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| Авторизация |
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| Cazes J., Scott R.P.W. — Chromatography Theory |
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| Предметный указатель |
Adlard, E.R. 18
Adsorption isotherm, bi-layer 93 95
Adsorption isotherm, bi-layer, function for 96
Adsorption isotherm, chloroform, butylchloride 94
Adsorption isotherm, effect on peak shape 176
Adsorption isotherm, for alcohols 90
Adsorption isotherm, Freundlich 177
Adsorption isotherm, Langmuir 88
Adsorption isotherm, single layer 88
Alhedai, A. 45
Amundson, N.R. 17
Analysis, quantitative, from retention measurements 171
Arnold, J.H. 359
Ashley, J.W. 233
Asshauer, J. 286
Associated, methanol-water 125
Associated, solvents, solute interactions with 135
Association, methanol-water mixtures, standard enthalpy of 133
Association, methanol-water mixtures, standard entropy of 133
Association, methanol-water, thermodynamic properties 133
Assymetry, peak, causes 175
Atwood, J.G. 286 314
Avaerage mobile phase velocity 272
Available stationary phase 36
Barker, P.E. 442
Base line, definition of 14
Beesley, T.E. 85 142 164
Benedek, P. 442
Bi-layer adsorption 95
Bi-layer adsorption, isotherm for ethyl acetate 97
Bi-layer adsorption, isotherm, function for 96
Bird, R.B. 165
Bonded phase, brush type 92
Bonded phase, bulk type 92
Bonding, stationary phase, effect on retention 92
Bophemen, J. 233
Butyl chloride, adsorption isotherm 94
Capacity, peak, as function of capacity ratio 207
Capacity, peak, equation for 206
Capacity, plate 23
Capacity, ratio, equation for 27
Capacity, ratio, function of temperature 49
Capacity, ratio, limited by detector sensitivity 208
Capacity, ratio, of a solute 26
Cell, detector, low dispersion 308
Chilton, C.H. 234
Chloroform, adsorption isotherm 94
Chromatogram, alternative axes 238
Chromatogram, reduced 362
Chromatography, column design, applications 396
Chromatography, column design, capillary 386
Chromatography, column design, packed 360
Chromatography, column, expression for peak capacity 206
Chromatography, continuous, moving bed 434
Chromatography, continuous, simulated moving bed 439
Chromatography, definition of 4
Chromatography, development 7
Chromatography, preparative 420
Chromatography, terminology 14
Chromatography, theory, history of 4
Chromatography, theory, introduction to 3
Chromatography, thin layer 444
Chromatography, thin layer, effective capacity ratio 450
Chromatography, thin layer, efficiency measurement of 452
Chromatography, thin layer, plate dispersion 453
Chromatography, thin layer, resolution 450
Chromatography, thin layer, Rf factor 448 449
Chromatography, thin layer, Rx factor 448
Chromatography, vacancy 195
Chromatography, vacancy, elution curve equation 197
Chromatography, vacancy, multicomponent mixture 200
Claxton, G.C. 234
Co-elution temperature, expression for 82
Column design, data bases, analytical specifications 367
Column design, data bases, column specifications 366
Column design, data bases, elective variables 365
Column design, data bases, instrument constraints 364
Column design, data bases, performance criteria 362
Column design, optimum particle diameter 371
Column design, process for packed columns 368
Column, capillary, design 386
Column, capillary, maximum sample volume 393
Column, capillary, minimum elution time 392
Column, capillary, minimum H 391
Column, capillary, minimum length 391
Column, capillary, optimum flow rate 392
Column, capillary, optimum radius 389
Column, capillary, optimum velocity 391
Column, dead volume 34
Column, design, applications 396
Column, design, packed column 360
Column, design, protocol 360
Column, dispersion, accurate measurement of 317
Column, efficiency 179
Column, efficiency, expression for 181
Column, efficiency, plates necessary for separation 186
Column, expression for peak capacity 206
Column, moving phase 35
Column, optimized specifications 366
Column, optimized, minimum elution time 376
Column, packed 368
Column, packed, maximum sample volume 384
Column, packed, minimum H 376
Column, packed, minimum length 376
Column, packed, minimum solvent consumption 383
Column, packed, optimum flow rate 382
Column, packed, optimum particle diameter 371
Column, packed, optimum radius 380
Column, packed, optimum velocity 375
Column, packed, sources of dispersion 245
Column, peak capacity 202
Column, permitted extra column volume 290
Column, physical properties of 43
Column, preparative, mass overload 428
Column, preparative, optimum sample size 432
Column, preparative, overload 420
Column, preparative, volume overload 421
Column, resolving power 183
Column, static phase 35
Column, volume, distribution of 35
Compressibility , mobile phase 28
Conduits, tubular, dispersion in 296
Continuous chromatography, moving bed 434
Curtis, C.F. 164
Davis, J.M. 234
Dead, point, definition of 14
Dead, time, definition of 15
Dead, volume, definition of 15
Dead, volume, measurement of 39
Deeble, R.E. 442
Density, change on mixing, methanol-water 128
Design protocol, column 360
Desty, D.H. 233
Detector cell low dispersion 308
Detector, heat of adsorption, theory of 218
Detector, sensor volume, apparent dispersion 307
Detector, sensor volume, dispersion from Newtonian flow 306
Development, chromatographic 7
Development, displacement 7
Development, elution 9
Development, elution in TLC 12
Development, frontal analysis 8
Development, solvent profile in TLC 13
Diffusion, dispersion equation 245
Diffusion, eddy 246
Diffusion, effect of column pressure 275
Diffusion, effect of pressure on dispersion in LC 276
Diffusion, Ficks law 243
Diffusion, liquid, effect of pressure 274
Diffusion, process 243
| Diffusivity, function of molecular weight 339
Dipole moment, effect on dipole interactions 66
Dipole-dipole interactions 66
Dipole-induced-dipole interactions 67
dispersion 317
Dispersion, detector sensor volume apparant 307
Dispersion, detector sensor volume apparant, Newtonian flow 306
Dispersion, dynamics of 237
Dispersion, effect of detector time constant 311
Dispersion, extra column 288
Dispersion, extra column, maximum for a capillary column 393
Dispersion, extra column, sources 291
Dispersion, forces, effect of polarizability 64
Dispersion, forces, interaction energy of 64
Dispersion, from Newtonian flow 297
Dispersion, from sample volume 291
Dispersion, in a packed bed 245
Dispersion, in frits 295
Dispersion, in sample valves 294
Dispersion, in tubular conduits 296
Dispersion, in unions 295
Dispersion, interactive force 63
Dispersion, longitudinal diffusion 248
Dispersion, longitudinal diffusion, expression for mobile phase 249
Dispersion, longitudinal diffusion, expression for stationary phase 250
Dispersion, low, connecting tube 301
Dispersion, low, serpentine tubes 303
Dispersion, mobile phase, HETP equation corrected for gas compressibility 271
Dispersion, multipath, effect 246
Dispersion, multipath, expression for 247
Dispersion, on a thin layer plate 453
Dispersion, packed column, mobile phase compressibility effect on HETP 268
Dispersion, packed column, relationship to molecular weight 344
Dispersion, radial 240
Dispersion, radial, expression for 242
Dispersion, resistance to mass transfer, mobile phase 251
Dispersion, resistance to mass transfer, stationary phase 252
Dispersion, resistance to mass transfer, stationary phase expression 256
Displacement, development 7
Distribution coefficient, effect of temperature 49
Distribution coefficient, function of free energy 47
Distribution coefficient, in plate equilibrium 21
Distribution coefficient, retention control 47
Distribution coefficient, thermodynamic treatment 47
Done, J.N. 286
Dreyer, B. 45
Dynamics of peak dispersion 237
D’Arcy's equation 29
Eddy diffusion 246
Effective plate number 187
Effective plate number, equation for 188
Effective plate number, relationship to efficiency 189 190
Efficiency, column 179
Efficiency, column, expression for 181
Efficiency, column, plates necessary for resolution 186
Efficiency, relationship to effective plate number 189
Elective variables 365
Electron acceptor sites 76
Electron doner sites 76
Elution, curve, equation for 23
Elution, development in TLC 12
Elution, equation, Gaussian form 165
Elution, of a finite sample 190
Elution, of a finite sample, expression for 192
Elution, process of 9
Enantiomeric separations 81
Endele, R. 286
Energy driven distribution 50
Engelhardt, H. 45
Enthalpy, control of distribution 50
Enthalpy, from Vant Hoff curves 49
Enthalpy, physical significance 48
Enthalpy, positive effect on distribution 53
Enthalpy, standard, free 48
Enthalpy, standard, relationship with standard entropy 61
Entropy driven distribution 51
Entropy, control of distribution 50
Entropy, from Vant Hoff curves 49
Entropy, negative effect on distribution 53
Entropy, physical significance 48
Entropy, standard, for different group types 58
Entropy, standard, free 48
Entropy, standard, relationship with standard enthalpy 61
Eon, C. 313
Equilibrium, established between phases 11
Equilibrium, in a theoretical plate 21
Exit velocity, mobile phase 273
Extensions of the HETP equation 277
Extra column dispersion 288
Extra column dispersion, permitted for different columns 290
Extra column dispersion, sources of 291
Extra column volume 25
Eyring, H. 359
Feller, W. 260
Ficks law 244
Flow, optimum for capillary column 392
Flow, optimum for maximized column 382
Flow, programming 144
Flow, programming, compressible fluid, GC 146
Flow, programming, effect on retention time GC 149
Flow, programming, non compressible fluid, LC 144
Free energy, control of distribution 47
Free energy, distribution between groups 57
Free energy, distribution between interaction types 75
Free energy, standard 48
Freund, M. 442
Freundlich adsorption isotherm 177
Frits, dispersion in 295
Frontal analysis 8
Fudge factors 258
Geiss, F. 455
Gerlach, H.O. 313
Giddings equation 262
Giddings, J.C. 18 233 234 260 285 286 419 455
Gilbert, M.T. 313
Glasstone, S. 85
Gluekauf, E. 17
Golay equation 267
Golay, M.J.E. 18 45 261 286 314
Goldstein, J. 286
Goldup, A. 233
Golshan-Shirazi, S. 18 442
Gradient elution 157
Groszek, A.J. 234
Grushka, E. 359
Guiochon, G. 18 313 442
Gutierrez, J.E.N. 142
Gutlich, K.F. 313
Halasz, L. 286 313
Heat of adsorption detector, theory of 218
Height, of a theoretical plate 239
Height, peak, definition of 16
Height, peak, measurement, effect of assymetry 170
Herington, E.F.G. 18
HETP, minimum 279
Hildebrand, C.P. 233
Hirschfelder, J.O. 164
History of chromatography theory 4
Hofmann 313
Homologous series, thermodynamic analysis of 54
Horne, D.S. 260
Horvath and Lin equation 266
Horvath, Cs. 18 286 455
Huber equation 263
Huber, J.F.K. 18 285 286
Hulsman, A.R.J. 18 285
Hurrel, R. 442
Hurtubise, R.J. 142
Hussain, A. 142
Hydrophilic interactions 71
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