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| Авторизация |
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| McQuarrie D.A. — Statistical Mechanics |
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| Предметный указатель |
Second virial coefficient, triangle potential for 247
Selection rules, for harmonic oscillator 94
Selection rules, for rigid rotor 94
Shear modulus (Modulus of rigidity) 583
Shear viscosity 361 385 386 431
Shear viscosity, reduced 531 532 539 434 448
Sound, speed of 29 127 208 249 390 391 572
Space-time correlation function, distinct 545
Space-time correlation function, self 545 564
Spectral density 556 557
speed of light 593
Speed of sound 373
Spherical top 134
Spherical top, eigenvalues and degeneracy of 134
Spherical top, partition function for 135
Spin waves 219
Spin-orbit interaction 87
Spontaneous process 45 46
Square-well fluid 308
Square-well parameters and second virial coefficient data 433
Square-well parameters and viscosity data 433
Square-well potential 235
Standard free energy 19 154
Standing wave 178
State vector 613
Stationarity 496 509 539 554
Statistical weights 103 104 111
Stefan — Boltzmann constant 181 192
Stefan — Boltzmann law 180 181 192 193
Stirling’s approximation 21 32
Stochastic differential equation 453
Stochastic process 553
Stokes operator 381
Stosszahlansatz (molecular chaos, assumption) 410 422 425
Stream velocity 407
Streaming operator 409
Stress tensor 381 382 392 396 516
Strongly degenerate ideal Bose — Einstein gas 171
Strongly degenerate ideal Fermi — Dirac gas 164
Structure factor 260 291 300 301
Structure factor, from CWA 318
Structure factor, molecular dynamics of 301
Substantial derivative 381
Summational invariant 366
Superposition approximation 267 280 281 290 292
Superposition approximation, Rice — Lekner improvement for 283 284
Superposition approximation, test of 280 281
Superposition approximation, time-dependent 406
Superposition approximation, variational principal of 281
Sutherland constant 365
Sutherland potential 247
Symmetric top 134
Symmetric top, eigenvalue and degeneracy of 135
Symmetric top, partition function for 135
Symmetric top, polarizability of 533
Symmetric wave function 12
Symmetry number 101 105 133
Symmetry of wave functions 12 28 69 101 186
Teller — Redlich product rule 148 158
Tensor 382
Thermal conductivity coefficient 362 447
Thermal conductivity coefficient and time correlation function 521
Thermal conductivity coefficient, reduced 435 448 531 532 539
thermal diffusion 429
Thermal diffusion ratio 429
Thermal pressure 443
Thermal transport coefficients 361 364 428 430 447
Thermal transport coefficients and Chapman — Enskog method 364
Thermal transport coefficients and collision integrals 431
Thermal transport coefficients and density expansion 440
Thermal transport coefficients and kinetic theory 364
Thermal transport coefficients and rigorous derivation 579
Thermal transport coefficients and time-correlation functions 512 524 525
Thermal transport coefficients, reduced 435 448 531 532 539
Thermodynamic formulas for canonical ensemble 44 45 58
Thermodynamic formulas for grand canonical ensemble 54 65
Thermodynamic formulas for isothermal-isobaric ensemble 58 65
Thermodynamic formulas for microcanonical ensemble 57 58
Thermodynamic functions and partition functions, summary of 58
Thermodynamic functions of ideal diatomic gas 108
Thermodynamic functions of ideal monatomic gas 85 86 87
Thermodynamic functions of ideal polyatomic gas 136 137
Thermodynamic functions, table of 58
Thermodynamic tables 151-157
Thermodynamics, review of 13
Third law of thermodynamics 14 30 44 47 54 65 138 141
Third virial coefficient 237-239
Third virial coefficient, experimental 238 239
Third virial coefficient, hard-sphere potential and 240
Third virial coefficient, Lennard — Jones potential and 238
| Third virial coefficient, reduced form of 238
Third virial coefficient, square-well potential and 249
Time-correlation function 467
Time-correlation function and Chapman — Enskog theory 525
Time-correlation function and corresponding states 531 532 539
Time-correlation function and Enskog theory 529
Time-correlation function and integral differential equation 575
Time-correlation function and mean free path theory 523
Time-dependent operator 472
Time-displacement operator 405 418
Time-reversal paradox 415
Totally symmetric vibration 487
Trace of a matrix 183
Trajectories in phase space 118 123
Transition probability 471
Translational partition function 81 82 89 93 95 129
Translational quantum numbers 82 89 113
Transverse waves 179 201 620
traveling wave 177 178 201 621
Triangle potential 247
Two-body problem 26
Two-component system 90 248
Two-fluid theories 294
Two-state systems 78 79
Uncertainty principle 9
Undetermined multipliers, method of 23 40 43 53
Unit tensor 382
Unitary operator 537 616 617
Unperturbed system 302
Ursell functions 251
Ursell — Mayer expansion 251
Van der Waals constants 304 305 321 373
van der Waals equation of state 49 304
van der Waals equation of state and critical parameters 321
van der Waals equation of state and virial coefficients 321
van der Waals equation of state, generalized 321
van der Waals equation of state, reduced 321
van der Waals-1 theory 295 296 297
van der Waals-2 theory 295 296 297
Van Hove space-time correlation function 545
van Hove space-time correlation function, distinct 545
van Hove space-time correlation function, self 545 564
Vapor pressure, of solids 220
Variance 20
Vector identities 396
Vector potential 622
Vector space 613
Velocity contours 395
Verlet — Weis algorithm 323
Vibration-rotation spectrum 104
Vibrational partition function 96 130
Vibrational spectrum 94 110 111
Vibrational spectrum of a crystal 194
Vibrational temperature 97 132
Vineyard approximation 586
Virial coefficients and coulombic potential 327 351
Virial coefficients and intermolecular potential 226-233
Virial coefficients and mixtures 341
Virial coefficients and rigid spheres 234 239-241 279
Virial coefficients of Bose — Einstein gas 170 190
Virial coefficients of Fermi — Dirac gas 163 190
Virial coefficients, from integral equations 278 279 291
Virial coefficients, higher (fourth, fifth, ...) 239 240 241 252 257
Virial coefficients, Lennard — Jones potential and 236
Virial coefficients, quantum corrections and 241-243
Virial coefficients, square well potential and 235
Virial expansion 163 170 223 245
Virial expansion and rectangular conduit 394 395
Virial expansion, of thermodynamic functions 248
Viscosity coefficient 361 385 386 431 447
Viscosity coefficient and mixtures 449
Viscosity coefficient, determination of 393
Viscosity coefficient, reduced 431 448 531 532 539
Viscous flow 392
Volume expansion coefficient 217
Volume of an n-dimensional sphere 12 28 124
Wave equation 390 619 628
Wave equation, inhomogeneous 623
Wave function 9
Wave vector 178 201 207 628
Weakly-degenerate ideal Bose — Einstein gas 169
Weakly-degenerate ideal Fermi — Dirac gas 162
White spectrum 587
Wiener — Khintchine theorem 553
X-ray scattering 259-260 300 546
Zermelo’s paradox 416
Zero moment condition (electroneutrality) 355
Zero of energy 95 96 111 152 153
Zero point pressure 166
Zeta function 33 34 171 180 191
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