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Luder S., Zuffanti W.F. — The Electronic Theory of Acids and Bases
Luder S., Zuffanti W.F. — The Electronic Theory of Acids and Bases



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Название: The Electronic Theory of Acids and Bases

Авторы: Luder S., Zuffanti W.F.

Аннотация:

The theory of relativity in physics has led to an increased amount of correlation in physical phenomena and to a keener insight into the fundamental problems of physics. More recently, another kind of relativity theory has made its appearance in chemistry. We owe this theory to the brilliant intuition of G. N. Lewis, by whom it was first proposed in 1923. Unfortunately, it was largely overlooked until about 1940. Since then, numerous papers have been published supporting and developing the theory, which is becoming known as the electronic theory of acids and bases.
According to the Lewis theory, acidity and basicity have nothing to do with the presence of any one element or specific group of elements. Nor is any particular substance to be considered an acid or a base in an absolute sense. Acidity and basicity are relative terms indicating certain types of experimental behavior which may be exhibited by the vast majority of chemical compounds. Most of them may behave either as acids or as bases depending upon conditions.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: 1st edition

Год издания: 1946

Количество страниц: 165

Добавлена в каталог: 29.08.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Hydrogen fluoride      16
Hydrogen fluoride, catalyst in sulfonations and nitrations      132
Hydrogen fluoride, catalytic effect of      108 110 115 121 122 125
Hydrogen ion      3
Hydrogen ion, as an oxidizing agent      10 11
Hydrogen sulfide as an acid      4
Hydrogen-molecule ion      21
hydrolysis      8 63
Hydrolysis, of benzyl chloride      130
Hydronium ion      7 8 9 10
Hydroquinone, amphoteric behavior of      75
Hydrosulfide ion      9
Hydroxy ketones, preparation of      124
Hydroxyl ion      3 7 9
Hydroxyl ion, catalytic effect of      112
Hydroxyl ion, reducing action      53
Hydroxylamine, reaction with carbonyl compounds      127
Indicators      15 16 95 96
Inert solvents      4 57
Iodination with silver perchlorate catalyst      129
Iodine      55
Iodine heptafluoride      20 32 34
Iodine monochloride      32
Iodine pentachloride      32
Iodine trichloride      32
Iodine, basic behavior of      129
Ionic complexes, in Friedel — Crafts reactions      115
Ionic complexes, in halogenations      128
Ionization potentials      36
Jander      11
Knoevenagel reaction      143
Lavoisier      3
Leveling effect      57 104 105
Liebig      3
Magnesium aluminum alkoxides, catalytic action of      150
Magnesium, reaction with water      10 29 46
Malachite green      96
Mechanism, of acylations      123
Mechanism, of aldolization      138 151
Mechanism, of alkylation      110 116 119
Mechanism, of base-catalyzed Cannizzaro reaction      146
Mechanism, of benzoin reaction      147
Mechanism, of carbonyl condensations      138 139 140 141 143
Mechanism, of Claisen reaction      140
Mechanism, of crotonization      151
Mechanism, of cyclic ketone formation      132
Mechanism, of glycol ester formation      155
Mechanism, of halogenation      129 130
Mechanism, of Knoevenagel reaction      143
Mechanism, of nitration      131
Mechanism, of Perkin reaction      141
Mechanism, of sulfonation      131
Mercuric chloride, as an acid      4
Mercuric salts, acidic behavior of      130
Mercuric salts, catalytic effect of      130
Meta-directing groups      62 81
Metals, reactions of acids with      10 11 46 53 69
Metathesis      77 78
Methyl alcohol      4
Methyl iodide      14
Methylene blue, absorption curve      109
Molecular compounds      88
Molybdenum chlorides      20
Negative fragments      84
Neutralization, and Br${\o}$nsted theory      87 99
Neutralization, and displacement      87 103
Neutralization, electronic theory      15 16 17 43
Neutralization, Lewis theory      15 16 17 43
Neutralization, positive-negative theory      14
Neutralization, primary acids and bases      15 16 17 43 87
Neutralization, secondary acids and bases      60 87
Neutralization, solvent effect in      102 103
Neutralization, solvent-systems theory      10 11 12
Neutralization, water theory      3
Nitration mechanism      131
Nitric acid, titration of      92
Nitro radicals      81 82 85
Nitrobenzene, substitution in      82 85
Nitrogen dioxide      76
Non-metals, reactions of bases with      53 69
Nucleophilic radicals      80
Octet theory      19 20
Odd-electron molecules      75 76 77
Olefins, alkylation with      111
Oleum, catalyst in anthraquinone formation      133
One-electron bonds      21
One-element theories      5
Orbitals, atomic      18 21 22 23 25
Ortho- and para-directing groups      62 81
Osmium chlorides      35
Osmium fluorides      20 35
Oxidation-reduction      69 70 77 78
Oxidation-reduction, in positive-negative theory      14
Oxidizing agents, ammonium ion      10
Oxidizing agents, ammonium ion, cation of solvent      10 11 53 54 69
Oxidizing agents, ammonium ion, hydrogen ion      10 11 69
Oxidizing agents, ammonium ion, silver ion      73
Oximcs, formation of      127
Oxonium hydroxide      4
Oxonium salts      3
Oxyacids      38
Oxygen as a constituent of acids      5
Parachor      21
Perchloric acid      34 38
Periodic chart      24
Perkin reaction      141
Permanganic acid      34
Phenanthrene, halogenation of      129
Phenol, substitution in      83 85
Phenolphthalein      4
Phosgene      10 11 12 45 49 50
Phosphates, catalytic action of      142
Phosphorus pentabromide      30
Phosphorus pentachloride      30
Phosphorus pentafluoride      19 27 29 30
Phosphorus trifluoride      30
Piperidine      9
Positive fragments      84 108 109 110 111 128
Positive-negative theory      13 14
Potassium amide      10 12
Potassium chloride      12
Potassium cyanide      14
Potassium ethoxide      12
Potassium sulfite as a base      12
Primary acids and bases      60
Protective coatings      57
Proton-donor theory      6 (see also Br${\o}$nsted — Lowry theory)
Pyridine      16 43 44 45 49 51 63
Pyridine, basic behavior of      138
Pyridine, catalytic action of      142
Pyridine, titration of      91 92 94
Quantum numbers      23
Qumoline, catalytic action of      142
Radicals, acidic      81 82
Radicals, basic      81 83
Radicals, electron-release characteristics      81 83 84
Radicals, electron-withdrawal characteristics      81 82
Radicals, meta-directing      62 81
Radicals, nucleophilic      80
Radicals, ortho- and para-directing      62 81
Rare earths      24 28
Reducing agents, amide ion      73
Reducing agents, anion of solvent      53 54 55 69
Reducing agents, hydroxyl ion      53 69
Reducing agents, iodide ion      74
Reducing agents, sulfide ion      73
Related metals      21 24 25 26
Representative elements      20 24
Resonance      37 38
Rule of eight      19 20
rule of two      27 28 32
Salts      88
Secondary acids and bases      60
Selenium oxychloride      12 51 53 54
Semicarbazones, formation of      127
Sharing of electrons      23
Sidgwick      16
Silicon dioxide      5
Silicon tetrachloride      12
Silicon tetrafluoride      29 59
Silver hydroxide      101
Silver perchlorate, acidic behavior of      129
Silver perchlorate, titration of      91
smith      12
Sodium      14
Sodium amide      10
Sodium amoxide      4
Sodium ethoxide      4
Sodium hydroxide      15 16
Sodium oxide      6 14
Solvent, inert      4 57 102
Solvent, ionizable      102
Solvent, reaction of acids and bases with      46—58 165
Solvent-systems theory      9 10 11 12 13 45
Solvo acid      11
Stannic chloride      12 16 17 28 39 54 59
Stannic chloride, absorption curve      109
Stannic chloride, titration of      91 92
Strength of acids and bases      47 49 57 58 105 106
Substitution mechanism, acidic radicals in      84 85
Substitution mechanism, basic radicals in      84 85
Sulfates, catalytic action of      142
Sulfide ion      9
Sulfo radicals      81
Sulfonation, mechanism of      131
Sulfonation, of benzene      63 109
Sulfur dioxide, electronic formula      37
Sulfur dioxide, solvent      54
Sulfur fluorides      19 20 27 31
Sulfur hexafluoride      19 20 27
Sulfur monoxide      36 37 54 55
Sulfur trioxide, as an acid      12 14 16 43 46 47 63 109
Sulfur trioxide, catalytic activity of      110
Sulfur trioxide, electronic formula of      37
Sulfuric acid, conductance in ether      51
Sulfuric acid, electronic formula of      33 37 38
Sulfuric acid, solvent      4
Sulfuric acid, titration of      92
Tetramethylammonium sulfite      11
Thionyl chloride      11 54
Titanium chloride      12
Titration      15 16 92
Titration, of 1,four-dioxane      92
Titration, of acetic acid      92
Titration, of alcohols      92 93
Titration, of aluminum chloride      93
Titration, of ammonia      92
Titration, of anhydrides      93
Titration, of boron trichloride      91 92 93
Titration, of esters      94
Titration, of ethers      96
Titration, of H-acids      92
Titration, of hydrochloric acid      92
Titration, of nitric acid      92
Titration, of pyridine      91 92 94
Titration, of silver perchlorate      91
Titration, of stannic chloride      91 92
Titration, of sulfuric acid      92
Titration, of triethylamine      91 94
Titrations, in carbon tetrachloride solutions      93
Titrations, in chlorobenzene solutions      92
Titrations, in water solutions      92
Toluene as a solvent      4
Tri-$t$-butylboron      106
Triethylamine      16 53
Triethylamine, titration of      91 94
Trimethylamine      14 16 106
Trimethylboron      106
Triphenylmcthyl carbanion      140
Tungsten chlorides      20
Usanovich      13 14
Valence, coordinate covalence      38 39 40 41 42
Valence, covalence      29 30 31 32 33 34 35 36
Valence, electrovalence      28
Valence, origin of      27
Walden      46
Water solutions, titrations in      92 93
Water theory, inadequacy of      3 5
Water, as a base      4 8 43 44 70 72 75
Water, as a reducing agent      75
Water, as a solvent      12
Water, as an acid      7 45 72 75
Water, as an oxidizing agent      75
Wickert      12
Zinc acetate      56
Zinc amide      10 56
Zinc chloride, catalytic effect of      110 130
Zinc hydroxide      10 56
Zinc ion, hydrolysis      63
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