefficients in electrolytes from Debye’s approximation 399—401
Activity coefficients in electrolytes, compared with experiment 401—403
Activity coefficients, ionic, Guentelberg’s evaluation 407
Adhesion, free energy of, between liquid and vapour 445—448
Adsorption isotherm, atomic, for diatomic molecules 428
Adsorption isotherm, Langmuir’s 427
Adsorption isotherm, refined formula 441—443
Adsorption, Gibbs’ formula for 423 444
Alloys see metallic alloys
Amagat unit of volume, defined 282
Antisymmetrical Eigen functions 16
Assemblies gaseous dissociating 158—160
Assemblies gaseous dissociating, thermodynamic functions for 160—162
Assemblies, classical behaviour of 8—10
Assemblies, defined 1
Assemblies, external reactions of 54
Assemblies, obeying Bose — Einstein’s statistics 45
Assemblies, obeying Fermi — Dirac statistics 47
Assemblies, Schroedinger’s equation for 5 sqq.
Assemblies, stationary states of 4—7
Associated ion pairs, defined 411
Assumptions, fundamental, of statistical mechanics 3 7 18
Atomic constitution of matter 3
Averages, relevance of 2
Averaging, rules for 7
Avogadro’s law 71
Avogadro’s law, Perrin’s determination of 77
Avogadro’s number 69
Bands of electron states in crystals 466
Bands of electron states in metals 469—471
Barclay and Butler, Trouton’s rule 335
Beattie and Bridgman equation of state 276
Beattie, table of Debye’s function 144
Bernal classification of liquids 320
Bernal structure of water 380
Berthelot equation of state 274
Bethe’s method for order-disorder 589—595
Bethe’s method, equivalent of quasi-chemical method 595—598
Bimolecular reactions in solutions 530—536
Bimolecular reactions, activated complex in 510
Bimolecular reactions, activation energy for rate of 504
Bimolecular reactions, associated complex in 510
Bimolecular reactions, empirical form for rate of 504
Bimolecular reactions, kinetic salt effects on 536—540
Bimolecular reactions, refined theory of rate of 509—512
Bimolecular reactions, refined theory of rate of, applied 514—517
Bimolecular reactions, second order 501—505
Bimolecular reactions, simple and refined theories of, compared 512—514
Bimolecular reactions, simple collision theory of 505—509
Bimolecular reactions, temperature coefficient of rate of 503
Binary mixtures, second virial coefficient for 296—300
Bjerrum relation between osmotic and activity coefficients 382
Bjerrum theory of ionic association 409—412
Blackman heat capacity of crystals 126 131
Bohr’s correspondence principle 9
Boltzmann’s constant 68
Boltzmann’s constant distribution law 77
Boltzmann’s constant hypothesis 65
Boltzmann’s constant integro-differential equation 519
Born and Fuchs equation of state 301
Born and Goeppert-Mayer atomic theory of crystals 126
Born atomic theory of crystals 126
Born exposition of thermodynamics 38 56
Bose — Einstein statistics 45 49 159
Bose — Einstein statistics, obeyed by  , He 125
Boyle point, defined 281
Boyle’s law 71
Bragg and Williams approximation for order 570—574
Brillouin’s functions 630 676
Broensted and la Ìåã diameter of ions 403
Broensted kinetic salt effects 536—540
Buckingham intermolecular energies 279
Caratheodory principles of thermodynamics 56
Carnot’s theorem 57
Cauchy’s theorem, use of 34 48
Chang’s combinatory formula 696—698
Charles’ law 71
Chemical constants 171
Chemical constants in practical unite 197
Chemical constants of isotopic mixtures 174
Chemical equilibria 156 sqq.
Chemical equilibria in imperfect gases 271
Chemical kinetics 489 sqq.
Christiansen unimolecular reactions 519
Classical statistics 50—52
Clusius and Bartholeme heat capacity of HD,  93
Clusius and Bartholeme, and others vapour pressure data 200
Cluster of molecules, defined 305
Cluster of molecules, irreducible, defined 306
Cockcroft condensation temperatures on solids 436
Collisions in gas, classification of 491—494
Collisions in gas, number of energetic 494
Collisions in gas, number of head on energetic 494
Collisions in gas, number of, with internal energy 497—499
Collisions in solution, number of 531—534
Collisions in solution, number of energetic 533
Complexions, defined 10
Complexions, enumerated 29
Compressed gases, critical point for 345
Compressed gases, refined model for 336—350
Compressibility, effect of, on thermodynamic functions for electrolytes 398
Condensation, critical temperature of, on solid 435—437
Condensation, general theory of 301 sqq.
Condensation, theoretical point of, for vapour 311
Contact potential difference 486—488
Continuum, elastic, normal modes qf 127
Continuum, partition function for 129
Cooling by adiabatic demagnetization 653—655
Cooperative assemblies, defined 245
Correspondence principle 9
Corresponding states for heat capacities of crystals 145
Corresponding states of liquid and compressed gas 342—345
Crack field 640 671
Critical temperature for compressed gas 302 345
Critical temperature of condensation on solid 435—437
Critical temperature, customary theory of 314—318
Critical temperature, derived from  303
Critical temperature, nature of isotherms near 311 316
Critical temperature, surface tension near 450
Crystal-vapour equilibrium 175—177 179—181
Crystal-vapour equilibrium with inert gas 177
Crystalline field, asymmetry of 628
Crystalline field, effect on entropy of 656—658
Crystalline field, effect on paramagnetic susceptibility of 626—629
Crystalline field, Jahn and Teller’s theorem on 628
Crystalline field, Kramers’ theorem on 627
Crystals  , comparison of theory and experiment for 604 606
Crystals bands of electron states in 466
Crystals, distribution laws in 135
Crystals, equation of state of 149
Crystals, heat capacities of 141—149
Crystals, heat capacities of, for molecular,  -law 153
Crystals, heat capacity of, from elastic constants 148
Crystals, heat capacity, law of corresponding states for 145
Crystals, molecular, thermodynamic functions for 150—154
| Crystals, normal model of, Debye’s approximation for 133
Crystals, normal model of, Einstein’s approximation for 131
Crystals, partition function of, Debye’s approximation 133
Crystals, perfect 126 sqq.
Crystals, perfect mixed, partition function for 154
Crystals, perfect mixed, thermodynamic functions for 137—140 184
Crystals, reactions between, transition points of 198
Crystals, solutions of impurities in 552
Crystals, vapour pressure of see vapour pressure
Curie temperature for ferromagnetism 677
Curie temperature for order 573
Curie temperature for order, variation with composition 589
Curie’s law for paramagnetic susceptibility 619 626 629
Dalton’s law 71
Deactivation rate, importance of 520
Debye approximation for normal modes of crystals 133
Debye electrolytes, theory of see electrolytes
Debye heat capacity of crystals 126
Debye second virial coefficient for polar molecules 294—296
Degenerate systems 50
Degrees of freedom, classical 78
Degrees of freedom, electronic 79
Degrees of freedom, unexcited 79
Delbrueck and Moliere grand partition functions 232
Demagnetization, cooling by adiabatic 653—655
Demagnetizing coefficient 671
Dennison heat capacity of 91
Desorption, energy of 444
Devonshire mobile monolayers 425
Diamagnetic susceptibility of electron gas 668—670
Diamagnetic susceptibility, atomic 613—615
Diamagnetic susceptibility, defined 610
Diamagnetic susceptibility, eliminated from paramagnetic 616
Diatomic molecules, dissociation of 165—169
Diatomic molecules, heat capacity of see heat capacity
Dielectric constant in theory of electrolytes 394—396
Dielectric constant of imperfect gases 650
Dielectric constant of liquids 643—650
Dielectric constant of liquids, Debye’s formula for 644—646
Dielectric constant of liquids, Onsager’s and Debye’s, compared 648
Dielectric constant of liquids, Onsager’s and van Vleck’s, compared 649
Dielectric constant of liquids, Onsager’s formula for 646—649
Dielectric constant of water 405
Dieterici equation of state 275
Dilute solutions 370—374
Dilute solutions, heat of dilution of 374
Dilute solutions, homogeneous chemical equilibria in 375
Dipole moments 639 (see also electric susceptibility)
Dispersion energy 277
Dissociation of diatomic molecules 165—169
Dissociation of isotopic diatomic molecules 167—169
Dissociative equilibrium in electrolytes 377—379
Dissociative equilibrium, constant of 173
Dissociative equilibrium, simple examples 158
Distribution laws Fermi — Dirac for electron gas 454—461
Distribution laws for electron velocities 459—461
Distribution laws in crystals 135
Distribution laws in imperfect gases 259—261
du Bridge photoelectric effect 483
Dulong and Petit’s law 142
Ehrenfest and Oppenheimer accessible states 20
Ehrenfest and Trkal dissociation theory 156 162
Ehrenfest and Trkal symmetry numbers, classical 87
Ehrenfest meaning of adiabatisch-reversibel 255
Eigen functions, antisymmetrical 16
Eigen functions, defined 4
Eigen functions, symmetrical 16
Einstein heat capacity of crystals 126
Einstein normal modes of crystals 131
Elastic constants, heat capacity of crystals from 148
Electric field inside matter 640
Electric susceptibility 608 sqq.
Electric susceptibility for independent systems 633—639
Electric susceptibility for independent systems effects due only to non-rotating systems 636—638
Electric susceptibility for independent systems experimental values 638
Electric susceptibility for independent systems, Debye’s formula for 634
Electric susceptibility for independent systems, quantal theory of, for rigid rotator 635
Electric susceptibility, atomic, defined 613
Electrolytes 377 sqq.
Electrolytes anomalies of strong 381—383
Electrolytes Boltzmann’s formula, use of, in 388
Electrolytes dissociation, degree of, in 377—379
Electrolytes dissociation, hydration effects on 379
Electrolytes Poisson’s equation, use of, in 385—387
Electrolytes, activity coefficients in 381—383
Electrolytes, Debye’s theory of 385 sqq.
Electrolytes, Debye’s theory of, critique of 405—409
Electrolytes, Debye’s theory of, dependence on dielectric constant of 394—396
Electrolytes, Debye’s theory of, self-consistency of 391
Electrolytes, heat of dilution in 403—405
Electrolytes, osmotic coefficients in 381—383 (see osmotic)
Electrolytes, partition functions for see partition function for electrolytes
Electronic heat capacity for  at high temperatures 104—106
Electronic heat capacity for NO at low temperatures 104
Electronic heat capacity in diatomic gases 102—106
Electrons in metals, heat capacity of 472—475
Electrons in metals, thermodynamic functions for 472
Electrons rate of evaporation of 477
Electrons, absolute activity of 458
Electrons, atmosphere of, elementary theory of 475
Electrons, degrees of freedom of, partition function for 79
Electrons, free, in metals, defined 465—469
Electrons, gas of, diamagnetic susceptibility of 668—670
Electrons, gas of, formulae for, adapted to metals 463—465
Electrons, gas of, paramagnetic susceptibility of 667
Electrons, gas of, statistics of 453—461
Electrons, gas of, thermodynamic functions for 461—463
Electrons, transmission coefficient of, across barriers 478
Electrons, vapour pressure constant of 476
Encounters in solutions, defined 534
Energy of activation see activation energy
Energy of vibrations, distribution of 495—497
Energy, equipartition of 121—124
Entropy of evaporation at boiling point 334
Entropy of liquids, glasses and solutions 217—219
Entropy of melting 329
Entropy of mixing 163
Entropy of paramagnetic salts 652
Entropy, absolute 191
Entropy, calorimetric and spectroscopic, compared 210—215
Entropy, calorimetric, defined 196
entropy, defined 57
Entropy, effect of crystalline field on 656—658
Entropy, effect of magnetic interactions on 658—660
Entropy, general form of, below 1° K. 661
Entropy, molecular, of gas and crystal 189—191
Entropy, spectroscopic (spins omitted), defined 196
Equation of state of crystals 149
Equation of state of imperfect gases, empirical 273—276
Equation of state of perfect gases 71
Equation of state, reduced 316
Equilibrium between vapour and crystal 175—177
Equilibrium for heterogeneous reactions 183
Equilibrium for order—disorder 567 sqq.
Equilibrium ortho—para separations, effect of, on 187
Equilibrium phase, condition for 64
Equilibrium theory, applicability of, to reaction rates 517—519
Equilibrium, chemical 156 sqq.
Equilibrium, chemical, general 164
Equilibrium, equivalence of thermodynamic and statistical laws for 62—65
Equilibrium, homogeneous gaseous in external fields 229
Equilibrium, homogeneous gaseous, comparison of theory and experiment 215—217
Equilibrium, thermodynamic form of laws of 65—67
Equipartition of energy 121—124
Eucken heat capacity of diatomic gases 101 104
Eucken vapour pressure constants 204 216
Eulerian angles 106
Evaporation, entropy of, at boiling point 334
Exclusion principle 17
External fields, classical hamiltonian for systems in 608—610
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