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H. Reiss — Treatment of droplike clusters by means of the classical phase integral in nucleation theory
H. Reiss — Treatment of droplike clusters by means of the classical phase integral in nucleation theory



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Название: Treatment of droplike clusters by means of the classical phase integral in nucleation theory

Автор: H. Reiss

Аннотация:

The translation inconsistency in the theory of nucleation is discussed in historical perspective. A theory is then developed, beginning with the classical phase integral, which not only allows all approximations to be well defined, but also leads to the most natural droplike model for the cluster. The theory makes it possible to apply, in a consistent manner, the thermodynamics of curved surfaces or, alternatively, moleculardynamic numerical computation schemes to the evaluation of the partition function of the cluster. If the cluster is treated as a macroscopic drop (having the free energy of a macroscopic drop), the result for the distribution of clusters differs in only a minor way from that prescribed by the conventional theory of nucleation. It is concluded that for liquid nuclei the conventional theory is consistent, but that a replacement factor may be necessary for solid nuclei. In general, however, the major problems confronting the theory involve the precise evaluation of the work of cluster formation.


Язык: en

Рубрика: Физика/

Тип: Статья

Статус предметного указателя: Неизвестно

ed2k: ed2k stats

Год издания: 1970

Количество страниц: 19

Добавлена в каталог: 18.03.2012

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