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Rao C>N> — Ultra-Violet and Visible Spectroscopy: Chemical Applications
Rao C>N> — Ultra-Violet and Visible Spectroscopy: Chemical Applications



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Название: Ultra-Violet and Visible Spectroscopy: Chemical Applications

Автор: Rao C>N>

Аннотация:

It would be superfluous to stress the importance of electronic .spectroscopy in structural or analytic research. It has now become a matter of routine to record the ultra-violet or visible spectra of compounds for purposes of identification or structure elucidation. The spectrophotonletric methods of analysis have replaced the conventional methods in ever so rnany instances. The number of-publications in the different branches of chemistry, reporting data on or making use of electronic spectroscopy, is ever-increasing and it would be impossible to review the field completely. In this book, I have tried to introduce the basic concepts of electronic spectroscopy and to present its applications in analytical, structural and physico-chemical problems. As far as possible, the rnateripl has been selected to illustrate the basic: principles of modern theories in chemistry. While surveying the data on organic molecules, several empirical generalizations have been discussed. lVlany of the more recent developments like tIle far ultra-violet spectra of organic molecules, fluorescence spectra, charge transfer spectra, ligand field theory, optical rotatory dispersion etc., have been briefly discussed in the latter part of the book. All through the discussion, the recent notations of electronic transitions have been used, although the other commonly encountered notations have also been mentioned. I shall be most gratified if this book can be of help to chemists in using electronic spectroscopy more effectively in research or routine work.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 1st edition

Год издания: 1961

Количество страниц: 164

Добавлена в каталог: 30.08.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Monoheterocyclic compounds      102
Mulliken’s theory      115
Mycomycin      65
N-Acyldihydroindoles      65
N-Acylindoles      65
N-Ethyl phenazyl radicals      109
N-heterocyclic compounds      102
N-Nitrosoamides      65
Naphthacene      48 101 102
naphthalene      48 53 87 101 105 108 141
Naphthaquinone      63
Naphthyl sulphonic acids      105
neo-Carotenoids      69
neo-Lycopenes      70
Nitrate ions      22
Nitro compounds      20 138
Nitro compounds, aliphatic      21
Nitro compounds, olefins      33
Nitrobenzene      43 44
Nitrobenzenes      47
Nitromethane      23
Nitroparaffins      21
Nitrophenylazide      78
Nitroso compounds      21
Nitrosobutane      11
Nitrosonium ion      134
Nomenclature of benzene bands      39
Nucleic acids      56
Nucleoproteins      57
Nucleosides      58
o-Dihydroxy benzophenone      103
Octa-3,7-dien-5-yn-2-ol      25
Octant rule      139
Olefin complexes      121
Olefins      10 16 92—94
Olefins in sulphuric acid      134
Olefins of steroid family      94
Olefins of triterpenoid family      94
Olefins, cyclic      16 94
Olefins, determination      94
Olefins, small ring      94
Optical density      3 119
Optical dichroism      121
Optical rotatory dispersion      137
Optical system      5
Optical transition, perturbation      113
Orbitals, 5 d      125
Orbitals, molecular      115 120 127
Orbitals, molecular orbital model      125
Organic compounds, fluorescence      100
Orgel diagram      129
Orientation principle      120
Osazones      75
Oscillator strength      4
Ovalbumin      149
Overlap integral      118 120
Overlap of molecular orbitals      120
Overlap principle      120
Overlap, principle of maximum overlap      321
Oxalyl chloride, complexes with aromatics      117
Oxazolone structure      65
Oximes      30
Oxyhaemoglobin      136
p-Benzoquinone      32 134
p-Chloroaniline      45
p-Chlorophenol      45
P-Dinitrobenzene      44
p-Hydroxyacetophenone      45
p-Hydroxybenzaldehyde      45
p-Hydroxybenzoic acid      45
p-Nitroaniline      44 121
p-Nitroaniline derivatives      85
p-Nitrophenol      44 45
p-Xylene      95
Palmitates      101
Para-polyphenyls      35
Paracyclophanes      90
Paraffins      10 15
Paramagnetic atoms      99
Patulin      68
Penamaldates      64
Penicillins      64
Penicilloates      64
Penicilloates, N-acetylated      64
Pentacene      48 101
Pentazoles      53
Perylene      101 107
pH effect      148
pH, dependence of fluorescence on pH      105
Phellandrenes      66
Phenanthrene      48 87 95 101 107 141
Phenazine      53 102
Phenol      41 45 105
Phenol, blue      141
Phenols      47 144
Phenylbenzoates      47
Phosphonitrilic chlorides      50
phosphors      104
Photo-excitation      112
Photochemical isomerization      106
Photoreduction      100
Phthalazine      53
Picrates      111
Pigments      134
Pigments, visual      135
Piperazine      52
Piperidine      52
Piperylene      27
Plasma albumin, bovine      149
Platinum cyanide radical      104
Pleochromism      107
Polarization of fluorescent light      107
Polarization, forces of solvents      140
Polarization, red shift      140
Polyacetylenes      36
Polyalkyl azulenes      49
Polyene acids      33
Polyene azines      35
Polyene azomethines      35
Polyene complexes with Lewis acid      134
Polyenes      33 69 135
Polymers of dye molecules      137
Polypeptides      139
Polyphenyl derivatives      42
Polyphenyls      35
polystyrene      74
Porphyrin      102 104 135
Potassium azide      133
Potassium bromide pellets      7
Potassium dichromate      143
Potassium nitrate      143
Potential energy diagram      116
Predissociation      101
Promethium      104
Protein hydrogen bonds      148
Protein structure, co-operative changes      150
Protein-dye interactions      79
Proteins      139 148
Purification, control      61
Purine      57
Purines      105
Purity, specification      61
Purity, specification, spectrophotometry      61
Pyrazine      12 53 54 102
Pyrethrin      67
Pyrethrolone      67
Pyridazine      54 141
Pyridine      53 102
Pyridine derivatives      55 77
Pyridine, substituted      55
Pyridine-N-oxide      56
Pyridoxine      56
Pyrimidine      53 54 56
Pyrimidine, derivatives      56
Pyrimidines      105
Pyrimidones      56
Pyrrol      102
Pyrrole      52
Pyrrolidine      52
Quadratic Stark effect      141
Quantum efficiency      112
Quenching      99 106
Quenching, concentration      99
Quenching, internal      99
Quinhydrone      111 121
Quinine bisulphate      100
Quinoline      53
Quinoline ions      102
Quinolines, substituted      56
Quinolium ions      102
Quinoxaline      53
Radiation, fluorescent      2
Radicals, free      134
Rare earth ions      104
Rare earths      99
Rate constants      142
Ratio method      74
Reaction rates      78
Red-shift      12 139
Regions, far ultra-violet      1 92
Regions, near ultra-violet      1
Regions, vacuum ultra-violet      1
Regions, visible      1
Repetitive scanning attachments      78
Resonance      18
Resonance effects      40 44
Resonance parameters      44
Rhodamine      60 100
Rhoduline violet      103
Rhoduline-orange      99
Ribonuclease      148 149
Ring compounds, five-membered      28
Ring size, effect      29
Rings, three-membered      90
Rosamine      103
Rotational freedom      120
Rotatory dispersion curves, Cotton effect      138
Rotatory dispersion curves, plain      138
Rubidium halides      112
Rubies      107
Rydberg series      11
Salicylic acid      143
Self complexes      121
Semicarbazones      30
Semperivinine      65
Serum albumin, bovine      149
Silica, colloidal      100
Silicates      104
Siloxene group      104
Silver halides      133
Silver ion, complexes with ethylene      121
Single bond      82
Single bond, effect of twisting      82
Sodium      99
Sodium benzene sulphonate      104
Sodium bromide      104
Sodium chloride      104
Sodium formaldehyde-sulphoxylate      104
Sodium nitrate      22
Solute dipole-induced solvent dipole interactions      140
Solute dipole-solvent dipole interactions      140
Solvation energies      116
Solvent effects      12 13 22 139 142
Solvent effects on fluorescence      103
Solvent polarity      141
Solvent-solute interaction      108
Solvents, choice      7
Solvents, hydroxylic      141 142
Sorbaldehyde      25
Specific rotation      137
Spectra of charge transfer complexes      116
Spectra of gases      7
Spectra of solids      7
Spectra, absorption      1
Spectra, electronic      1
Spectra, emission      1
Spectra, luminescent      121
Spectrophotometer accessories      8
Spectrophotometer calibration      143
Spectrophotometers, method      119
Spectrophotometers, photoelectric      5
Spectrophotometers, slit width      6
Spectrophotometry in analysis      73
Spectrophotometry, differential      148
Spectrophotometry, preferential      58
Spectropolarimeters      137
Spectroscopic moments      43
Spectroscopy, applications      61
Spectrotitrimeter      78
Spin-orbital interaction, effect of increase      104
Standard free energy      118
Standards      6
Stearates      101
Stereoisomerism      105
Stereoisomerization      106
Steric effects      82 109 114
Steric effects, Type 1      85
Steric effects, Type 2      87
Steric effects, Type 3      87
Sterols, ergosterol content      73
Stilbenes      106
strain      90
Structure S-cis form      88
Structure S-trans form      88
Structure, identification and assignment      62
Structure, skew      87
Strychnine      65
Styrene anion      134
Substituent groups, electron-attracting      44
Substituent groups, electron-contributing      44
Substituent groups, meta-directing      44
Substituent groups, ortho-para directing      44
Substituents, effects      35 43 48
Substituents, ortho      89
Sydnones      58
Sym-di-(9-phenanthry-ethylene)      106
sym-Tetrazine      55
sym-triazine      53
Tautomerism      49 55 56 70 106
Tautomerism, azo-hydrazo      73
Tautomerism, keto-enol      70
Tautomerism, thione-thiol      72
Temperature effects      142
Terramycin      65
Testosterone-enolacetate      27
Tetrahydrofuran      52
Tetrahydropyran      52
Tetrahydropyrethrolone      29 67
Tetramethylbiphenyl      83
Tetramethylthiuram disulphide      108
Tetraphenyl cumulenes      37
Tetraphenylethylene      88
Tetraphenylstiboniumdichloride      42
Tetrazole      52
Tetrazoles, substituted      59
Thallous ion      104
Theophylline      58
Thermochromism      143
Thermochromism, negative      109
Thermodynamic criteria      120
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