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Название: Vanadium. Chemistry, biochemistry, pharmacology and practical applications
Авторы: Tracey A.S., Willsky G.R., Takeuchi E.S.
This book has evolved from over a quarter-century of research that concentrated on
delineating the aqueous coordination reactions that characterize the vanadium(V)
oxidation state. At the beginning of this time period, only a minor amount of research
was being done on vanadium aqueous chemistry. However, the basic tenets of
NMR spectroscopy were being elaborated, and some of the influences of ligand
properties and coordination geometry on the NMR spectra were being ascertained.
The power of NMR spectroscopy for the study of vanadium speciation had been
recognized by only one or two laboratories. This would change, and the demonstration
of the great value of this technique for determination of speciation, together
with the discovery that vanadium in the diet of rats could be used to ameliorate the
influence of diabetes, provided the impetus for rapid growth in this area of science.
The discovery of the vanadium-dependent haloperoxidases, the enzymes responsible
for a host of biological halogenation and oxidation reactions, added even more
impetus for understanding vanadium(V) chemistry, in particular that involving