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Rao C>N> — Ultra-Violet and Visible Spectroscopy: Chemical Applications
Rao C>N> — Ultra-Violet and Visible Spectroscopy: Chemical Applications



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Название: Ultra-Violet and Visible Spectroscopy: Chemical Applications

Автор: Rao C>N>

Аннотация:

It would be superfluous to stress the importance of electronic .spectroscopy in structural or analytic research. It has now become a matter of routine to record the ultra-violet or visible spectra of compounds for purposes of identification or structure elucidation. The spectrophotonletric methods of analysis have replaced the conventional methods in ever so rnany instances. The number of-publications in the different branches of chemistry, reporting data on or making use of electronic spectroscopy, is ever-increasing and it would be impossible to review the field completely. In this book, I have tried to introduce the basic concepts of electronic spectroscopy and to present its applications in analytical, structural and physico-chemical problems. As far as possible, the rnateripl has been selected to illustrate the basic: principles of modern theories in chemistry. While surveying the data on organic molecules, several empirical generalizations have been discussed. lVlany of the more recent developments like tIle far ultra-violet spectra of organic molecules, fluorescence spectra, charge transfer spectra, ligand field theory, optical rotatory dispersion etc., have been briefly discussed in the latter part of the book. All through the discussion, the recent notations of electronic transitions have been used, although the other commonly encountered notations have also been mentioned. I shall be most gratified if this book can be of help to chemists in using electronic spectroscopy more effectively in research or routine work.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 1st edition

Год издания: 1961

Количество страниц: 164

Добавлена в каталог: 30.08.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Cyanine dyes      35 89 134
Cyanine dyes, association      79
Cyclic compounds      101
Cyclo-octanone      19
Cyclo-octatetraene      49
Cyclobutadiene      49
Cyclobutanone      19
Cyclodecanone      19
Cyclohepta-1:3-diene      26
Cycloheptanone      19
Cycloheptatrienylium carbonium ion      49
Cyclohex-1-enylethylene      26
Cyclohexa-1:3-diene      25 26
Cyclohexanone      19
Cyclohexene      61
Cyclononanone      19
Cyclopentadiene      26 52
Cyclopentanone      18 19
Cyclopentanones, $\alpha\beta$-unsaturated      29
Cyclopropane      15 90
Cyclopropyl conjugation      90
Cyclopropyl derivatives      90
Cyclopropyl group      41
Cyclopropyl ketones      90
Cyclopropyl-benzene      90
Decamethylbiphenyl      84
Depolarization      107
Di-aza-naphthalenes      54
Di-o-tolyl guanidine      104
Di-p-xylylene      89
Diacetyl      100
Diacetylenes      36
Diamagnetic solids      99
Dianisylmethylene anthrones      108
Dianthrone      109
Diaryl ketones      32
Dibiphenylene-butadiene      89
Dibiphenylene-ethylene      89
Dicarbonyl compounds      32
Dichroism, optical      121
Dichromates      143
Dienes      25 65 94
Dienes, cyclic      25 26
Dienes, heteroannular      67
Dienes, homoannular      67
Dienes, linear      25 26
Dienes, polycyclic      26 69
Dienes, semicyclic      25 26
Dienes, steroid      26 66
Dienes, triterpenoid      26
Dienones, $\alpha\beta$-unsaturated      67
Diethyl ether      61
Diethyl keten      37
Diethylnitrosoamine      23
Difference spectrum      67
Dihydrojasmone      29
Diketones      89
Diketones cyclic      32
Dimethylacetophenone      85
Dimethylanilines, substituted      85
Dimethylbiphenyls      82
Diolefins      92 94
Dioxane      52
Diphenyilbutadiene      106
Diphenyl sulphone      143
Diphenylamine      42
Diphenylmethane dyes      89
Diphenylmethylene anthrones      108
Diphenylphosphate      143
Diphenylpolyacetylenes      36
Diphenylpolyenes      33
Dipole-dipole forces      140
Dipole-polarization forces      140
Dispersion curve      137
Dispersion, molecular      137
Dispersive interactions      140
Dissociation, homolytic      2
Dixanthogen      19
Dixanthylene      109
Diynes      27
Dodecapentaenic acid      142
Double bond, effect of twisting      88
Drude equation      137
Dyestuffs      134 137
Dyestuffs, fluorescence      102
Elaeostearic acid      74
Electron affinity      113 115 116
Electron affinity, high      114
Electron excitation      112 116
Electron excitation, energy      113
Electron-acceptation volume      118
Electron-resonance spectra      134
Electronegativity      20
Electronic interactions, decreased      82
Electronic interactions, increased      89
Electronic interactions, new      89
Electronic transitions, classification      11
Electrostatic model      125
Emission spectra      121
Emission spectra, low-temperature      108
Empirical regularities      47
Energy levels for polyatomic molecules      2
Energy states      114
Enones, $\alpha\beta$-unsaturated      67
Enthalpy      118 120
entropy      118
Enyne alcohols      27
Enynes      27
Enzyme reactions      79
Epimerizations      138
Equilibria, monomer-dimer      143
Equilibrium constant      118 120 142
Equilibrium constant for complex formation      119
Ergosterol      26 73 78
Ergosterol-D      26
ethane      15
Ethers      93 100
Ethyl acetoacetate      70
Ethyl allene      37
Ethyl azide      37
Ethyl dithioacetate      19
Ethyl isothiocyanate      37
ethylene      10 11 93
Ethylene complexes with silver ion      121
Ethylene oxide      52 92
Ethylene oxide derivatives      90
Ethylene trithiocarbonate      20 23
Ethylene, substitution of      16
Ethylenes, alkyl-substituted      16
Ethylenes, substituted      108
Ethylidene-acetone      29
Exciton effect      102
Expansion of valence shells      42
Extinction      3
Extinction coefficient      3 113 119
Extinction coefficient, deviations      3
F-centres      131
Ferrocene      49
Field limit, strong      128
Field limit, weak      128
Flavones      135
Fluorescein      99 106
Fluorescence      98
Fluorescence of inorganic compounds      104
Fluorescence of metallo-organic compounds      104
Fluorescence of organic compounds      100
Fluorescence spectra, photoelectric measurement      100
Fluorescence, dependence on pH      105
Fluorescence, low-temperature      107
Fluorescence, polarized      107
Fluorescence, solvent effects      103
Fluorescent light, polarization      107
Fluorobenzenes      47
Formation constants of complexes, successive      79
Franck — Condon principle      2 108 140
Frequency shifts, infra-red      111
Frequency shifts, Raman      111
Furan      52 102
Glyoxal      32
Guanine      58
Haemin      135
Haemoglobin      135
Halides of metals      108
Hammett reactivity constants      44
Heat of formation      79 114
Heat of formation of complexes      113
Heteroaromatic compounds      22
Heterocyclic compounds      52
Heterocyclic compounds, six-membered aromatic      53
Heterocyclic compounds, unsaturated five-membered      52
Hexachlorobiphenyl      87
Hexamethylbenzene      84
Hexatriene      25
Hydration equilibria      79
Hydrocarbons, benzenoid      48
Hydrocarbons, catacondensed      95
Hydrocarbons, monoaromatic      48
Hydrocarbons, saturated      92 100
Hydrocarbons, unsaturated      92
Hydrogen bonding      115 141 142 149
Hydrogen bonding forces      140
Hydrogen bonding in proteins      148
Hydrogen bonding, intermolecular      143
Hydrogen bonding, intramolecular      143
Hydrogen bonding, solute-solvent      143
Hydronaphthaquinone      63
Hydroxindanones      65
Hydroxybenzoic acid      143
Hydroxynaphthalenes, ionic      108
Hydroxynaphthalenes, molecular      108
Hydroxypyrene sulphonic acids      105
Hyperchromic effect      12
Hyperconjugation      16 18 20 41
Hypochromic effect      12
Hypsochromic shifts      12
Imidazole      52
Imides, cyclic      96
Indigo dye      102
Indole      53
Indole ions      102
Inductive effects      17 20 40 44
Inorganic compounds, colour centres      131
Inorganic compounds, fluorescence      104
Instruments      4
Instruments, calibration      6
Insulin      148 149
Intensity enhancement      117
Intensity factor      115
Intercarbonyl angles      33
Iodine complexes      114
Iodine complexes with benzene      119 120
iodobenzene      101
Ion pairs      113 114
Ionic contribution      116
Ionization bands      92
Ionization energies      15
Ionization potential      113—116
Ionization, homolytic      2
Ionones      66
Ions, inorganic      22
Irone      29
Iso-absorptive point      79
Isobestic point      74 79 142
Isobutenylvinylcarbinol      68
Isoduril      33
Isoflavones      135
Isomerism, cis-trans      69
Isomerism, optical      70
Isomerization reactions      78
Isomers, cis-trans      106
Isomers, cis-trans, photochemical isomerization      106
Isomers, geometrical      69
Isomethylbixin      101
Isomycomycin      65
Isopropene      26
Isoquinoline ions      102
Isoquinolium ions      102
Isothujone      29
Jahn — Teller effect      130
Ketelaar equation      119
Ketones      75
Ketones, $\alpha\beta$-unsaturated      28
Ketones, acetone      96
Ketones, alicyclic      18 19
Ketones, aliphatic      17 92 96 101
Ketones, asymmetric      138
Ketones, cyclopropyl      96
Ketones, steroid      138
L-Pimeric acid      26
Lanthanum chloride matrix      105
Levopimaric acid      66
Lewis acid, complexes with polyene      134
Ligand field stabilization energies      129
Ligand field theory      124
Ligands, in spectrochemical sequence      130
Linkages, isolated ethylenic      16
Linkages, metal-olefin      121
Linkages, nitrogen-nitrogen      22
Linkages, nitrogen-oxygen      20
Linkages, peptide      148
Linkages, substitution of ethylenic      16
Linoleic acid      74
Linolenic acid      74
Lycopene      135
Lysozyme      149
m-Cresosulphonaphthalein      143
Malachite green      89 103
Manganese halides      104
McRae expression      141
Menthadiene      26
Mercaptotetrazoles      72
Mercaptothiazoles      72
Mesityl oxide      13 27 29
Mesitylene      87 95
Meso-ionic compounds      58
Mesoporphyrin      104
meta-Polyphenyls      35
Metals, halides      108
methane      11 15
Methyl ethyl ketone      30 101
Methyl heliotrope O      103
Methyl i-propyl ketone      18
Methyl-iso-propenyl-ketone      29
Methylamine      11
Methylene blue      103
Methylvinyl-ketone      29
Michler’s hydrol blue      89
Microscopes, reflecting      8
Millimicron      1
Mixtures analysis      73
Mixtures, binary      79
Molecular weight determination      74
Molecular weight of aldehydes      75
Molecular weight of amines      75
Molecular weight of ketones      75
Molecular weight of saturated alcohols      75
Molecular weight of sugars      75
Molecules, aromatic      39
Molecules, conjugated      25
Molecules, inorganic      22
1 2 3 4
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