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Rao C>N> — Ultra-Violet and Visible Spectroscopy: Chemical Applications
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Название: Ultra-Violet and Visible Spectroscopy: Chemical Applications
Автор: Rao C>N>
Аннотация: It would be superfluous to stress the importance of electronic .spectroscopy in structural or analytic research. It has now become a matter of routine to record the ultra-violet or visible spectra of compounds for purposes of identification or structure elucidation. The spectrophotonletric methods of analysis have replaced the conventional methods in ever so rnany instances. The number of-publications in the different branches of chemistry, reporting data on or making use of electronic spectroscopy, is ever-increasing and it would be impossible to review the field completely. In this book, I have tried to introduce the basic concepts of electronic spectroscopy and to present its applications in analytical, structural and physico-chemical problems. As far as possible, the rnateripl has been selected to illustrate the basic: principles of modern theories in chemistry. While surveying the data on organic molecules, several empirical generalizations have been discussed. lVlany of the more recent developments like tIle far ultra-violet spectra of organic molecules, fluorescence spectra, charge transfer spectra, ligand field theory, optical rotatory dispersion etc., have been briefly discussed in the latter part of the book. All through the discussion, the recent notations of electronic transitions have been used, although the other commonly encountered notations have also been mentioned. I shall be most gratified if this book can be of help to chemists in using electronic spectroscopy more effectively in research or routine work.
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Рубрика: Физика /
Статус предметного указателя: Готов указатель с номерами страниц
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Издание: 1st edition
Год издания: 1961
Количество страниц: 164
Добавлена в каталог: 30.08.2009
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Предметный указатель
Monoheterocyclic compounds 102
Mulliken’s theory 115
Mycomycin 65
N-Acyldihydroindoles 65
N-Acylindoles 65
N-Ethyl phenazyl radicals 109
N-heterocyclic compounds 102
N-Nitrosoamides 65
Naphthacene 48 101 102
naphthalene 48 53 87 101 105 108 141
Naphthaquinone 63
Naphthyl sulphonic acids 105
neo-Carotenoids 69
neo-Lycopenes 70
Nitrate ions 22
Nitro compounds 20 138
Nitro compounds, aliphatic 21
Nitro compounds, olefins 33
Nitrobenzene 43 44
Nitrobenzenes 47
Nitromethane 23
Nitroparaffins 21
Nitrophenylazide 78
Nitroso compounds 21
Nitrosobutane 11
Nitrosonium ion 134
Nomenclature of benzene bands 39
Nucleic acids 56
Nucleoproteins 57
Nucleosides 58
o-Dihydroxy benzophenone 103
Octa-3,7-dien-5-yn-2-ol 25
Octant rule 139
Olefin complexes 121
Olefins 10 16 92—94
Olefins in sulphuric acid 134
Olefins of steroid family 94
Olefins of triterpenoid family 94
Olefins, cyclic 16 94
Olefins, determination 94
Olefins, small ring 94
Optical density 3 119
Optical dichroism 121
Optical rotatory dispersion 137
Optical system 5
Optical transition, perturbation 113
Orbitals, 5 d 125
Orbitals, molecular 115 120 127
Orbitals, molecular orbital model 125
Organic compounds, fluorescence 100
Orgel diagram 129
Orientation principle 120
Osazones 75
Oscillator strength 4
Ovalbumin 149
Overlap integral 118 120
Overlap of molecular orbitals 120
Overlap principle 120
Overlap, principle of maximum overlap 321
Oxalyl chloride, complexes with aromatics 117
Oxazolone structure 65
Oximes 30
Oxyhaemoglobin 136
p-Benzoquinone 32 134
p-Chloroaniline 45
p-Chlorophenol 45
P-Dinitrobenzene 44
p-Hydroxyacetophenone 45
p-Hydroxybenzaldehyde 45
p-Hydroxybenzoic acid 45
p-Nitroaniline 44 121
p-Nitroaniline derivatives 85
p-Nitrophenol 44 45
p-Xylene 95
Palmitates 101
Para-polyphenyls 35
Paracyclophanes 90
Paraffins 10 15
Paramagnetic atoms 99
Patulin 68
Penamaldates 64
Penicillins 64
Penicilloates 64
Penicilloates, N-acetylated 64
Pentacene 48 101
Pentazoles 53
Perylene 101 107
pH effect 148
pH, dependence of fluorescence on pH 105
Phellandrenes 66
Phenanthrene 48 87 95 101 107 141
Phenazine 53 102
Phenol 41 45 105
Phenol, blue 141
Phenols 47 144
Phenylbenzoates 47
Phosphonitrilic chlorides 50
phosphors 104
Photo-excitation 112
Photochemical isomerization 106
Photoreduction 100
Phthalazine 53
Picrates 111
Pigments 134
Pigments, visual 135
Piperazine 52
Piperidine 52
Piperylene 27
Plasma albumin, bovine 149
Platinum cyanide radical 104
Pleochromism 107
Polarization of fluorescent light 107
Polarization, forces of solvents 140
Polarization, red shift 140
Polyacetylenes 36
Polyalkyl azulenes 49
Polyene acids 33
Polyene azines 35
Polyene azomethines 35
Polyene complexes with Lewis acid 134
Polyenes 33 69 135
Polymers of dye molecules 137
Polypeptides 139
Polyphenyl derivatives 42
Polyphenyls 35
polystyrene 74
Porphyrin 102 104 135
Potassium azide 133
Potassium bromide pellets 7
Potassium dichromate 143
Potassium nitrate 143
Potential energy diagram 116
Predissociation 101
Promethium 104
Protein hydrogen bonds 148
Protein structure, co-operative changes 150
Protein-dye interactions 79
Proteins 139 148
Purification, control 61
Purine 57
Purines 105
Purity, specification 61
Purity, specification, spectrophotometry 61
Pyrazine 12 53 54 102
Pyrethrin 67
Pyrethrolone 67
Pyridazine 54 141
Pyridine 53 102
Pyridine derivatives 55 77
Pyridine, substituted 55
Pyridine-N-oxide 56
Pyridoxine 56
Pyrimidine 53 54 56
Pyrimidine, derivatives 56
Pyrimidines 105
Pyrimidones 56
Pyrrol 102
Pyrrole 52
Pyrrolidine 52
Quadratic Stark effect 141
Quantum efficiency 112
Quenching 99 106
Quenching, concentration 99
Quenching, internal 99
Quinhydrone 111 121
Quinine bisulphate 100
Quinoline 53
Quinoline ions 102
Quinolines, substituted 56
Quinolium ions 102
Quinoxaline 53
Radiation, fluorescent 2
Radicals, free 134
Rare earth ions 104
Rare earths 99
Rate constants 142
Ratio method 74
Reaction rates 78
Red-shift 12 139
Regions, far ultra-violet 1 92
Regions, near ultra-violet 1
Regions, vacuum ultra-violet 1
Regions, visible 1
Repetitive scanning attachments 78
Resonance 18
Resonance effects 40 44
Resonance parameters 44
Rhodamine 60 100
Rhoduline violet 103
Rhoduline-orange 99
Ribonuclease 148 149
Ring compounds, five-membered 28
Ring size, effect 29
Rings, three-membered 90
Rosamine 103
Rotational freedom 120
Rotatory dispersion curves, Cotton effect 138
Rotatory dispersion curves, plain 138
Rubidium halides 112
Rubies 107
Rydberg series 11
Salicylic acid 143
Self complexes 121
Semicarbazones 30
Semperivinine 65
Serum albumin, bovine 149
Silica, colloidal 100
Silicates 104
Siloxene group 104
Silver halides 133
Silver ion, complexes with ethylene 121
Single bond 82
Single bond, effect of twisting 82
Sodium 99
Sodium benzene sulphonate 104
Sodium bromide 104
Sodium chloride 104
Sodium formaldehyde-sulphoxylate 104
Sodium nitrate 22
Solute dipole-induced solvent dipole interactions 140
Solute dipole-solvent dipole interactions 140
Solvation energies 116
Solvent effects 12 13 22 139 142
Solvent effects on fluorescence 103
Solvent polarity 141
Solvent-solute interaction 108
Solvents, choice 7
Solvents, hydroxylic 141 142
Sorbaldehyde 25
Specific rotation 137
Spectra of charge transfer complexes 116
Spectra of gases 7
Spectra of solids 7
Spectra, absorption 1
Spectra, electronic 1
Spectra, emission 1
Spectra, luminescent 121
Spectrophotometer accessories 8
Spectrophotometer calibration 143
Spectrophotometers, method 119
Spectrophotometers, photoelectric 5
Spectrophotometers, slit width 6
Spectrophotometry in analysis 73
Spectrophotometry, differential 148
Spectrophotometry, preferential 58
Spectropolarimeters 137
Spectroscopic moments 43
Spectroscopy, applications 61
Spectrotitrimeter 78
Spin-orbital interaction, effect of increase 104
Standard free energy 118
Standards 6
Stearates 101
Stereoisomerism 105
Stereoisomerization 106
Steric effects 82 109 114
Steric effects, Type 1 85
Steric effects, Type 2 87
Steric effects, Type 3 87
Sterols, ergosterol content 73
Stilbenes 106
strain 90
Structure S-cis form 88
Structure S-trans form 88
Structure, identification and assignment 62
Structure, skew 87
Strychnine 65
Styrene anion 134
Substituent groups, electron-attracting 44
Substituent groups, electron-contributing 44
Substituent groups, meta-directing 44
Substituent groups, ortho-para directing 44
Substituents, effects 35 43 48
Substituents, ortho 89
Sydnones 58
Sym-di-(9-phenanthry-ethylene) 106
sym-Tetrazine 55
sym-triazine 53
Tautomerism 49 55 56 70 106
Tautomerism, azo-hydrazo 73
Tautomerism, keto-enol 70
Tautomerism, thione-thiol 72
Temperature effects 142
Terramycin 65
Testosterone-enolacetate 27
Tetrahydrofuran 52
Tetrahydropyran 52
Tetrahydropyrethrolone 29 67
Tetramethylbiphenyl 83
Tetramethylthiuram disulphide 108
Tetraphenyl cumulenes 37
Tetraphenylethylene 88
Tetraphenylstiboniumdichloride 42
Tetrazole 52
Tetrazoles, substituted 59
Thallous ion 104
Theophylline 58
Thermochromism 143
Thermochromism, negative 109
Thermodynamic criteria 120
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