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| Guggenheim E.A. — Thermodynamics |
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| Предметный указатель |
Gibbs function 22
Gibbs geometrical surface 49
Gibbs — Duhem relation 25
Gibbs — Duhem relation, for dilute solutions 222
Gibbs — Duhem relation, for electrolyte solutions 277
Gibbs — Duhem relation, for surface phase 48
Gibbs — Helmholtz relation 40 313
Gibbs' phase rule 33
Glew 252
Gorsky 257
Gravitational field 327 et seq.
Griffiths 315
Guggenheim 18 45 50 55 72 95 98 105 108 135 136 142 151 157 166 176 186 196 203 205 211 212 252 261 287 288 290 300 326 345 357 369
Habgood 126
Harned 285
Harteck 115
Heat 9
Heat capacities, at constant pressure 85
Heat capacities, at constant volume 88
Heat capacities, at saturation 122
Heat capacities, of two phases in equilibrium 121
Heat capacities, Relation between 89
Heat, and entropy 16
Heat, So-called mechanical equivalent of 86
Heat, theorem, Nernst's 154 313
Heine 349
Heitler 198
Helmholtz 10 313 369
Helmholtz function 22
Henderson 1
Herington 194
Herzberg 105 108
Hess' law 242
hilbert 22
Hildebrand 25 198
Hills 319
Holborn 101
Hueckel 281 285
Hydrogen, Entropy of 151
hydrolysis 289
Hydrostatic equilibrium 31
Hysteresis, magnetic 344 351
Ideal dilute solutions 233 see
Ideal dilute solutions of electrolytes 272
Ideal mixtures 186 see
Ideal mixtures, Solid 218
Imperfect gas mixtures 175 see
Imperfect gases 90 see
Interaction parameters (electrolytes) 286
Interfaces 45 159 207 237 293
Interfaces, Curved 50 54
Interfaces, Gas-solid 166
Interfaces, Gibbs — Duhem relation for 48
Interfaces, in mixtures 207 et seq.
Interfaces, in one-component systems 159 et seq.
Interfaces, in solutions 237
Interfaces, in solutions of electrolytes 293
Interfaces, Plane 45
Interfaces, Thermodynamic functions for 47
Interfacial tension, between two solutions 238
Interfacial tension, determination of 53
Interfacial tension, of curved interface 50
Interfacial tension, of plane interface 46
Interfacial tension, Temperature dependence of, for mixture 214 see
Internal degrees of freedom 77
Inversion temperature of a gas 100
Ionic diameter 285
Ionic solutions see “Electrolyte solutions”
Ionic strength 282
Ionization product of water 292
Irreversible processes, Thermodynamics of 362 et seq.
Isothermal, change in closed system 26
Isothermal, compressibility 38
Isothermal, cycle 44
Isotopic mixing 150
Ives 319
Jacobians, Use of, in thermodynamics 41
Joule 10 86 92
Joule — Thomson coefficient 99
Joule — Thomson experiment 92
Junction potentials 309
Katayama 164
Keesom 91 259 260
Kelley 245 315
Kelvin 9 17 18 92
Kelvin's relations for thermocouple 374
Kirchhoff's relations 243
Kister 194 196
Koenig 58
Kondo 56
Lambda point 255 257
Lambda point, Ferromagnetic 351
Lambda point, Pressure dependence of 262
Landau 107
Lange 315
Legendre transformation 22
Lewis 3 38 97 176 181 282
Liquid junction potentials 309
Liquids, Corresponding states of 135
Liquids, Equation of state for 141
Liquids, Fugacities of 135 180
Liquids, in gravitational field 329
Liquids, Interdiffusion of 375
Liquids, Mixtures of 177 et seq. see
Liquids, Phase equilibria involving 119 et seq.
Liquids, Relative activities in mixtures of 180
Liquids, Surface tension of 159
Liquids, Thermodynamics of 108 110
Lodge 1
Longuet-Higgins 142
Macleod 166
Macroscopic system 63 68
Magnetic, field intensity 343
Magnetic, induction 339
Magnetic, moment 342
Magnetic, saturation 348
Magnetic, systems 338 et seq.
Magnetic, vector potential 340
Magnetic, work 344
magnetization 343
Magnetization, Permanent 351
Magneton, Bohr's 352
Magnetostriction 346
Margules 185
Massieu 24
Massieu function 24
Massieu function, in statistical thermodynamics 67
Maxwell 7 39 130 131 365
Maxwell's equal area rule 130
Maxwell's relations 39
Maxwell's relations, Analogues of, for electrostatic systems 335
McBain 167
McGavock 251
McGlashan 136 176 190 198 200 205
Melting point, of pure solid 120
Melting point, Stationary, of solid mixture 218 see
Membrane equilibrium 34
Membrane equilibrium, Donnan 306
Membrane equilibrium, Non-osmotic 304
Membrane equilibrium, Osmotic 305
Membrane, Semi-permeable 182 190 206 229 304
Metastability 28 125 130 194
Michels 126
Miller 368 374 377
Milner 280
Miscibility, Partial 195 et seq.
Mixing, Critical 195 et seq.
Mixing, Entropy of, in ideal mixture 188 219
Mixing, Entropy of, of isotopes 150
Mixing, Excess functions for 191
| Mixing, Functions of 191 see
Mixtures 170 et seq. see
Mixtures, Athermal 205
Mixtures, Gaseous 173 et seq.
Mixtures, Ideal 186
Mixtures, Ideal, Solid 217
Mixtures, in gravitational field 406
Mixtures, Interfacial layers in 207
Mixtures, Liquid 177 et seq.
Mixtures, Non-ideal 190
Mixtures, of isotopes 150
Mixtures, of large and small molecules 205
Mixtures, Partial miscibility in 195 200
Mixtures, Simple 197
Mixtures, Solid 218
Mixtures, Surface tension of 207 et seq.
Mixtures, Symmetrical 196
Mixtures, Unsymmetrical 203
Mochel 198
Molalities 3 220
Molalities, Ionic 268
Mole 2 94
Mole fractions 24 170
Mole ratios 220
Mole ratios, Ionic 268
Motion, Systems in 378 et seq.
Moutier 45
Moutier's theorem 45
Natural process 12
Nernst 155
Nernst's distribution law 233 275
Nernst's heat theorem 154 313
Non-ideal mixtures 190 see
Nuclear spins 151
ogg 24
Onnes 22 91 348 355
Onsager 365
Onsager's reciprocal relations 362 et seq. 365
Open phase 14
Open system 14
Order, Degree of 257
Ortho hydrogen 151
Osmotic coefficient of solvent 226
Osmotic coefficient of solvent, in electrolyte solutions 273 305
Osmotic equilibrium 182
Osmotic membrane equilibrium 305
Osmotic pressure 183
Osmotic pressure, Electro- 367
Osmotic pressure, of athermal mixtures 206
Osmotic pressure, of dilute solutions 229
Osmotic pressure, of electrolyte solutions 273 305
Osmotic pressure, of ideal mixtures 190
Otto 101
Owen 285
Para hydrogen 151
Paramagnetic substances 351
Partial areas of surface 212
Partial miscibility 195 et seq.
Partial pressures 177
Partial pressures, Dalton's law of 175
Partial quantities 20 171
Partial quantities, at high dilution 173 223
Partial quantities, in dilute solutions 221
Partition functions 63 et seq.
Partition functions, of units 76
Pauling 149
Peltier effect 374
Perfect gas mixtures 173 see also “Gas mixtures”
Perfect gases 95 see
Permeability 334
Permeability, of a vacuum 339
Permittivity 334 343
Permittivity, of a vacuum 333 339
Perrin 369
Phase rule 33
Phases 6
Phases, at different pressures 132
Phases, Chemical content, of 19
Phases, Closed and open 14
Phases, Condensed 90 180 see
Phases, Degrees of freedom of 24
Phases, Electrically charged 298
Phases, Equilibrium distribution between 32
Phases, Equilibrium distribution between, at different pressures 132
Phases, Equilibrium of three pure 124
Phases, Equilibrium of two pure 118
Phases, Gaseous see “Gases”
Phases, in gravitational field 327
Phases, Internal stability of 30 33 194
Phases, Liquid see “Liquids”
Phases, Solid see “Solids”
Phases, Surface 45 see
Pitzer 3 135 315
Planck 1 12 24 124
Planck function 24
Planck function, in statistical thermodynamics 69
Planck's formula for radiation 359
Polarization, electric 342
Porter 22 198
Potter 136
Prausnitz 166
Pressure, critical 128 136
Pressure, osmotic 183 see
Pressure, partial 177
Pressure, standard 243
Pressure, Triple-point 124
Pressure, Vapour 121 177
Prigogine 17 37 362
Principle of corresponding states see “Corresponding states”
Probability, Thermodynamic 63 72
Processes 7 12
Processes, Irreversible, Thermodynamics of 362 et seq.
Proper quantities 3 20 171
Properties, Intensive and extensive 18 19
Radiation 357 et seq.
Ramberg 340 344
Randall 3 38 176 282
Rankine 7
Raoult's law 189
Raoult's law, Deviations from 191 et seq.
Raymond 194
Reaction, chemical 34 240 see
Reaction, Extent of 37 62
Reciprocal relations, Onsager's 362 et seq.
Redlich 194 196
Relative activities 180
Relative volatility 192
Relativistic formulae 378
Reversible, change 13
Reversible, cycle 43
Reversible, process 12 312
Robinson 289
Rossini 245 248
Rotational degrees of freedom 104 et seq. 151
Rowlinson 98 137
Scatchard 194 196 198
Schneider 126
Scott 25 198
Second law of thermodynamics 17
Second law of thermodynamics, Statistical basis of 66
Second order transitions 252 351
Second virial coefficient of a gas 91
Second virial coefficient of a gas, at high temperatures 97
Second virial coefficient of a gas, Dependence of, on composition 175
Second virial coefficient of a gas, Dependence of, on temperature 99
Seebeck effect 372
Separable degrees of freedom 77
Shaw 41
Simon 155 157 356
Simple mixtures 197 see
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