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Rubinstein M., Colby R.H. — Polymer Physics
Rubinstein M., Colby R.H. — Polymer Physics



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Название: Polymer Physics

Авторы: Rubinstein M., Colby R.H.

Аннотация:

Polymer Physics thoroughly details the fundamental concepts of polymer melts, solutions, and gels in terms of both static structure and dynamics. It goes beyond other introductory polymer texts, deriving the essential tools of the physical polymer chemist or engineer without skipping any steps.

The book is divided into four parts. Part One summarizes the necessary concepts of a first course on polymers and covers the conformations of single polymer chains. Part Two deals with the thermodynamics of polymer solutions and melts, including chain conformations in those states. Part Three applies the concepts of Part Two to the formation and properties of polymer networks. Part Four explains the essential aspects of how polymers move in both melt and solution states.

The text assumes a working knowledge of calculus, physics, and chemistry, but no prior knowledge of polymers. It is ideal for upper-level undergraduate and first-year graduate courses in Condensed Matter Physics, Soft Materials, and Polymers.


Язык: en

Рубрика: Физика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 2003

Количество страниц: 454

Добавлена в каталог: 26.09.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Activation energy for flow      337 357
Adsorption blob      110 131
Adsorption multi-chain      187 195
Adsorption single chain      110 112 130 192
Affine deformation      256
Affine network model      256
Alexander — de Gennes brush      186 194
Arrhenius equation      337
Atactic      4
Athermal solvent      98 101 118 129
Avogadro's number      3
Balloon      297
Beer's law      45
Bending energy      330
Bethe lattice      213 215 217 220 224 409
Binary mixtures      19
Binodal      150 153 154 166 172 173
Boltzmann constant      27
Boltzmann factor      59 75 98 160 395
Boltzmann superposition principle      285 289 292 303 304
Bond percolation      203 204 213 248
Bond vector      7
Brownian dynamics      395 420
Brownian motion      309
bulk modulus      296
Cayley tree      211
Chain interaction parameter      103 118 133
Characteristic degree of polymerization      210 232 233 244
Characteristic ratio      53 57—60 90
Characteristic ratio table      53
Cluster-cluster aggregation      202
Coexistence curve      150 152 163 173 174
Cohesive energy density      144
Collagen      15
Comb polymer dynamics      380 381 414 419
Combined chain      262 299
Common tangent rule      149
complexity      248
Compression blob      107 109 131
Concentrated poor solvent      193
Concentrated solution      180
Concentration      13
Concentration fluctuations      124 161 169 174
Confinement volume      362
Confining tube      265 361 395 408 409
Confining tube semidilute solution      368
Conformation      7 51
Connectivity transition      213
Constrained-junction model      270
Constraint release      387 388—391 416 418 419
Constraint release, self-consistent      390
Continuous phase transition      215
Contour length      50
Contrast matching      189 195
Cooperative diffusion coefficient      349
Coordination number      141
Copolymer      6 40
Copolymer ABC triblock      6
Copolymer alternating      6
Copolymer block      6 200
Copolymer block, diblock      6 96 194
Copolymer block, multiblock      6
Copolymer block, triblock      6
Copolymer graft      6
Copolymer random      6
Copolymer terpolymer      6
Correlation function      78; see “Pair correlation function”
correlation length      162
Correlation length adsorption blob      188
Correlation length Alexander — de Gennes brush      186 194
Correlation length miscible blend      162 163 169
Correlation length randomly branched polymers      234—240 251 343
Correlation length semidilute solution      176—185 191 325 368 407
Correlation volume      177 183 185 280
Creep compliance      288 290 303
Critical composition      152 173 191
Critical molar mass      341 367
Critical percolation      201 227 235 239 250 251
Critical point blend      151 152 173
Critical point gelation      199 202
Critical temperature      152 166 167 169 173
Crosslinks      199
Crosslinks elastically effective      263
Crosslinks fluctuations      259
Crosslinks functionality      201 216 218 248 262
Crosslinks thermoplastic elastomer      200
Crosslinks vulcanization      201 237
Curvilinear diffusion coefficient      363
Curvilinear displacement      382
Cutoff function      223 227 230 231 233 234 251
Cyclization      133
Dangling ends      262 263
Dangling loops      262 263
de Gennes scaling theory      179
de Gennes scaling theory semidilute correlation length      179 184
de Gennes scaling theory semidilute osmotic pressure      182 185
de Gennes scaling theory semidilute size      179
de Gennes scaling theory semidilute viscosity      330
de Gennes self-similar carpet      188 195
Debye function      86 95 161
Degeneracy      206 209 220
Degree of polymerization      2
Degree of polymerization, characteristic      223
Degree of polymerization, number-average      23
Degree of polymerization, number-average at gel point      219
Deluge      202
Dendrimer      6 211 247
Density profile      187 194 195
Detailed balance      395 396 421
Diffused-constraints model      271
Diffusion coefficient      309 310
Diffusion coefficient blend      354
Diffusion coefficient constraint release      388
Diffusion coefficient curvilinear      363
Diffusion coefficient dilute solution      347
Diffusion coefficient H-polymers and combs      381
Diffusion coefficient measurement      346 360
Diffusion coefficient reptation model      364 311 404 409
Diffusion coefficient ring polymer      412
Diffusion coefficient Rouse model      311 552
Diffusion coefficient semidilute solution      328 408
Diffusion coefficient simulation      399 420
Diffusion coefficient star polymer      380 410
Diffusion coefficient Zimm model      313 352
Diffusion-controlled reaction      202
Diffusion-limited aggregation      202
Diffusive motion      309
Dilute good solvent      102
Dilute poor solvent      193
Dilute solution      13
Dilute theta solutions      172 184 193 352
Disease spreading      203
DNA      7 8 57 74 78 408
Doi fluctuation model      376 384—386 413
Doi fluctuation model parameter determination      385
Doi — Edwards equation      367
Doolittle equation      337
Double reptation      419
Duality      391
Dynamic light scattering      345 360
Dynamic structure factor      348 350
Edwards tube      265
Effective chain      94 260 260
Einstein relation      309
Electrophotographic toner      246
Elution volume      37
End-to-end distance      92
End-to-end vector      51
Energy of mixing      140—145
Engineering stress      258
Ensemble average      51
Entanglement      264—267 281 341 361—391
Entanglement concentration      369 407 408
Entanglement molar mass      266 341 362
Entanglement molar mass table      362
Entanglement strand      265 368
Entanglement trapping factor      281 301
Entropic spring constant      72
entropy      70
Entropy ideal chain      71
Entropy mixing      139 166
Entropy network deformation      256 257
Entropy, stymied      140
epoxy      199
Equilibrium swelling ratio      275 301
Equilibrium swelling ratio gels in athermal solvent      278
Equilibrium swelling ratio gels in good solvent      279
Equilibrium swelling ratio gels in theta solvent      576
Equipartition principle      319
Equivalent freely jointed chain      54
Evans — Edwards model      398 399 420
Evans — Edwards model diffusion coefficient      399
Evans — Edwards model relaxation time      399
Evans — Edwards model viscosity      401
Exchange chemical potential      159
Excluded volume      99 114 117—119 127—129 132 156 169
Extent of reaction      20 213
Fetters overlap criterion for entanglement      406
Finite extensibility      263
Fisher exponent      228 229 233 243 244 249
flexibility      49
Flory construction      255 295
Flory interaction parameter      142 144 156 166 167
Flory interaction parameter, critical      152 173
Flory interaction parameter, measuring      159—163
Flory interaction parameter, table      145
Flory theory      102
Flory theory 2-dimensional chain      127
Flory theory adsorbed linear chain      111 130
Flory theory cancellation of errors      103
Flory theory collapsed linear chain      115
Flory theory confined linear chain      109
Flory theory dendrimer      248
Flory theory polyelectrolyte      129
Flory theory randomly branched      128
Flory theory randomly branched chain      236
Flory theory swollen linear chain      102 128
Flory theory swollen randomly branched chain      249
Flory — Huggins equation      143
Flory — Huggins theory      140 145
Fluctuation-dissipation theorem      310
Forest fire      203
Form factor      82 83 95
Fox — Flory equation      34 316 350 353
Fractal      9
Fractal dimension      10 79 87 91 240
Fractal dimension critical percolation      235
Fractal dimension ideal branched      40 226 227 237
Fractal dimension ideal linear      11 40 104
Fractal dimension linear (good solvent)      40 104 114 189
Fractal dimension rod      79
Fractal dimension table      12
Fractal dynamics      344
Fractal Koch curve      10 40
Fractal Menger sponge      40
Fractal scattering      87 123
Fractal Sierpinski carpet      40
Fractal Sierpinski gasket      11
Free energy see Helmholtz free energy      71
Free volume      337 341 356 357
Freely jointed chain model      52 60
Freely rotating chain model      55 60
Friction coefficient      309 310 352
Friction coefficient constraint release      418
Friction coefficient from side chains      381
Friction coefficient monomer      312
Friction coefficient Rouse model      311
Friction coefficient short chains      340
Friction coefficient Zimm model      313
Gas constant      27
Gauche-minus rotation state      50
Gauche-plus rotation state      50
Gaussian approximation      68
Gel      15 199
Gel curve      249
Gel fraction      214 215 217 227 229 241 248—251 281
Gel permeation chromatography      36
Gel point      199 216 237 248 250
Gel point table      204
Gelatin      15 19 199
Gelation      199
Gelation chemical      199
Gelation physical      199
Ginzburg criterion      169 174 239 250
Glass      15
Glass transition temperature      15
Glass transition temperature short chains      340
Glassy modulus      336 340 364
Glassy modulus table      339
Globule      40 92 114 116 192
Globule composition      173 175 176
Good solvent      101
Guinier function      85 96
H-polymer dynamics      380 381 414
Hamaker constant      131
Hard core repulsion      99
Head-to-head isomer      4
Head-to-tail isomer      4
Helmholtz free energy      167
Helmholtz free energy blend      140 143 146 148—150 166
Helmholtz free energy chain      71 102 116 129
Helmholtz free energy confinement      108 115 130 131
Helmholtz free energy rubber      253 257 268 295
Helmholtz free energy stretching      71 73 76 106 194
Heterogeneous mixture      137
Heteropolymer      6
Hindered rotation model      59 60 90
Homogeneous mixture      137
Homopolymer      5
Hooke's Law of Elasticity      282
Huggins coefficient      34
Huggins equation      34
Hydrodynamic coupling force      314
Hydrodynamic interaction      313 314 324 326 552 555 355
Hydrodynamic radius      311 318 347
Hydrodynamic radius table      347
Hydrodynamic screening length      325 326 328 342 352
Hyperbranched      201 206 233 247
Hyperscaling      235 236 342 344 357
Ideal chain      49 51
Ideal chain asymmetry      94
Ideal mixture      140
Incipient gel      213
Incompressible      257 296
Intensity      30
Interaction parameter      see “Chain interaction parameter” “Flory
Intrinsic viscosity      34 315 316 324
Intrinsic viscosity dendrimer      353
Intrinsic viscosity measuring      35 36
Intrinsic viscosity molar mass dependence      317
Intrinsic viscosity overlap concentration      353
Intrinsic viscosity temperature dependence      318
Isotactic      4
Kinematic viscosity      335
Kinetic gelation      201
Kraemer equation      35
Kramers theorem      65 91 224
Kratky — Porod model      57
Kuhn cylindrical monomer      99
Kuhn length      54 57
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