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Luder S., Zuffanti W.F. — The Electronic Theory of Acids and Bases |
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Предметный указатель |
— Benzoylbenzoic acid, in preparation of anthraquinone 132
— Keto esters, formation of 112
1, 2—Diplienylpropane, preparation of 122
1, 4—Dioxane, basic behavior of 92
3, 3—Diphenylpropanoic acid, preparation of 122
3-Phenyl-1-propene, preparation of 122
3–Phenyl-1-propene, alkylation with 122
Acceptor molecules 16
Acetate ion 7 8
Acetates, basic behavior of 138
Acetic acid 8 9 47 56
Acetic acid, association of 40
Acetic acid, titration of 92
Acetone, as a base 16
Acetone, displaced by pyridine 99
ACID 43
Acid-analogous 13
Acidic radicals 62 63
Activation 60 62
Acylation, mechanism of 123
Acylation, with carboxy anhydrides 125
Acylation, with carboxy compounds 124
Acylation, with esters 123
Addition compounds 88
Alcohols, basic behavior of 109 117
Alcohols, halogenation of 129
Alcohols, titration of 92 93
Aldehydes, acidic behavior of 112
Aldehydes, amphoteric behavior of 61
Aldehydes, basic behavior of 126 127
Aldehydes, reaction with semicarbazide 127
Aldol condensations 138 151
Alkali metal acetates, catalytic action of 141
Alkoxides, alkali metal 151
Alkoxides, aluminum 50
Alkoxides, basic behavior of 111
Alkoxides, catalytic effect of 111 126 140
Alkyl halides, alkylation with 115
Alkyl halides, basic behavior of 115
Alkylation, mechanism of 110 116 119
Alkylation, with alcohols 109 117
Alkylation, with alkyl halides 115
Alkylation, with allyl alcohol 122
Alkylation, with benzyl chloride 121
Alkylation, with cinnamic acid 122
Alkylation, with esters 120
Alkylation, with ethers 119
Alkylation, with olefins 111 116
Alkylation, with three-phenyl-1-propene 122
Allyl alcohol, alkylation with 122
Aluminum alkoxides, acidic behavior of 50 126 153
Aluminum alkoxides, catalytic effect of 126
Aluminum amide 56
Aluminum bromide 43 44
Aluminum chloride 10 11 12 16 19 20 45
Aluminum chloride, catalytic effect of 110 115 117 124
Aluminum chloride, titration of 93
Aluminum hydroxide 11 56 60
Aluminum sulfite 11
Amide ion 9 55
Amino radicals 81 83
Ammonia, as a base 6 7 9 17 39 41 42 43
Ammonia, displaced by triethylamine 99
Ammonia, solvent 10 56
Ammonia, titration of 92
Ammonium chloride 60
Ammonium iodide 10
Ammonium ion 6 7 8 9 41
Ammonium ion, as an oxidizing agent 10
Ammonium sulfide 14
Ammono acid 10
Amphoteric behavior 60 61 71
Amphoteric behavior of, aluminum amide 56
Amphoteric behavior of, aluminum hydroxide 56
Amphoteric behavior of, benzaldehyde 146
Amphoteric behavior of, hydrogen chloride 74
Amphoteric behavior of, iodide ion 65
Amphoteric behavior of, quinhy drone 75
Amphoteric behavior of, quinone 75
Amphoteric behavior of, water 74 75
Amphoteric behavior of, zinc acetate 56
Amphoteric behavior of, zinc amide 10 56
Amphoteric behavior of, zinc hydroxide 10 56
Anhydrides, titration of 93
Aniline, substitution in 83
Anion, increased concentration of, by bases 11 49—52
Anion, reducing action of 53 54 55 69
Anionoid radicals 80
Antimony pentasulfide 14
Antimony trichloride 12
Antimony trichloride, conductance in ether 51
Argon, boron trifluoride compound of 59
Arrhenius 1 3
Arsenic trichloride, conductance of in ether 51
Arsenious chloride 12
Atomic orbitals 18 21 22 23 25
Atomic structure chart 24
Barium hydroxide, basic behavior of 139
Base 43
Basic radicals 62 63
Benzaldehyde, acidic behavior of 112
Benzene, as a base 63
Benzene, solvent 4 57
Benzoin reaction 147
Benzyl alcohol, preparation of 130
Benzyl chloride, alkylation with 121
Benzyl chloride, hydrolysis of 130
Benzylate ion, catalytic effect of 147
Beryllium chloride 19
Berzelius, theory of acids and bases 5 6
Bismuth chloride 10
Bismuth iodide 10
Bismuth nitride 10
Bismuth oxide 10
Bisulfate ion 7
Boric acid 10
Boron amide 10
Boron hydrides 21
Boron trichloride 16 17 19 29 39 42 43 47
Boron trichloride, titration of 91 92 93
Boron trifluoride 51
Boron trifluoride, argon compound of 59
Boron trifluoride, catalyst in alkylations 109 111 118
Boron trifluoride, catalyst in sulfonation and nitration 130
Boyle, properties of acids 3
Brnsted — Lowry theory 5 6 7 8 9
Bromination of phenanthrene 129
Bromine pentafluoride 34
Bromine, basic behavior of 128
Cady and Elsey 11
Calcium chloride 11
Calcium oxide 5
Cannizzaro reaction, acid catalyzed 126
Cannizzaro reaction, base catalyzed 112 145 152
Carbanions 77 111 112
Carbon dioxide 3 4 6 47 49 62
Carbon dioxide, displaced by boron trichloride 98
Carbon dioxide, displaced by silicon dioxide 98
Carbon dioxide, displaced by stannic chloride 98
Carbon dioxide, electronic formula of 38
Carbon dioxide, secondary acid 62
Carbon monoxide 10
Carbon tetrachloride, as a solvent 4
Carbon tetrachloride, titrations in 93
Carbonates, basic behavior of 138 141
Carbonium ions 76 84 109 110 115 118 120 121 122 123 125 130
Carbonyl compounds, reaction with hydrazine 127
Carbonyl compounds, reaction with hydroxylamine 127
Carbonyl compounds, reaction with semicarbazide 127
Carbonyl group, amphoteric behavior of 61
| Carbonyls 20
Carboxy anhydrides, acylation writh 125
Carboxy compounds, acylation with 124
Catalysis 15
Catalysis, definition 107
Catalysts, acidic 108
Catalysts, basic 111
Catalysts, electron-release 145 152
Catalysts, electron-withdrawal 145 152
Catalytic action, of acetates 138
Catalytic action, of alkali metal acetates 141
Catalytic action, of alkali metal alkoxides 151
Catalytic action, of alkoxide 111
Catalytic action, of aluminum alkoxides 126 153
Catalytic action, of aluminum chloride 110 115 117 124
Catalytic action, of barium hydroxide 139
Catalytic action, of benzylate ions 147
Catalytic action, of boron trifluoride 109 111 118
Catalytic action, of carbonates 138 141
Catalytic action, of cyanides 147
Catalytic action, of hydrogen chloride 110
Catalytic action, of hydrogen fluoride 108 110 115 121 122 125
Catalytic action, of hydroxyl ions 112
Catalytic action, of magnesium aluminum alkoxides 150
Catalytic action, of mercuric ions 130
Catalytic action, of phosphates 142
Catalytic action, of pyridine 138 142
Catalytic action, of quinoline 142
Catalytic action, of sulfates 142
Catalytic action, of sulfur trioxide 110
Catalytic action, of triphenylmethyl carbanion 140
Catalytic action, of zinc chloride 110
Catalytic action, of “complex” alkoxides 154
Cation, increased concentration of, by acids 11 47—52
Cation, oxidizing action of 10 11 53 54 69
Chelation 106
Chloride ion displaced by water 99
Chlorine 14
Chlorobenzene solutions, titrations in 92
Chloroform as a solvent 4
Chromic acid 34
Cinnamic acid, alkylation with 122
Cinnamic acid, preparation of 142
Claisen condensation of esters 111
Claisen reaction 140
Classification of chemical reactions 77 78 79
Combination 77 78
Complex ions, of aluminum 27 39
Complex ions, of molybdenum 39
Complex ions, of silicon 27 29 39 59
Complex ions, of silver 100
Complex ions, of tin 59
Complex ions, of zirconium 39
Concentration effects, anion 52 70
Concentration effects, cation 52 70
Condensation, of aldehydes 138
Condensation, of carboxy anhydrides 141
Condensation, of esters 140
Condensation, of ketones 139
Conductance, antimony trichloride in ether 51
Conductance, arsenic trichloride in ether 51
Conductance, in ethylenediamine 64
Conductance, potassium iodide in ethylenediamine 64
Conductance, silver salts in ethylenediamine 64
Conductance, sulfuric acid in ether 51
Conjugate acid 9
Conjugate base 9
Conjugate pairs 7
Conjugate system 7
Coordinate covalent bond see Valence
Coordination compounds 20
covalent bond see Valence
Crotonization 151
Crystal violet, indicator in titrations 16 91 92 93
Crystal violet, quinoid structure 95
Cyanide ion 9
Cyanides, catalytic action of 147
Cyano radicals 81
Cyclic ion, in antliraquinone formation 134
Davy 3 6
Decomposition 77 78
Deuterium water in Cannizzaro reaction 146
Diacetone alcohol, formation of 139
Dimethyl ether as a base 4
Dioxane sulfotrioxide, reaction with olefins 109
Diphenylmethane, preparation of 121
Displacement 77 87 89 98 99 100
Dissociation constants 46 47 48 49 50 64
Donor molecules 16
Electro valence see Valence
Electrodotic reagents 71 72
Electrolysis 55
Electron affinity 36 37 38
Electron configuration 23 24 25 26
Electron-release catalysts 145 152
Electron-release effect of hydroxyl ions 146
Electron-withdrawal catalysts 146
Electron-withdrawal effect of cyanide ions 146
Electronic symbols 25 26 27
Electrophilic reagents 71 72
energy levels 22 23
Equilibrium constant 8
Ester anion formation 140
Esters, acidic behavior of 111
Esters, acylation with 123
Esters, alkylation with 120
Esters, basic behavior of 120 123
Esters, preparation from aldehydes 126
Esters, titration of 94
Ethers, alkylation with 119
Ethers, basic behavior of 119
Ethers, titration of 93
Ethoxide ion 9
Ethyl alcohol 7 12
Ethylenediamine, solvent 63 64 65
Excitation of secondary acids and bases 61
Experimental criteria of acid-base properties, Boyle 3
Experimental criteria of acid-base properties, Lewis 15 43
F-strain 106
Ferric bromide, acidic behavior of 128
Ferric chloride 11
Ferric cyanide 14
Fluorine 30
Franklin 9
Free radicals 75 76 77
Friedel — Crafts catalysts, boron trifluoride 109 111
Friedel — Crafts catalysts, hydrogen fluoride 108 110 115 121 122 125
Friedel — Crafts catalysts, phosphoric acid 108
Friedel — Crafts catalysts, sulfuric acid 108
Friedel — Crafts reactions 63
Fries reaction 124
Germann 10 11
Glycol ester formation 155
H-acids see Hydrogen acid
Halogenation, mechanism of 128
Halogenation, of alcohols 129
Halogenation, of aromatic compounds 128
Halogenation, of phenanthrene 129
Heat of activation in neutralization 60
Hexaphenylethane 76
Hydrazines, preparation of 127
Hydride ion removal, in carbonyl reactions 153
Hydrochloric acid 6 7 15
Hydrochloric acid, titration of 92
Hydrogen acid 45 99
Hydrogen acid, titration of 92
Hydrogen as a constituent of acids 5 6
Hydrogen bridge 40 44
Hydrogen chloride, as a base 60
Hydrogen chloride, catalytic activity of 110
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