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van Dijk M.A., Wakker A. — Concepts of Polymer Thermodynamics
van Dijk M.A., Wakker A. — Concepts of Polymer Thermodynamics



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Название: Concepts of Polymer Thermodynamics

Авторы: van Dijk M.A., Wakker A.

Аннотация:

Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends.
These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers.
Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture.
These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1998

Количество страниц: 212

Добавлена в каталог: 23.11.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Atomic index      41
Autocorrelation function      155
Binodal      19 24 74 76 85 148 149 173
Blend, miscible      1
Boltzmann, constant      26
Boltzmann, distribution      128
Bom — Oppenheimer approximation      133
Bond, index      41
Bond, rotation      54
Bond, valence angle      54
Boyle temperature      60
Boyle — Gay — Lussac law      25
Bragg condition      156
Brownian motion      16
Building block      1
Caley tree      110
Cell partition function      90 97 101
Chain, configuration      53 55 63
Chain, configurational freedom      63
Chain, conformation      52 53
Chain, deuterated      163
Chain, dimension      53
Chain, end-to-end distance      138
Chain, entropy      55
Chain, flexibility      52 91
Chain, flexible      64
Chain, gaussian      119
Chain, ideal      52 53 72
Chain, model      53
Chain, real      56 59 60
Chain, rigid-rod      119
Chain, single      138
Chain, statistics      52
Chain-infinite length      72
Chain-length      73 79 82 94 166
Chemical, equilibrium      11
Chemical, potential      7 8 9 12 15 28 68 71 73
Chemical, structure      39 50
Cloud point      74 148 151 172 180 196
Compatibilizer      2
Compatibilizing      2
composition      9 15
Composition, fluctuation      16 17 20
Composition, metastable      69
Composition, triangle      22
Compressibility effect      104
Compressibility effect, term      18
Computer simulation      3 125 127 136
Concentration fluctuation      148 154
Configuration      47
Connodal      21
Contacts, polymer-polymer      59
Contacts, segment-segment      59
Contribution, topological      39
Copolymer block      2
correlation length      184 186
Critical, concentration      84 150
Critical, solution temperature      168
Critical, temperature      166 174 190
Critical, value      152
Crystalline, component      24 25
Crystalline, material      23
Crystalline, solid      23
Crystallinity      164
Crystallization      23
Crystallization, behavior      134
Crystallization, Page      206
Dalton Law      26
de Gennes Theory      111
Debye function      184
Degrees of freedom      12 40 88 92 102
Demixing      24 86 94 169
Density, reduced      99
Destabilizing effect      18
Diffusion coefficient      153 156
DMA      164
Driving force      1 17
DSC      164
Einstein — Smoluchowski Theory      146
Electron clouds      134
Energy, cohesive      36
Energy, density      34
Energy, exchange      33
Energy, free      17 55 181
Energy, function      12
Energy, internal      5 34
Energy, kinetic      129
Energy, mixing      4
Energy, scale      129
Energy, total free      58
Energy, vaporization      34
Ensemble, Canonical      128 131 136
Ensemble, Grand Canonical      128 131
Ensemble, isothermal      128
Ensemble, isothermal-isobaric      131
Ensemble, microcanonical      128
Enthalpic parameter      179
Enthalpy      6
Enthalpy, mixing      13
Entropic parameter      179 180
entropy      5 25
Entropy, combinatorial      3 85 98
Entropy, configurational      93
Entropy, loss      23
Entropy, mixing      34
Equation-of-state      81
Equilibrium      11
Equilibrium, conditions, H liquid-liquid      6
Equilibrium, state      154
Ergodic condition      127
Euler theorem      7
Eutectic, composition      24
Eutectic, point      24
Eutectic, temperature      24
Flash calculations      76
Flory theory      92
Flory — Huggins Expression      3 65
Flory — Huggins theory      149
Fluctuation      12
Force, dispersion      39
Force, intermolecular      26
Freed Theory      82
Gibbs free energy      6 7 8 10
Gibbs phase rule      12
Gibbs — Duhem relation      8
Group contribution      35 38
Groups side      52
Growth mechanism      148
Gyration radius      55 121 133 163 184
Hard sphere liquid      90
Heat, fusion      23
Heat, vaporization      34
Helmholtz free energy      6 14 86 89 98
Heterogeneity index      52 75
Hildebrand Derivation      64
Hooke law      56
Hour-glass      176
Huggins Correction      65 68 84
Hybrid theories      126
Ideal gas      25 27
Inflection point      19
Interaction      25 26
Interaction parameter      66 70 146 176 183 189 191
Interaction, channel      102 105
Interaction, dispersive      59 101 108 166
Interaction, energetic      72
Interaction, energy      35 96 107 189
Interaction, enthalpic      56 165
Interaction, entropic      72
Interaction, mutual      27
Interaction, parameter      34 75 83 94 102
Interaction, potential      118
Interaction, segment-segment      72
Interaction, specific      191
Interaction, strength      107
Interface, vapor-liquid      12
Intermolecular distance      56
IPN      154
Isothermal compressibility      18
Kelvin Law      5
Kuhn statistical length      54
Lattice Fluid Theory      175
Lattice — Bethe, coordination number      45 84 103 115
Lattice — Bethe, cubic      56 57 125
Lattice — Bethe, fixed coordination number      100
Lattice — Bethe, segment      83
Lattice — Bethe, site      111
Lattice — Bethe, site volume      82
Lattice — Bethe, theories      45 142
Lattice — Bethe, two-dimensional      57
LCST      18 20 71 86 94 96 99 101 102 109 149 166 172 176 178 182 190
Lennard — Jones potential      90 91
Light scattering      154
Liquid phase      5
London forces      59
London — Van der Waals interaction      33
Mass, density      9
Mass, fraction, in Maxwell Equation      156
Mean spherical approximation      117
Melting point, depression      23
Melting point, U      9
Metastability      149
Miscibility      1 4 13
Miscibility, behavior      171
Miscibility, molecular scale      145
Miscibility, polymer-polymer      105
Mixing, endothermic      33
Mixing, entropy      23 27 46 61 62 64 96
Mixing, exothermic      3
Mixing, free energy      13 66
Mixing, function      20
Mixing, heat      33 39 48 163 177 195
Mixing, non-random      102
Mixture, binary      2
Mixture, entropy      63
Mixture, homogeneous      26
Mixture, ideal      25 27
Mixture, miscible      104
Mixture, multicomponent      21
Mixture, random      32
Mixture, regular      31
Mixture, ternary      22
Model, equation-of-state      85
Model, Flory      93 98 99 109
Model, Hole      97
Model, interaction site      117
Model, lattice      83
Model, Lory — Huggins      82
Model, Sanchez — Lacombe      81 109
Model, specific interactions      101
Model, Ten Brinke      109
Model, thermodynamic      81
Model, TRISM, U      8
Model, validation      165
Model, vector      110
Model, “Holes and Huggins”      81 100
Molar, attraction      38
Molar, quantities      9
Molar, volume      9
Mole fraction      8
Molecular, dynamics      126 133 136
Molecular, dynamics simulation      119
Molecular, modelling      3 197
Molecular, page      208
Molecular, parameters      172
Molecular, weight      9 50 51 52 75 176 180
Molecular, weight distribution      73 85
Monomer      50
Monte Carlo      3 58 126 134 135 138
Morphology      1 2
Multiphase system      1
Nernst theorem      26
Nucleation      148
Ornstein — Zemike Equation      116
Ornstein — Zemike Expression      159
Osmometry      30 52
Page      209
Periodic boundary      137
Phase equilibrium, U PICS      170
Phase, behavior      4 12 82 85 102 145
Phase, coexisting      16
Phase, diagram      3 18 20 24 68 70 78 148 150 76 183
Phase, equilibrium      74
Phase, glass      20
Phase, liquid-liquid      13 22
Phase, macroscopic      154
Phase, metastable      159
Phase, polymer-rich      5
Phase, rule      14
Phase, separation      17
Phase, stability      14 148
Phase, transition      105
Phase-thermodynamic stability      14
Planck constant      26
Poisson ratio      56
Polyacrylics      194
Polybutadiene      2
Polybutylacrylate      151
Polydispersity      85 184
Polyethene      50 51 52 53 94
Polyisobutylene      175
Polymer, blend      11 78 104
Polymer, chain      51
Polymer, coil      58 59 155
Polymer, concentration      72 85
Polymer, ideal mixture      61
Polymer, melt      125
Polymer, mixture      1 49 66 164
Polymer, mixtures      194
Polymer, pairs      1
Polymer, phase      63
Polymer, polydisperse      73 75
Polymer, segment      84
Polymer, solution      149 160 165 180
Polymer, structure      49
Polymerization anionic      52
Polymerization anionic, degree      50
Polymerization anionic, radical      51
Polymerization anionic, step-growth      52
Polymethylmethacrylate      40 41 42 75 178
Polypentylacrylate      151
Polyphenylene ether, Polypropylacrylate      151
polystyrene      50 51 83 94 109 155 165 178 182
Polystyrene, high impact      2
Polytetrafluoroethylene      119
Polytetrahydrofuran      161
Polyvinylchloride      75 151 194
Polyvinylmethylether      109 181
Pressure      174
Pressure, coefficient      173
Pressure, hydrostatic      6
Principle of energy conservation      5
PRISM prediction      120
PRISM Theory      116
probability distribution      55
quantum mechanics      26 132
Quenching      148 154
Random walk      53 54 56 57 63 141
Rayleigh ratio      157
Refractive index      158
1 2
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