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Pauling L., Goudsmit S. — The Structure of Line Spectra
Pauling L., Goudsmit S. — The Structure of Line Spectra

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Название: The Structure of Line Spectra

Авторы: Pauling L., Goudsmit S.

Аннотация:

The book gives the theoretical background of the principles governing the structure of line spectra, but not an account of all observed spectra, experimental data being introduced only as illustrative examples (as in Appendix III). A detailed account of the structure of spectra of different types with mention of all those known in 1927 is given in the excellent book by F. Hund, "Linienspektren und periodisches System der Elemente," J. Springer, Berlin, 1927.


Язык: en

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1930

Количество страниц: 263

Добавлена в каталог: 23.08.2009

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
$l_{i}$, selection rules for      93 137
$m_{i}$, quantum number      215
$m_{l}$, quantum number      33 75
$m_{s}$, quantum number      33 75
$\Gamma$-permanence rule      158
$\Gamma$-sum rule      158
$\Gamma$-values for configurations of equivalent electrons      159
$\Gamma$-values for more general configurations      164
(jj) coupling      108
(jj) coupling, allowed states with      257
(jj) coupling, fine structure for      125
a priori probability      77
Absorption spectra      1 48
Allowed states with (jj) coupling      257
Allowed states with Russell-Saunders coupling      153
Atomic models      11
Atomic models, potential functions      44
Auroral line, green      96
Azimuthal quantum number k      17
Balmer series of hydrogen      2
Band spectra      1
Barnett effect      238
Bismuth spectrum, hyperfine structure of      211
Bismuth spectrum, Zeeman effect of      217
Bohr correspondence principle      131
Bohr correspondence principle, frequency rule      6
Bohr correspondence principle, magneton      68
Bohr correspondence principle, orbits for hydrogen      19
Bohr correspondence principle, periodic system      147
Boltzmann factor      129
Brackett series of hydrogen      3
Calcium, level scheme for      94
Chemical valence, effect on X-ray edges      194
Chemical valence, relation to ionization potentials      167
Combination principle, Ritz      3
Correspondence principle      131
Coupling of atom core and emitting electron      111
Coupling of atom core and emitting electron, (jj)      108
Coupling of quantum vectors      104
Coupling, Russell — Saunders      107 108
Coupling, types of      104
Curie constant      230
Dirac, theory of electron      54 183
Dirac, transformation theory      10
Doublet, levels      53
Doublet, separations      58
Doublet, separations for X-ray levels      181
Doublet, separations in hydrogen      65
Doublet, separations in isoelectronic sequences      61
Doublet, separations, Lande formula for      60
Dynamical quantities, average values of      31
Eigenfunctions      25
Eigenfunctions for hydrogen-like atoms      27
Einstein transition probabilities      128
Einstein — de Haas effect      238
Einstein's coefficients of absorption and emission      129
Electron collisions, configurations of elements      145 148
Electron collisions, distribution function      30
Electron collisions, distribution function for alkali ions      36
Electron collisions, shells      145
Electron collisions, shells, completed, symmetry of      30
Electron collisions, shells, idealization of      37
Electron collisions, spinning      53
Electron collisions, spinning, Dirac theory of      54 183
Electron collisions, verification of term values by      51
Electrons, equivalent, allowed states for      153 257
Electrons, equivalent, allowed states for, $\Gamma$-values for      159
Exclusion principle      144
Exclusion principle, states allowed by      153 257
External screening      180
External screening, quantitative discussion of      187
f, hyperfine quantum number      204
f, selection rules for      205
Fine structure of alkali-like atoms      53
Fine structure of hydrogen and ionized helium      63
Fine-structure constant, Sommerfeld      58
Fine-structure separations, equations for doublets      58 60
Fine-structure separations, equations for many-electron atoms      124 157
Fine-structure separations, equations for triplets      97
Frequency rule, Bohr      6
g-factor of Lande      67 112
g-factor of Lande, tables of      71 115
g-permanence rule      120
g-sum rule      117 124
Heisenberg — Dirac resonance phenomenon      88
Heisenberg, quantum mechanics      8
Heisenberg, uncertainty principle      10
Helium and ionized lithium, spectra of      102
Helium, ionized, fine structure of      63
Hydrogen atom, in quantum mechanics      25
Hydrogen atom, quantum theory of      13
Hydrogen-like atoms, eigenfunctions for      27
Hydrogen-like atoms, fine structure of      63
Hydrogen-like atoms, orbits in      19
Hydrogen-like atoms, quantization of      13
Hydrogen-like atoms, Stark effect of      79 83
Hydrogen-like atoms, stationary states of      13
Hydrogen-like eigenfunctions      27
Hyperfine quantum number f      204
Hyperfine structure, of bismuth spectrum      211
Hyperfine structure, of bismuth spectrum, Zeeman effect of      217
Hyperfine structure, possible explanations of      202
Hyperfine structure, separation formulas for      208
Hyperfine structure, Zeeman effect of      217
i, nuclear spin quantum number      203
Intensity formulas, for multiplets      137
Intensity formulas, for Zeeman effect      142
Intensity of spectral lines      128
Interval rule      124
Inverted terms      161 163
Ion formation and ionization potentials      167
Ionization potentials      51
Ionization potentials and ion formation      167
Ionization potentials, table of      168
Iron, spectrum of      246
Irregular X-ray doublets      178
J, total angular momentum quantum number      55
j, total angular momentum quantum number, selection rules for      56 93 136
k, azimuthal quantum number      17
L, quantum number      27 33
l, quantum number, selection rules for      49 93 134 136
Lande doublet formula      60
Lande doublet formula, g-factor      67 112
Lande doublet formula, g-factor, 67, 112, tables of      71 115
Lande doublet formula, interval rule      125
Laporte rule      94
Lithium, ionized, spectrum of      102
Lorentz unit      70
Lyman series of hydrogen      3
m, magnetic quantum number      33 69
m, magnetic quantum number, selection and polarization rules for      71 135
Magnetic moments, from Stern-Gerlaeh experiment      226
Magnetic moments, of iron-group ions      234
Magnetic moments, of rare earth ions      232
Magnetic nucleus, interaction with extra-nuclear electrons      204
Magnetic quantum number m      33 69
Magneto-mechanical effects      238
Magneton, Bohr      68
Matrix mechanics      8
Metastable states      94
Model, atomic      11 37
Model, interpretation of stationary states in terms of      29
Model, vector for alkali-like atoms      67
Model, vector for many-electron atoms      108
Model, vector for two-electron atoms      87
Model, vector, description of      32
Moseley diagrams      175 184
Muitiplets      108
Muitiplets, intensity formulas for      137
Multiplet, separations for equivalent electrons      162
Multiplet, separations for general configurations      164
Multiplet, separations, magnitudes of      157
Multiplet, structure in X-ray spectra      192
n', radial quantum number      17
n, principal quantum number      17
Nebular lines, origin of      96
Neon, intensities in      142
Neon, spectrum of      252
Normal states of atoms and ions      148 166
Nuclear moments      221
Nuclear spin quantum number i      203
Nucleus, motion of, in hydrogen-like atoms      20
Optical, spectra, application of X-ray laws to      196
Optical, transition from X-ray spectra to      199
Orbits, Bohr      19
Orbits, non-penetrating      35
Orbits, non-penetrating, term values for      45
Orbits, penetrating      35
Orbits, penetrating, term values for      40
Paramagnetic susceptibilities      229
Paramagnetic susceptibilities of iron-group ions      234
Paramagnetic susceptibilities of rare-earth ions      232
Paramagnetism      229
Paschen series of hydrogen      3
Paschen — Back effect      73
Paschen — Back effect for many-electron atoms      118
Pauli exclusion principle      144
Pauli exclusion principle, states allowed by      153 257
Periodic system of elements      146
Polarizability of atoms and second-order Stark-effect      84
Polarization of atom core      45
Polarization of resonance radiation in a magnetic field      239
Polarization, rules for Zeeman efect      71 133
Potential functions, atomic      44
Principal quantum number n      17
Quantum, mechanics, development of      8
Quantum, theory      7
Quantum, weight      77
Radial quantun mber n'      17
Regular X-ray doublet      178
Relativistic, energy correction      64
Relativistic, X-ray doublets      178
Resonance, energy      87
Resonance, lines      50
Resonance, phenomenon      88
Resonance, potentials      51
Resonance, radiation, polarization in a magnetic field      239
Ritz combination principle      3
Ritz combination principle, term formula      39
Russell — Saunders coupling of quantum vectors      108
Russell — Saunders coupling, allowed states with      153
Rydberg, constant R      21
Rydberg, term formula      39
s, spin quantum number      53
s, spin quantum number, selection rules for      136
Schroedinger wave mechanics      9
Screening constants for main energy term      180
Screening constants for optical doublets      61
Screening constants for optical triplets      101
Screening constants for size of orbits      188
Screening constants for X-ray spin doublets      181
Screening Doublets, X-ray      185
Selection rules for alkali-like atoms      49 133
Selection rules for f      205
Selection rules for j      56 93 136
Selection rules for many-electron atoms      93 136
Selection rules for s      136
Selection rules for Zeeman effect      71 135
Separation formulas for hyperfine structure      208
Series of spectral lines      2 48
Series, Balmer      2
Series, Brackett      3
Series, Lyman      3
Series, Paschen      3
Series, term      39
Series, term, limits of      95 253
Sodium D-lines, Paschen — Back effect of      76
Sodium D-lines, Zeeman effect of      72
Sommerfeld, fine-structure constant      58
Sommerfeld, theory of X-ray fine structure      181
Spatial quantization of alkali-like atoms      70
Spatial quantization of hydrogen atom      20
Spectra, absorption      1 48
Spectra, band      1
Spectra, representative      246
Spectral lines, intensity of      128
Spectral terms, relative positions of      165
Spin doublets, X-ray      181
Spinning electron      53
Spinning electron, Dirac theory of      54 183
Stark effect      78
Stark effect for non-hydrogen-like atoms      85
Stark effect, first-order, hydrogen and ionized helium      79
Stark effect, second-order      83
Stationary states      6
Stationary states, properties and interpretation in terms of model      29
Stern — Gerlaeh experiment      226
Subgroups      174
Summation rules for intensities      137 142
Term diagrams      49
Term diagrams for calcium      95
Term diagrams for iron      246
Term diagrams for neon      253
Term diagrams for sodium      49 57
Term series and term values      39
Term symbols for alkali-like atoms      56
Term symbols for many-electron atoms      91
Term values, verification by electron collisions      51
Terms and energy levels      7
Terms, relative position of      165
Total angular momentum of atom      54
Transformation theory      10
Transition probabilities, Einstein      128
Triplet separations, equations for      97
Two-electron transition      137
Uncertainty principle      10
Valence, chemical, effect of on X-ray edges      194
Valence, chemical, relation to ionization potentials      167
Vector model for alkali-like atoms      67
Vector model for many-electron atoms      108
Vector model for two-electron atoms      87
Vector model, description of      32
Wave equation, solution of, for hydrogen atom      25
Wave mechanics      9
X-ray absorption edges      171
X-ray absorption edges, structure of      193
X-ray laws, application to optical spectra      196
X-ray levels      172
X-ray line spectra      178
X-ray screening doublets      185
X-ray spectra      170
X-ray spectra and optical spectra, relation of      199
X-ray spectra of higher rank      194
X-ray spectra, comparison with alkali-like and hydrogen-like spectra      191
X-ray spectra, multiplet structure in      192
X-ray spectroscopy      171
X-ray spin doublets      181
X-ray term values      176
X-ray term values, interpretation of      180
Zeeman effect for manv-electron atoms      112
Zeeman effect of alkali-like spectra      67
Zeeman effect of hyperfine structure      215
Zeeman effect, intensity formulas for      142
Zeeman effect, normal and anomalous      69
Zeeman effect, transition between weak and strong fields      77 119
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