Schreiber E. — Femtosecond real-time spectroscopy of small molecules and clusters :: Электронная библиотека попечительского совета мехмата МГУ

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Schreiber E. — Femtosecond real-time spectroscopy of small molecules and clusters

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Название: Femtosecond real-time spectroscopy of small molecules and clusters

Автор: Schreiber E.

Аннотация:

This book gives a detailed overview on this new and exciting field at the boundary of physics and chemistry.Laser-induced ultrafast molecuar dynamics is presented for many textbook-like examples of model molecules and clusters. Experimental results on phenomena like wave packet propagation, ultrafast photodissociation and femtosecond structural redistribution are presented and described theoretically.

Язык:

Рубрика: Физика/Физика твёрдого тела/Приложения/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1998

Количество страниц: 212

Добавлена в каталог: 29.09.2005

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID

Предметный указатель

Absorption, spectrum      167
Absorption, three-photon      162
Absorption, two-photon      155
Acousto-optic modulator      16
Adiabatic, expansion      27 181
Adiabatic, potential      73
Adiabatic, representation      64
Alternation, even-odd      146 152 175
Amplification, titanium sapphire      7
Anharmonicity      55 94
Argon ion laser, actively mode-locked      13
Autocorrelation      23
Autocorrelation, function      24 116
Autocorrelation, interferometric      17 32 123 124
Autocorrelation, trace      17
Autocorrelation, width $\Delta_{\tau_A}$       25
Autocorrelator      13
Autoionization      79
Background gas      37
Baffle      26
Bandwidth      13 17
Bandwidth, transform-limited      4
Beam waist      14 15
Beat structure      172
Beta ( $\beta$ -)barium borate (BBO)      20 36 149
Birefringent filter      17
Bohr frequency      177
Boltzmann distribution      113
Bond breaking      131
Born — Oppenheimer approximation      41 46 64 160
Branching ratio      134
Catalysis      5
Cavity      12
Cavity, length      20
Charge reversal, experiment      33
Charge reversal, process      6 7 46 155
Chirp      12 15
Chirp, negative      16
Chirp, positive      15
Chirped pulse amplification      34
Chromophore      177
Coexpansion      27
Coherence      3 42
Coherent, control      2
Coherent, radiation      18
Cohesion      153
Cold reflex discharge ion source (CORDIS)      37
Collision      155 165
Collision, reactive      182
Condon point      53
Configuration-interaction method (CI)      134 148
Control      3 176
Control, mechanism      83
Control, molecular dynamics      4 51 115
Control, parameter      83
Control, reaction      83 122
Convolution function      44 137
Critical stability      29
Cross correlation      22 44
Curve crossing      72
Dark state      3 117 124
Decay, constant      174
Decay, dissociative      6
Decay, radiative      6 134 136
Decay, single exponential      174
Decay, time      124 151 175
Deconvolution      167
Delay time $\Delta t$       10
Density matrix method      7 163
Density matrix method, time-dependent ab initio quantum chemical      47
Dephasing time      97
Depletion spectroscopy (DS)      5 103 123 132 139
Depopulation      132
Detection, mass-selected      9
Diabatic representation      64
Dichroic mirrors      149
dielectric constant      42
Difference potential analysis      77 78
Diffractive grating      35
Dipole, absorption      148
Dipole, approximation      42 66
Dipole, transition moment      42 66
Dipole, transition moment, function      112
Discrete variable representation (DVR)      41
Dissociation, channel      133 175
Dissociation, dynamics      5
Dissociation, photo      5
Dissociation, ultrafast      6
Downhill simplex method      46
Dunham fit      52
Dye laser, astigmatically compensated      13
Dye laser, colliding-pulse mode-locked (CPM)      7 12
Dye laser, continuous wave (cw)      12
Dye laser, synchronously pumped      12
Eigenenergies      1
Electron      41
Electron, excess      156
Electronic state, crossing      172
Electronic state, dissociative      43
Electronic state, double minimum      176
Electronic state, excited      166
Electronic state, ground      87 127 137 173 174
Electronic state, perturbed      173
Energy detachment, adiabatic      165
Energy detachment, vertical (VDE)      165
Energy, conservation      19
Energy, eigenstates      1
Energy, gap      84
Energy, Hartree      113
Energy, kinetic      38 41 111 162
Energy, level scheme      145
Energy, potential      41 111
Energy, shift      172
Energy, transfer      5 123
Energy-level model      175
Energy-level model, extended      45 124
Energy-level model, simple      44 137
Excitation, selective      122
Faraday rotator      35
Fast Fourier transform (FFT) propagation      112
Fluctuation, pulse-to-pulse      7
Fourier analysis      33 55 68 78 171 173
Fourier component      79
Fourier limit      17
Fourier spectrum      59 91 116 128 174
Fourier transform      89
Fourier transform propagation method      40
Fourier transform spectroscopy      52
Fourier transform, algorithm      42
Fourier transform, method      42
Fourier transform, second-order differencing fast (SOD-FFT)      67
Fourier transform, sliding-window      60
Fourier transformation      3
Fragmentation      5 43 124 132 136 144 151 166
Fragmentation, dynamics      139
Fragmentation, ionic      153
Fragmentation, model      140
Fragmentation, photoinduced      132 133
Fragmentation, probability      5 134 138 142 145 152
Fragmentation, process      138
Fragmentation, time constant      138 175
Franck — Condon detachment process      159
Franck — Condon factor      73 121 155 159 162 165 175
Franck — Condon overlap      169
Franck — Condon point      96
Franck — Condon principle      52
Franck — Condon process, vertical      159
Franck — Condon transition      47 96 181
Franck — Condon window      3 53 77 82 173
Frequency, mixing      36

Frequency, resolved optical gating (FROG)      25
Full width half maximum (FWHM)      12
Gain, media      14 15
Gain, profile      14
Geometrical phase      112
Gires — Tournois interferometer (GTI)      16 17
Grid propagation      47
Group velocity dispersion (GVD)      12 15 17 32
Hamilton matrix      41 110
Hamiltonian      41 64 65 111
Hamiltonian, Watson      47
harmonic oscillator      47
Harmonic progression      139
Hartree — Fock formalism      41
Heat-pipe oven      94
Helium clusters      179
Hole, dynamical      88
Interference      168
Interference, quantum      177
Interferogram      177
Internal energy transfer      131
Intersystem crossing (ISC)      63
Intersystem crossing (ISC), process      3 118
Intramolecular vibrational redistribution (IVR)      3 101 120 144 164 179 181
inversion      15
Ion, continuum model      84
Ion, deflector      29
Ion, fragment      166
Ion, lens      37
Ion, trajectory      39
Ion, trap      37
Ion, yield      167
Ionization (TPI), two-photon, two-color      144
Ionization, limit      133
Ionization, multiphoton (MPI)      1 9 123 159
Ionization, multiphoton (MPI), resonantly enhanced (REMPI)      9
Ionization, potential (IP)      157 160 165
Ionization, potential (IP), vertical      159
Ionization, probability      159
Ionization, three-photon (3PI)      32 172
Ionization, threshold      148
Ionization, two-photon (TPI)      9 156 169
Isomer, bond-length      176
Isomerization      7 165 176 179
Isotope      3 52 68 97 172
Isotope, selective      172
Isotopic, correction factor      97
Isotopic, shift      97
Jahn — Teller (JT) distortion      101
Jahn — Teller (JT) effect      111
Jahn — Teller (JT) effect, pseudo- (PJT)      111
Jahn — Teller (JT) effect, second-order      181
Jahn — Teller (JT) system      102
Jellium model      144 152 175
Langmuir — Taylor detector      29
Laser-induced fluorescence (LIF)      6 52
Least-squares fit      167
Least-squares fit, algorithm      142 151 175
Least-squares fit, functions      143
Least-squares fit, routine      46 137
Lifetime      5 124 134 136 146 175
Lifetime, radiative      134 138
Lithium triborate (LBO)      20
Littrow incidence      35
Mass-to-charge ratio (m/e)      29
Master-slave technique      21
Michelson interferometer      24
Mode, asymmetric bending      174
Mode, asymmetric stretch      104
Mode, breathing      105
Mode, normal      110
Mode, pseudorotational      121
Mode, symmetric bending      104 165 174
Mode, symmetric stretch      104 116 128 165 174
Mode, vibrational      174
Mode-locking, active      12
Mode-locking, amplitude-modulation      13
Mode-locking, colliding-pulse      7
Mode-locking, Kerr-lens      7
Mode-locking, passive      12
Mode-locking, regenerative      7 16
Mode-locking, self-      7
Mode-selective excitation      179
Molecular Dynamics      160
Molecular dynamics, control      40 172-174
Molecular supersonic beam      26
Molecular vibration frequency $\omega_{cl}$       53
Momentum conservation      19
Nd:YLF laser      34
Nonequilibrium state      175
Nonlinear crystal      24
Nozzle      28
Nucleation      27
Optical encoder      31
Optical Kerr effect (OKE)      15
Optical parametric amplifier (OPA), travelling-wave (tw—OPA)      36
Optical parametric generation (OPG)      36
Optical parametric oscillation (OPO)      7
Optical parametric oscillator (OPO)      18 149
Optical parametric oscillator (OPO), continuous wave (cw) mode-locked      19
Optical parametric oscillator (OPO), idler      18
Optical parametric oscillator (OPO), signal      18
Optical parametric oscillator (OPO), synchronously pumped      19
Optical-optical double resonance      52
Overall system response      44 124 137 142 167
Perturbation      51 75 172
Perturbation matrix      73
Phase noise spectral density (PNSD)      23
Phase, compensation, cubic      12
Phase, compensation, quadratic      12
Phase, space density      163
Phase-frequency detector      22
Photo, detachment      6 33 155 175
Photo, diode      16
Photo, dissociation      148 174
Photo, electron      155
Photo, excitation      175
Photo, excited      10
Photo, ionization      33
Photo, probability      175
Pickup source      177
Piezoelectric transducer (PZT)      20 22
PIN Photodiode      22
Plasmon      147
Pockels cell      35
Point group symmetry, $C_{2v}$       165
Polarization, optically induced      18
Population density      44 140
Population density, initial      142
Population density, transient      141
Population dynamics      71
Potassium dideuterium phosphate (KD*P)      35
Potential-energy surface (PES)      4 9 41
Potential-energy surface (PES), Mexican hat      161
Potential-energy surface (PES), repulsive      123 132 172 175
Potential-energy surface (PES), torsional      180
Power, average      13
Predissociation      6 133 135 139 175
Predissociation, lifetime      139
Predissociation, threshold      137
Pseudorotation      4 51 103 104 133 161 162 174
Pseudorotation, angular coordinate      105 112
Pseudorotation, barrier      181
Pseudorotation, lifetime      162
Pseudorotation, radial coordinate      105
Pulse, $2\pi$       88
Pulse, $\pi$       88
Pulse, compressor      34
Pulse, duration      13
Pulse, Fourier-limited      3

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