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Авторизация |
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Поиск по указателям |
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Holden A. — Bonds Between Atoms |
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Предметный указатель |
acetylene 78
Adamantane 95
Adamantine solids 15
Alcohols, boiling points of 11
Alkali metals, bonding in 87
Alkali metals, halides of 17
Aluminum ion 100
Ammonia, bonds in molecule of 70 72
Ammonia, dipole moment of 74
Ammonium sulphate 15
Angles between bonds 72ff
Angstrom unit 18
anthracene 85 90
Antibonding states 46 64 68 69 70 91
Antisymmetry, principle of 56 65
Arabian alchemy 2
Argon, chemical inertness of 27
Argon, crystals of 13 31
Aristotle, doctrine of the elements 1
Atomic orbitals 61 (see also “Aufbauprinzip”)
Atomic orbitals, shapes of hybrid 76ff
Atomic orbitals, shapes of p 72
Aufbauprinzip 70ff
Avogadro’s number 18
Bamberger structure of 82
Bamberger structure of, delocalized electrons in 82 83 90ff
Bamberger structure of, delta-well model for 90ff
Bamberger structure of, resonance energy of 84 93
Bamberger, Eugen 82
Barium ion 100
Barlow, William 6
Benitoite 100
benzene 14
Benzene, Kekule structure of 81
Beryl 100
Beryllium, excited state of 76
Beryllium, ion 100
Beryllium, oxide 79
Beryllium, valency of 75
Berzelius, Jons 4 5 17
Binding energy 30 38
Boiling temperature 11
Bond energies (see “Binding energy”)
copper 15
Coulomb, Charles — Augustin 3
Covalent bonds 7 37
Dative bonds 85
Davy, Sir Humphry 4 5 17
de Broglie wavelength 7 41 92
Degeneracy, orbital 64
Delocalization of bonding electrons 80ff
Delta-well model for benzene 90
Delta-well model for hydrogen molecule 55
Delta-well model for hydrogen-molecule ion 43 49ff
Delta-well model for nitrous oxide 89
diamond 8 14 95 100
Dichlorobenzenes 81
Dipoles 9
Dipoles of water 72 100
Dipoles, as criterion of structure 83 85
Dipoles, fluctuating 11 27ff
Dipoles, in plastics and proteins 97
Dipoles, induced 12 22 100
Dispersion forces 13 14 27
Dispersion forces, ff 97
Dispersion forces, in graphite 87
Dissociation energy 38 41
Dissociation energy of alkali halides 17 19 21
Dissociation energy of hydrogen molecule 67
Dissociation energy of hydrogen-molecule ion 48
Dissociation energy of sodium chloride 5 6
Dissociation energy, aliphatic compounds of 76ff
Dissociation energy, angles between 72ff
Dissociation energy, aromatic compounds of 80ff
Dissociation energy, as criterion for bond-type 5
Dissociation energy, Bonding states 46 64 68 91
Dissociation energy, Born, Max 39
Dissociation energy, Boyle, Robert 2
Dissociation energy, Bridges, oxygen 99
Dissociation energy, Calcite 15
Dissociation energy, Calomel 15
Dissociation energy, Carborundum 15
Dissociation energy, Carcinogenic hydrocarbons 103
Dissociation energy, Cellulose, wetting of 100 102
Dissociation energy, close-packed 13
Dissociation energy, Compressibility of atoms 19
Dissociation energy, Cristobalite 100
Dissociation energy, Cross-linking 96
Dissociation energy, dioxide 79
Dissociation energy, effective ionic radii in 26
Dissociation energy, electronic 13
Dissociation energy, excited state of 76
Dissociation energy, ff 15
Dissociation energy, in graphite 86
Dissociation energy, ionic 7 9
Dissociation energy, ionization potential of 93
Dissociation energy, law of 13 24 38
Dissociation energy, quadrupole moment of 10
Dissociation energy, valency of 75
Dissociation energy, validity of electrostatic picture of 46
Donor-acceptor bonds 85
Double bonds, in carbon compounds 76 78 8
Double bonds, in nitrous oxide 85
Dualistic hypothesis 4 17
Dufay, Charles 3
Economy, principle of 94
Effective radii of ions 26 100
Electrolysis see also Conduction, electrical 4 7
Electron affinity 19 98
Electron-deficient bonds 64 87
Electron-pair bonds 37 47 53ff
Electronegativities of atoms 72 94 96
Electrons, exchange of 7 53 55 60
Electrons, exclusion principle for 7 19 53 55
Electrons, gain or loss by atoms 5
Electrons, identification of 4
Electrons, magnitude of charge on 17
Electrons, principle of antisymmetry 56
Electrostatic bonding 1 4 14 17 46 65 94
Energy units 18
ethane 78
ethylene 78
Exchange integral 68
Exchange of electrons 7 53 65 69ff
Excited atomic states 76
Exclusion principle 7 19 53 55
Feynman, Richard 46
First ionization energy 32 67 93
Flesh 97
Fluorine molecule 70 75
Geber 2
Glaciers 102
graphite 85
Ground-states of atoms 70
Halides of alkali metals 17
Halides of hydrogen 33
Hardness 15
Harmonic oscillators, coupled 29 33
Harmonic oscillators, zero-point energy of 26
Helium, diatomic molecule of 70
Helium, hydride ion 79
Helium, hydride molecule 69
Helium, ion 43 48
Hybrid, orbitals 76ff
Hybrid, structures 85
| Hydrocarbons, benzenoid 8
Hydrocarbons, boiling points of 11
Hydrocarbons, bonds between oxygen atoms 102
Hydrocarbons, compared with its ion 47
Hydrocarbons, disobedient to dualistic hypothesis 4
Hydrocarbons, formal electronic arrangements in 8
Hydrocarbons, halides 33
Hydrocarbons, Hydrogen molecule 53
Hydrocarbons, Hydrogen-molecule ion 37ff
Hydrocarbons, ionization potential of 67 93
Hydrocarbons, sulphide 72
ICE 102
Impurities in solids 16
Ionic states in covalent bonds 62 64 72 85 96
Ionization potential 19 32 67 93
Iron 15
Jabir ibn Hayyan 2
Kekule, Friedrich 81 90
Kilogramme-calorie per mole 18
LCAO approximation 62 64
Living matter (see “Organic compounds”)
Localization of electrons 8 14 80 90
Melting of ionic solids 5
Melting of molecular solids 9 10
Mercury, as metallic principle 2
Mesomers 8
Metals, bonding in 13 87
Metals, ions of, in minerals 99
Methane, bonds in molecule of 76
Methane, solid binding energy 32
Minerals 97
Model, one-dimensional for benzene 90
Model, one-dimensional for hydrogen molecule 55
Model, one-dimensional for hydrogen-molecule ion 41 43
Model, one-dimensional for nitrous oxide 89
Molecular orbitals 61 64
Multipole forces 9 11 12 15
Muscle 97
naphthalene 85 90
Neon, chemical inertness of 27
Neon, solid binding energy of 32
Newton, Sir Isaac 1 3 94
Nicholson, William 4
Nitrogen, bonding in molecule of 72 75 77
Nitrogen, electronegativity of atom of 72 94 96
Nitrogen, nonbonding pair in 85 88
Nitrogen, solid binding energy of 32
Nitrous oxide 84 87 89
Nonbonding pair 85 88
Nylon 96
Occam’s razor 94
Octane, normal 94 96
One-dimensional model (see “Model”)
One-electron bond 37ff
Oppenheimer, J Robert 39
Orbitals 61
Orbitals, degeneracy of 64
Orbitals, hybrid 76ff
Orbitals, overlap of atomic 69
Organic compounds 94
Organic compounds, bonding in aliphatic 76ff
Organic compounds, bonding in aromatic 80ff
oscillators (see “Harmonic oscillators”)
Oxygen, electronegativity of atom of 72 94 96
Oxygen, ground state of atom of 70
Oxygen, orbital degeneracy in molecule of 64
Oxygen, role of, in silicates 99ff
Paper, wetting of 100
Paracelsus, tria prima of 2
Paraffin 8 15
Periodic table of elements 70 75
Perylene 85
Phenanthrene 85 90
Phosphine 72
Photon 32
Pi bonds 75 77
Pile, voltaic 2
Plastics 96
Plausible models 37
Polar states (see “Ionic states”)
Polarizability 11 22ff
Polyamides 98
Polythene 8 96
Potassium chloride 13
Potential wells 39ff
Proteins 97
Protons, fathering a ‘protonics’ industry 103 (see also “Hydrogen”)
Protons, polarizing other atoms 100 (see also “Hydrogen”)
Quadrupole moment 11
Quartz 100
Radicals, chemical 4
Rare gases 15 17 27
Repulsive energy 19 31 41 48 67 70
Resonance combinations 82 85
Resonance energy 84 93
Rocks 97
Rotation about bonds 78 94
Rubber 96
Rutherford, Sir Ernest 17
Salt (see “Sodium chloride”)
Sceptical Chymist, The 2
Schrodinger, Erwin 1
Semiconductors 15
Sigma bonds 75 77
Silicates 98ff
Silicon see also Silicates 97 103
Silicon see also Silicates, dioxide 100
Snowflake 102
Sodium, chloride 5 6 19 26 100
Sodium, metal 15 87
Spins (see “Electrons”)
Sticks representing bonds 79
Sulphate ion 14
Sulphur, in vulcanization 96
Sulphur, melting of 9
Symmetry of electronic states 56 65
Symmetry, ion 43
tetrahedral bonding 76 95 98
Thales of Miletus 3
Thomson, Sir Joseph John 4 17
Three-body problem 38
Titanium ion 100
Tria prima of Paracelsus 2
Triple bonds, in carbon compounds 77 78
Triple bonds, in nitrogen molecule 75 77
triplet state 57
Tungsten 15
UNITS 18
Valency, saturated 64 78
Valency, saturated, van der Waals, Johannes 12 95 99
Valency, saturated, van Helmont, Jean Baptiste 3
Vaporization of alkali halides 17
Vaporization of hydrogen halides 33
Vaporization of solid argon 30
Variational calculation 63
Virial theorem 49
Volta, Alessandro 3
Vulcanization 96
Wells potential 39ff
Wetting 100
Wood, wetting of 100
X-ray diffraction, crystal structures by 6
Zero-point energy 26
Zinc blende 15
Zircon 98
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